CN103666073A - Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof - Google Patents
Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666073A CN103666073A CN201310618215.5A CN201310618215A CN103666073A CN 103666073 A CN103666073 A CN 103666073A CN 201310618215 A CN201310618215 A CN 201310618215A CN 103666073 A CN103666073 A CN 103666073A
- Authority
- CN
- China
- Prior art keywords
- parts
- ink
- minute
- screen
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010439 graphite Substances 0.000 claims abstract description 7
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims abstract description 4
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002050 silicone resin Polymers 0.000 claims abstract description 4
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000000016 photochemical curing Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- DMWHWJCBCKCPAS-UHFFFAOYSA-N [Se].C(C)C(=O)C(=O)C Chemical compound [Se].C(C)C(=O)C(=O)C DMWHWJCBCKCPAS-UHFFFAOYSA-N 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 6
- 235000019362 perlite Nutrition 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 6
- -1 titanic acid ester Chemical class 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 abstract description 7
- 238000007639 printing Methods 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000011669 selenium Substances 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000010428 oil painting Methods 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses novel ultraviolet-curable silk-screen pearlescent ink. The ink is characterized in that the ink is made from raw materials in parts by weight as follows: 1-3 parts of organic pigment, 20-24 parts of urethane acrylate, 1-2 parts of expanded graphite, 1-3 parts of expanded perlite powder, 1-2 parts of selenium acetylacetonate, 5-8 parts of 2,4,6-trimethylbenzoyldiphenyl phosphine oxide, 3-4 parts of linseed oil, 12-14 parts of organic silicone resin, 2-3 parts of polytetrafluoroethene, 10-12 parts of trimethylolpropane triacrylate, 4-8 parts of a 1173 photoinitiator, 2-4 parts of zinc naphthenate, 1-2 parts of diethylamine and 4-5 parts of an assistant. The assistant can improve the toughness of the ink, so that the ink is even in dispersion, and the stability of the ink is maintained; the ink has good adhesive force to printing stocks and has good flexibility, abrasive resistance, scratch resistance and resistance to various solvents, and silk-screen printing requirements can be met.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of new ultra-violet photocuring silk screen pearl ink and preparation method thereof.
Background technology
Silk screen printing is that silk fabrics, synthetic fabrics or wire cloth are stretched tight on screen frame, adopts manual method of carving paint film or photochemistry plate-making to make screen printing forme.Modern screen printing technique, to utilize sensitive materials by photomechanical method, to make the flat carriers such as screen printing forme (making the silk screen hole of picture and text part on screen printing forme is through hole, and the silk screen hole of non-graphic part is plugged) oil painting, etching, pictorial poster, business card, binding and layout front cover, commodity packaging, product tag, dyeing textile product, glass and metal etc.
Pearly pigment is as a kind of mode of printing of special-effect, rely on its unique pearliness, make printed matter surface produce graceful unique, the soft pleasing reward effect of looking, the characteristic simultaneously with anti-duplicating, there is certain antifalse effect, in numerous mode of printings, take the course of its own, become popular a kind of false proof and decorating printing technology.The application of pearly-lustre silk-screen ink can well embody the distinctive effect of pearly-lustre, in fields such as banknote, security, Package and labels, is widely applied.
Summary of the invention
The object of this invention is to provide a kind of new ultra-violet photocuring silk screen pearl ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of new ultra-violet photocuring silk screen pearl ink, raw material by following weight part is made: pigment dyestuff 1-3, urethane acrylate 20-24, expanded graphite 1-2, swelling perlite powder 1-3, methyl ethyl diketone selenium 1-2,2,4,6-trimethylbenzoyl diphenyl phosphine oxide 5-8, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, Viscoat 295 10-12,1173 light trigger 4-8, zinc naphthenate 2-4, diethylamine 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
New ultra-violet photocuring silk screen pearl ink of the present invention, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, expanded graphite, swelling perlite powder, methyl ethyl diketone selenium stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1173 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1173 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Between ink of the present invention and each stock, all there is good sticking power, snappiness, wear-resisting scratch resistance intensity, resistance to all kinds of solvent natures, can meet the requirement of silk screen printing.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of new ultra-violet photocuring silk screen pearl ink, by following weight part (kilogram) raw material make: pigment dyestuff 1, urethane acrylate 20, expanded graphite 1, swelling perlite powder 1, methyl ethyl diketone selenium 1,2,4,6-trimethylbenzoyl diphenyl phosphine oxide 5, oleum lini 3, silicone resin 12, tetrafluoroethylene 2, Viscoat 295 10,1173 light triggers 4, zinc naphthenate 2, diethylamine 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, linking agent TAC2, polyisobutene 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, phenylformic acid amine 1, Viscoat 295 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
New ultra-violet photocuring silk screen pearl ink of the present invention, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, expanded graphite, swelling perlite powder, methyl ethyl diketone selenium stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1173 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1173 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a new ultra-violet photocuring silk screen pearl ink, it is characterized in that, raw material by following weight part is made: pigment dyestuff 1-3, urethane acrylate 20-24, expanded graphite 1-2, swelling perlite powder 1-3, methyl ethyl diketone selenium 1-2,2,4,6-trimethylbenzoyl diphenyl phosphine oxide 5-8, oleum lini 3-4, silicone resin 12-14, tetrafluoroethylene 2-3, Viscoat 295 10-12,1173 light trigger 4-8, zinc naphthenate 2-4, diethylamine 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. new ultra-violet photocuring silk screen pearl ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, expanded graphite, swelling perlite powder, methyl ethyl diketone selenium stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1173 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1173 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618215.5A CN103666073B (en) | 2013-11-29 | 2013-11-29 | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618215.5A CN103666073B (en) | 2013-11-29 | 2013-11-29 | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666073A true CN103666073A (en) | 2014-03-26 |
| CN103666073B CN103666073B (en) | 2016-04-27 |
Family
ID=50304879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310618215.5A Expired - Fee Related CN103666073B (en) | 2013-11-29 | 2013-11-29 | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666073B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194478A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠首创滤清器有限公司 | Organic silicon resin printing ink dyed by soy sauce |
| CN106398387A (en) * | 2016-10-07 | 2017-02-15 | 苏州高精特专信息科技有限公司 | Optical fiber coloring ink capable of being solidified by LED and preparing method thereof |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | A color-changing ink |
| CN115433515A (en) * | 2022-09-19 | 2022-12-06 | 广东希贵光固化材料有限公司 | High-hardness and super-wear-resistant UV transfer adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310618215.5A patent/CN103666073B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194478A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠首创滤清器有限公司 | Organic silicon resin printing ink dyed by soy sauce |
| CN106398387A (en) * | 2016-10-07 | 2017-02-15 | 苏州高精特专信息科技有限公司 | Optical fiber coloring ink capable of being solidified by LED and preparing method thereof |
| CN106398387B (en) * | 2016-10-07 | 2020-11-13 | 广东昊辉新材料有限公司 | A kind of optical fiber coloring ink which can be cured by LED lamp and its manufacturing method |
| CN110437676A (en) * | 2019-09-16 | 2019-11-12 | 杭州科望特种油墨有限公司 | A color-changing ink |
| US12404418B2 (en) | 2019-09-16 | 2025-09-02 | Hangzhou Bomei Solar Energy Technology Co., Ltd | Scenario-adaptable color-changing ink and solar glass product |
| CN115433515A (en) * | 2022-09-19 | 2022-12-06 | 广东希贵光固化材料有限公司 | High-hardness and super-wear-resistant UV transfer adhesive and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666073B (en) | 2016-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103666073B (en) | A kind of Novel ultraviolet-curable silk-screen pearlescent ink and preparation method thereof | |
| CN103666032B (en) | A kind of ultraviolet light polymerization packaging ink and preparation method thereof | |
| CN103666033B (en) | A kind of novel UV solidifies serigraphy pearl ink and preparation method thereof | |
| CN100554347C (en) | Coloured conductive ink and preparation method thereof | |
| CN103666076B (en) | A kind of ultraviolet curing pearl silk-screen ink and preparation method thereof | |
| CN103589238B (en) | Red brown silver light ink for silk screen printing | |
| CN103666035B (en) | A kind of UV cured printing ink and preparation method thereof for serigraphy | |
| CN103666071A (en) | Light-curable printing ink used for silk screen printing and preparation method thereof | |
| CN103666079A (en) | Ultraviolet curing printing ink for silk-screen printing and preparation method thereof | |
| CN103666072B (en) | A kind of UV curable ink for electronic component mark and preparation method thereof | |
| CN103666060A (en) | UV-curing printing ink with high flexibility and preparation method thereof | |
| CN103666034B (en) | UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof | |
| CN103666028B (en) | A kind of ultraviolet curing glass printing ink for digital product and preparation method thereof | |
| CN108047832A (en) | A kind of decorating film | |
| CN103666030B (en) | A kind of UV cured printing ink for digital product touch-screen glass printing and preparation method thereof | |
| CN103666055A (en) | Photo-cured and environment-friendly screen printing ink and preparation method thereof | |
| CN103666113B (en) | A kind of UV solidifies jetted ink and preparation method thereof | |
| CN103589224B (en) | Bright silver red ink for silk screen printing | |
| CN103666097A (en) | UV printing ink for silk-screen printing and preparation method thereof | |
| CN112026391A (en) | In-mold injection molding transfer printing film with protective layer having multiple characteristic regions and preparation method | |
| CN103666038B (en) | A kind of one-step print ultraviolet curing pearl ink and preparation method thereof | |
| CN103666062B (en) | A kind of ultraviolet curing embossed printing ink and preparation method thereof | |
| CN103589237B (en) | Blackish green silver ink for silk screen printing | |
| CN103666104A (en) | Ultraviolet curing digital printing ink and preparation method thereof | |
| KR100467052B1 (en) | Composition for ink used in optically variable coloring coin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: He Yuankai Inventor before: Dong Liangqing |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170307 Address after: 523430 Guangdong city in Dongguan Province town of Liaobu Fu Ling Industrial Zone Zhushan Basin Patentee after: Dongguan Haiya printing material Co. Ltd. Address before: South Taibai town 243161 Anhui city of Ma'anshan province Dangtu County Xintai white road Patentee before: Dangtu County Ke Hui commerce and trade Co., Ltd |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160427 Termination date: 20181129 |