CN103666040A - UV cured printing ink with high flowability and gloss, and preparation method thereof - Google Patents
UV cured printing ink with high flowability and gloss, and preparation method thereof Download PDFInfo
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- CN103666040A CN103666040A CN201310600462.2A CN201310600462A CN103666040A CN 103666040 A CN103666040 A CN 103666040A CN 201310600462 A CN201310600462 A CN 201310600462A CN 103666040 A CN103666040 A CN 103666040A
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Abstract
本发明公开了一种流动好光泽好的紫外光固化油墨，其特征在于，由下列重量份的原料制备制成：纳米碳酸钙粉2-3、有机颜料1-2、白云石粉1-2、蒙脱石1-2、钛酸酯偶联剂TMC-TTS 1-2、聚氨酯丙烯酸脂20-30、2-羟基-2-甲基-苯丙酮6-8、橘子油1-2、安息香双甲醚5-8、丙烯基缩水甘油醚1-2、UV聚醚丙烯酯9-12、丙烯酸-2-羟基丙酯10-12、二缩三丙二醇二丙烯酸酯10-12、交联剂TAC 1-2、4,4-二（6-叔丁基-间甲苯基）硫酚3-4、三壬基苯基亚磷酸酯4-6、助剂4-5；本发明助剂提高了油墨的韧性，使油墨分散均匀，并且维持了油墨的稳定性；本发明油墨固化快、颜色艳、光泽好、流动性佳、印刷性能好和耐溶剂洗擦。The invention discloses an ultraviolet curable ink with good flow and good gloss, which is characterized in that it is prepared from the following raw materials in parts by weight: 2-3 nanometer calcium carbonate powder, 1-2 organic pigment, 1-2 dolomite powder, Montmorillonite 1-2, titanate coupling agent TMC-TTS 1-2, polyurethane acrylate 20-30, 2-hydroxy-2-methyl-propiophenone 6-8, orange oil 1-2, benzoin bis Methyl ether 5-8, propenyl glycidyl ether 1-2, UV polyether acrylate 9-12, acrylate-2-hydroxypropyl 10-12, tripropylene glycol diacrylate 10-12, crosslinking agent TAC 1-2, 4,4-bis(6-tert-butyl-m-tolyl)thiophenol 3-4, trinonylphenyl phosphite 4-6, auxiliary agent 4-5; the auxiliary agent of the present invention improves The toughness of the ink enables the ink to disperse evenly and maintains the stability of the ink; the ink of the invention has fast curing, bright color, good gloss, good fluidity, good printing performance and solvent scrubbing resistance.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly UV curable ink of a kind of good good luster that flows and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide UV curable ink of a kind of good good luster that flows and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of UV curable ink of the good good luster that flows, raw material by following weight part is made: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS 1-2, polyurethane acroleic acid fat 20-30, 2-hydroxy-2-methyl-Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyethers propylene 9-12, vinylformic acid-2-hydroxy propyl ester 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curable ink of the good good luster that flows of the present invention, by following concrete steps, made: first add nano-calcium carbonate calcium powder, pigment dyestuff, ground dolomite, montmorillonite, titanate coupling agent TMC-TTS, polyurethane acroleic acid fat, mandarin oil,, benzoin dimethylether,, propenyl glycidyl ether, UV polyethers propylene,, vinylformic acid-2-hydroxy propyl ester, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2-hydroxy-2-methyl-Propiophenone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2-hydroxy-2-methyl-Propiophenone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Ink solidification of the present invention is fast, color is gorgeous, good luster, mobility is good, printing performance good and resistance to solvent shampooing.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of UV curable ink of the good good luster that flows, raw material by following weight part is made: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS 1-2, polyurethane acroleic acid fat 20-30, 2-hydroxy-2-methyl-Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyethers propylene 9-12, vinylformic acid-2-hydroxy propyl ester 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, tea-polyphenol 2, neopentyl glycol 5, p-tert-butyl benzoic acid 1, oxidation inhibitor 1,035 1,2-butoxy-ethanol 3, linking agent TAC2, ethoxylated trimethylolpropane triacrylate 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curable ink of the good good luster that flows of the present invention, by following concrete steps, made: first add nano-calcium carbonate calcium powder, pigment dyestuff, ground dolomite, montmorillonite, titanate coupling agent TMC-TTS, polyurethane acroleic acid fat, mandarin oil,, benzoin dimethylether,, propenyl glycidyl ether, UV polyethers propylene,, vinylformic acid-2-hydroxy propyl ester, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2-hydroxy-2-methyl-Propiophenone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2-hydroxy-2-methyl-Propiophenone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curable ink of the good good luster that flows, it is characterized in that, raw material by following weight part is made: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS 1-2, polyurethane acroleic acid fat 20-30, 2-hydroxy-2-methyl-Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyethers propylene 9-12, vinylformic acid-2-hydroxy propyl ester 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the UV curable ink of the good good luster that flows according to claim 1, it is characterized in that, by following concrete steps, made: first add nano-calcium carbonate calcium powder, pigment dyestuff, ground dolomite, montmorillonite, titanate coupling agent TMC-TTS, polyurethane acroleic acid fat, mandarin oil,, benzoin dimethylether,, propenyl glycidyl ether, UV polyethers propylene,, vinylformic acid-2-hydroxy propyl ester, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 2-hydroxy-2-methyl-Propiophenone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 2-hydroxy-2-methyl-Propiophenone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600462.2A CN103666040B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good luster that flowed and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600462.2A CN103666040B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good luster that flowed and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103666040A true CN103666040A (en) | 2014-03-26 |
| CN103666040B CN103666040B (en) | 2016-04-13 |
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Citations (7)
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| CN101292000A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Curable inkjet ink set and inkjet printing method |
| CN101291816A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Curable Liquid Set and Inkjet Printing Method |
| CN102369248A (en) * | 2009-04-08 | 2012-03-07 | 大日精化工业株式会社 | Color composition for pixel-forming ink, pigment dispersion liquid, pixel-forming ink, color filter, and production methods thereof |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103232751A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | UV (ultraviolet) curing ink and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310600462.2A patent/CN103666040B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101292000A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Curable inkjet ink set and inkjet printing method |
| CN101291816A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Curable Liquid Set and Inkjet Printing Method |
| CN102369248A (en) * | 2009-04-08 | 2012-03-07 | 大日精化工业株式会社 | Color composition for pixel-forming ink, pigment dispersion liquid, pixel-forming ink, color filter, and production methods thereof |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103232751A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | UV (ultraviolet) curing ink and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
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| CN103666040B (en) | 2016-04-13 |
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Granted publication date: 20160413 |