CN103865323B - Wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof - Google Patents
Wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof Download PDFInfo
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- CN103865323B CN103865323B CN201410067519.1A CN201410067519A CN103865323B CN 103865323 B CN103865323 B CN 103865323B CN 201410067519 A CN201410067519 A CN 201410067519A CN 103865323 B CN103865323 B CN 103865323B
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Abstract
The wear-resisting printing-ink of a kind of polymolecularity, is made up of the raw material of following weight part: polyester acrylate 24-28, methyl-etherified aminoresin 14-18, Whitfield's ointment 2-3, ultra-fine barium sulfate 6-9, trimeric cyanamide 20-24, glycerine 4-6, dipentaerythritol acrylate 16-19, Trifluoroacetic Acid Ethyl Ester 5-8, glycidyl methacrylate 10-12, peroxidation trimethylacetic acid tert-butyl ester 1-2, Mono-n-butyltin 1-2, pigment dyestuff 3-4, auxiliary agent 4-5.Ink of the present invention, by using ultra-fine barium sulfate, trimeric cyanamide list, glycerine, effectively improves dispersiveness, the oilness of resin ink, and not sticky ink roller, improves print speed and quality, may be used for code-spraying printing, roller coating.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, anti-oxidant, makes color bright-coloured lastingly, and improves slickness, wear resistance, extend working time.
Description
Technical field
The invention belongs to printing ink paint field, particularly relate to wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof.
Background technology
The color (form and aspect) of ink, body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Some resins and solvent or water etc. make low-melting ink vehicle.These are all decide according to the object of printing and stock, printing process, the type of printing plate and drying means etc.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study to harm as far as possible little, that production efficiency is high, environmental friendliness, cost are low ink have profound significance.
Summary of the invention
The object of the present invention is to provide wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof, this distributes ink is good, printing quality is high.
Technical scheme of the present invention is as follows:
The wear-resisting printing-ink of a kind of polymolecularity, is characterized in that being made up of the raw material of following weight part: polyester acrylate 24-28, methyl-etherified aminoresin 14-18, Whitfield's ointment 2-3, ultra-fine barium sulfate 6-9, trimeric cyanamide 20-24, glycerine 4-6, dipentaerythritol acrylate 16-19, Trifluoroacetic Acid Ethyl Ester 5-8, glycidyl methacrylate 10-12, peroxidation trimethylacetic acid tert-butyl ester 1-2, Mono-n-butyltin 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, phytic acid 1-2, morpholine 3-4, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 3-4, vinyl acetate 2-3, oxidation inhibitor 10352-3, linking agent TAC1-2, ethanol 20-24; Preparation method is by Silane coupling reagent KH-570, phytic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stir 30-40 minutes, to obtain final product.
The preparation method of the wear-resisting printing-ink of described polymolecularity, it is characterized in that comprising the following steps: by polyester acrylate, methyl-etherified aminoresin, Whitfield's ointment, trimeric cyanamide, glycerine, Trifluoroacetic Acid Ethyl Ester mixes, under stirring at 1200-1500 rev/min, 60-80 DEG C is heated to the speed of 6-8 DEG C/minute, add the peroxidation trimethylacetic acid tert-butyl ester, Mono-n-butyltin, stirring reaction 15-20 minute, add dipentaerythritol acrylate, glycidyl methacrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μm, obtain.
Beneficial effect of the present invention
Ink of the present invention, by using ultra-fine barium sulfate, trimeric cyanamide list, glycerine, effectively improves dispersiveness, the oilness of resin ink, and not sticky ink roller, improves print speed and quality, may be used for code-spraying printing, roller coating.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, and isolated air, prevents the surface of water and other molecule etch resistant ink and painting objects in air, anti-oxidant, makes color bright-coloured lastingly, and improves slickness, wear resistance, extends working time.
Embodiment
The wear-resisting printing-ink of a kind of polymolecularity, is made up of the raw material of following weight part (kilogram): polyester acrylate 26, methyl-etherified aminoresin 16, Whitfield's ointment 2.5, ultra-fine barium sulfate 8, trimeric cyanamide 22, glycerine 5, dipentaerythritol acrylate 17, Trifluoroacetic Acid Ethyl Ester 7, glycidyl methacrylate 11, the peroxidation trimethylacetic acid tert-butyl ester 1.5, Mono-n-butyltin 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): Silane coupling reagent KH-570 2.5, phytic acid 1.5, morpholine 3.5, methacrylic acid-2-hydroxy methacrylate 2.5, neopentyl glycol 3.5, vinyl acetate 2.5, oxidation inhibitor 10352.5, linking agent TAC1.5, ethanol 22; Preparation method is by Silane coupling reagent KH-570, phytic acid, ethanol mixing, is heated to 65 DEG C, stirs after 26 minutes, then add other remaining component, be warming up to 84 DEG C, stir 34 minutes, to obtain final product.
The preparation method of the wear-resisting printing-ink of described polymolecularity, comprise the following steps: by polyester acrylate, methyl-etherified aminoresin, Whitfield's ointment, trimeric cyanamide, glycerine, Trifluoroacetic Acid Ethyl Ester mixes, under stirring at 1300 revs/min, 70 DEG C are heated to the speed of 7 DEG C/minute, add the peroxidation trimethylacetic acid tert-butyl ester, Mono-n-butyltin, stirring reaction 17 minutes, add dipentaerythritol acrylate, glycidyl methacrylate, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μm, obtain.
Ink quality of the present invention is homogeneous, tinting strength, adhere firmly degree, and viscosity, first dryness and other performances reach the requirement of QB/T2024-94 standard.
Claims (1)
1. the wear-resisting printing-ink of polymolecularity, is characterized in that being made up of the raw material of following weight part: polyester acrylate 24-28, methyl-etherified aminoresin 14-18, Whitfield's ointment 2-3, ultra-fine barium sulfate 6-9, trimeric cyanamide 20-24, glycerine 4-6, dipentaerythritol acrylate 16-19, Trifluoroacetic Acid Ethyl Ester 5-8, glycidyl methacrylate 10-12, peroxidation trimethylacetic acid tert-butyl ester 1-2, Mono-n-butyltin 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, phytic acid 1-2, morpholine 3-4, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 3-4, vinyl acetate 2-3, oxidation inhibitor 10352-3, linking agent TAC1-2, ethanol 20-24;
The preparation method of described auxiliary agent is by Silane coupling reagent KH-570, phytic acid, ethanol mixing, is heated to 60-70 DEG C, stirs after 20-30 minute, then add other remaining component, be warming up to 80-85 DEG C, stir 30-40 minutes, to obtain final product;
The preparation method of the wear-resisting printing-ink of described polymolecularity comprises the following steps: by polyester acrylate, methyl-etherified aminoresin, Whitfield's ointment, trimeric cyanamide, glycerine, Trifluoroacetic Acid Ethyl Ester mixes, under stirring at 1200-1500 rev/min, 60-80 DEG C is heated to the speed of 6-8 DEG C/minute, add the peroxidation trimethylacetic acid tert-butyl ester, Mono-n-butyltin, stirring reaction 15-20 minute, add dipentaerythritol acrylate, glycidyl methacrylate, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μm, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410067519.1A CN103865323B (en) | 2014-02-27 | 2014-02-27 | Wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410067519.1A CN103865323B (en) | 2014-02-27 | 2014-02-27 | Wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103865323A CN103865323A (en) | 2014-06-18 |
| CN103865323B true CN103865323B (en) | 2016-04-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410067519.1A Active CN103865323B (en) | 2014-02-27 | 2014-02-27 | Wear-resisting printing-ink of a kind of polymolecularity and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194470A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠德美过滤技术有限公司 | Anti-abrasive plant printing ink |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004256726A (en) * | 2003-02-27 | 2004-09-16 | Kansai Paint Co Ltd | Ink composition of white pigment |
| CN101326124B (en) * | 2005-12-16 | 2014-09-10 | 堺化学工业株式会社 | Ultrafine barium sulfate particle, water-based coating composition and water-based ink composition |
| CN103555052A (en) * | 2013-10-30 | 2014-02-05 | 合肥市华美光电科技有限公司 | High-lubricity printing ink and preparation method thereof |
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Address after: Seven road 236112 Anhui city in Fuyang Province Economic Development Zone No. 99 Ying Ying Patentee after: Yingmei Polytron Technologies Inc, Anhui Address before: Seven road 236112 Anhui city in Fuyang Province Economic Development Zone No. 99 Ying Ying Patentee before: ANHUI YINGMEI COLOR PRINTING & PACKAGING CO., LTD. |