CN103666041B - A kind of UV curable ink and preparation method thereof - Google Patents
A kind of UV curable ink and preparation method thereof Download PDFInfo
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- CN103666041B CN103666041B CN201310600481.5A CN201310600481A CN103666041B CN 103666041 B CN103666041 B CN 103666041B CN 201310600481 A CN201310600481 A CN 201310600481A CN 103666041 B CN103666041 B CN 103666041B
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- ink
- curable ink
- light trigger
- auxiliary agent
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- 238000002360 preparation method Methods 0.000 title claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 229910000077 silane Inorganic materials 0.000 claims abstract description 7
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 7
- 239000013638 trimer Substances 0.000 claims abstract description 7
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims abstract description 4
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 4
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 4
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 4
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 10
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 235000010388 propyl gallate Nutrition 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000000016 photochemical curing Methods 0.000 abstract description 3
- 239000012298 atmosphere Substances 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 25
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- -1 ion free radical Chemical class 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of UV curable ink, it is characterized in that, raw material by following weight portion is made: pigment 4-5, UV pure acrylic resin 40-45, trimethylolpropane triacrylate 10-15, ethyl acetate 5-8, methyl methacrylate 12-15, zirconium-n-propylate 3-4, sodium phosphate trimer 5-6, nickel nitrate 1-2, Arabic gum 1-2, butyl acrylate 3-4, dipentaerythritol acrylate 6-9, antioxidant 1035? 2-3, triethyl citrate 3-4, captax 1-2, silane resin acceptor kh-550? 2-3, auxiliary agent 4-5, light trigger 184? 6-12, auxiliary agent of the present invention has improved the toughness of ink, makes distributes ink even, and has maintained the stability of ink, the UV curable ink photocuring time of the present invention is short, does not need heating, saves energy resource consumption, pollution-free to atmosphere, high comprehensive performance.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of UV curable ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under ultraviolet ray is irradiated, utilizes the ultraviolet light of different wave length and energy to make ink film forming and dry ink. The curing mechanism of UV curable ink is, the light trigger in system directly or indirectly absorbs after ultraviolet luminous energy, from ground state transition to excited singlet, alters and jump to excited triplet state between being; After excited singlet or triplet state experience unimolecule or bimolecular chemical action, the biologically active fragment that generation can trigger monomer polymerization, these fragments can be free radical, cation, anion or ion free radical. Utilize different ultraviolet spectras, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymer, so the look film of UV ink has good machinery and chemical property. The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, anti-wear performance is good. In UV ink, light trigger is that one is subject to light activated compound, after absorption illumination, is excited into free radical, and energy is transferred to photonasty molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur. UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil. Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, chemical-resistance excellence, the advantage such as low-consuming.
Summary of the invention
The object of this invention is to provide a kind of UV curable ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of UV curable ink, is made up of the raw material of following weight portion: pigment 4-5, UV pure acrylic resin 40-45, trimethylolpropane triacrylate 10-15, ethyl acetate 5-8, methyl methacrylate 12-15, zirconium-n-propylate 3-4, sodium phosphate trimer 5-6, nickel nitrate 1-2, Arabic gum 1-2, butyl acrylate 3-4, dipentaerythritol acrylate 6-9, antioxidant 10352-3, triethyl citrate 3-4, captax 1-2, silane resin acceptor kh-550 2-3, auxiliary agent 4-5, light trigger 1846-12;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, antioxidant 10351-2, crosslinking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
UV curable ink of the present invention, made by following concrete steps:
First add pigment, UV pure acrylic resin, trimethylolpropane triacrylate, ethyl acetate, methyl methacrylate, zirconium-n-propylate, sodium phosphate trimer to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except light trigger 184, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add light trigger 184, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
Beneficial effect of the present invention: auxiliary agent of the present invention has improved the toughness of ink, makes distributes ink even, and has maintained the stability of ink; The UV curable ink photocuring time of the present invention is short, does not need heating, saves energy resource consumption, pollution-free to atmosphere, high comprehensive performance.
Specific embodiments
Below by instantiation, the present invention is described in detail.
A kind of UV curable ink, by following weight portion (kilogram) raw material make: pigment 4, UV pure acrylic resin 40, trimethylolpropane triacrylate 10, ethyl acetate 5, methyl methacrylate 12, zirconium-n-propylate 3, sodium phosphate trimer 5, nickel nitrate 1, Arabic gum 1, butyl acrylate 3, dipentaerythritol acrylate 6, antioxidant 10352, triethyl citrate 3, captax 1, silane resin acceptor kh-550 2, auxiliary agent 4, light trigger 1846;
Described auxiliary agent by following weight portion (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, antioxidant 10351, crosslinking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, n-propyl gallate 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
UV curable ink of the present invention, made by following concrete steps:
First add pigment, UV pure acrylic resin, trimethylolpropane triacrylate, ethyl acetate, methyl methacrylate, zirconium-n-propylate, sodium phosphate trimer to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except light trigger 184, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add light trigger 184, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a UV curable ink, it is characterized in that, be prepared from by the raw material of following weight portion: pigment 4-5, UV pure acrylic resin 40-45, trimethylolpropane triacrylate 10-15, ethyl acetate 5-8, methyl methacrylate 12-15, zirconium-n-propylate 3-4, sodium phosphate trimer 5-6, nickel nitrate 1-2, Arabic gum 1-2, butyl acrylate 3-4, dipentaerythritol acrylate 6-9, antioxidant 10352-3, triethyl citrate 3-4, captax 1-2, silane resin acceptor kh-550 2-3, auxiliary agent 4-5, light trigger 1846-12;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, antioxidant 10351-2, crosslinking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. UV curable ink according to claim 1, is characterized in that, is made up of following concrete steps:
First add pigment, UV pure acrylic resin, trimethylolpropane triacrylate, ethyl acetate, methyl methacrylate, zirconium-n-propylate, sodium phosphate trimer to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except light trigger 184, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add light trigger 184, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600481.5A CN103666041B (en) | 2013-11-25 | 2013-11-25 | A kind of UV curable ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600481.5A CN103666041B (en) | 2013-11-25 | 2013-11-25 | A kind of UV curable ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666041A CN103666041A (en) | 2014-03-26 |
| CN103666041B true CN103666041B (en) | 2016-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310600481.5A Active CN103666041B (en) | 2013-11-25 | 2013-11-25 | A kind of UV curable ink and preparation method thereof |
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| CN (1) | CN103666041B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103923526B (en) * | 2014-04-30 | 2016-02-24 | 苏州安洁科技股份有限公司 | Semi-transparent grey environment-friendly ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL103705A (en) * | 1991-11-15 | 1995-12-08 | Kuehnle Manfred R | Electrothermal printing ink and method and apparatus for electronic printing therewith |
| CN1552778B (en) * | 2003-06-06 | 2010-04-28 | 深圳市海川实业股份有限公司 | Ultraviolet photocurable anti-static printing ink |
| CN101870834B (en) * | 2010-06-18 | 2013-06-19 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
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| Publication number | Publication date |
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| CN103666041A (en) | 2014-03-26 |
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Effective date of registration: 20230323 Address after: No. 259, Mount Taishan Road, National Economic and Technological Development Zone, Hebi, Henan 458030 Patentee after: HEBI RUITELONG BIOMASS MATERIALS TECHNOLOGY Co.,Ltd. Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd. |