CN103666078B - A kind of inkjet printer UV curable ink and preparation method thereof - Google Patents
A kind of inkjet printer UV curable ink and preparation method thereof Download PDFInfo
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- CN103666078B CN103666078B CN201310619066.4A CN201310619066A CN103666078B CN 103666078 B CN103666078 B CN 103666078B CN 201310619066 A CN201310619066 A CN 201310619066A CN 103666078 B CN103666078 B CN 103666078B
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- ink
- diacrylate
- inkjet printer
- diatomite
- auxiliary agent
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- -1 alkenyl imidazoline Chemical compound 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims abstract description 7
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 7
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000012467 final product Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- KWIPUXXIFQQMKN-UHFFFAOYSA-N 2-azaniumyl-3-(4-cyanophenyl)propanoate Chemical compound OC(=O)C(N)CC1=CC=C(C#N)C=C1 KWIPUXXIFQQMKN-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 229940090948 ammonium benzoate Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000002904 solvent Substances 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000002932 luster Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a kind of inkjet printer UV curable ink, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-2, tetrafluoroethylene 2-3, diatomite 1-2,2-ethylamino 17 alkenyl imidazoline 1-2, E-12 epoxy resin 30-34,1.6 glycol diacrylate 7-10, m-xylene diamine 4-6, tri (propylene glycol) diacrylate 12-16, polyester acrylate 8-10, polyether acrylate 12-15, sec.-propyl distearyl acyloxy Aluminate 1-2, ethyl propenoate 8-10,2959 light trigger 5-9, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even; Ink non-volatility solvent of the present invention, environmental pollution is little, energy consumption is few, print that good, the solidification rate of fluency is fast, pattern bright color, to print ground range of applicability wide, and preparation technology is simple.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of inkjet printer UV curable ink and preparation method thereof.
Background technology
Large inkjet printer ink, according to the difference of its main ingredient, can be divided into three major types: water color ink, solvent type ink and UV curable ink.Water color ink cost is low, not pollution, bright in luster, but because the picture of water color ink air brushing is not easily dry and easily by Absorption of Medium, it requires that painting medium has special coating, be mainly used on paper and various fiber-like (cloth) ground, cated painting medium.And the solvent in solvent type ink generally directly can merge with ground, do not require that medium is covered with coating, and its evaporation rate is fast, meets the requirement of flying print.But the maximum problem of solvent type ink is exactly friendly not to environment, because volatilizable organic content is high in ink, is certain in the long run be subject to many limitations gradually.
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can different-energy be produced, the monomer polymerization in different ink vehicle is become polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, solvent resistant, wear resisting property is good.In UV ink, light trigger is that one is subject to light activated compound, after absorb light is shone, be excited into free radical, and energy trasfer, to photosensitivity molecule or photocrosslinking agent, makes UV ink that photocuring reaction occur.Current UV ink has become a kind of more ripe ink technology, and its pollutant emission is almost nil.Except not containing solvent, UV ink also just like not easily scumming, the advantages such as site is clear, the bright-coloured light of mass colour, and chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide a kind of inkjet printer UV curable ink and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of inkjet printer UV curable ink, is made up of the raw material of following weight part: pigment dyestuff 1-2, tetrafluoroethylene 2-3, diatomite 1-2,2-ethylamino 17 alkenyl imidazoline 1-2, E-12 epoxy resin 30-34,1.6 glycol diacrylate 7-10, m-xylene diamine 4-6, tri (propylene glycol) diacrylate 12-16, polyester acrylate 8-10, polyether acrylate 12-15, sec.-propyl distearyl acyloxy Aluminate 1-2, ethyl propenoate 8-10,2959 light trigger 5-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, Ammonium benzoate 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Inkjet printer UV curable ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, tetrafluoroethylene, diatomite, 2-ethylamino 17 alkenyl imidazoline, E-12 epoxy resin, 1.6 glycol diacrylates, m-xylene diamine, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2959 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2959 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even; Ink non-volatility solvent of the present invention, environmental pollution is little, energy consumption is few, print that good, the solidification rate of fluency is fast, pattern bright color, to print ground range of applicability wide, and preparation technology is simple.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of inkjet printer UV curable ink, is made up of the raw material of following weight part (kilogram): pigment dyestuff 1, tetrafluoroethylene 2, diatomite 1,2-ethylamino 17 alkenyl imidazoline 1, E-12 epoxy resin 30,1.6 glycol diacrylate 7, m-xylene diamine 4, tri (propylene glycol) diacrylate 12, polyester acrylate 8, polyether acrylate 12, sec.-propyl distearyl acyloxy Aluminate 1, ethyl propenoate 8,2959 light trigger 5, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, linking agent TAC2, polyisobutene 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, Ammonium benzoate 1, Viscoat 295 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Inkjet printer UV curable ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, tetrafluoroethylene, diatomite, 2-ethylamino 17 alkenyl imidazoline, E-12 epoxy resin, 1.6 glycol diacrylates, m-xylene diamine, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2959 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2959 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. an inkjet printer UV curable ink, it is characterized in that, be prepared from by the raw material of following weight part: pigment dyestuff 1-2, tetrafluoroethylene 2-3, diatomite 1-2,2-ethylamino 17 alkenyl imidazoline 1-2, E-12 epoxy resin 30-34,1.6 glycol diacrylate 7-10, m-xylene diamine 4-6, tri (propylene glycol) diacrylate 12-16, polyester acrylate 8-10, polyether acrylate 12-15, sec.-propyl distearyl acyloxy Aluminate 1-2, ethyl propenoate 8-10,2959 light trigger 5-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, Ammonium benzoate 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. inkjet printer UV curable ink according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, tetrafluoroethylene, diatomite, 2-ethylamino 17 alkenyl imidazoline, E-12 epoxy resin, 1.6 glycol diacrylates, m-xylene diamine, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2959 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2959 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310619066.4A CN103666078B (en) | 2013-11-29 | 2013-11-29 | A kind of inkjet printer UV curable ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310619066.4A CN103666078B (en) | 2013-11-29 | 2013-11-29 | A kind of inkjet printer UV curable ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666078A CN103666078A (en) | 2014-03-26 |
| CN103666078B true CN103666078B (en) | 2016-04-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310619066.4A Active CN103666078B (en) | 2013-11-29 | 2013-11-29 | A kind of inkjet printer UV curable ink and preparation method thereof |
Country Status (1)
| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310619066.4A patent/CN103666078B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103666078A (en) | 2014-03-26 |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB02 | Change of applicant information |
Inventor after: Wei Renshan Inventor after: Yi Bin Inventor before: Dong Liangqing |
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| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161215 Address after: Baoan District Shiyan street of Shenzhen city in Guangdong Province on the 518000 Avenue house Tian Industrial Zone tenth Patentee after: Shenzhen Haizhonghui Ink Products Co.,Ltd. Address before: South Taibai town 243161 Anhui city of Ma'anshan province Dangtu County Xintai white road Patentee before: DANGTU KEHUI TRADE Co.,Ltd. |
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| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 518000 Hangwei Avenue, Shangwu Community, Shiyan Street, Baoan District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Haizhonghui New Material Technology Co.,Ltd. Address before: 518000 Tianxin Industrial Zone, Shangwu Avenue, Shiyan Street, Baoan District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Haizhonghui Ink Products Co.,Ltd. |
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Effective date of registration: 20230518 Address after: 511500 No. 15 Xiongxing Industrial Avenue, Yinzhan Community, Longtang Town, Qingcheng District, Qingyuan City, Guangdong Province Patentee after: Guangdong Haihui New Material Technology Co.,Ltd. Address before: 518000 Hangwei Avenue, Shangwu Community, Shiyan Street, Baoan District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Haizhonghui New Material Technology Co.,Ltd. |