CN103666038B - A kind of one-step print ultraviolet curing pearl ink and preparation method thereof - Google Patents
A kind of one-step print ultraviolet curing pearl ink and preparation method thereof Download PDFInfo
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- CN103666038B CN103666038B CN201310600459.0A CN201310600459A CN103666038B CN 103666038 B CN103666038 B CN 103666038B CN 201310600459 A CN201310600459 A CN 201310600459A CN 103666038 B CN103666038 B CN 103666038B
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Abstract
The invention discloses a kind of one-step print ultraviolet curing pearl ink, it is characterized in that, made by the raw material of following weight portion: organic pigment 1-2, E-12 epoxy resin 20-23, nanometer iron ore ground slag 1-2, bisphenol A epoxy acrylate 30-35, polyester acrylate 14-18, ethoxylated trimethylolpropane triacrylate 10-12,1173 light trigger 4-7, diamino diphenyl sulfone 5-7, cinnamon essential oil 1-2, antioxidant 1035? 2-3, auxiliary agent 4-5; Auxiliary agent of the present invention has improved the toughness of ink, makes distributes ink even, and has maintained the stability of ink; Ink of the present invention only needs one-step print, and ultraviolet light polymerization just can form pearl effect lucuriant in design, by screen painting mode be imprinted on gold and silver paperboard, above PVP card.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of one-step print ultraviolet curing pearl ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under ultraviolet ray is irradiated, utilizes the ultraviolet light of different wave length and energy to make ink film forming and dry ink. Utilize different ultraviolet spectras, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymer, so the look film of UV ink has good machinery and chemical property. The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, anti-wear performance is good. Ultraviolet curing pearl ink is a kind of screen printing ink, the irradiation of the uviol lamp of process specific wavelength forms pearl effect lucuriant in design, this ink can be widely used in high-grade packaging aspect, can be formulated into versicolor pearl ink according to customer requirement, its curing rate and adhesive force are all good. What use at present is generally solvent-borne type, and contaminated environment affect the shortcomings such as operating personnel are healthy, it is dry be formed as natural drying, need tens minutes, production efficiency is low.
Summary of the invention
The object of this invention is to provide a kind of one-step print ultraviolet curing pearl ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of one-step print ultraviolet curing pearl ink, is made up of the raw material of following weight portion: organic pigment 1-2, E-12 epoxy resin 20-23, nanometer iron ore ground slag 1-2, bisphenol A epoxy acrylate 30-35, polyester acrylate 14-18, ethoxylated trimethylolpropane triacrylate 10-12,1173 light trigger 4-7, diamino diphenyl sulfone 5-7, cinnamon essential oil 1-2, antioxidant 10352-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, Tea Polyphenols 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, antioxidant 10351-2,2-butoxy-ethanol 3-4, crosslinking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
One-step print ultraviolet curing pearl ink of the present invention, made by following concrete steps: first add organic pigment, E-12 epoxy resin, nanometer iron ore ground slag, bisphenol A epoxy acrylate, polyester acrylate, ethoxylated trimethylolpropane triacrylate to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 1173 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1173 light triggers, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Ink of the present invention only needs one-step print, and ultraviolet light polymerization just can form pearl effect lucuriant in design, by screen painting mode be imprinted on gold and silver paperboard, above PVP card.
Specific embodiments
Below by instantiation, the present invention is described in detail.
A kind of one-step print ultraviolet curing pearl ink, by following weight portion (kilogram) raw material make: organic pigment 1, E-12 epoxy resin 20, nanometer iron ore ground slag 1, bisphenol A epoxy acrylate 30, polyester acrylate 14, ethoxylated trimethylolpropane triacrylate 10,1173 light triggers 4, diamino diphenyl sulfone 5, cinnamon essential oil 1, antioxidant 10352, auxiliary agent 4;
Described auxiliary agent by following weight portion (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, Tea Polyphenols 2, neopentyl glycol 5, p-tert-butyl benzoic acid 1, antioxidant 10351,2-butoxy-ethanol 3, crosslinking agent TAC2, ethoxylated trimethylolpropane triacrylate 10, n-propyl gallate 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
One-step print ultraviolet curing pearl ink of the present invention, made by following concrete steps: first add organic pigment, E-12 epoxy resin, nanometer iron ore ground slag, bisphenol A epoxy acrylate, polyester acrylate, ethoxylated trimethylolpropane triacrylate to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 1173 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1173 light triggers, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. an one-step print ultraviolet curing pearl ink, it is characterized in that, be prepared from by the raw material of following weight portion: organic pigment 1-2, E-12 epoxy resin 20-23, nanometer iron ore ground slag 1-2, bisphenol A epoxy acrylate 30-35, polyester acrylate 14-18, ethoxylated trimethylolpropane triacrylate 10-12,1173 light trigger 4-7, diamino diphenyl sulfone 5-7, cinnamon essential oil 1-2, antioxidant 10352-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight portion: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, Tea Polyphenols 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, antioxidant 10351-2, butoxy ethanol 3-4, crosslinking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, n-propyl gallate 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. one-step print ultraviolet curing pearl ink according to claim 1, it is characterized in that, made by following concrete steps: first add organic pigment, E-12 epoxy resin, nanometer iron ore ground slag, bisphenol A epoxy acrylate, polyester acrylate, ethoxylated trimethylolpropane triacrylate to stir and evenly mix, be heated to 80-90 DEG C, stir 25-35 minute; Then add all the other residual components except 1173 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1173 light triggers, stirring reaction 40-50 minute, cooling after, grind obtain 20-40 μ m slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600459.0A CN103666038B (en) | 2013-11-25 | 2013-11-25 | A kind of one-step print ultraviolet curing pearl ink and preparation method thereof |
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| CN201310600459.0A CN103666038B (en) | 2013-11-25 | 2013-11-25 | A kind of one-step print ultraviolet curing pearl ink and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103666038A CN103666038A (en) | 2014-03-26 |
| CN103666038B true CN103666038B (en) | 2016-05-04 |
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| CN113072863A (en) * | 2021-03-25 | 2021-07-06 | 深圳Tcl数字技术有限公司 | Pre-coated metal plate, back plate, display device and manufacturing method of back plate |
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| CN102264545B (en) * | 2008-12-22 | 2015-05-20 | 技术解决顾问有限公司 | Flexographic printing process with wet on wet capability |
| CN102286230B (en) * | 2011-09-15 | 2013-10-09 | 哈尔滨大东方新材料科技股份有限公司 | Ultraviolet curable ink and preparation method thereof |
| CN103160168B (en) * | 2011-12-12 | 2014-12-10 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
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