CN101560348B - Ultraviolet light curing offset printing ink and preparation method thereof - Google Patents
Ultraviolet light curing offset printing ink and preparation method thereof Download PDFInfo
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- CN101560348B CN101560348B CN 200910011718 CN200910011718A CN101560348B CN 101560348 B CN101560348 B CN 101560348B CN 200910011718 CN200910011718 CN 200910011718 CN 200910011718 A CN200910011718 A CN 200910011718A CN 101560348 B CN101560348 B CN 101560348B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000007645 offset printing Methods 0.000 title claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 176
- 229920005989 resin Polymers 0.000 claims abstract description 176
- 238000007639 printing Methods 0.000 claims abstract description 45
- 239000000178 monomer Substances 0.000 claims abstract description 36
- 229920000728 polyester Polymers 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 8
- 229920000570 polyether Polymers 0.000 claims abstract description 8
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 84
- 239000007788 liquid Substances 0.000 claims description 65
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 44
- 239000006185 dispersion Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 23
- 239000002994 raw material Substances 0.000 claims description 21
- 238000009736 wetting Methods 0.000 claims description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- -1 chloride acrylic ester Chemical class 0.000 claims description 8
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 6
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 claims description 6
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 claims description 3
- 159000000013 aluminium salts Chemical class 0.000 claims description 3
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 3
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004258 Ethoxyquin Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000000498 cooling water Substances 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 229940093500 ethoxyquin Drugs 0.000 claims description 2
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019285 ethoxyquin Nutrition 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000004482 other powder Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 238000006735 epoxidation reaction Methods 0.000 claims 1
- 238000012546 transfer Methods 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000003999 initiator Substances 0.000 description 74
- 239000000976 ink Substances 0.000 description 67
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 238000004090 dissolution Methods 0.000 description 10
- 239000011259 mixed solution Substances 0.000 description 10
- 239000000123 paper Substances 0.000 description 10
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 8
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- 101100234822 Caenorhabditis elegans ltd-1 gene Proteins 0.000 description 4
- 238000003848 UV Light-Curing Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910002012 Aerosil® Inorganic materials 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- 241000557626 Corvus corax Species 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- CKRZKMFTZCFYGB-UHFFFAOYSA-N N-phenylhydroxylamine Chemical compound ONC1=CC=CC=C1 CKRZKMFTZCFYGB-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- VBBRYJMZLIYUJQ-UHFFFAOYSA-N cyclopropanone Chemical compound O=C1CC1 VBBRYJMZLIYUJQ-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- YMCOIFVFCYKISC-UHFFFAOYSA-N ethoxy-[2-(2,4,6-trimethylbenzoyl)phenyl]phosphinic acid Chemical compound CCOP(O)(=O)c1ccccc1C(=O)c1c(C)cc(C)cc1C YMCOIFVFCYKISC-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- HNMCSUXJLGGQFO-UHFFFAOYSA-N hexaaluminum;hexasodium;tetrathietane;hexasilicate Chemical class [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].S1SSS1.S1SSS1.[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] HNMCSUXJLGGQFO-UHFFFAOYSA-N 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to an ultraviolet light curing offset printing ink and a preparation method thereof. The ultraviolet light curing offset printing ink is made of 25.0-50.0% of polyfunctional polyester acrylic resin or polyfunctional chlorinated polyester acrylate, 0.0-15.0% of epoxy acrylate oligopolymer, 0.0-20.0% of polyfunctional urethane acrylate, 0.0-15.0% of difunctional or polyfunctional acrylic monomer, 0.0-20.0% of grinding-type resin, 2.0-10.0% of polyether acrylate modified by nano silicon dioxide, 0.0-5.0% of adhesion promoter, 3.0-5.0% of photoinitiator, 0.1-2.0% of polymerization inhibitor, 0.0-10.0% of filler, 16.0-55.0% of paint or dye and 0.2-5.0% of accessory ingredient. The prepared offset printing ink has high transparency as well as good adhesive attraction and flexility, and can be widely applied to packages printing industry and the printing of various transfer paper.
Description
Technical field
The present invention relates to and belongs to the printing-ink field that artificial resin is the master, relates to the printing-ink that contains light-cured resin.Be specifically related to light-curable ink that is used for offset printing and preparation method thereof.
Background technology
Since German Bayer AG in 1967 develops first-generation ultraviolet light polymerization (UV curing) coating, the UV curing technology worldwide obtains develop rapidly, and applies in electronics, printing, building, decoration, medicine, machinery, chemical industry and automobile and other industries rapidly.UV curing inks quick solidifying, pollution-free, film quality is high, hardness is high, damage resistant, corrosion-resistant, has complied with the developing direction of modern coating, printing ink, extremely people pay close attention to.At present, ultraviolet light cured printing ink is as a big class of UV solidify material, in packages printing industry and printed wiring industry, developed rapidly and widespread use, spreaded all over print fields such as offset printing, protruding seal (comprising flexographic printing), gravure, wire mark and ink jet printing.
But the utilisation technology with regard to UV-curing technology still needs further expansion and perfect, people such as Zhu Ling have studied ink-jet printed with UV curable ink (Shanghai textile technology, 2005 33 (3)), the little brave grade of Dong has been studied lamination circuit board UV curable ink (thermosetting resin, 2005 the 20th volume third phases), also have, Chinese invention patent (CN 200410027270.8) UV curable ink that people such as the Zhang Chuanhai of Guangdong Province declare is mainly used in silk screen printing.But do not see with regard to the ultraviolet glue printing ink and to mention, especially be directed to the UV curable ink of using on the transfer paper, because it has the higher requirement standard, technology is difficult to break through for a long time.
Illustrate: transfer paper is a kind of novel environment friendly printing material, it is to substitute the paperboard that film was arranged originally, his surface does not have plastics film, such material is that quantity of plastics has been saved in environmental protection again, and the recycling of can also degrading after packing uses up be unlikely to impact to environment, but this paper comparatively speaking, intensity descends to some extent, and is also higher to the printing ink requirement of printing thereon.
Summary of the invention
The purpose of this invention is to provide a kind of cured offset printing ink and preparation method, particularly ultraviolet cured offset printing ink that can be complementary with novel transfer environmental protection paper and preparation method thereof.This printing ink adopts the improved polyether acrylate of interpolation nano silicon to do starting material, and is good with all kinds of gloss oil (water light and UV light) matching; Can directly be printed on the novel environment friendly paper (transfer paper), have good sticking power and snappiness; And has environmental protection, low smell, the low residual characteristic of VOC, can be widely used in the tobacco bale dress, electronic product, high-grade packages printing industries such as makeup, medical packaging, wall calendar, artwork reach the foodstuff packaging industry field higher to environmental requirement, particularly plastics, gold and silver paperboard, aluminium-foil paper and all kinds of transfer paper print fields such as drinks, moon cake.
(1) composition of product:
The composition of each component and weight percent are in the printing ink:
1. polyfunctionality polyester acrylic resin (or polyfunctionality chlorinated polyester vinylformic acid 25.0～50.0 esters)
2. epoxy acrylate oligomer 0.0～15.0
3. multifunctional urethane acrylate 0.0～20.0
4. difunctionality Acrylic Acid Monomer (or polyfunctionality Acrylic Acid Monomer) 0.0～15.0
5. grind dispersion resin 0.0～20.0
6. the improved polyether acrylate 2.0～10.0 of nano silicon
7. adhesion promoter 0.0～5.0
8. light trigger 3.0～5.0
9. stopper 0.1～2.0
10. filler 0.0～10.0
11. pigment or dyestuff 16.0～55.0
12. auxiliary agent 0.2～5.0
1, above polyfunctionality polyester acrylic resin (or polyfunctionality polyester chloride acrylic ester) of stating is meant polyester or the chlorinated polyester acrylic resin of functionality between 4-10, as the CN2203 of U.S.'s Sartomer, CN736, CN738, CN750; 6350,6351,6353 of Changxing, Taiwan;
The EBECRYL811 of the special company of U.S.'s cyanogen, EBECRYL812, EBECRYL845, EBECRYL857, EBECRYL859, EBECRYL657, EB1ECRYL657, EBECRYL436, EBECRYL438;
Strange titanizing worker's SP236; 705 of Taiwan Xin Limei company, 710C60,710G60; Japan East Asia synthetic M-8060.With 3～5 kinds in raising variety.
2, above epoxy acrylate oligomer of stating is meant the special epoxy of 2-6 functionality or through property modification, as the CN2204 of U.S.'s Sartomer, and PRO8008A, among the CNUVE-150 1～2 kind.
3, above polyfunctionality polyurethane acrylic resin of stating is meant 2-6 functionality, has the resin of property, as one of among the UVU6451 of UV2630, the Shaanxi Xi Laiwu of middle mountain Chiba.
4, above difunctionality Acrylic Acid Monomer of stating (or polyfunctionality Acrylic Acid Monomer) is meant Viscoat 295 commonly used, tri (propylene glycol) diacrylate, 1.6-hexanediyl ester is abbreviated as TMPTA respectively, TPGDA and HDDA, but it is highly purified product that the present invention requires, and there is its high purity product present every family supply commercial city.As the SR351HP of Sartomer, SR306HP, SR238HP; The EM231-TF in Changxing, EM223-TF, EM221-TF; The product in Korea S U.S. source: M300, M220, M200; Use wherein 1～2 kind.
5, above grinding dispersion resin of stating is meant the extraordinary special defects resin of pigment wetting, LR9013 as German BASF AG, the EBECRYL860 of the special company of U.S.'s cyanogen, the DAP-A resin that also has Japanese Da Cao strain scholar commercial firm is dissolved in the ethoxyquin Viscoat 295 (such as the EM2380 in Changxing) by 40% concentration, and we claim that it is a self-control DAP-A-40 resin.(liquid monomer EM2380 and DAP-A solid resin were dissolved into liquid resin for making the DAP-A-40 resin by oneself by 6: 4) uses wherein 1～2 kind
6, the improved polyether acrylate of above nano silicon of stating is meant the LR9026V of German BASF AG.
7, above adhesion promoter of stating is meant the Acrylic Acid Monomer or the acrylated oligomer of phosphoric acid modification, as the CD9050 and the CD9051 of U.S. Sartomer company; The EBECRYL168 and the EBECRYL170 of the special company of U.S.'s cyanogen; The PHOTOMER4073 and 4703 of Germany Kening Co.,Ltd; The TA-12P of du pont company, the TAA of Taiwan Borica company, AP-100.Use wherein 1～2 kind.
8; above light trigger of stating is 907 (2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone); 184 (1-hydroxy-cyclohexyl phenyl ketones); 369 (2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone); ITX (2-isopropyl thioxanthone); EDAB (4-(N; the N-dimethylamino) ethyl benzoate); 651 (benzoin dimethylethers); 1173 (2-hydroxy-2-methyls-1-phenyl-acetone), 819 (phenyl two (2,4; the 6-trimethylbenzoyl) phosphine oxide); TPO (2,4,6-trimethylbenzoyl-diphenyl phosphine oxide).TPO-L (2,4,6-trimethylbenzoyl phenyl-phosphonic acid ethyl ester) uses wherein 2～5 kinds.
9, above stopper of stating is that 510 (3 (N-nitroso-group N-phenyl hydroxyl ammonia) aluminium salt) are solid-state, ST-1 (3 (N-nitroso-group-N-phenyl hydroxyl ammonia) aluminium salt) liquid state, TBQ (tertiary butyl para benzoquinone), MEHQ.Use wherein 1～2 kind.
10, above filler of stating is a superfine talcum powder, nanometer grade calcium carbonate SPO-500 (SPO-100, SPO-500 etc.), and aerosil M-5 uses wherein 1～2 kind.
11, above pigment of stating: white is the titanium dioxide (RDI-S of Finland, the R-706 of Dupont), black is the carbon black (M-L of Cabot, M-E, R250, Gao Sha 2500, the RAVEN 760Ultra of Colombia's chemistry), yellow is the GRX-86 of Clariant, the LCT Huang of vapour crust, the LBL Huang of vapour crust etc.; Redness be the 57:1 fuchsin (L4BN of vapour crust, the 6B233S of DIC company, 6B236S), 53:1 golden red (131FD of DIC, the CONC of DIC), 146# is bright red, blueness is 15:4 phthalocyanine blue (5412SD of DIC), the 5380E of DIC etc.Use wherein 1～2 kind.
12, above auxiliary agent of stating is meant dispersion agent, as the German BYK BYK163 of company, BYK168, hyper-dispersant 24000,32000; Damage resistant auxiliary agent: BYK2500, BYK-3510, wax powder (CERAFLOUR 991 of BYK, the FS-731MG of the U.S. three leaf companies, the multiple product of 675A etc.) etc.Use wherein 1～3 kind.
(2) technical process
1. premix: with the improved polyether acrylate of nano silicon, polyfunctionality polyester acrylic resin, polyfunctionality polyester chloride acrylic ester, epoxy acrylate oligomer, multifunctional urethane acrylate and grinding dispersion resin stir in stirring tank, filter, get feed liquid one;
2. dissolving: with solid photoinitiator respectively with all monomers in the prescription or add a part of mixed feed liquid one (monomer molar ratio less situation under) dissolving in advance, filtration again;
3. disperse: in feed liquid one, add dispersing auxiliary, after stirring at low speed is even, add pigment and dyestuff, filler again, add stopper simultaneously, after stirring at low speed mixed, (600-1200 changeed/min) stirs, when raising the temperature to 50 degrees centigrade of left and right sides at a high speed, about restir 30 minutes, make pigment and filler abundant wetting being uniformly dispersed in resin liquid.Reduce stirring velocity then and add other powder auxiliary agents such as wax powder, stirring gets final product;
4. grind: on three-roll grinder, grind (5-10 time) for several times, control roller temperature (30-50 degree centigrade) with recirculated cooling water.The printing ink fineness is reached below 10 microns;
5. add or dilution the back: it is good and cross filterable light trigger to add dissolving in advance on high speed dispersor, adds other auxiliary agents and comprises and stir adhesion promoter and feed liquid etc.;
6. ground and mixed: the above-mentioned ink body that stirs is gone on three-roll grinder again, to keep printing ink thorough mixing and printing ink outward appearance sophistication;
7. check: check every index;
The packing: the packing get final product finished product.
(3) ink printing performance
Adopt designed prescription and above-mentioned technology, the printing ink color and luster of production is pure, the transparency height, and good fluidity, dot reproduction is strong, and the color reductibility is good.Anti-fly China ink, ink-water balance is good, printability is good.Good with all kinds of gloss oil (water light and UV light) matching, can not only with water light coupling, and can also with glossy coupling, the wide adaptability of printing ink.
Described acquisition printing ink is printed on the cigarette-brand transfer paper on the UV of Heidelberg CD102-6 printing press, and film performance is as follows after the UV of 120J/cm solidifies:
1. the light of filming is level and smooth, has good recoatability.
2. to the wide adaptability of after-processing technology, reduced the difficulty of after-processing technologies such as gold stamping, glazing, make its easy realization, reduced the cost of post-treatment, improved product qualified rate.
3. sticking power extra-heavy, 3M adhesive tape test sticking power, 100% does not have come off (cross-hatching is tested its sticking power, and the edge is very smooth, does not have to come off).
4. have good snappiness, doubling does not have quick-fried China ink 20 times.Snappiness than other printing ink improves more than 4 times.
5. curing speed is fast, and the printing ink molding time can shorten to 0.28 second, shortens more than 30% than other printing ink molding times, has improved production efficiency greatly.
6. film and detect VOC content, 16 indexs and are far smaller than the industry value of limiting the quantity of all in the limiting the quantity of of industry regulation, and multinomial detection indexs such as benzene, ethanol, propyl carbinol, propylene glycol monomethyl ether, 4-methyl-2 pentanone, cyclopropanone do not detect in addition.
The advantage that the present invention had is:
1. this invention gained printing ink exemplary application is on novel environment friendly paper (transfer paper), and the more original printing ink of sticking power has raising greatly;
2. consider the aftertreatment technology of ink pellet surface when this printing ink is developed, adopt the improved polyether acrylate of interpolation nano silicon to do starting material, therefore easily gold stamping, easily glazing is good with all kinds of gloss oil (water light and UV light) matching.
3. through repeatedly experimental verification, gained printing ink of the present invention moment moulding after UV-irradiation has good snappiness, also can be applicable to the packaging industry fields higher to environmental requirement such as food.
4. printing ink of the present invention is environmentally friendly, and film process does not have noxious gas emission, and low VOC is residual on the printed matter, and 16 indexs all in limiting the quantity of, belong to environment-friendly type printing ink.
5. technology of the present invention is simple, and has used the prescription that grinds the dispersion resin dispersed color, has improved production efficiency widely, and is very easy to operation and popularization.
6. ink solidification speed of the present invention is fast, improves printing efficiency, saves the print production place.
Below the invention will be further described with embodiment.
Embodiment
The preparation of embodiment 1 UV curable ink:
Raw materials used kind and weight (Kg) prescription is:
| (1) the special EB859 resin of cyanogen | 5 |
| (1) Taiwan Xin Limei 705 | 5 |
| (1) the special EB436 resin of cyanogen | 12 |
| (1) synthetic 8060 resins in East Asia | 5 |
| (2) Sartomer CN2204 resin | 5 |
| (3) mountain Chiba UV2630 resin in | 20 |
| (4) TPGDA monomer | 2 |
| (4) HDDA monomer | 1.5 |
| (5) BASF LR9013 resin | 5 |
| (6) BASF 9026V resin | 2 |
| (8) 184 initiators | 2 |
| (8) ITX initiator | 1 |
| (8) 651 initiators | 3 |
| (8) 369 initiators | 1 |
| (8) 907 initiators | 3 |
| (11) Clariant GRX-86 Huang | 11 |
| (11) LBL Huang | 8.5 |
| (10) talcum powder | 3 |
| ?(7)TAA | 3 |
| (9) 510 stoppers | 0.5 |
| (12) 32000 dispersion agents | 0.5 |
| (12) wax powder | 1 |
| Add up to | 100 |
Making method:
1. LR9013 is ground dispersion resin 5kg, EB859 resin 5kg, 705 resin 5kg, CN2204 resin 5kg, UV2630 resin 20kg mixes with 9026V resin 2kg, the stirring that stirs in stirring tank is filtered, feed liquid one;
2. get feed liquid one 15kg and add TPGDA monomer 2kg and HDDA monomer 1.5kg, stir, 369 initiator 1kg, ITX initiator 1kg, 651 initiator 3kg, 907 initiator 3kg and 184 initiator 2kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
3. add 32000 dispersion agent 0.5kg in remaining feed liquid one, stirring at low speed is even; Amount to 19.5kg, talcum powder 3kg, 510 stopper 0.5kg to wherein adding 2 kinds of yellow ultramarines again, 600 commentaries on classics/min are stirred to about 45 ℃ of material temperature.Restir 25 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
4. above-mentioned mixed solution is ground on three-roll grinder 8 times, roller temperature is controlled at 30 ℃.
5. then other all raw materials (TAA) in feed liquid two and the prescription are added, mix, stir.Get Yellow ink 99kg.
6. various test ratings see attached list 1 and subordinate list 2.
The preparation of embodiment 2 UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| (1) Sartomer CN2203 resin | 5 |
| (1) the special EB657 resin of cyanogen | 3 |
| (1) the special EB438 resin of cyanogen | 18 |
| (2) Sartomer CNUVE-150 resin | 5 |
| (3) mountain Chiba UV2630 resin in | 8 |
| (5) BASF LR9013 resin | 10 |
| (6) BASF 9026V resin | 5 |
| (4) TPGDA monomer | 6 |
| (8) 184 initiators | 5 |
| (8) ITX initiator | 1 |
| (8) 369 initiators | 1 |
| (8) 907 initiators | 1 |
| (11) 57:1 fuchsin | 22 |
| (10) talcum powder | 3 |
| (7) Sartomer CD9051 sticking power promotes monomer | 5 |
| (9) ST-1 stopper | 0.5 |
| (12) BYK163 dispersion agent | 0.5 |
| (12) wax powder | 1 |
| Add up to | 100 |
Making method:
1. LR9013 is ground dispersion resin 10kg, EB438 resin 18kg, EB657 resin 3kg, CN2203 resin 5kg, UV2630 resin 8kg mixes with 9026V resin 5kg, the stirring that stirs in stirring tank is filtered, feed liquid one;
2. get feed liquid one 10kg and add TPGDA monomer 6kg, stir, 369 initiator 1kg, ITX initiator 1kg, 907 initiator 1kg and 184 initiator 5kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
3. add BYK163 dispersion agent 0.5kg in remaining feed liquid one, stirring at low speed is even; Amount to 22kg, talcum powder 3kg, ST-1 stopper 0.5kg to wherein adding the 57:1 cochineal again, 600 commentaries on classics/min are stirred to about 45 ℃ of material temperature.About restir 30 minutes, make pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
4. above-mentioned mixed solution is ground on three-roll grinder 8 times, roller temperature is controlled at 30 ℃.
5. then other all raw materials (CD9051 sticking power promotes monomer 5kg) in feed liquid two and the prescription are added, mix, stir.
6. above-mentioned printing ink is gone on three-roll grinder again Yellow ink 96kg.
7. various test ratings see attached list 1 and subordinate list 2.
The preparation of embodiment 3 UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| ?(1)EB1657 | 7 |
| (1) Sartomer CN750 resin | 14 |
| (1) 6350 resins in Changxing | 5 |
| (3) mountain Chiba UV2630 resin in | 10 |
| (4) TMPTA monomer | 15 |
| (6) BASF 9026V resin | 5 |
| (5) BASF LR9013 resin | 10 |
| (8) 651 initiators | 3 |
| (8) ITX initiator | 1 |
| (8) EDAB initiator | 1 |
| (8) 907 initiators | 4 |
| (7) the PHOTOMER4073 resin of Kening Co.,Ltd | 2 |
| (9) ST-1 stopper | 0.5 |
| (12) BYK168 dispersion agent | 0.5 |
| (11) the blue powder of 5412SD | 19 |
| ?(10)M-5 | 2 |
| (12) wax powder | 1 |
| Add up to | 100 |
Making method:
1. LR9013 is ground dispersion resin 10kg, EB1657 resin 7kg, 6350 resin 5kg, CN750 resin 14kg, UV2630 resin 10kg mixes with 9026V resin 5kg, the stirring that stirs in stirring tank is filtered, feed liquid one;
2. get the 15kgTMPTA monomer, 651 initiator 3kg, ITX initiator 1kg, EDAB initiator 1kg and 907 initiator 4kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
3. add BYK168 dispersion agent 0.5kg in feed liquid one, stirring at low speed is even; Amount to 19kg, M-53kg, ST-1 stopper 0.5kg to wherein adding the 5412SD blue pigments again, 600 commentaries on classics/min are stirred to about 45 ℃ of material temperature.About restir 30 minutes, make pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
4. above-mentioned mixed solution is ground on three-roll grinder 7 times, roller temperature is controlled at 30 ℃.
5. then other all raw materials (4073 resin 2kg) in feed liquid two and the prescription are added, mix, stir.
6. above-mentioned printing ink is gone on three-roll grinder again blue ink 98kg.
7. various test ratings see attached list 1 and subordinate list 2.
Embodiment 4: the preparation of UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| (1) Sartomer CN736 resin | 17 |
| (1) 6351 of Changxing | 5 |
| (1) the special EB811 resin of cyanogen | 5 |
| (4) TPGDA monomer | 1 |
| (4) HDDA monomer | 1 |
| (5) self-control DAP-A-40 resin | 8 |
| (5) BASF LR9013 grinds dispersion resin | 12 |
| (6) BASF 9026V resin | 5 |
| (8) 184 initiators | 3 |
| (8) ITX initiator | 3 |
| (8) 369 initiators | 1 |
| (8) 907 initiators | 8 |
| (11) carbon black pigment | 20 |
| (10) talcum powder | 3 |
| (10) lime carbonate SPO-500 | 3.5 |
| (12) 24000 dispersion agents | 1 |
| (9) TBQ stopper | 1 |
| (9) 510 stoppers | 1 |
| (12) wax powder | 1 |
| (12)BYK3510 | 0.5 |
| Add up to | 100 |
Making method:
1. with EM2380 with the DAP-A solid resin by being dissolved into liquid resin DAP-A-40 at 6: 4;
2. LR9013 is ground dispersion resin 12kg, CN736 resin 15kg, 6351 resin 5kg, EB811 resin 5kg, self-control DAP-A-40 resin 8kg mixes with 9026V resin 5kg, the stirring that in stirring tank, stirs, filtration must feed liquid one;
3. get feed liquid one 15kg and add TPGDA monomer 3kg and HDDA monomer 1kg, stir, 369 initiator 1kg, ITX initiator 3kg, 907 initiator 8kg and 184 initiator 3kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
4. add 24000 dispersion agent 1kg in remaining feed liquid one, stirring at low speed is even; To wherein adding carbon black pigment 20kg, talcum powder 3kg, lime carbonate SPO-5003.5kg, TBQ stopper 1kg, 510 stopper 1kg, 600 commentaries on classics/min are stirred to about 50 ℃ of material temperature again, and restir 35 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
5. above-mentioned mixed solution is ground on three-roll grinder 5 times, roller temperature is controlled at 30 ℃.
6. then other all raw materials (BYK3510) in feed liquid two and the prescription are added, mix, stir.
7. above-mentioned printing ink is gone on three-roll grinder again black ink 97kg.
8. various test ratings see attached list 1 and subordinate list 2.
Embodiment 5: the preparation of UV curable ink:
Raw materials used kind and weight (kg) prescription is:
Making method:
1. CN2203 resin 5kg, SA236 resin 15kg, EB1657 resin 5kg are mixed with 9026V resin 2kg, the stirring that stirs in stirring tank is filtered, and gets feed liquid one;
2. with TPO initiator 2kg and 184 initiator 4kg and HDDA monomer 4kg mixed dissolution, filter, it is standby to get feed liquid two;
3. add 24000 dispersion agent 0.5kg in feed liquid one, stirring at low speed is even; To wherein adding 706 titanium dioxide 55kg, talcum powder 4kg, MEHQ stopper 2kg, 600 commentaries on classics/min are stirred to about 50 ℃ of material temperature again.Restir 35 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 0.5kg then, stir;
4. above-mentioned mixed solution is ground on three-roll grinder 5 times, roller temperature is controlled at 30 ℃.
5. then other all raw materials (PHOTOMER40731kg) in feed liquid two and the prescription are filtered the back and add, mix, stir.
6. above-mentioned printing ink is gone on three-roll grinder again white ink 97kg.
7. various test ratings see attached list 1 and subordinate list 2.
The preparation of embodiment 6 UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| (1) Xin Limei 710C60 resin | 5 |
| (1) the special EB436 resin of cyanogen | 20.2 |
| (1) the special EB845 resin of cyanogen | 5 |
| (6) BASF 9026V resin | 10 |
| (2) Sartomer PR08008A resin | 5 |
| (3) happiness comes black UVU6451 resin | 4 |
| (4) TPGDA monomer | 3 |
| (5) self-control DAP-A-40 resin | 6 |
| (5) the special EB860 resin of cyanogen | 6 |
| (7) the PHOTOMER4073 resin of Kening Co.,Ltd | 1 |
| (7) Sartomer CD9050 | 1 |
| (9) 510 stoppers | 0.1 |
| (8) 184 initiators | 2 |
| (8) ITX initiator | 2 |
| (8) 369 initiators | 1 |
| (8) 651 initiators | 6 |
| (12) 32000 dispersion agents | 0.2 |
| (11) vapour crust LBL Huang | 8 |
| (11) vapour crust LCT Huang | 8.5 |
| (10) talcum powder | 3 |
| (12) wax powder | 1 |
| (12)BYK2500 | 3 |
| Add up to | 100 |
Making method:
1. with EM2380 with the DAP-A solid resin by being dissolved into liquid resin DAP-A-40 at 6: 4;
2. DAP-A-40 being ground dispersion resin 6kg, EB860 grinds each 6kg of dispersion resin, 710C60 resin 5kg, EB436 resin 20.2kg, EB845 resin 5kg, PR08008A resin resin 5kg, UVU6451 resin 4kg and mixes with 9026V resin 10kg, stirring stirs in stirring tank, filter, get feed liquid one;
3. get feed liquid one 15kg and add TPGDA monomer 3kg, stir, 369 initiator 1kg, ITX initiator 2kg, 651 initiator 6kg and 184 initiator 2kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
4. add 32000 dispersion agent 0.2kg in remaining feed liquid one, stirring at low speed is even; Amount to 16.5kg, talcum powder 3kg, 510 stopper 0.1kg to wherein adding yellow powder again, 600 commentaries on classics/min are stirred to about 50 ℃ of material temperature.Restir 35 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
5. above-mentioned mixed solution is ground on three-roll grinder 6 times, roller temperature is controlled at 30 ℃.
6. then other all raw materials (BYK3510, PHOTOMER4073 promotor, CD9050) in feed liquid two and the prescription are added, mix, stir.
7. above-mentioned printing ink is gone on three-roll grinder again Yellow ink 98.5kg.
8. various test ratings see attached list 1 and subordinate list 2.
The preparation of embodiment 7 UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| (1) Xin Limei 705 resins | 10 |
| (1) Xin Limei 710C60 resin | 15 |
| (1) the special EB857 resin of cyanogen | 2.5 |
| (6) BASF 9026V resin | 5 |
| (2) Sartomer PR08008A resin | 4 |
| (2) Sartomer CNUVE-150 resin | 5.4 |
| (3) happiness comes black UVU6451 resin | 3 |
| (4) TPGDA monomer | 3 |
| (5) LR9013 grind resin | 6 |
| (6) self-control DAP-A-40 resin | 6 |
| (7) the PHOTOMER4073 resin of Kening Co.,Ltd | 1 |
| (7) the special EB170 of cyanogen | 1 |
| (9) ST-1 stopper | 0.1 |
| (8) 184 initiators | 2 |
| (8) ITX initiator | 2 |
| (8) 1173 initiators | 1 |
| (8) EDAB initiator | 1 |
| (8) 907 initiators | 5 |
| (12) 32000 dispersion agents | 1 |
| (11) 53:1 golden red | 19 |
| (10) aerosil M-5 | 3 |
| (12) wax powder | 1 |
| ?(12)BYK3510 | 3 |
| Add up to | 100 |
Making method:
1. with EM2380 with the DAP-A solid resin by being dissolved into liquid resin DAP-A-40 at 6: 4;
2. DAP-A-40 being ground dispersion resin 6kg, LR9013 grinds each 6kg of dispersion resin, 710C60 resin 15kg, 705 resin 10kg, EB857 resin 2.5kg, PR08008A resin resin 4kg, Sartomer CNUVE-150 resin 5.4kg, UVU6451 resin 3kg and mixes with 9026V resin 5kg, stirring stirs in stirring tank, filter, get feed liquid one;
3. get feed liquid one 15kg and add TPGDA monomer 3kg, stir, EDAB initiator 1kg, ITX initiator 2kg, 1173 initiator 1kg, 907 initiator 5kg and 184 initiator 2kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
4. add 32000 dispersion agent 1kg in remaining feed liquid one, stirring at low speed is even; Amount to 19kg, aerosil M-53kg, ST-1 stopper 0.1kg to wherein adding the golden red toner again, 600 commentaries on classics/min are stirred to about 45 ℃ of material temperature.Restir 30 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
5. above-mentioned mixed solution is ground on three-roll grinder 7 times, roller temperature is controlled at 30 ℃.
6. then other all raw materials in feed liquid two and the prescription (BYK3510, PHOTOMER4073 promotor, the special EB170 of cyanogen) are added, mix, stir.
7. above-mentioned printing ink is gone on three-roll grinder again Yellow ink 98kg.
8. various test ratings see attached list 1 and subordinate list 2.
The preparation of embodiment 8 UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| (1) Japanese East Asia M-8060 resin | 10 |
| (1) the special EB859 resin of cyanogen | 5 |
| (1) strange titanium SA236 resin | 20.5 |
| (2) Sartomer CNUVE-150 resin | 5 |
| (3) happiness comes black UVU6451 resin | 3 |
| (4) HDDA monomer | 6 |
| (5) LR9013 grind resin | 6 |
| (5) the special EB860 resin of cyanogen | 3 |
| (6) BASF 9026V resin | 5 |
| (7) the PHOTOMER4073 resin of Kening Co.,Ltd | 1 |
| ?(7)TAA | 1 |
| (9) TBQ stopper | 0.1 |
| (8) 184 initiators | 2 |
| (8) ITX initiator | 2 |
| (8) 369 initiators | 1 |
| (8) 907 initiators | 6 |
| (12) 32000 dispersion agents | 1.1 |
| (11) the blue powder of 5380E | 17.3 |
| (10) lime carbonate SPO-500 | 3 |
| (12) wax powder | 1 |
| ?(12)BYK2500 | 1 |
| Add up to | 100 |
Making method:
1. with LR9013 and each 6kg of EB860 resin ground dispersion resin and 3kg, M-8060 resin 10kg, EB859 resin 5kg, SA236 resin 20.5kg, CNUVE-150 resin 5kg, UVU6451 resin 3kg, mix with 9026V resin 5kg, stirring stirs in stirring tank, filter, get feed liquid one;
2. get feed liquid one 10kg and add HDDA monomer 6kg, stir, 369 initiator 1kg, ITX initiator 2kg, 907 initiator 6kg and 184 initiator 2kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
3. add 32000 dispersion agent 1.1kg in remaining feed liquid one, stirring at low speed is even; To wherein adding the blue powder 17.3kg of 5380E, lime carbonate SPO-5003kg, TBQ stopper 0.1kg, 600 commentaries on classics/min are stirred to about 50 ℃ of material temperature again.Restir 30 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
4. above-mentioned mixed solution is ground on three-roll grinder 5 times, roller temperature is controlled at 30 ℃.
5. then other all raw materials (BYK2500, TAA, PHOTOMER4073 promotor) in feed liquid two and the prescription are added, mix, stir.
6. above-mentioned printing ink is gone on three-roll grinder again blue ink 98kg.
7. various test ratings see attached list 1 and subordinate list 2.
The preparation of embodiment 9 UV curable ink:
Raw materials used kind and weight (kg) prescription is:
| (1) Japanese East Asia M-8060 resin | 7 |
| (1) Xin Limei 710G60 resin | 10 |
| (1) the special EB812 resin of cyanogen | 6 |
| (1) the special EB657 of cyanogen | 2 |
| (2) Sartomer PR08008A resin | 7 |
| (2) Sartomer CNUVE-150 resin | 8 |
| (3) happiness comes black UVU6451 resin | 3 |
| (6) BASF 9026V resin | 5 |
| (5) LR9013 grind resin | 9 |
| (5) self-control DAP-A-40 resin | 6 |
| (7) the PHOTOMER4073 resin of Kening Co.,Ltd | 1 |
| (7) the special EB168 of cyanogen | 1 |
| (9) TBQ stopper | 0.3 |
| (8) 184 initiators | 2 |
| (8) ITX initiator | 2 |
| (8) 369 initiators | 1 |
| (8) 651 initiators | 2 |
| (8) 907 initiators | 4 |
| (12) 32000 dispersion agents | 0.5 |
| (11) carbon black pigment | 17.7 |
| (10) talcum powder | 2.5 |
| (12) wax powder | 1 |
| ?(12)BYK3510 | 3 |
| Add up to | 100 |
Making method:
1. with EM2380 with the DAP-A solid resin by being dissolved into liquid resin DAP-A-40 at 6: 4;
2. LR9013 is ground dispersion resin 9kg, self-control DAP-A-40 resin 6kg, M-8060 resin 7kg, 710G60 resin 10kg, EB812 resin 6kg, EB657 resin 2kg, PR08008A resin 7kg, CNUVE-150 resin 8kg, UVU6451 resin 3g mixes with 9026V resin 5kg, stirring stirs in stirring tank, filter, get feed liquid one;
3. get feed liquid one 15kg, 369 initiator 1kg, ITX initiator 2kg, 651 initiator 2kg, 907 initiator 4kg and 184 initiator 2kg mixed dissolutions in wherein, are filtered, it is standby to get feed liquid two;
4. add 32000 dispersion agent 1kg in remaining feed liquid one, stirring at low speed is even; To wherein adding carbon black pigment 250R17.7kg, lime carbonate SPO-5002.5kg, TBQ stopper 0.3kg, 600 commentaries on classics/min are stirred to about 50 ℃ of material temperature again.Restir 30 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
5. above-mentioned mixed solution is ground on three-roll grinder 7 times, roller temperature is controlled at 40 ℃.
6. then other all raw materials (BYK3510, PHOTOMER4073 promotor, EB168) in feed liquid two and the prescription are added, mix, stir.
7. above-mentioned printing ink is gone on three-roll grinder again black ink 97kg.
8. various test ratings see attached list 1 and subordinate list 2.
Embodiment 10:
Raw materials used kind and weight (kg) prescription is:
Making method:
1. CN738 resin 45kg, 6353 resin 6kg, EB811 resin 2kg are mixed with 9026V resin 2kg, the stirring that stirs in stirring tank is filtered, and gets feed liquid one;
2. with 819 initiator 1kg and 184 initiator 2kg and TMPTA monomer 4.5kg mixed dissolution, filter, it is standby to get feed liquid two;
3. add BYK168 dispersion agent 1kg in feed liquid one, stirring at low speed is even; To wherein adding RDI-S titanium dioxide 35kg, talcum powder 1kg, 510 stopper 0.5kg, 600 commentaries on classics/min are stirred to about 40 ℃ of material temperature again.Restir 25 minutes makes pigment abundant wetting being uniformly dispersed in resin.Add wax powder 1kg then, stir;
4. above-mentioned mixed solution is ground on three-roll grinder 5 times, roller temperature is controlled at 35 ℃.
5. then other all raw materials (AP-100 adhesion promoter) in feed liquid two and the prescription are filtered the back and add, mix, stir.
6. above-mentioned printing ink is gone on three-roll grinder again white ink 98kg.
7. various test ratings see attached list 1 and subordinate list 2.
Subordinate list 1: performance index detected result
| Project | Color | Fineness (μ m) | Viscosity (mPaS) | Viscosity (n/m2) | Degree of mobilization (mm) | Emulsification value (g) | Solidify (m/min) |
| Company standard | Approximate standard specimen | ≤10 | 150000～ 450000 | 5～25 | 20～45 | 25～ 35 | 15～35 |
| Example 1 | Approximate standard specimen | 6 | 190000～ 260000 | 11.5 | 28.2 | 32.1 | 32 |
| Example 2 | Approximate standard specimen | 7 | 180000～ 270000 | 10.0 | 29.5 | 29.5 | 35 |
| Example 3 | Approximate standard specimen | 6 | 120000～ 230000 | 16.9 | 29.7 | 30.1 | 31 |
| Example 4 | Approximate standard specimen | 5 | 260000～ 360000 | 10.4 | 30.0 | 30.5 | 30 |
| Example 5 | Approximate standard specimen | 7 | 140000～ 250000 | 11.9 | 32.5 | 29.8 | 34 |
| Example 6 | Approximate standard specimen | 5 | 180000～ 250000 | 12.7 | 30.9 | 30.5 | 30 |
| Example 7 | Approximate standard specimen | 3 | 130000～ 240000 | 15.6 | 30.6 | 31.6 | 33 |
| Example 8 | Approximate standard specimen | 6 | 170000～ 280000 | 14.8 | 31.5 | 29.6 | 32 |
| Example 9 | Approximate standard specimen | 5 | 190000～ 280000 | 13.2 | 30.7 | 29.4 | 31 |
| Example 10 | Approximate standard specimen | 4 | 100000～ 110000 | 17.6 | 31.5 | 29.0 | 32 |
Subordinate list 2: printing ink VOC content analysis detected result
Unit: PPM
| Analysis project | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | Example 7 | Example 8 | Example 9 | Example 10 | Enterprise's value of limiting the quantity of |
| Benzene | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Must not check |
| Ethanol | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | 1200 |
| Virahol | 64.5 | 81.8 | 61.6 | 57.12 | 62.35 | 71.39 | 71.28 | 54.96 | 67.68 | 72.486 | 120 |
| Acetone | 2.320 9 | 2.3252 | 2.5404 | 2.3077 | 2.3798 | 2.8932 | 2.9145 | 3.3146 | 2.8714 | 3.4103 | 21 |
| Butanone | 1.457 9 | 2.5596 | 0.9346 | 0.8286 | 1.0359 | 1.3461 | 1.7859 | 1.9684 | 1.6481 | 1.0301 | 9 |
| Ethyl acetate | 1.640 2 | 0.4672 | 2.3621 | 2.9467 | 3.0125 | 3.7981 | 3.2546 | 3.6532 | 2.8567 | 3.015 | 210 |
| Isopropyl acetate | 1.856 4 | 1.9429 | 2.3465 | 3.921 | 2.5794 | 4.1695 | 5.1897 | 2.6439 | 0.6247 | 0.6219 | 60 |
| Propyl carbinol | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | 45 |
| The third two | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | 1740 |
| The alcohol methyl ether | |||||||||||
| N-propyl acetate | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | 1440 |
| 4-methyl-2-pentanone | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | 15 |
| Toluene | 3.986 | Do not detect | 4.1235 | 5.1469 | 8.5362 | 7.5469 | 2.2587 | 3.0698 | 6.3789 | 9.9436 | 15 |
| N-butyl acetate | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | Do not detect | 120 |
| Ethylbenzene | 1.296 8 | 1.2822 | 1.6532 | 3.8078 | 2.6534 | 2.7595 | 3.5698 | 4.2131 | 2.9878 | 3.6969 | 7.5 |
| Dimethylbenzene | 2.612 4 | 3.1614 | 2.1302 | 3.1803 | 2.0322 | 1.2678 | 1.8765 | 2.0961 | 1.8125 | 1.8029 | 7.5 |
| Pimelinketone | 0.310 9 | 0.2198 | 0.5476 | 0.6526 | 0.3963 | 0.2564 | 0.2968 | 0.4587 | 0.3126 | 0.5025 | 24 |
Claims (2)
1. a ultraviolet cured offset printing ink is characterized in that the quality index of product is: fineness :≤10 μ m, viscosity: 150000～450000Mpa.s, viscosity: 5～25n/m
2, degree of mobilization: 20～40mm, emulsification value: 25～35g solidifies: 15～35m/min; Weight percent by following component is formed:
Wherein: described polyfunctionality polyester acrylic resin or polyfunctionality polyester chloride acrylic ester are meant polyester or the chlorinated polyester acrylic resin of functionality between 4～10, are the CN2203 of U.S.'s Sartomer, CN736, CN738, CN750; 6350,6351,6353 of Changxing, Taiwan; The EBECRYL811 of the special company of U.S.'s cyanogen, EBECRYL812, EBECRYL845, EBECRYL857, EBECRYL859, EBECRYL657, EB1ECRYL1657, EBECRYL436, EBECRYL438; Strange titanizing worker's SP236; 705 of Taiwan Xin Limei company, 710C60,710G60; Japan East Asia synthetic M-8060 is with 3～5 kinds in raising variety;
Described epoxy acrylate oligomer is meant the acrylic ester oligomer of the epoxidation modification of 2～6 functionality, is the CN2204 of U.S.'s Sartomer, PRO8008A, among the CNUVE-150 1～2 kind;
Described polyfunctionality urethane acrylate is meant the polyurethane acrylic resin with 2～6 functionality, a kind of among the UVU6451 of UV2630, the Shaanxi Xi Laiwu of middle mountain Chiba;
Described difunctionality or polyfunctionality Acrylic Acid Monomer are meant in Viscoat 295 commonly used, tri (propylene glycol) diacrylate, the 1.6-hexanediyl ester 1～2 kind;
Described grind resin is meant the extraordinary resin of pigment wetting, be meant the LR9013 of German BASF AG, the EBECRYL860 of the special company of U.S.'s cyanogen, the DAP-A resin of Japan Da Cao strain scholar commercial firm is dissolved in the ethoxyquin Viscoat 295 by 40% concentration, in the DAP-A-40 resin 1～2 kind; Described DAP-A-40 resin is by being dissolved into liquid resin at 6: 4 liquid monomer EM2380 and DAP-A solid resin;
The improved polyether acrylate of described nano silicon is meant the LR9026V of German BASF AG;
Described adhesion promoter is meant the Acrylic Acid Monomer or the acrylated oligomer of phosphoric acid modification, is the CD9050 and the CD9051 of U.S. Sartomer company; The EBECRYL168 and the EBECRYL170 of the special company of U.S.'s cyanogen; The PHOTOMER4073 and 4703 of Germany Kening Co.,Ltd, the TA-12P of du pont company, the TAA of Taiwan Borica company, AP-100 is with 1～2 kind in raising variety;
Described light trigger is 907,184,369, among ITX, EDAB, 651,1173,819, TPO, the TPO-L 2～5 kinds;
Described stopper is 1～2 kind in 510 solid aluminum salt, ST-1 liquid aluminium salt, TBQ, the MEHQ;
Described pigment is that white is titanium dioxide, and black is carbon black, and yellow is the GRX-86 of Clariant, the yellow and LBL Huang of the LCT of vapour crust, and redness is the 57:1 fuchsin, the 53:1 golden red, 146# is bright red, and blueness is the 15:4 phthalocyanine blue, and the 5380E of DIC is with 1～2 kind in raising variety;
Described auxiliary agent is meant dispersion agent: the German BYK BYK163 of company, BYK168, hyper-dispersant 24000,32000; Damage resistant auxiliary agent: BYK2500, BYK-3510; The CERAFLOUR 991 of wax powder: BYK, the FS-731MG of the U.S. three leaf companies, 675A; With 1～3 kind in raising variety.
2. the preparation method of ultraviolet cured offset printing ink as claimed in claim 1 is characterized in that raw materials used quality per distribution ratio is:
Step of preparation process is:
(1) premix: with the improved polyether acrylate of nano silicon, polyfunctionality polyester acrylic resin or polyfunctionality polyester chloride acrylic ester, epoxy acrylate oligomer, multifunctional urethane acrylate and grind resin, in stirring tank, stir, filter, get feed liquid one;
(2) dissolving: solid photoinitiator is dissolved in advance with difunctionality Acrylic Acid Monomer or polyfunctionality Acrylic Acid Monomer, filter;
(3) disperse: in feed liquid one, add dispersing auxiliary, after stirring at low speed is even, add pigment or dyestuff, filler again, add stopper simultaneously, after stirring at low speed mixes, stir with 600～1200rpm, when raising the temperature to 50 degrees centigrade of left and right sides, restir 30min makes pigment and filler abundant wetting being uniformly dispersed in resin liquid, reduce stirring velocity then and add wax powder and other powder auxiliary agents, stirring gets final product;
(4) grind: on three-roll grinder, grind 5～10 times, at 30～50 ℃ the printing ink fineness is reached below the 10 μ m with recirculated cooling water control roller temperature;
(5) add or dilution the back: interpolation is dissolved good in advance and is crossed filterable light trigger on high speed dispersor, adds other auxiliary agents, adhesion promoter, stirs;
(6) ground and mixed: the above-mentioned ink body that stirs is gone on three-roll grinder again, to keep printing ink thorough mixing and printing ink outward appearance sophistication;
(7) check: check every index;
(8) packing: the packing get final product finished product.
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240466A (en) * | 1996-12-17 | 2000-01-05 | 美国3M公司 | Curable ink composition |
| CN1884401A (en) * | 2005-06-24 | 2006-12-27 | 上海华明高技术（集团）有限公司 | Ultraviolet light cured printing ink |
| CN101225267A (en) * | 2007-12-10 | 2008-07-23 | 佛山市儒林化工有限公司 | Environment-friendly type ultraviolet-curing metal decorating gloss oil and curing technology thereof |
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| CN101560348A (en) | 2009-10-21 |
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Assignee: Wuxi Jinqiao Fine Ink Co.,Ltd. Assignor: Wang Jingquan Contract record no.: 2012320000330 Denomination of invention: Ultraviolet light curing offset printing ink and preparation method thereof Granted publication date: 20111109 License type: Exclusive License Open date: 20091021 Record date: 20120329 |
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