CN103666073B - A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof - Google Patents
A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof Download PDFInfo
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- CN103666073B CN103666073B CN201310618215.5A CN201310618215A CN103666073B CN 103666073 B CN103666073 B CN 103666073B CN 201310618215 A CN201310618215 A CN 201310618215A CN 103666073 B CN103666073 B CN 103666073B
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- ink
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- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- DMWHWJCBCKCPAS-UHFFFAOYSA-N [Se].C(C)C(=O)C(=O)C Chemical compound [Se].C(C)C(=O)C(=O)C DMWHWJCBCKCPAS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000975 dye Substances 0.000 claims abstract description 7
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010439 graphite Substances 0.000 claims abstract description 7
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 7
- 239000010451 perlite Substances 0.000 claims abstract description 7
- 235000019362 perlite Nutrition 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 230000008961 swelling Effects 0.000 claims abstract description 7
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 4
- 239000004305 biphenyl Substances 0.000 claims abstract description 4
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims abstract description 4
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002050 silicone resin Polymers 0.000 claims abstract description 4
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims abstract description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000012467 final product Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- KWIPUXXIFQQMKN-UHFFFAOYSA-N 2-azaniumyl-3-(4-cyanophenyl)propanoate Chemical compound OC(=O)C(N)CC1=CC=C(C#N)C=C1 KWIPUXXIFQQMKN-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 229940090948 ammonium benzoate Drugs 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- -1 titanic acid ester Chemical class 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 238000007650 screen-printing Methods 0.000 abstract description 7
- 239000002904 solvent Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000010428 oil painting Methods 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of Novel ultraviolet-curable silk-screen pearlescent ink, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 20-24, expanded graphite 1-2, swelling perlite powder 1-3, methyl ethyl diketone selenium 1-2,2,4,6-trimethyl benzoyl diphenyl base phosphine oxide 5-8, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, Viscoat 295 10-12,1173 light trigger 4-8, zinc naphthenate 2-4, diethylamine 1-2, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink; All have good sticking power between ink of the present invention and each stock, snappiness, wear-resisting scratch resistance intensity, resistance to all kinds of solvent nature, can meet the requirement of silk screen printing.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof.
Background technology
Silk screen printing is stretched tight on screen frame by silk fabrics, synthetic fabrics or wire cloth, adopts manual method of carving paint film or photochemistry plate-making to make screen printing forme.Modern screen printing technology, then utilize sensitive materials to make the flat carriers etc. such as screen printing forme (make the silk screen hole of areas on screen printing forme be through hole, but not the silk screen hole of areas being plugged) oil painting, etching, pictorial poster, business card, binding and layout front cover, commodity packaging, product tag, printed textile, glass and metal by photomechanical method.
Pearly pigment is as a kind of mode of printing of special-effect, by means of the pearliness of its uniqueness, printed matter surface is produced and graceful unique, softly pleasing looks reward effect, there is the characteristic of anti-duplicating simultaneously, there is certain antifalse effect, take the course of its own in numerous mode of printing, become popular one false proof with decorating printing technology.The application of pearly-lustre silk-screen ink can well embody the distinctive effect of pearly-lustre, is widely applied in fields such as banknote, security, Package and labels.
Summary of the invention
The object of this invention is to provide a kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of Novel ultraviolet-curable silk-screen pearlescent ink, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 20-24, expanded graphite 1-2, swelling perlite powder 1-3, methyl ethyl diketone selenium 1-2,2,4,6-trimethyl benzoyl diphenyl base phosphine oxide 5-8, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, Viscoat 295 10-12,1173 light trigger 4-8, zinc naphthenate 2-4, diethylamine 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, Ammonium benzoate 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Novel ultraviolet-curable silk-screen pearlescent ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, expanded graphite, swelling perlite powder, methyl ethyl diketone selenium stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1173 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1173 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; All have good sticking power between ink of the present invention and each stock, snappiness, wear-resisting scratch resistance intensity, resistance to all kinds of solvent nature, can meet the requirement of silk screen printing.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of Novel ultraviolet-curable silk-screen pearlescent ink, be made up of the raw material of following weight part (kilogram): pigment dyestuff 1, urethane acrylate 20, expanded graphite 1, swelling perlite powder 1, methyl ethyl diketone selenium 1,2,4,6-trimethyl benzoyl diphenyl base phosphine oxide 5, oleum lini 3, silicone resin 12, tetrafluoroethylene 2, Viscoat 295 10,1173 light trigger 4, zinc naphthenate 2, diethylamine 1, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, linking agent TAC2, polyisobutene 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, Ammonium benzoate 1, Viscoat 295 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Novel ultraviolet-curable silk-screen pearlescent ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, expanded graphite, swelling perlite powder, methyl ethyl diketone selenium stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1173 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1173 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet light polymerization silk screen pearl ink, it is characterized in that, be prepared from by the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 20-24, expanded graphite 1-2, swelling perlite powder 1-3, methyl ethyl diketone selenium 1-2,2,4,6-trimethyl benzoyl diphenyl base phosphine oxide 5-8, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, Viscoat 295 10-12,1173 light trigger 4-8, zinc naphthenate 2-4, diethylamine 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, Ammonium benzoate 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. ultraviolet light polymerization silk screen pearl ink according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, expanded graphite, swelling perlite powder, methyl ethyl diketone selenium stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1173 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1173 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618215.5A CN103666073B (en) | 2013-11-29 | 2013-11-29 | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618215.5A CN103666073B (en) | 2013-11-29 | 2013-11-29 | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666073A CN103666073A (en) | 2014-03-26 |
| CN103666073B true CN103666073B (en) | 2016-04-27 |
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| CN201310618215.5A Expired - Fee Related CN103666073B (en) | 2013-11-29 | 2013-11-29 | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194478A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠首创滤清器有限公司 | Organic silicon resin printing ink dyed by soy sauce |
| CN106398387B (en) * | 2016-10-07 | 2020-11-13 | 广东昊辉新材料有限公司 | A kind of optical fiber coloring ink which can be cured by LED lamp and its manufacturing method |
| CN110437676B (en) | 2019-09-16 | 2022-10-25 | 杭州科望特种油墨有限公司 | High-light-transmittance UV (ultraviolet) ink for solar panel |
| CN115433515B (en) * | 2022-09-19 | 2023-06-23 | 广东希贵光固化材料有限公司 | High-hardness super-wear-resistant UV transfer printing adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310618215.5A patent/CN103666073B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
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| CN103666073A (en) | 2014-03-26 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: He Yuankai Inventor before: Dong Liangqing |
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| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170307 Address after: 523430 Guangdong city in Dongguan Province town of Liaobu Fu Ling Industrial Zone Zhushan Basin Patentee after: Dongguan Haiya printing material Co. Ltd. Address before: South Taibai town 243161 Anhui city of Ma'anshan province Dangtu County Xintai white road Patentee before: Dangtu County Ke Hui commerce and trade Co., Ltd |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160427 Termination date: 20181129 |
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| CF01 | Termination of patent right due to non-payment of annual fee |