CN103666025A - Metallic-luster printing ink and preparation method thereof - Google Patents
Metallic-luster printing ink and preparation method thereof Download PDFInfo
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- CN103666025A CN103666025A CN201310575045.7A CN201310575045A CN103666025A CN 103666025 A CN103666025 A CN 103666025A CN 201310575045 A CN201310575045 A CN 201310575045A CN 103666025 A CN103666025 A CN 103666025A
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- acid
- luster
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- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000002932 luster Substances 0.000 title abstract description 6
- 238000007639 printing Methods 0.000 title abstract description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000180 alkyd Polymers 0.000 claims abstract description 8
- -1 polysiloxane Polymers 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 7
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 4
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 7
- 235000010469 Glycine max Nutrition 0.000 claims description 7
- 244000068988 Glycine max Species 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- APZPSKFMSWZPKL-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CO)CO APZPSKFMSWZPKL-UHFFFAOYSA-N 0.000 claims description 6
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- FUPMSLTYEIZSLZ-UHFFFAOYSA-N cobalt;naphthalene-1-carboxylic acid Chemical compound [Co].C1=CC=C2C(C(=O)O)=CC=CC2=C1 FUPMSLTYEIZSLZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 238000005502 peroxidation Methods 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 6
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 2
- GKZPEYIPJQHPNC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GKZPEYIPJQHPNC-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 abstract 1
- 244000046052 Phaseolus vulgaris Species 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 abstract 1
- NRLCNVYHWRDHTJ-UHFFFAOYSA-L cobalt(2+);naphthalene-1-carboxylate Chemical compound [Co+2].C1=CC=C2C(C(=O)[O-])=CC=CC2=C1.C1=CC=C2C(C(=O)[O-])=CC=CC2=C1 NRLCNVYHWRDHTJ-UHFFFAOYSA-L 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- ZNVWLZGTXSHPMH-UHFFFAOYSA-N tert-butyl 3-hydroperoxy-2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)COO ZNVWLZGTXSHPMH-UHFFFAOYSA-N 0.000 abstract 1
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a metallic-luster printing ink which is prepared from the following raw materials in parts by weight: 2-3 parts of cobalt naphthoate, 4-6 parts of industrial glycerol, 1-2 parts of lithium hydroxide, 5-7 parts of m-phthalic acid, 2-3 parts of zinc oxide, 1-2 parts of mica powder, 20-23 parts of bean oil alkyd resin, 20-25 parts of methacrylate, 3-4 parts of sulfhydryl polysiloxane, 10-12 parts of bis pentaerythritol hexaacrylate, 8-10 parts of vinyl acetate, 1-2 parts of monobutyl tin oxide, 1-2 parts of tert-butyl peroxylpivalate, 3-4 parts of organic pigment and 4-5 parts of assistant. The ink has the characteristics of favorable luster, high adhesive force, oil resistance, wear resistance, water resistance, weather resistance and moderate hardness, and has metallic luster. The assistant can form a protective film on the ink surface to isolate air, prevent water and other molecules in air from corroding the surfaces of the ink and sprayed objects and resist oxidation, so that the color can be bright permanently; and the smoothness and wear resistance are enhanced, and the service time is prolonged.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of metalluster printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of metalluster printing-ink and preparation method thereof, this ink has metalluster, and electrical isolation is water-fast.
Technical scheme of the present invention is as follows:
A metalluster printing-ink, is characterized in that being made by the raw material of following weight part: naphthoic acid cobalt 2-3, industry glycerol 4-6, lithium hydroxide 1-2, m-phthalic acid 5-7, zinc oxide 2-3, mica powder 1-2, soybean alkyd 20-23, methacrylic ester 20-25, sulfydryl polysiloxane 3-4, double pentaerythritol methacrylate 10-12, vinyl acetate 8-10, Mono-n-butyltin 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described metalluster printing-ink, it is characterized in that comprising the following steps: by industry glycerol, lithium hydroxide, m-phthalic acid, soybean alkyd, methacrylic ester, sulfydryl polysiloxane mixes, under 1100-1400 rev/min of stirring, add naphthoic acid cobalt, Mono-n-butyltin, the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-7 ℃/minute is heated to 70-90 ℃, add zinc oxide, double pentaerythritol methacrylate, vinyl acetate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, it is beneficial effect of the present invention
It is base material that ink of the present invention is used soybean alkyd, methacrylic ester, adds other monomers simultaneously, and the ink obtaining has good luster, strong adhesion, oil resistant, wear-resisting, water-fast, weather, feature that hardness is moderate; By using zinc oxide, make ink there is metalluster; Light degree of the present invention is high, lovely luster, and preparation method is simple simultaneously, and preparation time is short.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A metalluster printing-ink, by following weight part (kilogram) raw material make: naphthoic acid cobalt 2.5, industry glycerol 5, lithium hydroxide 1.5, m-phthalic acid 6, zinc oxide 2.5, mica powder 1.5, soybean alkyd 22, methacrylic ester 23, sulfydryl polysiloxane 3.5, double pentaerythritol methacrylate 11, vinyl acetate 9, Mono-n-butyltin 1.5, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described metalluster printing-ink, comprise the following steps: by industry glycerol, lithium hydroxide, m-phthalic acid, soybean alkyd, methacrylic ester, sulfydryl polysiloxane mixes, under 1300 revs/min of stirrings, add naphthoic acid cobalt, Mono-n-butyltin, the peroxidation trimethylacetic acid tert-butyl ester, with the speed of 6 ℃/minute, be heated to 80 ℃, add zinc oxide, double pentaerythritol methacrylate, vinyl acetate, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.8 hours, grinding distribution becomes the slurry of 30 μ m, it is beneficial effect of the present invention
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a metalluster printing-ink, is characterized in that being made by the raw material of following weight part: naphthoic acid cobalt 2-3, industry glycerol 4-6, lithium hydroxide 1-2, m-phthalic acid 5-7, zinc oxide 2-3, mica powder 1-2, soybean alkyd 20-23, methacrylic ester 20-25, sulfydryl polysiloxane 3-4, double pentaerythritol methacrylate 10-12, vinyl acetate 8-10, Mono-n-butyltin 1-2, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of metalluster printing-ink according to claim 1, it is characterized in that comprising the following steps: by industry glycerol, lithium hydroxide, m-phthalic acid, soybean alkyd, methacrylic ester, sulfydryl polysiloxane mixes, under 1100-1400 rev/min of stirring, add naphthoic acid cobalt, Mono-n-butyltin, the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-7 ℃/minute is heated to 70-90 ℃, add zinc oxide, double pentaerythritol methacrylate, vinyl acetate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575045.7A CN103666025A (en) | 2013-11-18 | 2013-11-18 | Metallic-luster printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575045.7A CN103666025A (en) | 2013-11-18 | 2013-11-18 | Metallic-luster printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666025A true CN103666025A (en) | 2014-03-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310575045.7A Pending CN103666025A (en) | 2013-11-18 | 2013-11-18 | Metallic-luster printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666025A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349778A (en) * | 2016-08-25 | 2017-01-25 | 阜南县天亿工艺品有限公司 | Low-shrinking-percentage light-aging-resistant inorganic-organic composite coating for weaving artware |
| CN111607098A (en) * | 2020-05-22 | 2020-09-01 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
-
2013
- 2013-11-18 CN CN201310575045.7A patent/CN103666025A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349778A (en) * | 2016-08-25 | 2017-01-25 | 阜南县天亿工艺品有限公司 | Low-shrinking-percentage light-aging-resistant inorganic-organic composite coating for weaving artware |
| CN111607098A (en) * | 2020-05-22 | 2020-09-01 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20140326 |