CN103666026A - UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof - Google Patents
UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof Download PDFInfo
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- CN103666026A CN103666026A CN201310600859.1A CN201310600859A CN103666026A CN 103666026 A CN103666026 A CN 103666026A CN 201310600859 A CN201310600859 A CN 201310600859A CN 103666026 A CN103666026 A CN 103666026A
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- 238000002360 preparation method Methods 0.000 title claims description 8
- 238000003848 UV Light-Curing Methods 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- NRZWYNLTFLDQQX-UHFFFAOYSA-N p-tert-Amylphenol Chemical compound CCC(C)(C)C1=CC=C(O)C=C1 NRZWYNLTFLDQQX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 239000000976 ink Substances 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 6
- 150000001924 cycloalkanes Chemical class 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 229940091853 isobornyl acrylate Drugs 0.000 claims description 6
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 3
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 238000001723 curing Methods 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000000016 photochemical curing Methods 0.000 abstract description 2
- -1 isobornyl acrylic ester Chemical class 0.000 abstract 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical group CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000002932 luster Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses UV (Ultraviolet) curing ink with excellent comprehensive properties. The ink is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 20-23 parts of hydroxy acrylic resin, 3-4 parts of crylic acid, 10-12 parts of vinyl acetate, 4-5 parts of naphthene dicarboxylic acid monoester, 2-3 parts of styrene, 5-8 parts of isobornyl acrylic ester, 1-2 parts of triethanolamine, 3-4 parts of tert-amylphenol, 12-14 parts of methacrylic acid-2-hydroxyethyl, 18-20 parts of polyester acrylic ester, 10-12 parts of trimethylolpropane triacrylate, 5-8 parts of 2959 photoinitiator, 2-3 parts of alums, 5-9 parts of tributyl citrate and 4-5 parts of auxiliary. The auxiliary disclosed by the invention improves the toughness of the ink, the ink can be uniformly dispersed, and the stability of the ink is maintained; the UV curing ink disclosed by the invention is short in photo-curing time, does not need to be heated, can greatly shorten the drying time and save the energy consumption, and is good in gloss and mobility, energy-saving and environment-friendly.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly UV curing inks of a kind of high comprehensive performance and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide UV curing inks of a kind of high comprehensive performance and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A UV curing inks for high comprehensive performance, is made by the raw material of following weight part: pigment dyestuff 1-3, Hydroxylated acrylic resin 20-23, vinylformic acid 3-4, vinyl-acetic ester 10-12, Cycloalkane dicarboxylic acid monoesters 4-5, vinylbenzene 2-3, iso-bornyl acrylate 5-8, trolamine 1-2, Pentaphen 3-4, methacrylic acid-2-hydroxy methacrylate 12-14, polyester acrylate 18-20, Viscoat 295 10-12,2959 light trigger 5-8, alum 2-3, tributyl citrate 5-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curing inks of high comprehensive performance of the present invention, by following concrete steps, made: first add pigment dyestuff, Hydroxylated acrylic resin, vinylformic acid, vinyl-acetic ester, Cycloalkane dicarboxylic acid monoesters, vinylbenzene, iso-bornyl acrylate, trolamine, Pentaphen, methacrylic acid-2-hydroxy methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; The curing speed of ink of the present invention improves, and does not need heating, can significantly reduce time of drying, save energy consumption, good luster, good fluidity, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A UV curing inks for high comprehensive performance, by following weight part (kilogram) raw material make: pigment dyestuff 1, Hydroxylated acrylic resin 20, vinylformic acid 3, vinyl-acetic ester 10, Cycloalkane dicarboxylic acid monoesters 4, vinylbenzene 2, iso-bornyl acrylate 5, trolamine 1, Pentaphen 3, methacrylic acid-2-hydroxy methacrylate 12, polyester acrylate 18, Viscoat 295 10,2959 light triggers 5, alum 2, tributyl citrate 5, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curing inks of high comprehensive performance of the present invention, by following concrete steps, made: first add pigment dyestuff, Hydroxylated acrylic resin, vinylformic acid, vinyl-acetic ester, Cycloalkane dicarboxylic acid monoesters, vinylbenzene, iso-bornyl acrylate, trolamine, Pentaphen, methacrylic acid-2-hydroxy methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curing inks of a high comprehensive performance, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, Hydroxylated acrylic resin 20-23, vinylformic acid 3-4, vinyl-acetic ester 10-12, Cycloalkane dicarboxylic acid monoesters 4-5, vinylbenzene 2-3, iso-bornyl acrylate 5-8, trolamine 1-2, Pentaphen 3-4, methacrylic acid-2-hydroxy methacrylate 12-14, polyester acrylate 18-20, Viscoat 295 10-12,2959 light trigger 5-8, alum 2-3, tributyl citrate 5-9, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the UV curing inks of high comprehensive performance according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, Hydroxylated acrylic resin, vinylformic acid, vinyl-acetic ester, Cycloalkane dicarboxylic acid monoesters, vinylbenzene, iso-bornyl acrylate, trolamine, Pentaphen, methacrylic acid-2-hydroxy methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2959 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2959 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600859.1A CN103666026A (en) | 2013-11-25 | 2013-11-25 | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600859.1A CN103666026A (en) | 2013-11-25 | 2013-11-25 | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666026A true CN103666026A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310600859.1A Pending CN103666026A (en) | 2013-11-25 | 2013-11-25 | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666026A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101469152A (en) * | 2007-12-27 | 2009-07-01 | 深圳富泰宏精密工业有限公司 | Ink composition and use method thereof |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101993629A (en) * | 2009-08-14 | 2011-03-30 | 比亚迪股份有限公司 | Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition |
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
| CN102226049A (en) * | 2011-05-27 | 2011-10-26 | 东周化学工业（昆山）有限公司 | Printable ultraviolet light solidified waterproof printing ink for optical disk |
-
2013
- 2013-11-25 CN CN201310600859.1A patent/CN103666026A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101469152A (en) * | 2007-12-27 | 2009-07-01 | 深圳富泰宏精密工业有限公司 | Ink composition and use method thereof |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101993629A (en) * | 2009-08-14 | 2011-03-30 | 比亚迪股份有限公司 | Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition |
| CN102093782A (en) * | 2011-03-30 | 2011-06-15 | 北京神彩优维喷墨材料科技有限公司 | Ultraviolet-cured digital painting ink and preparation method thereof |
| CN102226049A (en) * | 2011-05-27 | 2011-10-26 | 东周化学工业（昆山）有限公司 | Printable ultraviolet light solidified waterproof printing ink for optical disk |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140326 |
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| RJ01 | Rejection of invention patent application after publication |