CN103666113B - A kind of UV solidifies jetted ink and preparation method thereof - Google Patents

A kind of UV solidifies jetted ink and preparation method thereof Download PDF

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Publication number
CN103666113B
CN103666113B CN201310618739.4A CN201310618739A CN103666113B CN 103666113 B CN103666113 B CN 103666113B CN 201310618739 A CN201310618739 A CN 201310618739A CN 103666113 B CN103666113 B CN 103666113B
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China
Prior art keywords
ink
trimethylolpropane triacrylate
solidifies
auxiliary agent
minute
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Expired - Fee Related
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CN201310618739.4A
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Chinese (zh)
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CN103666113A (en
Inventor
王鹏
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Dandong Qunli Environmental Protection Color Printing Packaging Co., Ltd.
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Dandong Qunli Environmental Protection Color Printing Packaging Co Ltd
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Priority to CN201310618739.4A priority Critical patent/CN103666113B/en
Publication of CN103666113A publication Critical patent/CN103666113A/en
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Publication of CN103666113B publication Critical patent/CN103666113B/en
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Abstract

The invention discloses a kind of UV and solidify jetted ink, it is characterized in that, raw material by following weight portion is made: organic pigment 1-3,1,6-hexanediyl ester 12-16, hydroxy-ethyl acrylate 6-9, calcined gypsum 1-2, alumen 1-2, urethane acrylate 25-30, trimethylolpropane triacrylate 14-17, tri (propylene glycol) diacrylate 10-12, esterase 3-4, turpentine oil 1-2,2959 light trigger 5-9, bisphenol-A 1-2, auxiliary agent 4-5; Auxiliary agent of the present invention has improved the toughness of ink, makes distributes ink even, and has maintained the stability of ink; After ink spraying of the present invention, solidify rapidly, do not need and heat, save energy consumption, and adhesive force excellence, the mechanical strength of paint film is relatively good.

Description

A kind of UV solidifies jetted ink and preparation method thereof
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of UV solidifies jetted ink and preparation method thereof.
Background technology
The development of jetted ink has also illustrated the development of ink-jet printing technology to a certain extent, because ink has not only determined the quality of ink jet image, has also determined the shape of ink droplet and the reliability of print system. Jetted ink is generally made up of colorant, link stuff and additive. Ink vehicle can be water, oily matter, solvent, resin etc., and it has determined the dynamic attribute that ink distributes; In jetted ink, link stuff accounts for 40%-90%. Colorant mainly plays a part colour developing in ink, generally accounts for 1%-10%. Remaining part is referred to as additive, is mainly used to improve viscosity, adhesive strength, heat endurance, light resistance and the surface tension etc. of ink. UV cured printing ink is adapted at printing on various soft and rigid printable fabrics, and as corrugated board and metal forming, UV ink curing rate under the effect of UV light is very fast, and durability is stronger. Be applicable to very much in DOD application, as retail point display advertisement, phonecard, credit card and the frequent purchase card using.
Summary of the invention
The object of this invention is to provide a kind of UV and solidify jetted ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of UV solidifies jetted ink, raw material by following weight portion is made: organic pigment 1-3,1,6-hexanediyl ester 12-16, hydroxy-ethyl acrylate 6-9, calcined gypsum 1-2, alumen 1-2, urethane acrylate 25-30, trimethylolpropane triacrylate 14-17, tri (propylene glycol) diacrylate 10-12, esterase 3-4, turpentine oil 1-2,2959 light trigger 5-9, bisphenol-A 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, crosslinking agent TAC2-3, polyisobutene 2-3, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 2-3, benzoic acid amine 1-2, trimethylolpropane triacrylate 10-12, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
UV of the present invention solidifies jetted ink, made by following concrete steps: first add organic pigment, 1,6-hexanediyl ester, hydroxy-ethyl acrylate, calcined gypsum, alumen, urethane acrylate, trimethylolpropane triacrylate stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; After ink spraying of the present invention, solidify rapidly, do not need and heat, save energy consumption, and adhesive force excellence, the mechanical strength of paint film is relatively good.
Specific embodiments
Below by instantiation, the present invention is described in detail.
A kind of UV solidifies jetted ink, by following weight portion (kilogram) raw material make: organic pigment 1,1,6-hexanediyl ester 12, hydroxy-ethyl acrylate 6, calcined gypsum 1, alumen 1, urethane acrylate 25, trimethylolpropane triacrylate 14, tri (propylene glycol) diacrylate 10, esterase 3, turpentine oil 1,2959 light triggers 5, bisphenol-A 1, auxiliary agent 4;
Described auxiliary agent by following weight portion (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, crosslinking agent TAC2, polyisobutene 2, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 2, benzoic acid amine 1, trimethylolpropane triacrylate 10, n-propyl gallate 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
UV of the present invention solidifies jetted ink, made by following concrete steps: first add organic pigment, 1,6-hexanediyl ester, hydroxy-ethyl acrylate, calcined gypsum, alumen, urethane acrylate, trimethylolpropane triacrylate stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.

Claims (2)

1. a UV solidifies jetted ink, it is characterized in that, raw material by following weight portion is made: organic pigment 1-3,1,6-hexanediyl ester 12-16, hydroxy-ethyl acrylate 6-9, calcined gypsum 1-2, alumen 1-2, urethane acrylate 25-30, trimethylolpropane triacrylate 14-17, tri (propylene glycol) diacrylate 10-12, esterase 3-4, turpentine oil 1-2,2959 light trigger 5-9, bisphenol-A 1-2, auxiliary agent 4-5; Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, crosslinking agent TAC2-3, polyisobutene 2-3, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 2-3, benzoic acid amine 1-2, trimethylolpropane triacrylate 10-12, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. UV solidifies jetted ink according to claim 1, it is characterized in that, made by following concrete steps: first add organic pigment, 1,6-hexanediyl ester, hydroxy-ethyl acrylate, calcined gypsum, alumen, urethane acrylate, trimethylolpropane triacrylate stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
CN201310618739.4A 2013-11-29 2013-11-29 A kind of UV solidifies jetted ink and preparation method thereof Expired - Fee Related CN103666113B (en)

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CN103666113B true CN103666113B (en) 2016-05-18

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101925061B1 (en) 2015-09-21 2018-12-04 주식회사 엘지화학 Uv-curable ink composition for inkjetting having a superior infrared ray transmittance

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3558387A (en) * 1966-06-10 1971-01-26 Sun Chemical Corp Radiation-curable compositions
CN101283060A (en) * 2005-09-30 2008-10-08 齐尼亚科技有限公司 Inkjet printing
CN102876132A (en) * 2012-10-11 2013-01-16 江苏科技大学 Ultraviolet-cured ink-jet ink composition and preparation method thereof
CN102925001A (en) * 2012-11-20 2013-02-13 天津傲彩科技有限公司 Flexible ultraviolet-curing ink-jet ink and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3558387A (en) * 1966-06-10 1971-01-26 Sun Chemical Corp Radiation-curable compositions
CN101283060A (en) * 2005-09-30 2008-10-08 齐尼亚科技有限公司 Inkjet printing
CN102876132A (en) * 2012-10-11 2013-01-16 江苏科技大学 Ultraviolet-cured ink-jet ink composition and preparation method thereof
CN102925001A (en) * 2012-11-20 2013-02-13 天津傲彩科技有限公司 Flexible ultraviolet-curing ink-jet ink and preparation method thereof

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Inventor after: Wang Peng

Inventor before: Dong Liangqing

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Effective date of registration: 20160414

Address after: 118000 A-013, environmental protection industrial park, Liaoning, Dandong

Applicant after: Dandong Qunli Environmental Protection Color Printing Packaging Co., Ltd.

Address before: South Taibai town 243161 Anhui city of Ma'anshan province Dangtu County Xintai white road

Applicant before: Dangtu County Ke Hui commerce and trade Co., Ltd

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160518

Termination date: 20161129

CF01 Termination of patent right due to non-payment of annual fee