CN103666034B - UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof - Google Patents

UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof Download PDF

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Publication number
CN103666034B
CN103666034B CN201310593201.2A CN201310593201A CN103666034B CN 103666034 B CN103666034 B CN 103666034B CN 201310593201 A CN201310593201 A CN 201310593201A CN 103666034 B CN103666034 B CN 103666034B
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viscosity
ink
atbc
printing ink
cyclohexyl
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CN103666034A (en
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万红霞
陈可亮
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Dongguan Haocai Ink Technology Co ltd
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Tongling Founder Plastics Technology Co Ltd
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Abstract

The invention discloses the UV cured printing ink of the little good luster of a kind of viscosity, it is characterized in that, made by the raw material of following weight portion: organic pigment 2-3, dimethicone 3-5, ATBC 3-4, kaolin 1-2, iron chloride 1-2, double pentaerythritol methacrylate 12-14, silane coupler KH560? 1-2, urethane acrylate 16-19, ethylene bis stearamide 1.3-1.5, ATBC 13-16,1-hydroxyl-cyclohexyl-phenyl ketone (184) 6-9, ethylene glycol bis glycidol ether 1-2, auxiliary agent 4-5; Auxiliary agent of the present invention has improved the toughness of ink, makes distributes ink even, and has maintained the stability of ink; Viscosity of the present invention is little, and all has good adhesive force between each stock, has good pliability and wear-resisting scratch resistance intensity, and glossiness is good, energy-conserving and environment-protective.

Description

UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under ultraviolet ray is irradiated, utilizes the ultraviolet light of different wave length and energy to make ink film forming and dry ink. Utilize different ultraviolet spectras, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymer, so the look film of UV ink has good machinery and chemical property. The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, anti-wear performance is good. In UV ink, light trigger is that one is subject to light activated compound, after absorption illumination, is excited into free radical, and energy is transferred to photonasty molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur. UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil. Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, chemical-resistance excellence, the advantage such as low-consuming.
Summary of the invention
The object of this invention is to provide UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A UV cured printing ink for the little good luster of viscosity, is made up of the raw material of following weight portion: organic pigment 2-3, dimethicone 3-5, ATBC 3-4, kaolin 1-2, iron chloride 1-2, double pentaerythritol methacrylate 12-14, silane coupler KH5601-2, urethane acrylate 16-19, ethylene bis stearamide 1.3-1.5, ATBC 13-16,1-hydroxyl-cyclohexyl-phenyl ketone (184) 6-9, ethylene glycol bis glycidol ether 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 2-3, crosslinking agent TAC2-3, polyisobutene 2-3, hydroquinones 1-2, trimethylolpropane triacrylate 10-12, acrylic acid dimethylamino ethyl ester 2-3, phenyl glycidyl ether 1-2, cobalt naphthenate 2-3, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV cured printing ink of the little good luster of viscosity of the present invention, made by following concrete steps: first add organic pigment, dimethicone, ATBC, kaolin, iron chloride, double pentaerythritol methacrylate, silane coupler KH560 to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 1-hydroxyl-cyclohexyl-phenyl ketone (184), stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxyl-cyclohexyl-phenyl ketone (184), stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Viscosity of the present invention is little, and all has good adhesive force between each stock, has good pliability and wear-resisting scratch resistance intensity, and glossiness is good, energy-conserving and environment-protective.
Specific embodiments
Below by instantiation, the present invention is described in detail.
A UV cured printing ink for the little good luster of viscosity, by following weight portion (kilogram) raw material make: organic pigment 2, dimethicone 3, ATBC 3, kaolin 1, iron chloride 1, double pentaerythritol methacrylate 12, silane coupler KH5601, urethane acrylate 16, ethylene bis stearamide 1.3, ATBC 13,1-hydroxyl-cyclohexyl-phenyl ketone (184) 6, ethylene glycol bis glycidol ether 1, auxiliary agent 4;
Described auxiliary agent by following weight portion (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 2, crosslinking agent TAC2, polyisobutene 2, hydroquinones 1, trimethylolpropane triacrylate 10, acrylic acid dimethylamino ethyl ester 2, phenyl glycidyl ether 1, cobalt naphthenate 2, n-propyl gallate 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV cured printing ink of the little good luster of viscosity of the present invention, made by following concrete steps: first add organic pigment, dimethicone, ATBC, kaolin, iron chloride, double pentaerythritol methacrylate, silane coupler KH560 to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 1-hydroxyl-cyclohexyl-phenyl ketone (184), stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxyl-cyclohexyl-phenyl ketone (184), stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.

Claims (2)

1. the UV cured printing ink of the little good luster of viscosity, it is characterized in that, be prepared from by the raw material of following weight portion: organic pigment 2-3, dimethicone 3-5, ATBC 3-4, kaolin 1-2, iron chloride 1-2, double pentaerythritol methacrylate 12-14, silane coupler KH5601-2, urethane acrylate 16-19, ethylene bis stearamide 1.3-1.5, ATBC 13-16,1-hydroxyl-cyclohexyl-phenyl ketone 6-9, ethylene glycol bis glycidol ether 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 2-3, crosslinking agent TAC2-3, polyisobutene 2-3, hydroquinones 1-2, trimethylolpropane triacrylate 10-12, acrylic acid dimethylamino ethyl ester 2-3, phenyl glycidyl ether 1-2, cobalt naphthenate 2-3, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. the UV cured printing ink of the little good luster of viscosity according to claim 1, it is characterized in that, made by following concrete steps: first add organic pigment, dimethicone, ATBC, kaolin, iron chloride, double pentaerythritol methacrylate, silane coupler KH560 to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 1-hydroxyl-cyclohexyl-phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxyl-cyclohexyl-phenyl ketone, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
CN201310593201.2A 2013-11-23 2013-11-23 UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof Active CN103666034B (en)

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US11624000B2 (en) 2017-05-23 2023-04-11 Alpha Assembly Solutions Inc. Graphene enhanced and engineered materials for membrane touch switch and other flexible electronic structures
CN108329750A (en) * 2018-01-08 2018-07-27 天长市嘉瑞包装材料有限公司 A kind of environment-friendly ink of medical respiration bag printing

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709181A (en) * 2009-12-03 2010-05-19 上海英威喷墨科技有限公司 UV curable ink for large inkjet printer and preparation method thereof
CN102220062A (en) * 2011-05-13 2011-10-19 武汉大学 Aqueous UV curing coating and preparation method thereof
CN102241920A (en) * 2011-08-15 2011-11-16 江苏海田技术有限公司 Ultraviolet (UV) transfer ink
CN102286230A (en) * 2011-09-15 2011-12-21 哈尔滨大东方卷烟材料科技开发有限责任公司 Ultraviolet curable ink and preparation method thereof
CN102417759A (en) * 2011-11-01 2012-04-18 高邮市卫星卷烟材料有限公司 Nano high-glaze tipping paper UV (Ultraviolet) ink
CN102585573A (en) * 2011-12-23 2012-07-18 上海奇想青晨新材料科技股份有限公司 Ultraviolet (UV) gloss oil and preparation method thereof
CN102702848A (en) * 2012-06-05 2012-10-03 无锡金桥精细油墨有限公司 Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709181A (en) * 2009-12-03 2010-05-19 上海英威喷墨科技有限公司 UV curable ink for large inkjet printer and preparation method thereof
CN102220062A (en) * 2011-05-13 2011-10-19 武汉大学 Aqueous UV curing coating and preparation method thereof
CN102241920A (en) * 2011-08-15 2011-11-16 江苏海田技术有限公司 Ultraviolet (UV) transfer ink
CN102286230A (en) * 2011-09-15 2011-12-21 哈尔滨大东方卷烟材料科技开发有限责任公司 Ultraviolet curable ink and preparation method thereof
CN102417759A (en) * 2011-11-01 2012-04-18 高邮市卫星卷烟材料有限公司 Nano high-glaze tipping paper UV (Ultraviolet) ink
CN102585573A (en) * 2011-12-23 2012-07-18 上海奇想青晨新材料科技股份有限公司 Ultraviolet (UV) gloss oil and preparation method thereof
CN102702848A (en) * 2012-06-05 2012-10-03 无锡金桥精细油墨有限公司 Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof

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Denomination of invention: A UV curable ink with low viscosity and good gloss and its preparation method

Effective date of registration: 20231113

Granted publication date: 20160504

Pledgee: Shanghai Yudi Aviation Supplies Co.,Ltd.

Pledgor: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd.

Registration number: Y2023980065339

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Date of cancellation: 20231219

Granted publication date: 20160504

Pledgee: Shanghai Yudi Aviation Supplies Co.,Ltd.

Pledgor: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd.

Registration number: Y2023980065339

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Effective date of registration: 20240103

Address after: Room 101, No. 165 Qiaoli Nanmen Road, Changping Town, Dongguan City, Guangdong Province, 523575

Patentee after: DONGGUAN HAOCAI INK TECHNOLOGY CO.,LTD.

Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province

Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd.