CN103666040B - UV curable ink of a kind of good luster that flowed and preparation method thereof - Google Patents
UV curable ink of a kind of good luster that flowed and preparation method thereof Download PDFInfo
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- CN103666040B CN103666040B CN201310600462.2A CN201310600462A CN103666040B CN 103666040 B CN103666040 B CN 103666040B CN 201310600462 A CN201310600462 A CN 201310600462A CN 103666040 B CN103666040 B CN 103666040B
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Abstract
The invention discloses a kind of UV curable ink of the good luster that flowed, it is characterized in that, be made up of the raw material of following weight part: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS? 1-2, polyurethane acroleic acid fat 20-30, 2-hydroxy-2-methyl-Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyethers propylene 9-12, 2-hydroxypropyl acrylate 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5, auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink, ink solidification of the present invention is fast, color is gorgeous, good luster, mobility are good, printing performance good and solvent resistant shampooing.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of UV curable ink and preparation method thereof of the good luster that flowed.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can different-energy be produced, the monomer polymerization in different ink vehicle is become polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, solvent resistant, wear resisting property is good.In UV ink, light trigger is that one is subject to light activated compound, after absorb light is shone, be excited into free radical, and energy trasfer, to photosensitivity molecule or photocrosslinking agent, makes UV ink that photocuring reaction occur.Current UV ink has become a kind of more ripe ink technology, and its pollutant emission is almost nil.Except not containing solvent, UV ink also just like not easily scumming, the advantages such as site is clear, the bright-coloured light of mass colour, and chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide UV curable ink of a kind of good luster that flowed and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of UV curable ink of the good luster that flowed, be made up of the raw material of following weight part: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS1-2, polyurethane acroleic acid fat 20-30, 2-hydroxy-2-methyl-Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyethers propylene 9-12, 2-hydroxypropyl acrylate 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 10351-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV curable ink of the good luster that flowed of the present invention, be made up of following concrete steps: first add nano-calcium carbonate calcium powder, pigment dyestuff, ground dolomite, montmorillonite, titanate coupling agent TMC-TTS, polyurethane acroleic acid fat, mandarin oil, benzoin dimethylether, propenyl glycidyl ether, UV polyethers propylene, 2-hydroxypropyl acrylate, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2-hydroxy-2-methyl-Propiophenone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2-hydroxy-2-methyl-Propiophenone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; Ink solidification of the present invention is fast, color is gorgeous, good luster, mobility are good, printing performance good and solvent resistant shampooing.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of UV curable ink of the good luster that flowed, be made up of the raw material of following weight part: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS1-2, polyurethane acroleic acid fat 20-30, 2-hydroxy-2-methyl-Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyethers propylene 9-12, 2-hydroxypropyl acrylate 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, tea-polyphenol 2, neopentyl glycol 5, p-tert-butyl benzoic acid 1, oxidation inhibitor 10351,2-butoxy-ethanol 3, linking agent TAC2, ethoxylated trimethylolpropane triacrylate 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV curable ink of the good luster that flowed of the present invention, be made up of following concrete steps: first add nano-calcium carbonate calcium powder, pigment dyestuff, ground dolomite, montmorillonite, titanate coupling agent TMC-TTS, polyurethane acroleic acid fat, mandarin oil, benzoin dimethylether, propenyl glycidyl ether, UV polyethers propylene, 2-hydroxypropyl acrylate, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2-hydroxy-2-methyl-Propiophenone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2-hydroxy-2-methyl-Propiophenone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curable ink of the good luster that flowed, it is characterized in that, be prepared from by the raw material of following weight part: nano-calcium carbonate calcium powder 2-3, pigment dyestuff 1-2, ground dolomite 1-2, montmorillonite 1-2, titanate coupling agent TMC-TTS1-2, urethane acrylate 20-30, 2-hydroxy-2-methyl Propiophenone 6-8, mandarin oil 1-2, benzoin dimethylether 5-8, propenyl glycidyl ether 1-2, UV polyether acrylate 9-12, 2-hydroxypropyl acrylate 10-12, tri (propylene glycol) diacrylate 10-12, linking agent TAC1-2, 4, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol 3-4, trisnonylphenyl phosphite 4-6, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 10351-2, butoxy ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. the UV curable ink of the good luster that flowed according to claim 1, it is characterized in that, be made up of following concrete steps: first add nano-calcium carbonate calcium powder, pigment dyestuff, ground dolomite, montmorillonite, titanate coupling agent TMC-TTS, urethane acrylate, mandarin oil, benzoin dimethylether, propenyl glycidyl ether, UV polyether acrylate, 2-hydroxypropyl acrylate, tri (propylene glycol) diacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2-hydroxy-2-methyl Propiophenone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2-hydroxy-2-methyl-Propiophenone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600462.2A CN103666040B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good luster that flowed and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310600462.2A CN103666040B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good luster that flowed and preparation method thereof |
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| CN103666040A CN103666040A (en) | 2014-03-26 |
| CN103666040B true CN103666040B (en) | 2016-04-13 |
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Citations (7)
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| CN101292000A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Curable inkjet ink set and methods for inkjet printing |
| CN101291816A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Set of curable liquids and methods for inkjet printing |
| CN102369248A (en) * | 2009-04-08 | 2012-03-07 | 大日精化工业株式会社 | Color composition for pixel-forming ink, pigment dispersion liquid, pixel-forming ink, color filter, and production methods thereof |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103232751A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | UV (ultraviolet) curing ink and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310600462.2A patent/CN103666040B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101292000A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Curable inkjet ink set and methods for inkjet printing |
| CN101291816A (en) * | 2005-10-21 | 2008-10-22 | 爱克发印艺公司 | Set of curable liquids and methods for inkjet printing |
| CN102369248A (en) * | 2009-04-08 | 2012-03-07 | 大日精化工业株式会社 | Color composition for pixel-forming ink, pigment dispersion liquid, pixel-forming ink, color filter, and production methods thereof |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103232751A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | UV (ultraviolet) curing ink and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
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| CN103666040A (en) | 2014-03-26 |
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