CN103555058A - Epoxy resin-based light ageing-resistant printing ink and preparation method thereof - Google Patents
Epoxy resin-based light ageing-resistant printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN103555058A CN103555058A CN201310523435.XA CN201310523435A CN103555058A CN 103555058 A CN103555058 A CN 103555058A CN 201310523435 A CN201310523435 A CN 201310523435A CN 103555058 A CN103555058 A CN 103555058A
- Authority
- CN
- China
- Prior art keywords
- parts
- epoxy resin
- printing ink
- ethylene glycol
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses epoxy resin-based light ageing-resistant printing ink. The epoxy resin-based light ageing-resistant printing ink is prepared from the following raw materials in parts by weight: 10-12 parts of 1,4 butanediol, 4-5 parts of ethylene glycol, 40-60 parts of E-12 epoxy resin, 4-6 parts of dibutyl phthalate, 1-2 parts of cyclohexanone peroxide, 9-12 parts of pentaerythritol, 3-4 parts of titanium dioxide powder, 5-8 parts of methyl methacrylate, 3-5 parts of ethylene glycol monoethyl ether acetate, 1-2 parts of isoamyl butyrate, 1-2 parts of cobalt naphthenate, 3-4 parts of organic pigments and 4-5 parts of auxiliaries. The printing ink provided by the invention has the characteristics of good toughness, high hardness, high firmness, good wear resistance and ultraviolet light ageing resistance, good dispersion and easiness for spraying. The printing ink provided by the invention is applicable to coating easy-wearing surfaces such as ground and an engineering vehicle. The auxiliary in the invention can form a protective film on the surface of the printing ink and is oxidation-resisting, so that the color is permanently bright; moreover, the smoothness and the wear resistance are improved, and the using time is prolonged.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of epoxy resin-matrix light aging resisting printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink is influential to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of epoxy resin-matrix light aging resisting printing-ink and preparation method thereof, this ink is wear-resisting, light aging resisting.
Technical scheme of the present invention is as follows:
A kind of epoxy resin-matrix light aging resisting printing-ink, it is characterized in that being made by the raw material of following weight part: Isosorbide-5-Nitrae butyleneglycol 10-12, ethylene glycol 4-5, E-12 epoxy resin 40-60, dibutyl phthalate 4-6, cyclohexanone peroxide 1-2, tetramethylolmethane 9-12, titanium dioxide 3-4, methyl methacrylate 5-8, ethylene glycol ether acetate 3-5, isoamyl butyrate 1-2, cobalt naphthenate 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described epoxy resin-matrix light aging resisting printing-ink, it is characterized in that comprising the following steps: by 1, 4 butyleneglycols, ethylene glycol, E-12 epoxy resin, dibutyl phthalate, tetramethylolmethane, ethylene glycol ether acetate mixes, under 1000-1400 rev/min of stirring, add cyclohexanone peroxide, cobalt naphthenate, speed with 5-8 ℃/minute is heated to 60-80 ℃, add methyl methacrylate, isoamyl butyrate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
It is base material that ink of the present invention is used E-12 epoxy resin, and in conjunction with adding titanium dioxide, the ink obtaining has good toughness, hardness is high, fastness is high feature, and wear resistance and preventing ultraviolet aging resistance are fine, and good dispersity, and spraying is easy; Printing ink producing cost of the present invention is low, and production efficiency is high, is applicable to the application on the surfaces easy to wear such as ground, engineering truck.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A kind of epoxy resin-matrix light aging resisting printing-ink, by following weight part (kilogram) raw material make: Isosorbide-5-Nitrae butyleneglycol 11, ethylene glycol 4.5, E-12 epoxy resin 50, dibutyl phthalate 5, cyclohexanone peroxide 1.5, tetramethylolmethane 11, titanium dioxide 3.5, methyl methacrylate 7, ethylene glycol ether acetate 4, isoamyl butyrate 1.5, cobalt naphthenate 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described epoxy resin-matrix light aging resisting printing-ink, comprise the following steps: by 1,4 butyleneglycols, ethylene glycol, E-12 epoxy resin, dibutyl phthalate, tetramethylolmethane, ethylene glycol ether acetate mix, under 120 revs/min of stirrings, add cyclohexanone peroxide, cobalt naphthenate, with the speed of 7 ℃/minute, be heated to 70 ℃, add methyl methacrylate, isoamyl butyrate, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 2.3 hours, grinding distribution becomes the slurry of 30 μ m, obtains.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. an epoxy resin-matrix light aging resisting printing-ink, it is characterized in that being made by the raw material of following weight part: Isosorbide-5-Nitrae butyleneglycol 10-12, ethylene glycol 4-5, E-12 epoxy resin 40-60, dibutyl phthalate 4-6, cyclohexanone peroxide 1-2, tetramethylolmethane 9-12, titanium dioxide 3-4, methyl methacrylate 5-8, ethylene glycol ether acetate 3-5, isoamyl butyrate 1-2, cobalt naphthenate 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of epoxy resin-matrix light aging resisting printing-ink according to claim 1, it is characterized in that comprising the following steps: by 1, 4 butyleneglycols, ethylene glycol, E-12 epoxy resin, dibutyl phthalate, tetramethylolmethane, ethylene glycol ether acetate mixes, under 1000-1400 rev/min of stirring, add cyclohexanone peroxide, cobalt naphthenate, speed with 5-8 ℃/minute is heated to 60-80 ℃, add methyl methacrylate, isoamyl butyrate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 2-2.5 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310523435.XA CN103555058A (en) | 2013-10-30 | 2013-10-30 | Epoxy resin-based light ageing-resistant printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310523435.XA CN103555058A (en) | 2013-10-30 | 2013-10-30 | Epoxy resin-based light ageing-resistant printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103555058A true CN103555058A (en) | 2014-02-05 |
Family
ID=50009432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310523435.XA Pending CN103555058A (en) | 2013-10-30 | 2013-10-30 | Epoxy resin-based light ageing-resistant printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103555058A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865331A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Flexible ageing-resistant printing ink and preparation method thereof |
| CN104292965A (en) * | 2014-11-10 | 2015-01-21 | 合肥宏图彩印有限公司 | High-temperature-resistant printing ink with fruit flavor and preparation method thereof |
| CN108329845A (en) * | 2018-03-09 | 2018-07-27 | 海南鑫申绿色建筑科技有限公司 | A kind of assembled wall board adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687259A (en) * | 2005-04-12 | 2005-10-26 | 王崇高 | Dedicated printing ink for electroplating products and preparation method thereof |
| CN1865361A (en) * | 2006-04-27 | 2006-11-22 | 兰州理工大学 | Silk screen branding iron anticorrosion printing ink and its preparation method |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN103102743A (en) * | 2012-12-12 | 2013-05-15 | 张家港威迪森化学有限公司 | Plastic ink and preparation method thereof |
-
2013
- 2013-10-30 CN CN201310523435.XA patent/CN103555058A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687259A (en) * | 2005-04-12 | 2005-10-26 | 王崇高 | Dedicated printing ink for electroplating products and preparation method thereof |
| CN1865361A (en) * | 2006-04-27 | 2006-11-22 | 兰州理工大学 | Silk screen branding iron anticorrosion printing ink and its preparation method |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN103102743A (en) * | 2012-12-12 | 2013-05-15 | 张家港威迪森化学有限公司 | Plastic ink and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865331A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Flexible ageing-resistant printing ink and preparation method thereof |
| CN104292965A (en) * | 2014-11-10 | 2015-01-21 | 合肥宏图彩印有限公司 | High-temperature-resistant printing ink with fruit flavor and preparation method thereof |
| CN108329845A (en) * | 2018-03-09 | 2018-07-27 | 海南鑫申绿色建筑科技有限公司 | A kind of assembled wall board adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103131298B (en) | A kind of Flame Retardant Powder Coatings containing hydration zinc borate | |
| CN103555053A (en) | UV curable offset printing ink and preparation method thereof | |
| CN103555058A (en) | Epoxy resin-based light ageing-resistant printing ink and preparation method thereof | |
| CN103642305A (en) | High-bonding printing ink and preparation method thereof | |
| CN103666093A (en) | Fluorocarbon-resin-base printing ink and preparation method thereof | |
| CN103804988A (en) | Heat-resistant and oxidation-resistant printing ink and preparation method thereof | |
| CN110669427A (en) | Two-component water-based UV coating, preparation method and application thereof, and coating piece | |
| CN103666089A (en) | Heat-resistant oxidation-resistant printing ink and preparation method thereof | |
| CN103666094B (en) | A kind of printing-ink and its preparation method | |
| CN103865330B (en) | A kind of glassine paper rosin base gravure ink and preparation method thereof | |
| CN103666084A (en) | Durable printing ink and preparation method thereof | |
| CN103555052A (en) | High-lubricity printing ink and preparation method thereof | |
| CN103865326A (en) | Printing ink for surface of light-resistant metal and preparation method thereof | |
| CN103666025A (en) | Metallic-luster printing ink and preparation method thereof | |
| CN103525196A (en) | Inkjet printing ink and preparation method thereof | |
| CN103555060A (en) | Quick-drying printing ink and preparation method thereof | |
| CN103666024B (en) | Printing-ink and preparation method thereof | |
| CN103865323B (en) | Wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof | |
| CN103642312A (en) | Printing ink and preparation method thereof | |
| CN103666083A (en) | High-printability printing ink and preparation method thereof | |
| CN103952032A (en) | Heat resistant oxidation resistant printing ink and its preparation method | |
| CN103666085A (en) | High-fastness fast-curing printing ink and preparation method thereof | |
| CN103205177B (en) | A kind of preparation method of the powder coating containing dibutyl phthalate | |
| CN103555061A (en) | IMD (In-Mold Decoration) printing ink and preparation method thereof | |
| CN103725175B (en) | A kind of thick-film modified alkyd paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140205 |