CN103666074A - Safe and environmental-friendly ultraviolet curing ink and preparation method thereof - Google Patents
Safe and environmental-friendly ultraviolet curing ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666074A CN103666074A CN201310618290.1A CN201310618290A CN103666074A CN 103666074 A CN103666074 A CN 103666074A CN 201310618290 A CN201310618290 A CN 201310618290A CN 103666074 A CN103666074 A CN 103666074A
- Authority
- CN
- China
- Prior art keywords
- ink
- auxiliary agent
- isopropyl thioxanthone
- minute
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000000843 powder Substances 0.000 claims abstract description 13
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- WPYCRFCQABTEKC-UHFFFAOYSA-N Diglycidyl resorcinol ether Chemical compound C1OC1COC(C=1)=CC=CC=1OCC1CO1 WPYCRFCQABTEKC-UHFFFAOYSA-N 0.000 claims abstract description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- 150000004645 aluminates Chemical class 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 230000007613 environmental effect Effects 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- -1 titanic acid ester Chemical class 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000002904 solvent Substances 0.000 abstract description 5
- 239000012855 volatile organic compound Substances 0.000 abstract 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 25
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
本发明公开了一种安全环保紫外光固化油墨，其特征在于，由下列重量份的原料制备制成：有机颜料1-3、纳米硅藻土粉1-2、氧化铝2-3、氢氧化镁1-2、间苯二酚双缩水甘油醚11-14、异丙基硫杂蒽酮5-8、双氰胺2-3、二缩三丙二醇二丙烯酸酯10-12、聚酯丙烯酸酯12-15、聚醚丙烯酸酯10-12、二季戊四醇六丙烯酸酯8-10、铝酸酯偶联剂DL-4111-2、助剂4-5；本发明助剂提高了油墨的韧性，使油墨分散均匀，并且维持了油墨的稳定性；本发明油墨产品的各组分中不含有毒溶剂，无可挥发有机物(VOC)排放，环境友好，绿色环保，而且性能优异，印刷适性良好。The invention discloses a safe and environment-friendly ultraviolet light curing ink, which is characterized in that it is prepared from the following raw materials in parts by weight: organic pigment 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, hydroxide Magnesium 1-2, Resorcinol Bisglycidyl Ether 11-14, Isopropyl Thioxanthone 5-8, Dicyandiamide 2-3, Tripropylene Glycol Diacrylate 10-12, Polyester Acrylate 12-15, polyether acrylate 10-12, dipentaerythritol hexaacrylate 8-10, aluminate coupling agent DL-4111-2, auxiliary agent 4-5; the auxiliary agent of the present invention improves the toughness of ink, making The ink is uniformly dispersed, and the stability of the ink is maintained; each component of the ink product of the invention does not contain toxic solvents, does not emit volatile organic compounds (VOC), is environmentally friendly, green and environmentally friendly, and has excellent performance and good printability.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of safety and environmental protection UV curable ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.UV curable ink due in system containing solvent, there is efficient, wide adaptability, economy, energy-conservation, environmental friendliness, become tool novel ink with broad prospects for development.
Summary of the invention
The object of this invention is to provide a kind of safety and environmental protection UV curable ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A safety and environmental protection UV curable ink, is made by the raw material of following weight part: pigment dyestuff 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, magnesium hydroxide 1-2, Resorcinol bisglycidyl ether 11-14, isopropyl thioxanthone 5-8, Dyhard RU 100 2-3, tri (propylene glycol) diacrylate 10-12, polyester acrylate 12-15, polyether acrylate 10-12, dipentaerythritol acrylate 8-10, aluminate coupling agent DL-411 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Safety and environmental protection UV curable ink of the present invention, by following concrete steps, made: first add pigment dyestuff, nano diatomite powder, aluminum oxide, magnesium hydroxide, Resorcinol bisglycidyl ether, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except isopropyl thioxanthone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add isopropyl thioxanthone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; In each component of ink product of the present invention, not containing noxious solvent, without volatilizable organism (VOC), discharge, environmental friendliness, environmental protection, and excellent performance, printability is good.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A safety and environmental protection UV curable ink, by following weight part (kilogram) raw material make: pigment dyestuff 1, nano diatomite powder 1, aluminum oxide 2, magnesium hydroxide 1, Resorcinol bisglycidyl ether 11, isopropyl thioxanthone 5, Dyhard RU 100 2, tri (propylene glycol) diacrylate 10, polyester acrylate 12, polyether acrylate 10, dipentaerythritol acrylate 8, aluminate coupling agent DL-411 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, linking agent TAC2, polyisobutene 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, phenylformic acid amine 1, Viscoat 295 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Described safety and environmental protection UV curable ink, by following concrete steps, made: first add pigment dyestuff, nano diatomite powder, aluminum oxide, magnesium hydroxide, Resorcinol bisglycidyl ether, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except isopropyl thioxanthone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add isopropyl thioxanthone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a safety and environmental protection UV curable ink, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, magnesium hydroxide 1-2, Resorcinol bisglycidyl ether 11-14, isopropyl thioxanthone 5-8, Dyhard RU 100 2-3, tri (propylene glycol) diacrylate 10-12, polyester acrylate 12-15, polyether acrylate 10-12, dipentaerythritol acrylate 8-10, aluminate coupling agent DL-411 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. safety and environmental protection UV curable ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, nano diatomite powder, aluminum oxide, magnesium hydroxide, Resorcinol bisglycidyl ether, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except isopropyl thioxanthone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add isopropyl thioxanthone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618290.1A CN103666074B (en) | 2013-11-29 | 2013-11-29 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618290.1A CN103666074B (en) | 2013-11-29 | 2013-11-29 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666074A true CN103666074A (en) | 2014-03-26 |
| CN103666074B CN103666074B (en) | 2016-04-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310618290.1A Active CN103666074B (en) | 2013-11-29 | 2013-11-29 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
Country Status (1)
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| CN (1) | CN103666074B (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06157962A (en) * | 1992-07-09 | 1994-06-07 | Heidelberger Druckmas Ag | Ink especially uv-curing printing ink for offset printing and apparatus and method for drying this ink |
| JPH11140368A (en) * | 1997-11-05 | 1999-05-25 | Sakura Color Prod Corp | Ultraviolet-curing phosphorescent ink and process for printing inorganic material therewith |
| JP2992866B2 (en) * | 1994-08-08 | 1999-12-20 | 株式会社サクラクレパス | UV curable ink composition and method of printing inorganic material using the same |
| US6096797A (en) * | 1997-09-10 | 2000-08-01 | Basf Aktiengesellschaft | Radiation-curable binder for printing inks |
| JP2009275174A (en) * | 2008-05-16 | 2009-11-26 | Hitachi Maxell Ltd | Active energy ray-curable type ink composition and its cured product |
| CN102382508A (en) * | 2011-09-07 | 2012-03-21 | 张家港市威迪森油墨有限公司 | Printing ink for identifying electronic component by curing with ultraviolet light and preparation method thereof |
| CN102464919A (en) * | 2010-11-12 | 2012-05-23 | 惠州市华阳光学技术有限公司 | Optical color-changing flexo printing ink |
| CN102702855A (en) * | 2012-06-28 | 2012-10-03 | 中山市中益油墨涂料有限公司 | UV (Ultraviolet) offset printing ink and preparation method thereof |
| CN102863848A (en) * | 2012-09-03 | 2013-01-09 | 杭华油墨化学有限公司 | Ultraviolet-light-emitting diode (UV-LED) low-energy cured printing ink |
-
2013
- 2013-11-29 CN CN201310618290.1A patent/CN103666074B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06157962A (en) * | 1992-07-09 | 1994-06-07 | Heidelberger Druckmas Ag | Ink especially uv-curing printing ink for offset printing and apparatus and method for drying this ink |
| JP2992866B2 (en) * | 1994-08-08 | 1999-12-20 | 株式会社サクラクレパス | UV curable ink composition and method of printing inorganic material using the same |
| US6096797A (en) * | 1997-09-10 | 2000-08-01 | Basf Aktiengesellschaft | Radiation-curable binder for printing inks |
| JPH11140368A (en) * | 1997-11-05 | 1999-05-25 | Sakura Color Prod Corp | Ultraviolet-curing phosphorescent ink and process for printing inorganic material therewith |
| JP2009275174A (en) * | 2008-05-16 | 2009-11-26 | Hitachi Maxell Ltd | Active energy ray-curable type ink composition and its cured product |
| CN102464919A (en) * | 2010-11-12 | 2012-05-23 | 惠州市华阳光学技术有限公司 | Optical color-changing flexo printing ink |
| CN102382508A (en) * | 2011-09-07 | 2012-03-21 | 张家港市威迪森油墨有限公司 | Printing ink for identifying electronic component by curing with ultraviolet light and preparation method thereof |
| CN102702855A (en) * | 2012-06-28 | 2012-10-03 | 中山市中益油墨涂料有限公司 | UV (Ultraviolet) offset printing ink and preparation method thereof |
| CN102863848A (en) * | 2012-09-03 | 2013-01-09 | 杭华油墨化学有限公司 | Ultraviolet-light-emitting diode (UV-LED) low-energy cured printing ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666074B (en) | 2016-04-27 |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Du Yaoxin Inventor before: Dong Liangqing |
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| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160926 Address after: 515000, Guangdong Province, Chenghai District, Shantou Town, West Village Yao West Road Patentee after: GUANGDONG CHIHUI ENVIRONMENTAL PROTECTION PACKAGING CO.,LTD. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20160926 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: South Taibai town 243161 Anhui city of Ma'anshan province Dangtu County Xintai white road Patentee before: DANGTU KEHUI TRADE Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A safe and environmentally friendly UV curable ink and its preparation method Granted publication date: 20160427 Pledgee: Shantou Bay Rural Commercial Bank Co.,Ltd. Zhushi Sub branch Pledgor: GUANGDONG CHIHUI ENVIRONMENTAL PROTECTION PACKAGING CO.,LTD. Registration number: Y2025980004231 |