CN103666089A - Heat-resistant oxidation-resistant printing ink and preparation method thereof - Google Patents
Heat-resistant oxidation-resistant printing ink and preparation method thereof Download PDFInfo
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- CN103666089A CN103666089A CN201310575001.4A CN201310575001A CN103666089A CN 103666089 A CN103666089 A CN 103666089A CN 201310575001 A CN201310575001 A CN 201310575001A CN 103666089 A CN103666089 A CN 103666089A
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Abstract
The invention relates to heat-resistant oxidation-resistant printing ink which is prepared from the following raw materials in parts by weight: 30-34 parts of phenolic resin, 13-15 parts of linseed alkyd resin, 6-8 parts of ethylene glycol, 3-5 parts of ethanolamine, 10-12 parts of dichloromethane, 20-30 parts of amino resin, 6-9 parts of cyclohexanone, 1-2 parts of silane coupling agent KH-550, 1-2 parts of glycidyl methacrylate, 2-3 parts of bistetradecyl ester, 1-2 parts of tert-butyl peroxypivalate, 1-2 parts of cobalt naphthenate, 3-4 parts of organic pigment and 4-5 parts of assistant. The ink provided by the invention has the characteristics of high temperature resistance, oil resistance, water resistance, oxidation resistance, high hardness and favorable fastness, and is applicable to printing of products working in harsh environments such as kitchen utensils, cables, pump bodies and the like; the assistant provided by the invention can form a protecting film on the surface of the ink, thereby isolating air, preventing water and other molecules in the atmosphere from eroding the surfaces of the ink and ink-coated objects, resisting oxidation, permanently keeping a brilliant color and improving the smoothness and wear resistance.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of heat-resistant oxidized printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of heat-resistant oxidized printing-ink and preparation method thereof, this ink is heat-resisting, resistance to oxidation.
Technical scheme of the present invention is as follows:
A heat-resistant oxidized printing-ink, is characterized in that being made by the raw material of following weight part: resol 30-34, oleum lini Synolac 13-15, ethylene glycol 6-8, thanomin 3-5, methylene dichloride 10-12, aminoresin 20-30, cyclohexanone 6-9, silane resin acceptor kh-550 1-2, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, peroxidation trimethylacetic acid tert-butyl ester 1-2, cobalt naphthenate 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described heat-resistant oxidized printing-ink, it is characterized in that comprising the following steps: by resol, ethylene glycol, thanomin, methylene dichloride, cyclohexanone, glycidyl methacrylate is mixed, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add aminoresin, the peroxidation trimethylacetic acid tert-butyl ester, cobalt naphthenate, stirring reaction 10-20 minute, add silane resin acceptor kh-550, two ten four carbon alcohols esters, oleum lini Synolac, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention is used the monomer polymerizations such as resol, aminoresin, that the ink obtaining has is high temperature resistant, oil resistant, water-fast, resistance to oxidation, hardness is high, fastness is good feature, is applicable to the product printing that kitchen utensils, cable, the pump housing etc. are worked under severe environment; Printing ink producing cost of the present invention is low, and production efficiency is high.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A heat-resistant oxidized printing-ink, by following weight part (kilogram) raw material make: resol 33, oleum lini Synolac 14, ethylene glycol 7, thanomin 4, methylene dichloride 11, aminoresin 25, cyclohexanone 7, silane resin acceptor kh-550 1.5, glycidyl methacrylate 1.5, two ten four carbon alcohols esters 2.5, the peroxidation trimethylacetic acid tert-butyl ester 1.5, cobalt naphthenate 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, dimethylaminoethyl methacrylate 3.5, morpholine 1.5, neopentyl glycol 3.5, oxidation inhibitor 1,035 1.5, ricinolic acid 1.5, linking agent TAC1.5, ethanol 23; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 25 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 35 minutes, obtains.
The preparation method of described heat-resistant oxidized printing-ink, comprise the following steps: by resol, ethylene glycol, thanomin, methylene dichloride, cyclohexanone, glycidyl methacrylate is mixed, under 1200 revs/min of stirrings, with the speed of 7 ℃/minute, be heated to 70 ℃, add aminoresin, the peroxidation trimethylacetic acid tert-butyl ester, cobalt naphthenate, stirring reaction 15 minutes, add silane resin acceptor kh-550, two ten four carbon alcohols esters, oleum lini Synolac, continue stirring reaction 25 minutes, add other remaining components, continue stirring reaction 1.7 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a heat-resistant oxidized printing-ink, is characterized in that being made by the raw material of following weight part: resol 30-34, oleum lini Synolac 13-15, ethylene glycol 6-8, thanomin 3-5, methylene dichloride 10-12, aminoresin 20-30, cyclohexanone 6-9, silane resin acceptor kh-550 1-2, glycidyl methacrylate 1-2, two ten four carbon alcohols ester 2-3, peroxidation trimethylacetic acid tert-butyl ester 1-2, cobalt naphthenate 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, dimethylaminoethyl methacrylate 3-4, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, ricinolic acid 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of heat-resistant oxidized printing-ink according to claim 1, it is characterized in that comprising the following steps: by resol, ethylene glycol, thanomin, methylene dichloride, cyclohexanone, glycidyl methacrylate is mixed, under 1000-1400 rev/min of stirring, speed with 5-8 ℃/minute is heated to 60-80 ℃, add aminoresin, the peroxidation trimethylacetic acid tert-butyl ester, cobalt naphthenate, stirring reaction 10-20 minute, add silane resin acceptor kh-550, two ten four carbon alcohols esters, oleum lini Synolac, continue stirring reaction 20-30 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575001.4A CN103666089A (en) | 2013-11-18 | 2013-11-18 | Heat-resistant oxidation-resistant printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310575001.4A CN103666089A (en) | 2013-11-18 | 2013-11-18 | Heat-resistant oxidation-resistant printing ink and preparation method thereof |
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| CN103666089A true CN103666089A (en) | 2014-03-26 |
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| CN201310575001.4A Pending CN103666089A (en) | 2013-11-18 | 2013-11-18 | Heat-resistant oxidation-resistant printing ink and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403408A (en) * | 2014-11-10 | 2015-03-11 | 合肥宏图彩印有限公司 | Wear and oxidation resistant printing ink and manufacturing method thereof |
| CN105968946A (en) * | 2016-06-30 | 2016-09-28 | 安徽智博新材料科技有限公司 | Printing ink special for food packaging bag and preparation method of printing ink |
| CN106118232A (en) * | 2016-06-30 | 2016-11-16 | 安徽智博新材料科技有限公司 | A kind of medical equipment printing-ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN103342922A (en) * | 2013-07-30 | 2013-10-09 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
-
2013
- 2013-11-18 CN CN201310575001.4A patent/CN103666089A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101831215A (en) * | 2010-04-28 | 2010-09-15 | 王学珍 | High-performance jet ink |
| CN103342922A (en) * | 2013-07-30 | 2013-10-09 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403408A (en) * | 2014-11-10 | 2015-03-11 | 合肥宏图彩印有限公司 | Wear and oxidation resistant printing ink and manufacturing method thereof |
| CN105968946A (en) * | 2016-06-30 | 2016-09-28 | 安徽智博新材料科技有限公司 | Printing ink special for food packaging bag and preparation method of printing ink |
| CN106118232A (en) * | 2016-06-30 | 2016-11-16 | 安徽智博新材料科技有限公司 | A kind of medical equipment printing-ink and preparation method thereof |
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Application publication date: 20140326 |