CN105348920A - Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof - Google Patents
Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof Download PDFInfo
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- CN105348920A CN105348920A CN201510769111.3A CN201510769111A CN105348920A CN 105348920 A CN105348920 A CN 105348920A CN 201510769111 A CN201510769111 A CN 201510769111A CN 105348920 A CN105348920 A CN 105348920A
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Abstract
The invention discloses a binary fluorescent anti-counterfeiting environmental-protection ink and a preparation method thereof. The ink is composed of the following components by the mass percentage: 30%-45% of composite resin, 0%-8% of a filling agent, 4%-35% of a pigment, 0%-5% of an auxiliary agent, and 30%-65% of a composite solvent. The ink does not contain benzene or ketone solvents, has the heavy metal content reach standards, and is safe and environmentally friendly; the ink has both fluorescent anti-counterfeit ink and watermark anti-counterfeiting technologies, is unique, and has quite good double anti-counterfeiting ability; the adhesion power is good and can reach more than or equal to 99%; the ink plasticity is good, and a printed product is not curly; the ink has good printability, the printing machine speed can reach more than or equal to 200 m/min, and the printed product is not anti-sticky and does not migrate; during lower-viscosity printing, a satisfactory effect can be obtained; the printed product is free from extraneous odor and has no color; and the ink has bright blue light and high color saturation degree under ultraviolet light irradiation, has an obvious watermark pattern under common light, and is easy to identify.
Description
Technical field
The present invention relates to a kind of intaglio plate inner-printing ink, particularly relate to a kind of binary fluorescence falsification preventing environment-friendly ink and preparation method thereof.
Background technology
Along with the fast development of economic technology, standard of living there occurs huge change.But the consequent is, commodity imitation behavior also increasingly
rampant, the economic interests of production firm have suffered massive losses, and its prestige subjected to unprecedented test.According to relevant statistics, the whole world because of counterfeit all kinds of high-grade name brands and forgery of negotiable instrument etc., causes damage and reaches 1,000 hundred million dollars more than every year.More alarming, in medicine, food, tobacco and wine, field of beverage, personation packaging is more rampant, often makes people hard to guard against.Not only cause serious financial loss, also directly jeopardize our health and lives.We are badly in need of wanting some means to protect us the rights and interests of self to preserve from.
Anti-forgery ink adds the anti-fake material of outstanding performance in ink vehicle, through the special printing inks of outstanding processes.Ink anti-counterfeiting technology is one of effective measure effectively stopping above-mentioned random phase.The type of current anti-forgery ink is mainly based on single anti-counterfeiting technology, and this ink exists following problem: adopt the hazardous solvents such as a large amount of benzene, ketone; False proofly singlely easily to be imitated by school; The product needed of ink printing could be differentiated by some any special measures, and ordinary consumer is not easy to identify.
To sum up, be badly in need of a kind of containing benzophenone safety and environmental protection, the high and printed matter anti-counterfeiting picture and text of multiple printing element adaptability can be used for easily by the anti-forgery ink of ordinary consumer identification.
Summary of the invention
One of goal of the invention of the present invention is: provide a kind of binary fluorescence falsification preventing environment-friendly ink, to solve the above problems.
The technical solution used in the present invention is such: a kind of binary fluorescence falsification preventing environment-friendly ink, is made up of the component of following mass percent:
Combination resin: 30%-45%
Weighting agent: 0%-8%
Pigment: 4%-35%
Auxiliary agent: 0%-5%
Combination solvent: 25%-45%;
Described combination resin is made up of urethane resin, modified EVA resin, modified polypropylene resin and acrylic resin, and its mass ratio is (30-40): (5-10): (2-4): (1-3);
Described pigment is fluorescence falsification preventing pigment;
Described auxiliary agent is made up of anti-settling agent, adhesion promoter, antiblocking agent and dispersion agent, and its mass ratio is (0.8-1.5): (1.0-1.4): (0.6-1.0): (0.4-0.8)
Described combination solvent is made up of n-propyl acetate, n-butyl acetate, vinyl acetic monomer and propylene glycol monomethyl ether, and its mass ratio is (12-18): (6-12): (2-8): (2-8).
The present inventor by lot of experiments, composite four kinds of resins: wherein, urethane resin is as main resin; Modified EVA resin and other components are coordinated mutually, and ink printing can be made to have obvious watermark picture and text effect; The sticking power of acrylic resin modified enhancing ink, and between resin, adopt suitable ratio, mutually collaborative as binder; And add suitable auxiliary agent, adopt suitable combination solvent simultaneously, mutually coordinate between these components, make the ink performance that obtains superior, can substantially solve the problem.
As preferred technical scheme, described pigment is rare earth fluorine fluorescent material.More preferably silver-colored imperial YH-010 rare earth fluorine fluorescent material, this pigment is nontoxic, has easy dispersion, not free settling, the feature that under UV-light, saturated colour concentration is high, can mix with colourless or other color ink and not change its state, make ink have high contamination resistance.
As preferred technical scheme, described anti-settling agent is aerosil.
The preferred German Clariant 3620 type dispersion agent of dispersion agent, anti-ink pigment overflow color changeable effect is splendid.
As preferred technical scheme, be made up of the component of following mass percent:
Urethane resin 32%, modified EVA resin 8%, modified polypropylene resin 3%, acrylic resin 2%, pigment 24%, polyethylene wax 1%, adhesion promoter 1%, aerosil 1.4%, aliphatic amine type tensio-active agent 0.6%, n-propyl acetate 14%, vinyl acetic monomer 6%, n-butyl acetate 4%, propylene glycol monomethyl ether 3%.
Object two of the present invention, be the preparation method providing a kind of above-mentioned binary fluorescence falsification preventing environment-friendly ink, the technical scheme of employing is: comprise the following steps:
By above-mentioned raw materials, except adhesion promoter, after the mixing of described ratio, dispersed with stirring, then adds the adhesion promoter of described ratio, and adds solvent adjustment viscosity and reach and be coated with 4# cup 40-50 second, filters and packages and get final product.
Adopt above-mentioned preparation method, simple for process, preparation cost is low.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows: ink of the present invention is not containing benzene, ketones solvent, and heavy metal content is up to standard, safety and environmental protection; Have Antiforge fluorescent ink and watermark anti-counterfeiting technology concurrently, shown unique characteristics good double anti-counterfeit capability; Sticking power is good, can reach more than 99%; Ink plasticity is good, and printed matter is not curling; This ink printability is excellent, printing press scooter more than 200 ms/min, and printing is not instead glued, do not moved; Also satisfied effect can be obtained when printing compared with low viscosity; Printed matter free from extraneous odour, without color; There are distinct blue light, fullness of shade high under UV-irradiation, under common light, have obvious watermark recovery, easy to identify.
Embodiment
The present invention is described in detail below.
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1:
A kind of binary fluorescence falsification preventing environment-friendly ink is provided, is made up of the raw material of following weight per-cent:
Urethane resin 32%, modified EVA resin 8%, modified polypropylene resin 3%, acrylic resin 2%, pigment 24%, polyethylene wax 1%, adhesion promoter 1%, aerosil 1.4%, aliphatic amine type tensio-active agent 0.6%, n-propyl acetate 14%, vinyl acetic monomer 6%, n-butyl acetate 4%, propylene glycol monomethyl ether 3%.
Its preparation method is:
After first in a reservoir mixed solvent being mixed according to the above ratio, reserve 20% to use as inking, after residue 80% mixed solvent and other raw materials (except adhesion promoter) are mixed in scuffing of cylinder bore, with homogenizer 800 revs/min, dispersed with stirring 20 minutes, after checking after dispersed under fineness ultraviolet light conditions that ink colors is qualified, add adhesion promoter in adjustment ink and add the 20% solvent adjustment viscosity reserved and reach and be coated with 4# cup 40-50 and can filter and package second, obtain, the product of gained is " product A ".
Embodiment 2:
Urethane resin 30%, modified EVA resin 8%, modified polypropylene resin 5%, acrylic resin 2%, pigment 24%, polyethylene wax 1%, adhesion promoter 1%, aerosil 1.4%, aliphatic amine type tensio-active agent 0.6%, n-propyl acetate 14%, vinyl acetic monomer 6%, n-butyl acetate 4%, propylene glycol monomethyl ether 3%.
The same A of its preparation method, obtained " product B "
Embodiment 3
Urethane resin 30%, modified EVA resin 8%, modified polypropylene resin 3%, acrylic resin 2%, pigment 24%, polyethylene wax 1%, adhesion promoter 1.5%, aerosil 1.4%, aliphatic amine type tensio-active agent 0.6%, n-propyl acetate 14.5%, vinyl acetic monomer 6%, n-butyl acetate 4%, propylene glycol monomethyl ether 3%.
The same A of its preparation method, obtained " products C "
Embodiment 4
Urethane resin 30%, modified EVA resin 8%, modified polypropylene resin 4%, acrylic resin 2%, pigment 24%, polyethylene wax 1%, adhesion promoter 1%, aerosil 1.4%, aliphatic amine type tensio-active agent 0.6%, n-propyl acetate 15%, vinyl acetic monomer 6%, n-butyl acetate 4%, propylene glycol monomethyl ether 3%.
The same A of its preparation method, obtained " product D ".
After testing, the Technique performance parameter of " product A ", " product B ", " products C " " product D " is as shown in table 1:
The technical feature of table 1 product and detected value
Claims (5)
1. a binary fluorescence falsification preventing environment-friendly ink, is characterized in that, is made up of the component of following mass percent:
Combination resin: 30%-45%
Weighting agent: 0%-8%
Pigment: 4%-35%
Auxiliary agent: 0%-5%
Combination solvent: 30%-65%;
Described combination resin is made up of urethane resin, modified EVA resin, modified polypropylene resin and acrylic resin, and its mass ratio is (30-40): (5-10): (2-4): (1-3);
Described pigment is fluorescence falsification preventing pigment;
Described auxiliary agent is made up of anti-settling agent, adhesion promoter, antiblocking agent and dispersion agent, and its mass ratio is (1.2-2.0): (1.0-1.4): (0.6-1.0): (0.8-1.0)
Described combination solvent is made up of n-butyl acetate, n-propyl acetate, vinyl acetic monomer and propylene glycol monomethyl ether, and its mass ratio is (12-18): (6-12): (2-8): (2-8).
2. binary fluorescence falsification preventing environment-friendly ink according to claim 1, is characterized in that, described pigment is rare earth fluorine fluorescent material.
3. binary fluorescence falsification preventing environment-friendly ink according to claim 1, is characterized in that, described anti-settling agent is aerosil.
4. binary fluorescence falsification preventing environment-friendly ink according to claim 1, is characterized in that, be made up of the component of following mass percent:
Urethane resin 32%, modified EVA resin 8%, modified polypropylene resin 3%, acrylic resin 2%, pigment 24%, polyethylene wax 1%, adhesion promoter 1%, aerosil 1.4%, aliphatic amine type tensio-active agent 0.6%, n-propyl acetate 14%, vinyl acetic monomer 6%, n-butyl acetate 4%, propylene glycol monomethyl ether 3%.
5. the preparation method of binary fluorescence falsification preventing environment-friendly ink according to claim 1, is characterized in that: comprise the following steps:
By above-mentioned raw materials, except adhesion promoter, after the mixing of described ratio, dispersed with stirring, then adds the adhesion promoter of described ratio, and adds solvent adjustment viscosity and reach and be coated with 4# cup 40-50 second, filters and packages and get final product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510769111.3A CN105348920A (en) | 2015-11-12 | 2015-11-12 | Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof |
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| CN201510769111.3A CN105348920A (en) | 2015-11-12 | 2015-11-12 | Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084984A (en) * | 2016-08-29 | 2016-11-09 | 苏州安洁科技股份有限公司 | A kind of printing-ink |
| CN106118233A (en) * | 2016-08-29 | 2016-11-16 | 苏州安洁科技股份有限公司 | A kind of fluorescent ink |
| CN106189498A (en) * | 2016-08-29 | 2016-12-07 | 苏州安洁科技股份有限公司 | A kind of ink for screen printing |
| CN107880768A (en) * | 2017-11-29 | 2018-04-06 | 张家港宝视特影视器材有限公司 | A kind of coating material for plastics curtain and preparation method thereof |
| CN108034358A (en) * | 2017-11-29 | 2018-05-15 | 张家港宝视特影视器材有限公司 | A kind of projection screen fluoresent coating material and preparation method thereof |
| CN108659613A (en) * | 2018-06-11 | 2018-10-16 | 江苏海田电子材料有限公司 | A kind of fluorescent ink and preparation method thereof |
| CN113004884A (en) * | 2021-03-01 | 2021-06-22 | 广东美纳防伪科技有限公司 | Invisible anti-counterfeiting material composition, preparation process and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921507A (en) * | 2010-07-01 | 2010-12-22 | 中国人民解放军军事交通学院 | Aqueous anti-counterfeiting stamp ink |
| CN103436093A (en) * | 2013-08-26 | 2013-12-11 | 孙宝林 | Anti-counterfeiting stamp-pad ink and preparation method thereof |
| CN103756403A (en) * | 2014-01-23 | 2014-04-30 | 繁昌县朱氏印务有限责任公司 | Luminous printing ink |
| CN104277585A (en) * | 2014-10-24 | 2015-01-14 | 成都普瑞斯特新材料有限公司 | Environment-friendly colorful printing ink for handkerchief paper packages and preparation method thereof |
-
2015
- 2015-11-12 CN CN201510769111.3A patent/CN105348920A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921507A (en) * | 2010-07-01 | 2010-12-22 | 中国人民解放军军事交通学院 | Aqueous anti-counterfeiting stamp ink |
| CN103436093A (en) * | 2013-08-26 | 2013-12-11 | 孙宝林 | Anti-counterfeiting stamp-pad ink and preparation method thereof |
| CN103756403A (en) * | 2014-01-23 | 2014-04-30 | 繁昌县朱氏印务有限责任公司 | Luminous printing ink |
| CN104277585A (en) * | 2014-10-24 | 2015-01-14 | 成都普瑞斯特新材料有限公司 | Environment-friendly colorful printing ink for handkerchief paper packages and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084984A (en) * | 2016-08-29 | 2016-11-09 | 苏州安洁科技股份有限公司 | A kind of printing-ink |
| CN106118233A (en) * | 2016-08-29 | 2016-11-16 | 苏州安洁科技股份有限公司 | A kind of fluorescent ink |
| CN106189498A (en) * | 2016-08-29 | 2016-12-07 | 苏州安洁科技股份有限公司 | A kind of ink for screen printing |
| CN107880768A (en) * | 2017-11-29 | 2018-04-06 | 张家港宝视特影视器材有限公司 | A kind of coating material for plastics curtain and preparation method thereof |
| CN108034358A (en) * | 2017-11-29 | 2018-05-15 | 张家港宝视特影视器材有限公司 | A kind of projection screen fluoresent coating material and preparation method thereof |
| CN108659613A (en) * | 2018-06-11 | 2018-10-16 | 江苏海田电子材料有限公司 | A kind of fluorescent ink and preparation method thereof |
| CN113004884A (en) * | 2021-03-01 | 2021-06-22 | 广东美纳防伪科技有限公司 | Invisible anti-counterfeiting material composition, preparation process and application thereof |
| CN113004884B (en) * | 2021-03-01 | 2021-09-28 | 广东美纳防伪科技有限公司 | Invisible anti-counterfeiting material composition, preparation process and application thereof |
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Application publication date: 20160224 |