CN103666074B - A kind of safety and environmental protection UV curable ink and preparation method thereof - Google Patents
A kind of safety and environmental protection UV curable ink and preparation method thereof Download PDFInfo
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- CN103666074B CN103666074B CN201310618290.1A CN201310618290A CN103666074B CN 103666074 B CN103666074 B CN 103666074B CN 201310618290 A CN201310618290 A CN 201310618290A CN 103666074 B CN103666074 B CN 103666074B
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- 238000002360 preparation method Methods 0.000 title claims description 7
- 230000007613 environmental effect Effects 0.000 title claims description 4
- 239000000843 powder Substances 0.000 claims abstract description 13
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- WPYCRFCQABTEKC-UHFFFAOYSA-N Diglycidyl resorcinol ether Chemical compound C1OC1COC(C=1)=CC=CC=1OCC1CO1 WPYCRFCQABTEKC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- 150000004645 aluminates Chemical class 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 13
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- KWIPUXXIFQQMKN-UHFFFAOYSA-N 2-azaniumyl-3-(4-cyanophenyl)propanoate Chemical compound OC(=O)C(N)CC1=CC=C(C#N)C=C1 KWIPUXXIFQQMKN-UHFFFAOYSA-N 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 229940090948 ammonium benzoate Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims 2
- 239000000975 dye Substances 0.000 claims 2
- 239000012467 final product Substances 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 2
- 239000000049 pigment Substances 0.000 claims 2
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000004423 acyloxy group Chemical group 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- -1 titanic acid ester Chemical class 0.000 claims 1
- 239000012860 organic pigment Substances 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 5
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract description 4
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 abstract description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012855 volatile organic compound Substances 0.000 abstract 2
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 4
- 230000005856 abnormality Effects 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229940075579 propyl gallate Drugs 0.000 description 2
- 235000010388 propyl gallate Nutrition 0.000 description 2
- 239000000473 propyl gallate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- OEMXNIIMRFWWGV-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid phenol Chemical compound C(C1=CC(C(=O)O)=CC=C1)(=O)O.C1(=CC=CC=C1)O OEMXNIIMRFWWGV-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
本发明公开了一种安全环保紫外光固化油墨，其特征在于，由下列重量份的原料制备制成：有机颜料1-3、纳米硅藻土粉1-2、氧化铝2-3、氢氧化镁1-2、间苯二酚双缩水甘油醚11-14、异丙基硫杂蒽酮5-8、双氰胺2-3、二缩三丙二醇二丙烯酸酯10-12、聚酯丙烯酸酯12-15、聚醚丙烯酸酯10-12、二季戊四醇六丙烯酸酯8-10、铝酸酯偶联剂DL-411？1-2、助剂4-5；本发明助剂提高了油墨的韧性，使油墨分散均匀，并且维持了油墨的稳定性；本发明油墨产品的各组分中不含有毒溶剂，无可挥发有机物(VOC)排放，环境友好，绿色环保，而且性能优异，印刷适性良好。The invention discloses a safe and environment-friendly ultraviolet light curing ink, which is characterized in that it is prepared from the following raw materials in parts by weight: organic pigment 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, hydroxide Magnesium 1-2, Resorcinol Bisglycidyl Ether 11-14, Isopropyl Thioxanthone 5-8, Dicyandiamide 2-3, Tripropylene Glycol Diacrylate 10-12, Polyester Acrylate 12-15, polyether acrylate 10-12, dipentaerythritol hexaacrylate 8-10, aluminate coupling agent DL-411? 1-2, auxiliary agent 4-5; the auxiliary agent of the present invention improves the toughness of ink , the ink is dispersed evenly, and the stability of the ink is maintained; each component of the ink product of the present invention does not contain toxic solvents, no volatile organic compound (VOC) emissions, environmentally friendly, green, and excellent performance, printing suitability good.
Description
技术领域 technical field
本发明涉及一种油墨及其制备方法，特别是一种安全环保紫外光固化油墨及其制备方法。 The invention relates to an ink and a preparation method thereof, in particular to a safe and environment-friendly ultraviolet light curing ink and a preparation method thereof.
背景技术 Background technique
紫外光固化（UV）油墨是指在紫外线照射下，利用不同波长和能量的紫外光使油墨成膜和干燥的油墨。利用不同紫外光谱，可产生不同能量，将不同油墨连结料中的单体聚合成聚合物，所以UV油墨的色膜具有良好的机械和化学性能。UV油墨的主要优点有：(1)不用溶剂；(2)干燥速度快，耗能少；(3)光泽好，色彩鲜艳；(4)耐水、耐溶剂，耐磨性能好。UV油墨中光引发剂是一种易受光激发的化合物，在吸收光照后激发成自由基，能量转移给感光性分子或光交联剂，使UV墨发生光固化反应。目前UV墨已成为一种较成熟的油墨技术，其污染物排放几乎为零。紫外光固化油墨由于体系中不含溶剂，具有高效、适应性广、经济、节能、环境友好，成为具有广阔发展前景的新型油墨。 Ultraviolet curing (UV) ink refers to the ink that uses ultraviolet light of different wavelengths and energies to form a film and dry the ink under ultraviolet radiation. Using different ultraviolet spectra, different energies can be generated to polymerize monomers in different ink binders into polymers, so the color film of UV ink has good mechanical and chemical properties. The main advantages of UV ink are: (1) No solvent is used; (2) Fast drying speed and less energy consumption; (3) Good gloss and bright colors; (4) Water resistance, solvent resistance, and good wear resistance. The photoinitiator in UV ink is a compound that is easily excited by light. After absorbing light, it is excited into a free radical, and the energy is transferred to the photosensitive molecule or photocrosslinking agent, so that the UV ink undergoes a photocuring reaction. At present, UV ink has become a relatively mature ink technology, and its pollutant discharge is almost zero. Since the UV-curable ink does not contain solvents in the system, it has the advantages of high efficiency, wide adaptability, economy, energy saving, and environmental friendliness, and has become a new type of ink with broad development prospects.
发明内容 Contents of the invention
本发明的目的是提供一种安全环保紫外光固化油墨及其制备方法。 The object of the present invention is to provide a safe and environment-friendly ultraviolet light curing ink and a preparation method thereof.
为了实现本发明的目的，本发明通过以下方案实施： In order to realize the purpose of the present invention, the present invention is implemented through the following schemes:
一种安全环保紫外光固化油墨，由下列重量份的原料制备制成：有机颜料1-3、纳米硅藻土粉1-2、氧化铝2-3、氢氧化镁1-2、间苯二酚双缩水甘油醚11-14、异丙基硫杂蒽酮5-8、双氰胺2-3、二缩三丙二醇二丙烯酸酯10-12、聚酯丙烯酸酯12-15、聚醚丙烯酸酯10-12、二季戊四醇六丙烯酸酯8-10、铝酸酯偶联剂DL-4111-2、助剂4-5； A safe and environment-friendly ultraviolet light curing ink is prepared from the following raw materials in parts by weight: organic pigment 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, magnesium hydroxide 1-2, isophthalic acid Phenol diglycidyl ether 11-14, isopropylthioxanthone 5-8, dicyandiamide 2-3, tripropylene glycol diacrylate 10-12, polyester acrylate 12-15, polyether acrylate 10-12, dipentaerythritol hexaacrylate 8-10, aluminate coupling agent DL-4111-2, auxiliary agent 4-5;
所述助剂由下列重量份的原料制备而成：纳米硅藻土粉0.2-0.3、纳米云母粉0.2-0.3、硅烷偶联剂KH5501-2、交联剂TAC2-3、聚异丁烯2-3、异丙基三（二辛基焦磷酸酰氧基）钛酸酯2-3、苯甲酸胺1-2、三羟甲基丙烷三丙烯酸酯10-12、没食子酸丙酯2-3、薏仁油1-2；其制备方法是将各物料混合，加热至60-70℃，搅拌反应30-40分钟，即得。 The auxiliary agent is prepared from the following raw materials in parts by weight: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane coupling agent KH5501-2, crosslinking agent TAC2-3, polyisobutylene 2-3 , Isopropyl tris(dioctyl pyrophosphate acyloxy) titanate 2-3, Ammonium benzoate 1-2, Trimethylolpropane triacrylate 10-12, Propyl gallate 2-3, Barley Oil 1-2; the preparation method is to mix all the materials, heat to 60-70°C, stir and react for 30-40 minutes to obtain.
本发明所述安全环保紫外光固化油墨，由以下具体步骤制成：首先加入有机颜料、纳米硅藻土粉、氧化铝、氢氧化镁、间苯二酚双缩水甘油醚、二缩三丙二醇二丙烯酸酯搅拌混匀，加热至80-90℃，搅拌25-35分钟；然后加入除异丙基硫杂蒽酮之外的其余剩余成分，搅拌反应3-5小时；最后降温至60-70℃，加入异丙基硫杂蒽酮，搅拌反应40-50分钟，冷却后，研磨得到20-40μm浆料，即得。 The safe and environment-friendly UV-curable ink of the present invention is made by the following specific steps: first, add organic pigments, nanometer diatomite powder, aluminum oxide, magnesium hydroxide, resorcinol bisglycidyl ether, tripropylene glycol di Stir and mix the acrylate, heat to 80-90°C, stir for 25-35 minutes; then add the remaining ingredients except isopropylthioxanthone, stir and react for 3-5 hours; finally cool down to 60-70°C , add isopropyl thioxanthone, stir and react for 40-50 minutes, after cooling, grind to obtain a 20-40 μm slurry.
本发明的有益效果是：本发明助剂提高了油墨的韧性，使油墨分散均匀，并且维持了油墨的稳定性；本发明油墨产品的各组分中不含有毒溶剂，无可挥发有机物(VOC)排放，环境友好，绿色环保，而且性能优异，印刷适性良好。 The beneficial effects of the present invention are: the auxiliary agent of the present invention improves the toughness of ink, makes ink disperse evenly, and maintains the stability of ink; In each component of ink product of the present invention, does not contain poisonous solvent, does not have volatile organic matter (VOC ) emissions, environment-friendly, green, and excellent performance, good printability.
具体实施方案 specific implementation plan
下面通过具体实例对本发明进行详细说明。 The present invention will be described in detail below through specific examples.
一种安全环保紫外光固化油墨，由下列重量份（公斤）的原料制备制成：有机颜料1、纳米硅藻土粉1、氧化铝2、氢氧化镁1、间苯二酚双缩水甘油醚11、异丙基硫杂蒽酮5、双氰胺2、二缩三丙二醇二丙烯酸酯10、聚酯丙烯酸酯12、聚醚丙烯酸酯10、二季戊四醇六丙烯酸酯8、铝酸酯偶联剂DL-4111、助剂4； A safe and environmentally friendly UV-curable ink, prepared from the following raw materials in parts by weight (kg): organic pigment 1, nano diatomite powder 1, aluminum oxide 2, magnesium hydroxide 1, resorcinol bisglycidyl ether 11. Isopropyl Thioxanthone 5, Dicyandiamide 2, Tripropylene Glycol Diacrylate 10, Polyester Acrylate 12, Polyether Acrylate 10, Dipentaerythritol Hexaacrylate 8, Aluminate Coupling Agent DL-4111, additive 4;
所述助剂由下列重量份（公斤）的原料制备而成：纳米硅藻土粉0.2、纳米云母粉0.2、硅烷偶联剂KH5501、交联剂TAC2、聚异丁烯2、异丙基三（二辛基焦磷酸酰氧基）钛酸酯2、苯甲酸胺1、三羟甲基丙烷三丙烯酸酯10、没食子酸丙酯2、薏仁油1；其制备方法是将各物料混合，加热至60-70℃，搅拌反应30-40分钟，即得。 The auxiliary agent is prepared from the following raw materials in parts by weight (kg): 0.2 nano-diatomite powder, 0.2 nano-mica powder, silane coupling agent KH5501, cross-linking agent TAC2, polyisobutylene 2, isopropyl tris(di Octyl pyrophosphate acyloxy) titanate 2, ammonium benzoate 1, trimethylolpropane triacrylate 10, propyl gallate 2, coix seed oil 1; the preparation method is to mix the materials and heat to 60 -70°C, stirred and reacted for 30-40 minutes, that is.
所述安全环保紫外光固化油墨，由以下具体步骤制成：首先加入有机颜料、纳米硅藻土粉、氧化铝、氢氧化镁、间苯二酚双缩水甘油醚、二缩三丙二醇二丙烯酸酯搅拌混匀，加热至80-90℃，搅拌25-35分钟；然后加入除异丙基硫杂蒽酮之外的其余剩余成分，搅拌反应3-5小时；最后降温至60-70℃，加入异丙基硫杂蒽酮，搅拌反应40-50分钟，冷却后，研磨得到20-40μm浆料，即得。 The safe and environment-friendly UV-curable ink is made by the following specific steps: first, add organic pigments, nano diatomite powder, aluminum oxide, magnesium hydroxide, resorcinol bisglycidyl ether, tripropylene glycol diacrylate Stir and mix well, heat to 80-90°C, stir for 25-35 minutes; then add the remaining ingredients except isopropylthioxanthone, stir and react for 3-5 hours; finally cool down to 60-70°C, add Isopropylthioxanthone, stirred and reacted for 40-50 minutes, cooled, ground to obtain a 20-40 μm slurry, that is.
所得的油墨，使用划格法牛皮胶带剥离，划格间距1mm，100%附着；使用浸有酒精的棉球，300克压力擦拭50次，无异状；浸泡于色拉油中（常温）8小时，无异状；使用浸有盐水的棉球，300克压力擦拭50次，无异状。 The obtained ink was peeled off with cross-cut kraft tape, with a cross-cut distance of 1mm, and 100% adhesion; using a cotton ball soaked in alcohol, wiped 50 times with a pressure of 300 grams, no abnormality; soaked in salad oil (at room temperature) for 8 hours , no abnormality; use a cotton ball soaked in salt water, wipe 50 times with 300 grams of pressure, no abnormality.
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