CN103666089A - Heat-resistant oxidation-resistant printing ink and preparation method thereof - Google Patents
Heat-resistant oxidation-resistant printing ink and preparation method thereof Download PDFInfo
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- CN103666089A CN103666089A CN201310575001.4A CN201310575001A CN103666089A CN 103666089 A CN103666089 A CN 103666089A CN 201310575001 A CN201310575001 A CN 201310575001A CN 103666089 A CN103666089 A CN 103666089A
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- 230000003647 oxidation Effects 0.000 title claims abstract description 9
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims description 10
- 238000007639 printing Methods 0.000 title abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 21
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 15
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920003180 amino resin Polymers 0.000 claims abstract description 8
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 7
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 12
- 229910000077 silane Inorganic materials 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920003987 resole Polymers 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- -1 carbon alcohols ester Chemical class 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 238000005502 peroxidation Methods 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 6
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 230000003628 erosive effect Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 235000004426 flaxseed Nutrition 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to heat-resistant oxidation-resistant printing ink which is prepared from the following raw materials in parts by weight: 30-34 parts of phenolic resin, 13-15 parts of linseed alkyd resin, 6-8 parts of ethylene glycol, 3-5 parts of ethanolamine, 10-12 parts of dichloromethane, 20-30 parts of amino resin, 6-9 parts of cyclohexanone, 1-2 parts of silane coupling agent KH-550, 1-2 parts of glycidyl methacrylate, 2-3 parts of bistetradecyl ester, 1-2 parts of tert-butyl peroxypivalate, 1-2 parts of cobalt naphthenate, 3-4 parts of organic pigment and 4-5 parts of assistant. The ink provided by the invention has the characteristics of high temperature resistance, oil resistance, water resistance, oxidation resistance, high hardness and favorable fastness, and is applicable to printing of products working in harsh environments such as kitchen utensils, cables, pump bodies and the like; the assistant provided by the invention can form a protecting film on the surface of the ink, thereby isolating air, preventing water and other molecules in the atmosphere from eroding the surfaces of the ink and ink-coated objects, resisting oxidation, permanently keeping a brilliant color and improving the smoothness and wear resistance.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of heat-resistant oxidized printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of heat-resistant oxidized printing-ink and preparation method thereof, this ink is heat-resisting, resistance to oxidation.
Technical scheme of the present invention is as follows:
A heat-resistant oxidized printing-ink, is characterized in that being made by the raw material of following weight part: resol 30-34, oleum lini Synolac 13-15, ethylene glycol 6-8, thanomin 3-5, methylene dichloride 10-12, aminoresin 20-30, cyclohexanone 6-9, silane resin acceptor kh-550 1-2, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, peroxidation trimethylacetic acid tert-butyl ester 1-2, cobalt naphthenate 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described heat-resistant oxidized printing-ink, it is characterized in that comprising the following steps: by resol, ethylene glycol, thanomin, methylene dichloride, cyclohexanone, glycidyl methacrylate is mixed, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add aminoresin, the peroxidation trimethylacetic acid tert-butyl ester, cobalt naphthenate, stirring reaction 10-20 minute, add silane resin acceptor kh-550, two ten four carbon alcohols esters, oleum lini Synolac, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention is used the monomer polymerizations such as resol, aminoresin, that the ink obtaining has is high temperature resistant, oil resistant, water-fast, resistance to oxidation, hardness is high, fastness is good feature, is applicable to the product printing that kitchen utensils, cable, the pump housing etc. are worked under severe environment; Printing ink producing cost of the present invention is low, and production efficiency is high.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A heat-resistant oxidized printing-ink, by following weight part (kilogram) raw material make: resol 33, oleum lini Synolac 14, ethylene glycol 7, thanomin 4, methylene dichloride 11, aminoresin 25, cyclohexanone 7, silane resin acceptor kh-550 1.5, glycidyl methacrylate 1.5, two ten four carbon alcohols esters 2.5, the peroxidation trimethylacetic acid tert-butyl ester 1.5, cobalt naphthenate 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described heat-resistant oxidized printing-ink, comprise the following steps: by resol, ethylene glycol, thanomin, methylene dichloride, cyclohexanone, glycidyl methacrylate is mixed, under 1200 revs/min of stirrings, with the speed of 7 ℃/minute, be heated to 70 ℃, add aminoresin, the peroxidation trimethylacetic acid tert-butyl ester, cobalt naphthenate, stirring reaction 15 minutes, add silane resin acceptor kh-550, two ten four carbon alcohols esters, oleum lini Synolac, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a heat-resistant oxidized printing-ink, is characterized in that being made by the raw material of following weight part: resol 30-34, oleum lini Synolac 13-15, ethylene glycol 6-8, thanomin 3-5, methylene dichloride 10-12, aminoresin 20-30, cyclohexanone 6-9, silane resin acceptor kh-550 1-2, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, peroxidation trimethylacetic acid tert-butyl ester 1-2, cobalt naphthenate 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of heat-resistant oxidized printing-ink according to claim 1, it is characterized in that comprising the following steps: by resol, ethylene glycol, thanomin, methylene dichloride, cyclohexanone, glycidyl methacrylate is mixed, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add aminoresin, the peroxidation trimethylacetic acid tert-butyl ester, cobalt naphthenate, stirring reaction 10-20 minute, add silane resin acceptor kh-550, two ten four carbon alcohols esters, oleum lini Synolac, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575001.4A CN103666089A (en) | 2013-11-18 | 2013-11-18 | Heat-resistant oxidation-resistant printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575001.4A CN103666089A (en) | 2013-11-18 | 2013-11-18 | Heat-resistant oxidation-resistant printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666089A true CN103666089A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310575001.4A Pending CN103666089A (en) | 2013-11-18 | 2013-11-18 | Heat-resistant oxidation-resistant printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666089A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403408A (en) * | 2014-11-10 | 2015-03-11 | 合肥宏图彩印有限公司 | Wear and oxidation resistant printing ink and manufacturing method thereof |
| CN105968946A (en) * | 2016-06-30 | 2016-09-28 | 安徽智博新材料科技有限公司 | Printing ink special for food packaging bag and preparation method of printing ink |
| CN106118232A (en) * | 2016-06-30 | 2016-11-16 | 安徽智博新材料科技有限公司 | A kind of medical equipment printing-ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN103342922A (en) * | 2013-07-30 | 2013-10-09 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
-
2013
- 2013-11-18 CN CN201310575001.4A patent/CN103666089A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN103342922A (en) * | 2013-07-30 | 2013-10-09 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403408A (en) * | 2014-11-10 | 2015-03-11 | 合肥宏图彩印有限公司 | Wear and oxidation resistant printing ink and manufacturing method thereof |
| CN105968946A (en) * | 2016-06-30 | 2016-09-28 | 安徽智博新材料科技有限公司 | Printing ink special for food packaging bag and preparation method of printing ink |
| CN106118232A (en) * | 2016-06-30 | 2016-11-16 | 安徽智博新材料科技有限公司 | A kind of medical equipment printing-ink and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20140326 |