CN103436079A - Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof - Google Patents
Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an environmental-friendly water-based nylon printing ink used for screen printing. The environmental-friendly water-based nylon printing ink comprises following ingredients, by weight: 30 to 65% of modified water-based acrylic acid emulsion, 0 to 15% of modified water-based polyurethane emulsion, 5 to 20% of deionized water, 0 to 10% water-based acrylic resin solution used for grinding and dispersing, 1 to 10% of an adhesion promoter, 0 to 15% of a cosolvent, 0 to 5% of a hydrophobic agent, 1 to 10% of a filling material, 0 to 25% of a pigment or a dye, and 0.2 to 15% of an auxiliary agent. The invention also discloses a preparation method of the environmental-friendly water-based nylon printing ink. The environmental-friendly water-based nylon printing ink prepared according to the formula above and by the preparation method is high in stability, contains no curing agent, and is easy for use and storage; is excellent in screenability, can be diluted with water, contains no irritating or harmful solvents such as benzenes, ketones and esters, is not toxic, not irritant, not combustible and not explosive, possesses less smell, will not cause VOC residue, and is an environmental-friendly ink. No harmful gas is generated in film-forming process of the environmental-friendly water-based nylon printing ink. If the environmental-friendly water-based nylon printing ink is used in the screen printing process, the screen can be washed with water. The grinding and dispersing resin is used for dispersing the pigment, so that production efficiency is increased greatly, and operation and popularization are relatively easy.
Description
Technical field
The present invention relates to the chemical industry technical field of polymer materials, particularly a kind of environment-friendly type wire mark water-based nylon printing ink and preparation method thereof.
Background technology
Along with social development, under the dual-pressure of energy dilemma and the motion of global anti-ring environment pollution, the screen printing ink solvent free has been a kind of trend.On following screen printing ink market, traditional solvent type ink is harmful because of it, and the solvent of volatilization causes topsoil, does not meet the environmental protection policy that national energy-saving reduces discharging and will be eliminated gradually, and wire mark use printing ink and UV printing ink will replace.
A kind of as printing consumable material, treated nylon cloth is widely used in making high-grade sportwear, umbrella, parasols, outdoor advertising vertically hung scroll etc., for people's life offers convenience and color.At present in screen printing ink market nylon printing ink roughly to be divided into solvent-borne type single-component low temperature baking-type printing ink, solvent-based two-component printing ink, UV silk-screen nylon printing ink and water-based nylon printing ink several.Solvent-borne type nylon printing ink is harmful, has volatile gases to produce, and easily to environment, will be eliminated gradually; The required ultraviolet light polymerization facility investment of UV silk-screen nylon printing ink is large, and is difficult for solidifying more difficult promoting the use of when the China ink layer is thicker; And water-based nylon printing ink because it is nontoxic, nonirritant, do not fire, the characteristic such as not quick-fried, extremely people's favor, the application on nylon cloth will be more and more extensive.
But, with traditional solvent-borne type nylon printing ink, to compare, water-based nylon printing ink has dry slow, water-wash resistance is poor, the defects such as the more traditional solvent-borne type nylon printing ink of sticking power is poor, can not the satisfying the market requirement, therefore at present in screen printing ink market traditional solvent-borne type nylon printing ink still account for larger specific gravity.For strengthening water tolerance and the sticking power of water-based nylon printing ink, part Printing ink producing business takes the mode of adding solidifying agent or stiffening agent to be improved, but consequent problem is greatly to reduce the quality guaranteed period of water-based nylon printing ink, add the printing ink of solidifying agent within general 4 to 5 hours, to occur to solidify, and the reaction of solidifying agent makes the wire mark performance extreme difference of printing ink, the phenomenon of mesh often appears stopping up, simultaneously also for printing ink using and storage is made troubles.
Summary of the invention
For the problem of prior art, the present invention proposes a kind of environment-friendly type wire mark water-based nylon printing ink and preparation method thereof, and prepared printing ink does not add solidifying agent, belongs to single-component system, stable system, fast drying and have good water tolerance.
To achieve the object of the present invention, component and weight percent thereof that environment-friendly type wire mark water-based nylon printing ink of the present invention comprises are: modified aqueous acrylic acid emulsion 30-65%, modified aqueous polyurethane emulsion 0-15%, deionized water 5-20%, grinding distribution use acrylic resin liquid 0-10%, adhesion promoter 1-10%, solubility promoter 0-15%, hydrophobizing agent 0-5%, filler 1-10%, pigment or dyestuff 0-25%, and auxiliary agent 0.2-15%.
Preferably, described solubility promoter comprises ethanol, Virahol, ethylene glycol or quadrol.
Preferred again, described filler is to have water-fast, as to increase cunning, wear-resisting effect wax powder or wax slurry and aerosil.
Preferred again, described auxiliary agent comprises dispersion agent, defoamer, flow agent, base material wetting agent, thickening material, and pH adjusting agent.
Another object of the present invention is the preparation method who proposes a kind of above-mentioned environment-friendly type wire mark water-based nylon printing ink, and described preparation method comprises: mill base and preparation water-based nylon printing ink for preparation water-based nylon printing ink; Wherein said preparation water-based nylon printing ink comprises the steps: with mill base
Premix: grinding distribution use ACRYLIC EMULSION, deionized water are stirred in stirring tank;
Regulation system pH: adding pH adjusting agent to reconcile system pH is 7～10;
Disperse: add load weighted other auxiliary agents and comprise dispersion agent, defoamer etc. on high speed dispersor, stir; Then add pigment etc., make pigment fully wetting in system; And
Grind: scattered mill base system is ground on three-roll grinder, with recirculated cooling water, control roller temperature, the printing ink fineness is reached below 10 microns, stand-by;
Described preparation water-based nylon printing ink comprises the steps:
Premix: by modified aqueous acrylic acid emulsion, modified aqueous polyurethane emulsion, deionized water etc., stir in stirring tank;
Regulation system pH: adding pH adjusting agent to reconcile system pH is 7～10;
Disperse: in the system that is 7～10 at pH, add while stirring auxiliary agent and the solubility promoters such as load weighted defoamer, flow agent, adhesion promoter, hydrophobizing agent, thickening material, after stirring at low speed mixes, and then add filler, stir;
Rear interpolation: add ground mill base in the above-mentioned system mixed, stir;
Ground and mixed: the above-mentioned ink body stirred is ground on three-roll grinder; And
Check and packing: the check indices, qualified rear packing gets final product to obtain finished product.
Preferably, adopt the fineness of above-mentioned formula and the prepared printing ink of above-mentioned technique≤10 μ m, viscosity is 4000～10000Mpa.s, and be 30～60min the time of drying of 75～90 ℃.
The wire mark water-based nylon printing ink that the above-mentioned formula of employing of the present invention and preparation method produce, good stability,, containing solidifying agent, be not easy to use and store; Nontoxic low smell, nonirritant, do not fire not quick-friedly, and VOC free is residual, and film process, without noxious gas emission, belongs to environment-friendly type printing ink; Used the formula of grinding distribution resin dispersion pigment, improved widely production efficiency, and be very easy to operation and promote.
The accompanying drawing explanation
By the detailed description below in conjunction with accompanying drawing, aforesaid purpose, the feature and advantage with other of the present invention will become apparent.Wherein:
Figure 1 shows that preparation method's schema of environment-friendly type wire mark water-based nylon printing ink of the present invention;
Figure 2 shows that the flow chart of steps of the preparation water-based nylon printing ink of Fig. 1 with mill base;
Figure 3 shows that the flow chart of steps of the preparation water-based nylon printing ink of Fig. 1.
Embodiment
Component and weight percent thereof that environment-friendly type wire mark water-based nylon printing ink of the present invention comprises are: modified aqueous acrylic acid emulsion 30-65%, modified aqueous polyurethane emulsion 0-15%, deionized water 5-20%, grinding distribution use acrylic resin liquid 0-10%, adhesion promoter 1-10%, solubility promoter 0-15%, hydrophobizing agent 0-5%, filler 1-10%, pigment or dyestuff 0-25%, and auxiliary agent 0.2-15%.
Above-mentioned aqueous acrylic emulsion, refer to the self-crosslinking aqueous emulsion through special processing, Bayer Bay hydrol A 2457 as the Shanghai Bayer, France A Kema 752 emulsions, Bai Ke front yard, Shanghai GA-3018, 2026 emulsions, jade-like stone Ninghua, Guangzhou work R-48, the R-91 emulsion, the blue Sa SF10 of the new light Supreme Being in Hengshui, SF150, HS123, the HS168A emulsion, Zhuhai lucky power chemical industry WA-2007, WA-2008, the JL-25E emulsion, sincere chemical industry HS6420 emulsion is closed in Guangzhou, the J-89 of BASF, Joncryl 74-A, FLX 5002, FLX 5010, FLX 5020, Niu Peisi resin PB-3, HBS-2, east, Beijing connection chemical industry DL-624, the DL-6618 emulsion, they can be allocated separately according to kind and the ratio of other emulsions, also or in twos allotment or multiple composite, described aqueous polyurethane emulsion, all pass through special processing or property modification, PU218A as Guangzhou hat will chemical industry, PU202C, PU303B, the R-86 of jade-like stone Ninghua, Guangzhou work, R-50, DSM resin R2005, R674, 6630, the KT706 of section's sky chemical industry, KT703, DOW CORNING D620, D630, Mitsui Chemicals WS-5100, WS-6021, W-5030, 6106 polyaminoester emulsions of Yantai Wanhua Polyurethane Co., Ltd, the international holding PU406 of Zhong Hua, they can be allocated separately according to kind and the ratio of other emulsions, also or in twos allotment or multiple composite.
In addition, described deionized water makes through ion exchange resin, described grinding distribution use acrylic resin liquid requires to have pigment wettability and higher stability in storage preferably, R-70A as peaceful as the Guangzhou jade-like stone, DSM resin B T-20, BT-24, the chemical industry SR661 of Guangzhou You Ni section can be 1～2 kind that uses wherein; Described adhesion promoter requires to have higher stability and sticking power promoter action preferably, as Germany watt gram AG628, Yi Siman chemical industry Texanol, Bi Ke chemistry BYK-4500, BYK-4510, upper seamount dimerization work DC-51, SJ2176, public credit international trade ZINPLEX 15.
Separately, described solubility promoter refers to alcohols and the amine of a small amount of interpolation, as ethanol, Virahol, ethylene glycol, glycerol or quadrol; Described hydrophobizing agent requires to have stability and water tolerance preferably, as the mechanical ohm Film S40 of Wuxi section, DISPER CI655, and Germany watt gram ECKO-50, ECKO-52, ECKO-53, Shenzhen Hai Run chemical industry BS206, can select wherein 1～2 kind.
Described filler refer to have water-fast, increase cunning, the wax powder of wear-resisting effect or wax slurry, as German Bi Ke chemistry CERACOL 39, CERACOL 601, CERACOL 603, CERACOL 607, global chemical industry (China) AQUAPOLYSILK of company limited 19, AQUAPOLYFLUO 411, AQUAPOLY 250, MICROSPERSION 411-50, Shanghai Bei Meng chemistry NP2400, NP2401, NP2404, and there is the aerosil that improves the ink system rheological property, as moral mountain chemical industry QS-102, QS-20, QS-30, QS-40, the M-5 of Cabot, win the 0K520 of wound Degussa, OK412, the SY-350 of Japanese fuji, it can be 1～3 kind that uses wherein.
Printing ink of the present invention pigment used can be: titanium dioxide (Dupont 706,902; The R595 of Mei Lilian; The TR52 that Britain's Hensel is graceful, TR-92; The former R-828 of Japan's stone; The RDI-S of Finland), as carbon black (MA-100 of Mitsubishi, MA-75; The M-L of Cabot, the special 4A of Degussa, the U carbon black), permanent yellow (14 ° of water-based yellow pigments), organic yellow (yellow), as TCY00302, TCY01403, permanent bordeaux, everbright fast red (redness), as TCR48101, TCR49102, TCR53101, phthalocyanine blue (blueness), as TCB15308 etc., select wherein one or more as required.
Environment-friendly type wire mark water-based nylon printing ink of the present invention auxiliary agent used comprises that dispersion agent comprises:
Dispersion agent, as the zetasperse 1200 mineral dye dispersion agents of U.S.'s aerochemistry, zetasperse 1600 pigment dyestuff dispersion agents, zetasperse 2100 carbon black dispersants; Shenzhen Hai Run chemical industry DP2837, DP2883, the luxuriant and rich with fragrance chemical development in science and technology DS-960 of company limited of Tianjin match, hamming this chemical W-18, W-920, the high auxiliary agent 750W of enlightening, French A Kema 123K, P30;
Defoamer, as U.S. aerochemistry Surfynol DF-58, Surfynol DF-40; Prosperous titanium digests learns 628K, Ke Naiou trade T-4201, Shenzhen Hai Run chemical industry CF268, CF439, the luxuriant and rich with fragrance chemical development in science and technology DF-220M of company limited of Tianjin match, German Bi Ke chemistry BYK-011, BYK-044, DOW CORNING DC-89, the high auxiliary agent 822 of enlightening, K3,830,810, Bai Ke front yard, Shanghai 8370;
Flow agent, as U.S. aerochemistry Surfynol 465 tensio-active agents; The high auxiliary agent 100 of enlightening, DOW CORNING DC-401LS, DC-205SL, the virtuous trade TA-4613 in Pu, Shanghai, Bi Ke chemistry BYK-301, BYK-331;
The base material wetting agent, as Shenzhen Hai Run chemical industry NS2125, NS2510, the WORLEE/ moral composes happy 340, DOW CORNING DC-67, Germany Bi Ke chemistry BYK345, BYK346, BYK347, BYK348, BYK381, sea, Shanghai ease science and trade C77, C1211, the high auxiliary agent Wet 270 of enlightening, KL 245, DO-75, WET500, the luxuriant and rich with fragrance chemical development in science and technology S-182 of company limited of Tianjin match, LS-101E, FS-204E;
Thickening material, as Ke Naiou trade XLS525, Shenzhen Hai Run chemical industry R625, TS2751, TA2851, golden fraternal chemical industry UH-450VF, UH-420, Bai Ke front yard, Shanghai 8W, A200, French A Kema 53L, 2025,6050, XS71;
PH adjusting agent, as Ke Naiou trade PHLEX110, Germany watt gram AMP-95, Shenzhen Hai Run chemical industry BS168, this chemical DMEA of hamming.
Below with a specific embodiment, illustrate that the preparation method of environment-friendly type wire mark water-based nylon printing ink of the present invention is as follows:
The raw material adopted and weight (Kg) proportion is as follows:
Referring to figs. 1 through the processing step of Fig. 3, preparation process is as follows:
First part: preparation water-based nylon printing ink mill base, it comprises the steps:
S1. premix: grinding distribution use ACRYLIC EMULSION BT-24, deionized water are stirred in stirring tank;
S2. regulation system pH: adding AMP-95 to reconcile system pH is 7～10;
S3. disperse: add load weighted dispersion agent 1600, BYK-345 on high speed dispersor, defoamer DC-89, stir; Then add pigment TCR48101, make pigment fully wetting in system; And
S4. grind: scattered mill base system is ground for several times on three-roll grinder, preferred, for 2-10 time), control roller temperature (preferred, the control temperature is 30-50 degree centigrade) with recirculated cooling water, the printing ink fineness is reached below 10 microns, stand-by.
Second section: preparation water-based nylon printing ink, it comprises the steps:
S1. premix: by modified aqueous acrylic acid emulsion BAYER2457,752, SF10, FLX5010; Modified aqueous polyurethane emulsion WS5030, D620, deionized water stir in stirring tank;
S2. regulation system pH: adding pH adjusting agent AMP-95 to reconcile system pH is 7～10;
S3. disperse: in the system that is 7～10 at pH, add while stirring load weighted defoamer DC-89, flow agent BYK301, adhesion promoter DC-51, BYK4510, hydrophobizing agent BS206, ECKO-50, thickening material UH450VF and ethanol, ethylene glycol, glycerol, after stirring at low speed mixes, and then add SY-350, M-5, CERACOL603, stir and get final product;
S4. add afterwards: add ground mill base in the above-mentioned system mixed, stir;
S5. ground and mixed: the above-mentioned ink body stirred is gone on three-roll grinder again, fully mixed and printing ink outward appearance sophistication to keep printing ink;
S6. check and pack: the check indices, qualified rear packing gets final product to obtain finished product.
The project that the printing ink made according to above-mentioned method is detected and index result are as follows:
| Project | Viscosity | Rate of drying (90 degree temperature) | Color | Fineness (μ m) |
| Index | 9500mpa.s | 30mim | The approximate test sample | 8μm |
Described acquisition printing ink is upper at the umbrella cover nylon cloth (treated nylon cloth surface) of paradise, Hangzhou umbrella group with 250 order half tone silk screen printings, 90 degree temperature baking 30min; As follows by the test film performance:
Adopt above-mentioned formula and the printing ink of above-mentioned explained hereafter, beautiful in colour, good fluidity, dot reproduction is strong, and the color reductibility is good; Printability is good, and film performance is good, after heat treatment on nylon cloth, has excellent sticking power and water-wash resistance.Described acquisition printing ink is by silk screen printing on treated nylon cloth surface, and film performance is as follows:
1. the coating film gloss degree is good, has good recoatability;
2. to the strong adaptability of stock, black bed thickness is real, has stronger feel and stereoscopic sensation;
3. strong adhesion, 3M adhesive tape test sticking power, 100% without coming off;
4. have good wash durability: bubble is after 1 hour, and through firmly rubbing, paint film comes off;
5. be environment-friendly type printing ink, nontoxic nonirritant, do not fire not quick-friedly, and low smell, can not cause environmental pollution and harm operator ' s health, and VOC free is residual.
The wire mark water-based nylon printing ink that adopts above-mentioned formula and preparation method to produce, not containing solidifying agent, belongs to mono-component aqueous nylon printing ink, is easy to use and store, and good stability, cross net splendid; Can dilute with water, wash version with water, containing benezene not, ketone, the pungency hazardous solvents such as ester class, nontoxic low smell, nonirritant, do not fire not quick-friedly, and printing process is safe and reliable; Film process, without noxious gas emission, can not cause environmental pollution and harm operator ' s health, belongs to environment-friendly type printing ink; Used the formula of grinding distribution resin dispersion pigment, improved widely production efficiency, reduced energy consumption, and be very easy to operation and promote.
Gained printing ink of the present invention after heat treatment has no less than the sticking power of conventional solvent type nylon printing ink, and the wash durability excellence can replace the printing of solvent type ink for nylon cloth.And Printing ink producing cost of the present invention is low than conventional solvent type nylon printing ink, and the printed dimensions scope is large, can replace the decorating printing that conventional solvent type nylon printing ink is widely used in nylon cloth.
Printing ink of the present invention can free colour mixture, and transparent, opaque, light, dumb light can be adjusted voluntarily, varied to the decorative effect of nylon cloth.
The present invention is not limited to described embodiment, and those skilled in the art, not breaking away from spirit of the present invention openly in scope, still can do some corrections or change, therefore the scope that the scope of the present invention limits with claims is as the criterion.
Claims (8)
1. an environment-friendly type wire mark water-based nylon printing ink, it is characterized in that, the component that described printing ink comprises and weight percent thereof are: modified aqueous acrylic acid emulsion 30-65%, modified aqueous polyurethane emulsion 0-15%, deionized water 5-20%, grinding distribution use acrylic resin liquid 0-10%, adhesion promoter 1-10%, solubility promoter 0-15%, hydrophobizing agent 0-5%, filler 1-10%, pigment or dyestuff 0-25%, and auxiliary agent 0.2-15%.
2. environment-friendly type wire mark water-based nylon printing ink as claimed in claim 1, is characterized in that, described solubility promoter comprises ethanol, Virahol, ethylene glycol, glycerol or quadrol.
3. environment-friendly type wire mark water-based nylon printing ink as claimed in claim 1, is characterized in that, described filler is to have water-fast, as to increase cunning, wear-resisting effect wax powder or wax slurry and aerosil.
4. environment-friendly type wire mark water-based nylon printing ink as claimed in claim 1, is characterized in that, described auxiliary agent comprises dispersion agent, defoamer, flow agent, base material wetting agent, thickening material, and pH adjusting agent.
5. a preparation method who prepares environment-friendly type wire mark water-based nylon printing ink as claimed in claim 1, is characterized in that, described preparation method comprises: mill base and preparation water-based nylon printing ink for preparation water-based nylon printing ink; Wherein,
Described preparation water-based nylon printing ink comprises the steps: with mill base
Premix: grinding distribution use ACRYLIC EMULSION, deionized water and stirring is even;
Regulation system pH: adding pH adjusting agent to reconcile system pH is 7～10;
Disperse: add load weighted auxiliary agent on high speed dispersor, stir; Then add pigment to make it fully wetting in system;
Grind: scattered mill base system is ground on shredder, control roller temperature, the printing ink fineness is reached below 10 microns, stand-by;
Described preparation water-based nylon printing ink comprises the steps:
Premix: modified aqueous acrylic acid emulsion, modified aqueous polyurethane emulsion, deionized water and stirring is even;
Regulation system pH: adding pH adjusting agent to reconcile system pH is 7～10;
Disperse: in the system that is 7～10 at pH, add while stirring load weighted auxiliary agent and solubility promoter, add again filler after being uniformly mixed, stir;
Rear interpolation: add ground mill base in the above-mentioned system mixed, stir;
Ground and mixed: the above-mentioned ink body stirred is ground on roller mill; And
Check and packing: the check indices, qualified rear packing gets final product to obtain finished product.
6. the preparation method of environment-friendly type wire mark water-based nylon printing ink as claimed in claim 5, it is characterized in that, described preparation water-based nylon printing ink is with in the process of mill base, and in the described step that scattered mill base system is ground on three-roll grinder, the number of times of grinding is 2-10 time.
7. the preparation method of environment-friendly type wire mark water-based nylon printing ink as claimed in claim 5, it is characterized in that, described preparation water-based nylon printing ink is with in the process of mill base, in the described step that scattered mill base system is ground on three-roll grinder, controlling roller temperature is to be 30-50 degree centigrade with recirculated cooling water control roller temperature.
8. the preparation method of environment-friendly type wire mark water-based nylon printing ink as claimed in claim 5, is characterized in that, the fineness of prepared printing ink≤10 μ m, and viscosity is 4000～10000Mpa.s, be 30～60min the time of drying of 75～90 ℃.
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