CN103666026A - UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof - Google Patents
UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof Download PDFInfo
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- CN103666026A CN103666026A CN201310600859.1A CN201310600859A CN103666026A CN 103666026 A CN103666026 A CN 103666026A CN 201310600859 A CN201310600859 A CN 201310600859A CN 103666026 A CN103666026 A CN 103666026A
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Abstract
The invention discloses UV (Ultraviolet) curing ink with excellent comprehensive properties. The ink is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 20-23 parts of hydroxy acrylic resin, 3-4 parts of crylic acid, 10-12 parts of vinyl acetate, 4-5 parts of naphthene dicarboxylic acid monoester, 2-3 parts of styrene, 5-8 parts of isobornyl acrylic ester, 1-2 parts of triethanolamine, 3-4 parts of tert-amylphenol, 12-14 parts of methacrylic acid-2-hydroxyethyl, 18-20 parts of polyester acrylic ester, 10-12 parts of trimethylolpropane triacrylate, 5-8 parts of 2959 photoinitiator, 2-3 parts of alums, 5-9 parts of tributyl citrate and 4-5 parts of auxiliary. The auxiliary disclosed by the invention improves the toughness of the ink, the ink can be uniformly dispersed, and the stability of the ink is maintained; the UV curing ink disclosed by the invention is short in photo-curing time, does not need to be heated, can greatly shorten the drying time and save the energy consumption, and is good in gloss and mobility, energy-saving and environment-friendly.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly UV curing inks of a kind of high comprehensive performance and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide UV curing inks of a kind of high comprehensive performance and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A UV curing inks for high comprehensive performance, is made by the raw material of following weight part: pigment dyestuff 1-3, Hydroxylated acrylic resin 20-23, vinylformic acid 3-4, vinyl-acetic ester 10-12, Cycloalkane dicarboxylic acid monoesters 4-5, vinylbenzene 2-3, iso-bornyl acrylate 5-8, trolamine 1-2, Pentaphen 3-4, methacrylic acid-2-hydroxy methacrylate 12-14, polyester acrylate 18-20, Viscoat 295 10-12,2959 light trigger 5-8, alum 2-3, tributyl citrate 5-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curing inks of high comprehensive performance of the present invention, by following concrete steps, made: first add pigment dyestuff, Hydroxylated acrylic resin, vinylformic acid, vinyl-acetic ester, Cycloalkane dicarboxylic acid monoesters, vinylbenzene, iso-bornyl acrylate, trolamine, Pentaphen, methacrylic acid-2-hydroxy methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; The curing speed of ink of the present invention improves, and does not need heating, can significantly reduce time of drying, save energy consumption, good luster, good fluidity, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A UV curing inks for high comprehensive performance, by following weight part (kilogram) raw material make: pigment dyestuff 1, Hydroxylated acrylic resin 20, vinylformic acid 3, vinyl-acetic ester 10, Cycloalkane dicarboxylic acid monoesters 4, vinylbenzene 2, iso-bornyl acrylate 5, trolamine 1, Pentaphen 3, methacrylic acid-2-hydroxy methacrylate 12, polyester acrylate 18, Viscoat 295 10,2959 light triggers 5, alum 2, tributyl citrate 5, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curing inks of high comprehensive performance of the present invention, by following concrete steps, made: first add pigment dyestuff, Hydroxylated acrylic resin, vinylformic acid, vinyl-acetic ester, Cycloalkane dicarboxylic acid monoesters, vinylbenzene, iso-bornyl acrylate, trolamine, Pentaphen, methacrylic acid-2-hydroxy methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curing inks of a high comprehensive performance, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, Hydroxylated acrylic resin 20-23, vinylformic acid 3-4, vinyl-acetic ester 10-12, Cycloalkane dicarboxylic acid monoesters 4-5, vinylbenzene 2-3, iso-bornyl acrylate 5-8, trolamine 1-2, Pentaphen 3-4, methacrylic acid-2-hydroxy methacrylate 12-14, polyester acrylate 18-20, Viscoat 295 10-12,2959 light trigger 5-8, alum 2-3, tributyl citrate 5-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the UV curing inks of high comprehensive performance according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, Hydroxylated acrylic resin, vinylformic acid, vinyl-acetic ester, Cycloalkane dicarboxylic acid monoesters, vinylbenzene, iso-bornyl acrylate, trolamine, Pentaphen, methacrylic acid-2-hydroxy methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600859.1A CN103666026A (en) | 2013-11-25 | 2013-11-25 | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310600859.1A CN103666026A (en) | 2013-11-25 | 2013-11-25 | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof |
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| CN103666026A true CN103666026A (en) | 2014-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310600859.1A Pending CN103666026A (en) | 2013-11-25 | 2013-11-25 | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101469152A (en) * | 2007-12-27 | 2009-07-01 | 深圳富泰宏精密工业有限公司 | Ink composition and use method thereof |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101993629A (en) * | 2009-08-14 | 2011-03-30 | 比亚迪股份有限公司 | Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition |
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
| CN102226049A (en) * | 2011-05-27 | 2011-10-26 | 东周化学工业（昆山）有限公司 | Printable ultraviolet light solidified waterproof printing ink for optical disk |
-
2013
- 2013-11-25 CN CN201310600859.1A patent/CN103666026A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101469152A (en) * | 2007-12-27 | 2009-07-01 | 深圳富泰宏精密工业有限公司 | Ink composition and use method thereof |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101993629A (en) * | 2009-08-14 | 2011-03-30 | 比亚迪股份有限公司 | Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition |
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
| CN102226049A (en) * | 2011-05-27 | 2011-10-26 | 东周化学工业（昆山）有限公司 | Printable ultraviolet light solidified waterproof printing ink for optical disk |
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Application publication date: 20140326 |
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