CN106084984A - A kind of printing-ink - Google Patents

A kind of printing-ink Download PDF

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Publication number
CN106084984A
CN106084984A CN201610749370.4A CN201610749370A CN106084984A CN 106084984 A CN106084984 A CN 106084984A CN 201610749370 A CN201610749370 A CN 201610749370A CN 106084984 A CN106084984 A CN 106084984A
Authority
CN
China
Prior art keywords
ink
parts
printing
weight ratio
mixing composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610749370.4A
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Chinese (zh)
Inventor
王春生
贾志江
李明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Anjie Technology Co Ltd
Original Assignee
Suzhou Anjie Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Anjie Technology Co Ltd filed Critical Suzhou Anjie Technology Co Ltd
Priority to CN201610749370.4A priority Critical patent/CN106084984A/en
Publication of CN106084984A publication Critical patent/CN106084984A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • C09D11/105Alkyd resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/108Hydrocarbon resins

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of printing-ink, including the material of following weight portion: pigment 20 40 parts, link stuff 20 40 parts, solvent 25 45 parts, calcium carbonate 12 parts, defoamer 13 parts, levelling agent 13 parts, 26 parts of 5A molecular sieve, aerosil 12 parts, dispersant 26 parts, adhesion promoter 0.5 1.5 parts, colloid oil 25 parts, slip agent 13 parts, remove stick 14 parts, brucite 13 parts.Can strengthen the adhesive force of ink in the present invention, prevent ink from ink bleed occur, changing the phenomenons such as ink, chemical stability is strong, and the storage time is long, and printing performance is stable.

Description

A kind of printing-ink
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of printing-ink.
Background technology
Ink is for forming the material of graph text information in printing process, its directly determine leaflet epigraph contrast, Color, definition, therefore act on huge in printing process.But more existing printing-ink rate of dryings are the slowest, in print Brush often results in the phenomenon such as set-off, page sticking.Also have some printing-ink poor adhesive force, easily produce printing uneven, The phenomenons such as deinking, have a strong impact on printing quality, and the surface tension relationship of ink is holding to transfer performance and the trace of ink Stability on print face, when the surface tension of ink is more more than the surface tension in printing face, trace can shrink, even occur The aperture of fish-eye shaped;If printing face is close with the surface tension of ink, and the surface tension of half tone is more than the surface in printing face During tension force, printing there will be network blocking phenomenon, and how reconciliation statement surface tension is the problem needing to solve in fact, the storage effect of ink simultaneously Fruit is also the problem merited attention.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of printing-ink.
A kind of printing-ink that the present invention proposes, including the material of following weight portion: pigment 20-40 part, link stuff 20-40 Part, solvent 25-45 part, calcium carbonate 1-2 part, defoamer 1-3 part, levelling agent 1-3 part, 5A molecular sieve 2-6 part, aerosil 1-2 part, dispersant 2-6 part, adhesion promoter 0.5-1.5 part, colloid oil 2-5 part, slip agent 1-3 part, remove stick 1-4 part, Brucite 1-3 part.
Preferably, described slip agent is polypropylene wax.
Preferably, described link stuff is chlorinated polypropylene, rosin modified phenolic resin, alkyd resin and polyamide resin Fat is 1:2:1:1 mixing composition according to weight ratio.
Preferably, described solvent includes isopropanol, toluene, butyl ether, butyl acetate and butanone and is 3:3 according to weight ratio: 1:2:1 mixes composition.
Preferably, described defoamer is polyether-modified silicon.
Preferably, described levelling agent be polydimethylsiloxane and fluorinated siloxane be 2:1 mixing composition according to weight ratio.
Preferably, described adhesion promoter be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio.
Preferably, described dispersant is oleamide.
Preferably, to remove stick described in be eight aluminium carbonate, oleum lini and vaseline according to weight ratio is 2:2:1 mixing composition.
The present invention compared with prior art, the Advantageous Effects having:
In the present invention, select polypropylene wax can float over ink pellet surface as slip agent, reduce the surface tension of ink, make oil The coefficient of friction on second surface is reduced by ink, selects oleamide can reduce resin particle molding as dispersant melted glutinous Degree, improves mobility and has the function of slip agent simultaneously concurrently, and both cooperate can potentiation effect;Adding calcium carbonate can be right The viscosity of ink is adjusted, it is also possible to be filled with as extender pigment, to reduce cost;Due to ink in use Easily acting the quality of impact printing of steeping oneself-meeting, the polyether-modified silicon of defoamer combines polyethers with the advantage of both organic silicon defoamers, Acid and alkali resistance and inorganic salt, can be used for the froth breaking under harsh conditions, it is possible to decrease diagram of system surface tension, makes oneself to be prone at liquid Surface spreading and absorption, thus reduce liquid surface film-strength to reach froth breaking purpose;Levelling agent can make ink be dried to Membrane process is formed a film smooth, smooth, uniform, uses polydimethylsiloxane and fluorinated siloxane according to weight ratio For 2:1 mixing composition, polydimethylsiloxane possesses good apparent condition control ability, but shrinkage cavity can often occurs, adds Then can improve the wettability of base material after fluorinated siloxane, improve anti-shrinkage cavity ability;Adding aerosil can be at ink body System plays preferable anti-settling effect, but the levelability that more aerosil can make ink is deteriorated, and now adds 5A molecular sieve can improve the stability of ink, the polarity of the silicone hydroxyl on 5A molecular sieve hole wall can make 5A molecular sieve with Between polymer or the polymer monomer of polar group, there is the good compatibility so that the existence of molecular sieve can make link stuff Being coupled together with molecular sieve by chemical bond, the supply chain network structure making ink is more perfect, improves the storage time of ink;Link stuff Using chlorinated polypropylene, rosin modified phenolic resin, alkyd resin and polyamide is that 1:2:1:1 mixes according to weight ratio Being combined into, chlorinated polypropylene is a kind of polar thermoplastic resin introducing chlorine atom in polypropylene molecular chain, has good One-tenth colloidality and gloss, can be used as the adhesive of bonding plastics, metal or paper, polyamide has good printing and adapts to Property, surface rub resistance, rosin modified phenolic resin can be used to improve the transfer performance of improving gloss ink, the viscosity of alkyd resin The relatively low tackness that can reduce ink, complement each other to form between different resins a kind of become colloidality is good, adhesive force is relatively strong, stick together Moderate, the link stuff of applied range of property;Solvent includes isopropanol, toluene, butyl ether, butyl acetate and butanone and according to weight ratio For 3:3:1:2:1 mixing composition, amalgamation is good each other, for relatively single solvent, to link stuff resin especially polyamide Resin has the strongest dissolving power, and butyl ether is good with the separation property of water, generates peroxide when storage few;Adhesive force promotes Agent be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, epoxy radicals silicone hydride is novel epoxy radicals coupling Agent, has reaction active groups, has good yellowing resistance characteristic, and amino silane has two kinds of functional groups, i.e. amino and second Epoxide, wherein can react with various polymer with two active hydrogens on amino, thus by chemical bond by two kinds of property Combining of the diverse material tight of matter, both are with the use of improving the adhesive force of resin link stuff further, Prevent ink from ink bleed occurring, changes the phenomenons such as ink;Remove stick be eight aluminium carbonate, oleum lini and vaseline be 2:2:1 according to weight ratio Mixing composition, it is possible to decrease the tackness (TACK value) of ink, and do not change its fluidity, in lithographic plate and flexographic printing process, If owing to the surface strength of paper is low, the tackness of poor water resistance and ink is excessive etc., reason causes paper fussed, and goes out The existing fault such as scumming, heap rubber, appropriate interpolation removes stick and can be improved, additionally remove stick only can change ink viscosity and The fluidity of ink will not be changed, when the fluidity of ink is at more than 32mm, when viscosity is the most excessive, use removing of paste viscous simultaneously Agent can ensure that the body bone of ink, keeps the isolated complete of site;Brucite can improve the stability of ink, convenient transport and Store;Colloid oil can improve the set speed of ink, printing adaptability and good stability, can be used to adjust ink body bone and light Pool.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment 1
In the present embodiment, a kind of printing-ink, including the material of following weight portion: pigment 20 parts, link stuff 20 parts, solvent 25 parts, calcium carbonate 1 part, defoamer 1 part, levelling agent 1 part, 2 parts of 5A molecular sieve, aerosil 1 part, dispersant 2 parts, attachment Power accelerator 0.5 part, colloid oil 2 parts, slip agent 1 part, remove stick 1 part, brucite 1 part.
Slip agent is polypropylene wax, and link stuff is chlorinated polypropylene, rosin modified phenolic resin, alkyd resin and gathers Amide resin is 1:2:1:1 mixing composition according to weight ratio, and solvent includes isopropanol, toluene, butyl ether, butyl acetate and butanone also Being 3:3:1:2:1 mixing composition according to weight ratio, defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorination Siloxanes is 2:1 mixing composition according to weight ratio, and adhesion promoter is amino silane and epoxy radicals silicone hydride according to weight ratio is 1:2 mixes composition, and dispersant is oleamide, remove stick be eight aluminium carbonate, oleum lini and vaseline be 2:2:1 according to weight ratio Mixing composition.
Embodiment 2
In the present embodiment, a kind of printing-ink, including the material of following weight portion: pigment 30 parts, link stuff 30 parts, solvent 35 parts, calcium carbonate 1.5 parts, defoamer 2 parts, levelling agent 2 parts, 4 parts of 5A molecular sieve, aerosil 1.5 parts, dispersant 4 parts, Adhesion promoter 1 part, colloid oil 3.5 parts, slip agent 2 parts, remove stick 2.5 parts, brucite 2 parts.
Slip agent is polypropylene wax, and link stuff is chlorinated polypropylene, rosin modified phenolic resin, alkyd resin and gathers Amide resin is 1:2:1:1 mixing composition according to weight ratio, and solvent includes isopropanol, toluene, butyl ether, butyl acetate and butanone also Being 3:3:1:2:1 mixing composition according to weight ratio, defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorination Siloxanes is 2:1 mixing composition according to weight ratio, and adhesion promoter is amino silane and epoxy radicals silicone hydride according to weight ratio is 1:2 mixes composition, and dispersant is oleamide, remove stick be eight aluminium carbonate, oleum lini and vaseline be 2:2:1 according to weight ratio Mixing composition.
Embodiment 3
In the present embodiment, a kind of printing-ink, including the material of following weight portion: pigment 40 parts, link stuff 40 parts, solvent 45 parts, calcium carbonate 2 parts, defoamer 3 parts, levelling agent 3 parts, 6 parts of 5A molecular sieve, aerosil 2 parts, dispersant 6 parts, attachment Power accelerator 1.5 parts, colloid oil 5 parts, slip agent 3 parts, remove stick 4 parts, brucite 3 parts.
Slip agent is polypropylene wax, and link stuff is chlorinated polypropylene, rosin modified phenolic resin, alkyd resin and gathers Amide resin is 1:2:1:1 mixing composition according to weight ratio, and solvent includes isopropanol, toluene, butyl ether, butyl acetate and butanone also Being 3:3:1:2:1 mixing composition according to weight ratio, defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorination Siloxanes is 2:1 mixing composition according to weight ratio, and adhesion promoter is amino silane and epoxy radicals silicone hydride according to weight ratio is 1:2 mixes composition, and dispersant is oleamide, remove stick be eight aluminium carbonate, oleum lini and vaseline be 2:2:1 according to weight ratio Mixing composition.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (9)

1. a printing-ink, it is characterised in that include the material of following weight portion: pigment 20-40 part, link stuff 20-40 part, Solvent 25-45 part, calcium carbonate 1-2 part, defoamer 1-3 part, levelling agent 1-3 part, 5A molecular sieve 2-6 part, aerosil 1-2 Part, dispersant 2-6 part, adhesion promoter 0.5-1.5 part, colloid oil 2-5 part, slip agent 1-3 part, remove stick 1-4 part, neatly Stone 1-3 part.
A kind of printing-ink the most according to claim 1, it is characterised in that: described slip agent is polypropylene wax.
A kind of printing-ink the most according to claim 1, it is characterised in that: described link stuff be chlorinated polypropylene, Rosin modified phenolic resin, alkyd resin and polyamide are 1:2:1:1 mixing composition according to weight ratio.
A kind of printing-ink the most according to claim 1, it is characterised in that: described solvent includes isopropanol, toluene, fourth Ether, butyl acetate and butanone and according to weight ratio be 3:3:1:2:1 mixing composition.
A kind of printing-ink the most according to claim 1, it is characterised in that: described defoamer is polyether-modified silicon.
A kind of printing-ink the most according to claim 1, it is characterised in that: described levelling agent be polydimethylsiloxane and Fluorinated siloxane is 2:1 mixing composition according to weight ratio.
A kind of printing-ink the most according to claim 1, it is characterised in that: described adhesion promoter be amino silane and Epoxy radicals silicone hydride is 1:2 mixing composition according to weight ratio.
A kind of printing-ink the most according to claim 1, it is characterised in that: described dispersant is oleamide.
A kind of printing-ink the most according to claim 1, it is characterised in that removing stick described in: is eight aluminium carbonate, oleum lini With vaseline according to weight ratio be 2:2:1 mixing composition.
CN201610749370.4A 2016-08-29 2016-08-29 A kind of printing-ink Pending CN106084984A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163678A (en) * 2017-06-26 2017-09-15 太仓市鑫鹤印刷包装有限公司 Strong printing-ink of a kind of adhesive force and preparation method thereof
CN107384002A (en) * 2017-09-19 2017-11-24 张家港精工包装彩印有限公司 A kind of printing low viscosity ink
CN108504192A (en) * 2017-02-28 2018-09-07 理想科学工业株式会社 Oil-based ink-jet ink
CN110903693A (en) * 2019-12-30 2020-03-24 宏观世纪(天津)科技股份有限公司 Carton packaging silk-screen printing scarlet ink
US10793734B2 (en) 2017-02-28 2020-10-06 Riso Kagaku Corporation Oil-based inkjet ink
US10808137B2 (en) 2017-09-29 2020-10-20 Riso Kagaku Corporation Method for producing printed item
US10865320B2 (en) 2017-02-28 2020-12-15 Riso Kagaku Corporation Oil-based inkjet ink
US10865321B2 (en) 2017-02-28 2020-12-15 Riso Kagaku Corporation Oil-based inkjet ink
US10889730B2 (en) 2017-09-29 2021-01-12 Riso Kagaku Corporation Oil-based inkjet ink set and method for producing printed item
US10894897B2 (en) 2017-02-28 2021-01-19 Riso Kagaku Corporation Oil-based inkjet ink
WO2021176086A1 (en) * 2020-03-06 2021-09-10 Domino Uk Limited Ink composition for inkjet printing

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CN104804537A (en) * 2015-04-22 2015-07-29 黎司华 Low-temperature curing silk-screen printing ink for polypropylene materials
CN105348920A (en) * 2015-11-12 2016-02-24 成都普瑞斯特新材料有限公司 Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof

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CN104804537A (en) * 2015-04-22 2015-07-29 黎司华 Low-temperature curing silk-screen printing ink for polypropylene materials
CN105348920A (en) * 2015-11-12 2016-02-24 成都普瑞斯特新材料有限公司 Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108504192A (en) * 2017-02-28 2018-09-07 理想科学工业株式会社 Oil-based ink-jet ink
CN108504192B (en) * 2017-02-28 2021-09-28 理想科学工业株式会社 Oil-based ink-jet ink
US10793734B2 (en) 2017-02-28 2020-10-06 Riso Kagaku Corporation Oil-based inkjet ink
US10894897B2 (en) 2017-02-28 2021-01-19 Riso Kagaku Corporation Oil-based inkjet ink
US10865320B2 (en) 2017-02-28 2020-12-15 Riso Kagaku Corporation Oil-based inkjet ink
US10865321B2 (en) 2017-02-28 2020-12-15 Riso Kagaku Corporation Oil-based inkjet ink
US10865322B2 (en) 2017-02-28 2020-12-15 Riso Kagaku Corporation Oil-based inkjet ink
CN107163678A (en) * 2017-06-26 2017-09-15 太仓市鑫鹤印刷包装有限公司 Strong printing-ink of a kind of adhesive force and preparation method thereof
CN107384002A (en) * 2017-09-19 2017-11-24 张家港精工包装彩印有限公司 A kind of printing low viscosity ink
US10889730B2 (en) 2017-09-29 2021-01-12 Riso Kagaku Corporation Oil-based inkjet ink set and method for producing printed item
US10808137B2 (en) 2017-09-29 2020-10-20 Riso Kagaku Corporation Method for producing printed item
CN110903693A (en) * 2019-12-30 2020-03-24 宏观世纪(天津)科技股份有限公司 Carton packaging silk-screen printing scarlet ink
WO2021176086A1 (en) * 2020-03-06 2021-09-10 Domino Uk Limited Ink composition for inkjet printing
GB2595435A (en) * 2020-03-06 2021-12-01 Domino Uk Ltd Ink composition for inkjet printing

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