CN102585573A - Ultraviolet (UV) gloss oil and preparation method thereof - Google Patents
Ultraviolet (UV) gloss oil and preparation method thereof Download PDFInfo
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- CN102585573A CN102585573A CN2011104409837A CN201110440983A CN102585573A CN 102585573 A CN102585573 A CN 102585573A CN 2011104409837 A CN2011104409837 A CN 2011104409837A CN 201110440983 A CN201110440983 A CN 201110440983A CN 102585573 A CN102585573 A CN 102585573A
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Abstract
The invention relates to ultraviolet (UV) gloss oil. The UV gloss oil is prepared by stirring and mixing the following components in percent by weight: 40 to 50 percent of epoxy UV resin, 10 to 12 percent of amine functional monomer, 2 to 4 percent of active diluting agent, 10 to 18 percent of photoinitiator, 1 to 3 percent of trimethylol propane triacrylate, 6 to 15 percent of acrylic resin, 6 to 8 percent of tackifier, 3 to 5 percent of lubrication leveling agent, 0.3 to 0.5 percent of defoaming agent, 2 to 4 percent of wear-resisting assistant, and 10 to 25 percent of mixing solvent. The invention also relates to a preparation method for the UV gloss oil. The UV gloss oil provided by the invention has various excellent performance, excellent binding performance with printing ink, the characteristics of high glossiness, high leveling property, little odor, high wearing resistance and the like; and moreover, the UV gloss oil provided by the invention only needs one process when used in UV glazing, a priming step is omitted, the operating cost is saved, and the work efficiency is improved.
Description
Technical field
The present invention relates to a kind of UV (abbreviation of Ultra viole, promptly ultraviolet ray below all is called UV) gloss oil, particularly exempt from the UV gloss oil that feels secure, promptly the paper printing matter after the printing is directly carried out the UV glazing, and the preparation method of this UV gloss oil.
Background technology
Printing coating can strengthen the light fastness of printing ink, increases the ink lay solar heat protection, and moistureproof ability plays the effect that the protection trace beautifies the products substitution overlay film.
The UV glazing is meant and utilizes ultraviolet ray that gloss oil is carried out hardening with radiation that gloss oil solidifies rapidly, for printed matter brings high gloss, and prevents scratch.
The UV glazing rises rapidly and on many products, has much and replaces gesture plastic film coated and the solvent-borne type glazing, and this depends primarily on the following characteristics that itself have:
1) UV gloss oil solvent is few, and the organic volatile quantity discharged is also few, has therefore reduced atmospheric pollution, has improved Working environment, has also reduced the danger of presence of fire;
2) the UV gloss oil does not contain solvent, does not need heat energy during curing, and it solidifies required energy consumption and has only about 20% of infrared curing type oil polish.
3) printed matter after the UV glazing process is handled, color is obviously bright-coloured beautiful than other working methods, and the coating after solidifying is wear-resisting, has more resistance to chemical reagents and chemical resistant properties, and good stability can water and ethanol scouring.
4) defective that can avoid plastic film coated technology often to occur, the phenomenons such as wrinkling delamination of bubbling like alice, UV glazing product adhesion can stack after the curing and is placed with profit and opens back working procedure processing operations such as bookbinding.
UV gloss oil in the market mostly since with the not anti-adhesive tape tearing of the sticking power of printing-ink, need with the supporting use of oil at the bottom of the water-based, i.e. oil at the bottom of coating one deck water-based on the printed matter earlier; And then carry out the UV glazing; Obtain the brightness of UV glazing printed matter like this, fastness is all fine, also brings a problem but do like this; Promptly need two procedures, increased operating cost.
Summary of the invention
The object of the invention provides a kind of UV gloss oil to the problems referred to above exactly, and this UV gloss oil can be removed the bottoming step from, only needs one procedure, has practiced thrift operating cost, has increased working efficiency.
Another object of the present invention is to provide a kind of method for preparing UV gloss oil of the present invention.
The technical scheme that the present invention is adopted in order to reach the goal is:
The invention provides a kind of UV gloss oil, be prepared from through mixing following components in weight percentage:
Epoxy UV resin 40～50%, amine functional monomer 10～12%, reactive thinner 2～4%; Light trigger 10～18%, Viscoat 295 1～3%, vinyl resin 6～15%; Tackifier 6～8%, lubricated flow agent 3～5%, skimmer 0.3～0.5%; Antiwear assistant 2～4%, mixed solvent 10～25%.
Above-mentioned a kind of UV gloss oil, wherein, said light trigger comprises the hydroxy-cyclohexyl phenyl ketone, UVNUL MS-40 and benzoin dimethylether are composite by weight 3: 4: 5.5.
Above-mentioned a kind of UV gloss oil; Wherein, said amine functional monomer is the hydroxyl amine functional monomer, and its preparation method is: under nitrogen protection, thanomin slowly is added dropwise in the propenoate mixing liquid; With the tripropylene glycol diacrylate is solvent, and sustained reaction to titration tertiary amine content reaches 4%.
Above-mentioned a kind of UV gloss oil, wherein, said propenoate mixing liquid comprises methyl acrylate, Bing Xisuandingzhi, ethyl propenoate, Octyl acrylate, above-mentioned each component compound proportion in molar ratio is 1: 2: 1: 1.5.
Above-mentioned a kind of UV gloss oil; Wherein, Described reactive thinner is a tripropylene glycol diacrylate, the mixed solution of Viscoat 295 and four group monomer, and the preparation method of said four group monomer is: under nitrogen protection, quadrol slowly is added dropwise in the propenoate mixing liquid; With the tripropylene glycol diacrylate is solvent, and sustained reaction to titration tertiary amine content reaches 2%.
Above-mentioned a kind of UV gloss oil, wherein, said propenoate mixing liquid comprises methyl acrylate, Bing Xisuandingzhi, ethyl propenoate, Octyl acrylate, above-mentioned each component compound proportion in molar ratio is 2: 1: 1.5: 1.5.
Above-mentioned a kind of UV gloss oil, wherein, described vinyl resin is at least a among S 1, SR 1, SR30, the 678J; Described tackifier are at least a in rosin, obedient olefine resin, the chlorinatedpolyethylene; Described lubricated flow agent is an organic silicon modified by polyether alkane; Described antiwear assistant is polyether-modified reactive YSR 3286; Described skimmer is a MO organic silicon modified by polyether alive.
Above-mentioned a kind of UV gloss oil, wherein, said mixed solvent comprises toluene, ethanol, diethylene glycol monomethyl ether and butanone, by weight 0.5: 4: 1.5: 2.5 is composite.
The raw material of the invention described above gets by market purchasing.
The present invention also provides a kind of preparation method of above-mentioned UV gloss oil, may further comprise the steps:
(a) be dissolved in vinyl resin, tackifier in the reactive thinner respectively;
(b) amine functional monomer, light trigger, reactive thinner, mixed solvent are joined in the reaction kettle, stirring continues 40-60 minute, dissolves to light trigger to finish;
(c) continue acrylic resin soln, tackifier solution, lubricated flow agent, skimmer are joined in the reaction kettle, continue to stir 20-30 minute, extremely fully evenly;
(d) continue to add epoxy UV resin, stirred 20-30 minute, even to fully;
(e) add antiwear assistant at last, stirred 30-40 minute.
Each item excellent performance of UV gloss oil of the present invention, excellent with the bonding properties of printing ink, have the glossiness height, good leveling property; Characteristics such as smell is little, and wear resistance is good, and UV gloss oil of the present invention is used for the UV glazing and only needs one procedure; Remove the bottoming step from, practiced thrift operating cost, increased working efficiency.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Below through specific embodiment the present invention is carried out a step and sets forth, but should not limit the present invention by any way.
Embodiment 1:
(a) with 6 parts by weight of acrylic acid resin dissolves in ethanol, be made into 50% concentration; 7 weight part tackifier are dissolved in the toluene, are made into 50% concentration;
(b) with 12 portions of amine by weight function monomers, 15 weight part light triggers, 1 weight part Viscoat 295,1 weight part, four group monomer; 5 parts by weight of ethanol, 15 weight part mixed solvents join in the reaction kettle, stir; Continue 40-60 minute, finish to the light trigger dissolving;
(c) continue resulting acrylic resin soln, tackifier solution in (a), 3 weight parts lubricate flow agent, and 0.4 weight part skimmer joins in the reaction kettle, continue to stir 20-30 minute, to evenly complete;
(d) continue to add 45 weight part epoxy UV resins, stirred 20-30 minute, even to fully;
(e) add 3 weight part antiwear assistants at last, stir got final product in 30-40 minute UV gloss oil of the present invention.
The UV gloss oil that this embodiment prepares, its each item performance is following:
Outward appearance: little yellow transparent liquid
Viscosity: 50s (being coated with 4 glasss, 25 ℃)
Wear resistance: 1 grade
Glossiness: 88%.
Embodiment 2:
(a) with 10 parts by weight of acrylic acid resin dissolves in ethanol, be made into 50% concentration; 3 weight part tackifier are dissolved in the toluene, are made into 50% concentration;
(b) with 10 portions of amine by weight function monomers, 18 weight part light triggers, 3 weight part Viscoat 295s, 2 weight parts, four group monomer; 5 parts by weight of ethanol, 20 weight part mixed solvents join in the reaction kettle, stir; Continue 40-60 minute, finish to the light trigger dissolving;
(c) continue resulting acrylic resin soln, tackifier solution in (a), 5 weight parts lubricate flow agent, and 0.3 weight part skimmer joins in the reaction kettle, continue to stir 20-30 minute, to evenly complete;
(d) continue to add 50 weight part epoxy UV resins, stirred 20-30 minute, even to fully;
(e) add 4 weight part antiwear assistants at last, stir got final product in 30-40 minute UV gloss oil of the present invention.
The UV gloss oil that this embodiment prepares, its each item performance is following:
Outward appearance: light yellow transparent liquid
Viscosity: 58s (being coated with 4 glasss, 25 ℃)
Wear resistance: 1 grade
Glossiness: 86%.
Above embodiment only supplies to explain the present invention's usefulness; But not limitation of the present invention; The technician in relevant technologies field under the situation that does not break away from the spirit and scope of the present invention, can also make various conversion or modification; Therefore all technical schemes that are equal to also should belong to category of the present invention, should be limited each claim.
Claims (9)
1. a UV gloss oil is characterized in that, is prepared from through mixing following components in weight percentage:
Epoxy UV resin 40～50%, amine functional monomer 10～12%, reactive thinner 2～4%; Light trigger 10～18%, Viscoat 295 1～3%, vinyl resin 6～15%; Tackifier 6～8%, lubricated flow agent 3～5%, skimmer 0.3～0.5%; Antiwear assistant 2～4%, mixed solvent 10～25%.
2. a kind of UV gloss oil as claimed in claim 1 is characterized in that said light trigger comprises the hydroxy-cyclohexyl phenyl ketone, and UVNUL MS-40 and benzoin dimethylether are composite by weight 3: 4: 5.5.
3. a kind of UV gloss oil as claimed in claim 1; It is characterized in that; Said amine functional monomer is the hydroxyl amine functional monomer; Its preparation method is: under nitrogen protection, thanomin slowly being added dropwise in the propenoate mixing liquid, is solvent with the tripropylene glycol diacrylate, and sustained reaction to titration tertiary amine content reaches 4%.
4. a kind of UV gloss oil as claimed in claim 3 is characterized in that, said propenoate mixing liquid comprises methyl acrylate, Bing Xisuandingzhi, ethyl propenoate, Octyl acrylate, and above-mentioned each component compound proportion in molar ratio is 1: 2: 1: 1.5.
5. a kind of UV gloss oil as claimed in claim 1; It is characterized in that; Described reactive thinner is a tripropylene glycol diacrylate, the mixed solution of Viscoat 295 and four group monomer, and the preparation method of said four group monomer is: under nitrogen protection, quadrol slowly is added dropwise in the propenoate mixing liquid; With the tripropylene glycol diacrylate is solvent, and sustained reaction to titration tertiary amine content reaches 2%.
6. a kind of UV gloss oil as claimed in claim 5 is characterized in that, said propenoate mixing liquid comprises methyl acrylate, Bing Xisuandingzhi, ethyl propenoate, Octyl acrylate, and above-mentioned each component compound proportion in molar ratio is 2: 1: 1.5: 1.5.
7. a kind of UV gloss oil as claimed in claim 1 is characterized in that, described vinyl resin is at least a among S-20, SR-10, SR30, the 678J; Described tackifier are at least a in rosin, obedient olefine resin, the chlorinatedpolyethylene; Described lubricated flow agent is an organic silicon modified by polyether alkane; Described antiwear assistant is polyether-modified reactive YSR 3286; Described skimmer is a MO organic silicon modified by polyether alive.
8. a kind of UV gloss oil as claimed in claim 1 is characterized in that said mixed solvent comprises toluene, ethanol, diethylene glycol monomethyl ether and butanone, and by weight 0.5: 4: 1.5: 2.5 is composite.
9. the preparation method of a UV gloss oil as claimed in claim 1 is characterized in that, may further comprise the steps:
(a) be dissolved in vinyl resin, tackifier in the reactive thinner respectively;
(b) amine functional monomer, light trigger, reactive thinner, mixed solvent are joined in the reaction kettle, stirring continues 40-60 minute, dissolves to light trigger to finish;
(c) continue acrylic resin soln, tackifier solution, lubricated flow agent, skimmer are joined in the reaction kettle, continue to stir 20-30 minute, extremely fully evenly;
(d) continue to add epoxy UV resin, stirred 20-30 minute, even to fully;
(e) add antiwear assistant at last, stirred 30-40 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2011104409837A CN102585573B (en) | 2011-12-23 | 2011-12-23 | Ultraviolet (UV) gloss oil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011104409837A CN102585573B (en) | 2011-12-23 | 2011-12-23 | Ultraviolet (UV) gloss oil and preparation method thereof |
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| CN102585573A true CN102585573A (en) | 2012-07-18 |
| CN102585573B CN102585573B (en) | 2013-11-27 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103525261A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV (ultraviolet) polishing and priming-free UV coating and preparation method thereof |
| CN103627301A (en) * | 2013-11-12 | 2014-03-12 | 惠州市长润发涂料有限公司 | UV (ultraviolet) curing finishing coating for photos |
| CN103666034A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV (Ultraviolet) curing printing ink with low viscosity and good luster and preparation method of UV curing printing ink |
| CN104098942A (en) * | 2013-04-03 | 2014-10-15 | 上海劲嘉建材科技有限公司 | Nanometer wear-resistant coating and floor tile using same |
| CN106700688A (en) * | 2015-11-17 | 2017-05-24 | 洋紫荆油墨（浙江）有限公司 | Bottoming-free UV (ultraviolet) gloss oil and preparation method thereof |
| CN107118672A (en) * | 2017-06-29 | 2017-09-01 | 台昌树脂(佛山)有限公司 | Uv gloss oil and preparation method thereof |
| CN116120815A (en) * | 2023-02-20 | 2023-05-16 | 中荣印刷集团股份有限公司 | Plastic-replaced UV (ultraviolet) glazing paint for paper printing products and preparation method thereof |
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| CN101245200A (en) * | 2008-03-12 | 2008-08-20 | 武汉大学 | UV gloss oil, preparation method and application thereof |
| CN101935475A (en) * | 2010-09-08 | 2011-01-05 | 江门市制漆厂有限公司 | UV curable plastic paint |
| CN102031717A (en) * | 2009-09-29 | 2011-04-27 | 贵州若顿科技开发有限公司 | Water mist prevention UV (ultraviolet) gloss oil for gold card paper |
| CN102120908A (en) * | 2010-12-30 | 2011-07-13 | 浙江工业大学 | Paper package surface cold-transfer type gold blocking UV oil polish and application thereof |
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| CN101245200A (en) * | 2008-03-12 | 2008-08-20 | 武汉大学 | UV gloss oil, preparation method and application thereof |
| CN102031717A (en) * | 2009-09-29 | 2011-04-27 | 贵州若顿科技开发有限公司 | Water mist prevention UV (ultraviolet) gloss oil for gold card paper |
| CN101935475A (en) * | 2010-09-08 | 2011-01-05 | 江门市制漆厂有限公司 | UV curable plastic paint |
| CN102120908A (en) * | 2010-12-30 | 2011-07-13 | 浙江工业大学 | Paper package surface cold-transfer type gold blocking UV oil polish and application thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098942A (en) * | 2013-04-03 | 2014-10-15 | 上海劲嘉建材科技有限公司 | Nanometer wear-resistant coating and floor tile using same |
| CN104098942B (en) * | 2013-04-03 | 2016-08-03 | 上海劲嘉建材科技有限公司 | A kind of floor tile with anti-scratching wearproof effect |
| CN103525261A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV (ultraviolet) polishing and priming-free UV coating and preparation method thereof |
| CN103627301A (en) * | 2013-11-12 | 2014-03-12 | 惠州市长润发涂料有限公司 | UV (ultraviolet) curing finishing coating for photos |
| CN103627301B (en) * | 2013-11-12 | 2017-03-29 | 惠州市长润发涂料有限公司 | A kind of photograph UV solidifies Lacquer finish coating |
| CN103666034A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV (Ultraviolet) curing printing ink with low viscosity and good luster and preparation method of UV curing printing ink |
| CN103666034B (en) * | 2013-11-23 | 2016-05-04 | 铜陵方正塑业科技有限公司 | UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof |
| CN106700688A (en) * | 2015-11-17 | 2017-05-24 | 洋紫荆油墨（浙江）有限公司 | Bottoming-free UV (ultraviolet) gloss oil and preparation method thereof |
| CN107118672A (en) * | 2017-06-29 | 2017-09-01 | 台昌树脂(佛山)有限公司 | Uv gloss oil and preparation method thereof |
| CN116120815A (en) * | 2023-02-20 | 2023-05-16 | 中荣印刷集团股份有限公司 | Plastic-replaced UV (ultraviolet) glazing paint for paper printing products and preparation method thereof |
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|---|---|
| CN102585573B (en) | 2013-11-27 |
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Denomination of invention: The invention relates to a UV varnish and a preparation method thereof Effective date of registration: 20220222 Granted publication date: 20131127 Pledgee: Shanghai Rural Commercial Bank Co.,Ltd. Jinshan sub branch Pledgor: SHANGHAI MORFANT NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2022310000034 |
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Date of cancellation: 20230307 Granted publication date: 20131127 Pledgee: Shanghai Rural Commercial Bank Co.,Ltd. Jinshan sub branch Pledgor: SHANGHAI MORFANT NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2022310000034 |
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