CN103666074A - Safe and environmental-friendly ultraviolet curing ink and preparation method thereof - Google Patents
Safe and environmental-friendly ultraviolet curing ink and preparation method thereof Download PDFInfo
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- CN103666074A CN103666074A CN201310618290.1A CN201310618290A CN103666074A CN 103666074 A CN103666074 A CN 103666074A CN 201310618290 A CN201310618290 A CN 201310618290A CN 103666074 A CN103666074 A CN 103666074A
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Abstract
The invention discloses safe and environmental-friendly ultraviolet curing ink which is characterized by being made from raw materials in parts by weight as follows: 1-3 parts of an organic pigment, 1-2 parts of nano diatomite in powder, 2-3 parts of aluminum oxide, 1-2 parts of magnesium hydroxide, 11-14 parts of resorcinol diglycidyl ether, 5-8 parts of isopropyl thioxanthone, 2-3 parts of dicyandiamide, 10-12 parts of tripropylene glycol diacrylate, 12-15 parts of polyester acrylate, 10-12 parts of polyether acrylate, 8-10 parts of dipentaerythritol hexaacrylate, 1-2 parts of an aluminic acid ester coupling agent DL-411 and 4-5 parts of an assistant. According to the safe and environment-friendly ultraviolet curing ink, the tenacity of the ink is improved by the assistant, the oil is dispersed uniformly, and the stability of the ink is maintained; components of an ink product contain no toxic solvent, VOC (volatile organic compounds) are not discharged, and the ultraviolet curing ink is environmental-friendly, excellent in performance and good in printability.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of safety and environmental protection UV curable ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.UV curable ink due in system containing solvent, there is efficient, wide adaptability, economy, energy-conservation, environmental friendliness, become tool novel ink with broad prospects for development.
Summary of the invention
The object of this invention is to provide a kind of safety and environmental protection UV curable ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A safety and environmental protection UV curable ink, is made by the raw material of following weight part: pigment dyestuff 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, magnesium hydroxide 1-2, Resorcinol bisglycidyl ether 11-14, isopropyl thioxanthone 5-8, Dyhard RU 100 2-3, tri (propylene glycol) diacrylate 10-12, polyester acrylate 12-15, polyether acrylate 10-12, dipentaerythritol acrylate 8-10, aluminate coupling agent DL-411 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Safety and environmental protection UV curable ink of the present invention, by following concrete steps, made: first add pigment dyestuff, nano diatomite powder, aluminum oxide, magnesium hydroxide, Resorcinol bisglycidyl ether, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except isopropyl thioxanthone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add isopropyl thioxanthone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; In each component of ink product of the present invention, not containing noxious solvent, without volatilizable organism (VOC), discharge, environmental friendliness, environmental protection, and excellent performance, printability is good.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A safety and environmental protection UV curable ink, by following weight part (kilogram) raw material make: pigment dyestuff 1, nano diatomite powder 1, aluminum oxide 2, magnesium hydroxide 1, Resorcinol bisglycidyl ether 11, isopropyl thioxanthone 5, Dyhard RU 100 2, tri (propylene glycol) diacrylate 10, polyester acrylate 12, polyether acrylate 10, dipentaerythritol acrylate 8, aluminate coupling agent DL-411 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, linking agent TAC2, polyisobutene 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, phenylformic acid amine 1, Viscoat 295 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Described safety and environmental protection UV curable ink, by following concrete steps, made: first add pigment dyestuff, nano diatomite powder, aluminum oxide, magnesium hydroxide, Resorcinol bisglycidyl ether, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except isopropyl thioxanthone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add isopropyl thioxanthone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a safety and environmental protection UV curable ink, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, nano diatomite powder 1-2, aluminum oxide 2-3, magnesium hydroxide 1-2, Resorcinol bisglycidyl ether 11-14, isopropyl thioxanthone 5-8, Dyhard RU 100 2-3, tri (propylene glycol) diacrylate 10-12, polyester acrylate 12-15, polyether acrylate 10-12, dipentaerythritol acrylate 8-10, aluminate coupling agent DL-411 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. safety and environmental protection UV curable ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, nano diatomite powder, aluminum oxide, magnesium hydroxide, Resorcinol bisglycidyl ether, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except isopropyl thioxanthone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add isopropyl thioxanthone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618290.1A CN103666074B (en) | 2013-11-29 | 2013-11-29 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618290.1A CN103666074B (en) | 2013-11-29 | 2013-11-29 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103666074A true CN103666074A (en) | 2014-03-26 |
| CN103666074B CN103666074B (en) | 2016-04-27 |
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| CN201310618290.1A Active CN103666074B (en) | 2013-11-29 | 2013-11-29 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
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Citations (9)
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|---|---|---|---|---|
| JPH06157962A (en) * | 1992-07-09 | 1994-06-07 | Heidelberger Druckmas Ag | Ink especially uv-curing printing ink for offset printing and apparatus and method for drying this ink |
| JPH11140368A (en) * | 1997-11-05 | 1999-05-25 | Sakura Color Prod Corp | Ultraviolet-curing phosphorescent ink and process for printing inorganic material therewith |
| JP2992866B2 (en) * | 1994-08-08 | 1999-12-20 | 株式会社サクラクレパス | UV curable ink composition and method of printing inorganic material using the same |
| US6096797A (en) * | 1997-09-10 | 2000-08-01 | Basf Aktiengesellschaft | Radiation-curable binder for printing inks |
| JP2009275174A (en) * | 2008-05-16 | 2009-11-26 | Hitachi Maxell Ltd | Active energy ray-curable type ink composition and its cured product |
| CN102382508A (en) * | 2011-09-07 | 2012-03-21 | 张家港市威迪森油墨有限公司 | Printing ink for identifying electronic component by curing with ultraviolet light and preparation method thereof |
| CN102464919A (en) * | 2010-11-12 | 2012-05-23 | 惠州市华阳光学技术有限公司 | Photochromic flexible printing ink |
| CN102702855A (en) * | 2012-06-28 | 2012-10-03 | 中山市中益油墨涂料有限公司 | UV (Ultraviolet) offset printing ink and preparation method thereof |
| CN102863848A (en) * | 2012-09-03 | 2013-01-09 | 杭华油墨化学有限公司 | Ultraviolet-light-emitting diode (UV-LED) low-energy cured printing ink |
-
2013
- 2013-11-29 CN CN201310618290.1A patent/CN103666074B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06157962A (en) * | 1992-07-09 | 1994-06-07 | Heidelberger Druckmas Ag | Ink especially uv-curing printing ink for offset printing and apparatus and method for drying this ink |
| JP2992866B2 (en) * | 1994-08-08 | 1999-12-20 | 株式会社サクラクレパス | UV curable ink composition and method of printing inorganic material using the same |
| US6096797A (en) * | 1997-09-10 | 2000-08-01 | Basf Aktiengesellschaft | Radiation-curable binder for printing inks |
| JPH11140368A (en) * | 1997-11-05 | 1999-05-25 | Sakura Color Prod Corp | Ultraviolet-curing phosphorescent ink and process for printing inorganic material therewith |
| JP2009275174A (en) * | 2008-05-16 | 2009-11-26 | Hitachi Maxell Ltd | Active energy ray-curable type ink composition and its cured product |
| CN102464919A (en) * | 2010-11-12 | 2012-05-23 | 惠州市华阳光学技术有限公司 | Photochromic flexible printing ink |
| CN102382508A (en) * | 2011-09-07 | 2012-03-21 | 张家港市威迪森油墨有限公司 | Printing ink for identifying electronic component by curing with ultraviolet light and preparation method thereof |
| CN102702855A (en) * | 2012-06-28 | 2012-10-03 | 中山市中益油墨涂料有限公司 | UV (Ultraviolet) offset printing ink and preparation method thereof |
| CN102863848A (en) * | 2012-09-03 | 2013-01-09 | 杭华油墨化学有限公司 | Ultraviolet-light-emitting diode (UV-LED) low-energy cured printing ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666074B (en) | 2016-04-27 |
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Inventor after: Du Yaoxin Inventor before: Dong Liangqing |
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Effective date of registration: 20160926 Address after: 515000, Guangdong Province, Chenghai District, Shantou Town, West Village Yao West Road Patentee after: GUANGDONG CHIHUI ENVIRONMENTAL PROTECTION PACKAGING CO.,LTD. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20160926 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: South Taibai town 243161 Anhui city of Ma'anshan province Dangtu County Xintai white road Patentee before: DANGTU KEHUI TRADE Co.,Ltd. |