CN104327589B - A kind of black Environmental-protection water-based ink and preparation method thereof - Google Patents
A kind of black Environmental-protection water-based ink and preparation method thereof Download PDFInfo
- Publication number
- CN104327589B CN104327589B CN201410454723.9A CN201410454723A CN104327589B CN 104327589 B CN104327589 B CN 104327589B CN 201410454723 A CN201410454723 A CN 201410454723A CN 104327589 B CN104327589 B CN 104327589B
- Authority
- CN
- China
- Prior art keywords
- water
- black
- soluble
- chinese medicine
- based ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000003814 drug Substances 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002002 slurry Substances 0.000 claims abstract description 20
- 235000014220 Rhus chinensis Nutrition 0.000 claims abstract description 18
- 240000003152 Rhus chinensis Species 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 11
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 10
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 10
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 10
- 241000218231 Moraceae Species 0.000 claims abstract description 9
- 235000008708 Morus alba Nutrition 0.000 claims abstract description 9
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims abstract description 9
- 244000223014 Syzygium aromaticum Species 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 210000000582 semen Anatomy 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 238000000227 grinding Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 10
- 239000000049 pigment Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 230000004308 accommodation Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention provides a kind of black Environmental-protection water-based ink, formed by following raw material: water-borne acrylic resin emulsion, ethanol, black Chinese medicine slurry, deionized water. Wherein, black Chinese medicine slurry is made up of following raw material: cloves, Chinese gall, Ke Zi, mulberries, Semen sesami nigrum, nutgall, green vitriol, water-soluble molysite, water-soluble ferrous salt, azone, hydroxyethylcellulose. The present invention provides a kind of preparation method of black Environmental-protection water-based ink simultaneously, and step is as follows: (1) mixes Chinese medicine, and cold water soak, boils; (2), by water-soluble to green vitriol, water-soluble molysite, water-soluble ferrous salt, azone and hydroxyethylcellulose, stir and add clear liquid in step (1); (3) fine grinding; (4) raw material is mixed to dispersed with stirring; (5) cooling rear test package. The water color ink that adopts the present invention to make, without Harmful chemicals content, non-volatility pollutes, and color is naturally bright-coloured not to fade, and has natural faint scent.
Description
Technical field
The present invention relates to water color ink field, particularly relate to a kind of black Environmental-protection water-based ink and preparation method thereof.
Background technology
Along with the development of civilization of human society, increasing to the demand of ink, various printing materials, Packaging Printing Products etc. have been paved with market, simultaneously, requirement to ink quality is also more and more higher, in environmental pollution day by day violent today, people recognize that Development of Human Civilization is faster, and energy resource consumption is also larger, also larger on the impact of environment, environment-friendly ink is also subject to attracting attention of people, particularly water color ink, owing to can not distributing VOC VOC to atmosphere, water color ink is replacing the status of solvent type ink gradually. Because water color ink is mainly taking water as diluent, not containing organic solvent (as ester class, ketone, benzene class etc.), the in use volatilization of essentially no organic solvent and residual, therefore be specially adapted to the strict Packaging Printing Products of health conditions requiring such as cigarette, wine, food, beverage, medicine, toy for children, and the daily print product such as books ,newspapers and magazines, also because of reasons such as skin directly contact, paid close attention to by extensive environmental protection organization.
Chinese patent CN102093779A discloses a kind of Environmental-protection water-based ink and preparation method thereof, make Environmental-protection water-based ink by mill base, functional resin, wear-resistant wax slurry, wetting agent, defoamer and deionized water, this water color ink rate of drying is fast, folding is not ftractureed, but wherein in mill base, dispersion resin environmental-protecting performance is not high, and use compared with the chemicals such as multi-dispersant, wetting agent. Chinese patent CN103992691A discloses a kind of water color ink and preparation method thereof, feature is that different step has been used different types of resin, can improve the wearability of water color ink, but technological process complexity, very high to ingredient requirement, and in preparation process, used a large amount of chemicals. Chinese patent CN102533001A discloses formula of a kind of environment-friendly type high performance wallpaper use ink and preparation method thereof, organic pigment and function additive are used, harmless, but chemicals content is very high, can only be used for wallpaper and can not be used for the place that the safety requirements such as packaging for foodstuff are high. Chinese patent CN103642311A discloses a kind of water-base black ink, having added lavender oil, overcome the defect that ink smells foul, is the way that an index is not effected a permanent cure but add essence, wherein various chemistry auxiliary agents can not solve safety problem, and color gloss is not strong.
Summary of the invention
High in order to solve water color ink chemicals content, technological process complexity, the problem that environmental-protecting performance is low, we have proposed a kind of black Environmental-protection water-based ink and preparation method thereof, adopt the present invention can simplification of flowsheet, reduce chemicals content, improve gloss, improve wearability, improve environmental-protecting performance simultaneously.
The present invention is achieved by the following technical solutions:
For achieving the above object, the invention provides a kind of black Environmental-protection water-based ink, formed by the raw material of following weight portion:
Water-borne acrylic resin emulsion 5 ~ 15, ethanol 1 ~ 5, black Chinese medicine slurry 15 ~ 30, deionized water 1 ~ 10. Replace the chemicals such as defoamer, dispersant with Chinese medicine slurry, successful, without chemicals content, without volatilizable pollutant. Compared with traditional solvent based coating, water paint have price low, use safety, saving resource and the energy, reduce the advantages such as environmental pollution and public hazards.
Wherein, black Chinese medicine slurry is made up of the raw material of following percentage by weight:
Cloves 2 ~ 6, Chinese gall 3 ~ 10, Ke Zi 2 ~ 6, mulberries 1 ~ 4, Semen sesami nigrum 2 ~ 6, nutgall 1 ~ 4, green vitriol 0.5 ~ 2, water-soluble molysite 0.1 ~ 1, water-soluble ferrous salt 0.1 ~ 1, azone 0.1 ~ 1, hydroxyethylcellulose 0.01 ~ 0.1. Wherein cloves is bleeding agent, and pigment molecule is infiltrated through to whole ink system, does not use chemicals; Chinese gall, Ke Zi, mulberries, Semen sesami nigrum and nutgall are pigment and nutritional labeling, and this pigment agent formula can obtain the natural black of color and luster, and pigment can be more bright-coloured glossy simultaneously; Green vitriol is developer, aggregates into the large molecule of pigment of black by green vitriol and Chinese medicine pigment composition, ensures its stability on printed matter. Water-soluble molysite and water-soluble ferrous salt play coloration equally, can obtain the natural black of color and luster; Adding of azone can improve wearability, ensured its life-span on printed matter, is difficult for fading; Hydroxyethylcellulose is thickener, improves the thick of ink.
Preferably, above-mentioned water-soluble molysite is at least one in iron chloride, ferric sulfate, ferric nitrate.
Preferably, above-mentioned water-soluble ferrous salt is at least one in frerrous chloride, ferrous sulfate, ferrous nitrate.
The present invention also provides a kind of preparation method of black Environmental-protection water-based ink, and step is as follows:
(1) cloves, Chinese gall, Ke Zi, mulberries, Semen sesami nigrum, nutgall are mixed in proportion, cold water soak, after 2 ~ 6 hours, adds and boils, boil 1 ~ 3 hour, filter and obtain clear liquid, Chinese medicinal material is dry product mostly, before boiling, use cold water soak, can improve active ingredient decocting rate;
(2) green vitriol, water-soluble molysite, water-soluble ferrous salt, azone and hydroxyethylcellulose are dissolved in 30 ~ 50 DEG C of warm water in proportion, stir 12 ~ 24 hours, mix, add clear liquid described in step (1), stir 1 ~ 3 hour, cold filtration, is black Chinese medicine slurry;
(3) by sand mill, product in step (2) is carried out to fine grinding, be less than 10 microns to fineness;
(4) water-borne acrylic resin, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion to dispersed with stirring 24 ~ 48 hours in homogenizer;
(5) cooling rear test package, obtains black Environmental-protection water-based ink.
Compared with prior art, beneficial effect of the present invention is: without Harmful chemicals content, non-volatility pollutes, and color is naturally bright-coloured not to fade, and has natural faint scent, with low cost.
Detailed description of the invention
Below in conjunction with embodiment, be described more specifically content of the present invention. Should be appreciated that enforcement of the present invention is not limited to the following examples, any pro forma accommodation that the present invention is made or change all fall into protection domain of the present invention; And the method in following embodiment, if no special instructions, is the conventional method of this area.
Embodiment 1:
A kind of black Environmental-protection water-based ink, is made up of the raw material of following weight portion:
Water-borne acrylic resin emulsion 10, ethanol 3, black Chinese medicine slurry 25, deionized water 5.
Wherein, black Chinese medicine slurry is made up of the raw material of following weight portion:
Cloves 4, Chinese gall 6, Ke Zi 4, mulberries 2, Semen sesami nigrum 4, nutgall 2, green vitriol 1, iron chloride 0.2, frerrous chloride 0.2, azone 0.2, hydroxyethylcellulose 0.05.
The preparation method of this black Environmental-protection water-based ink, step is as follows:
(1) cloves, Chinese gall, Ke Zi, mulberries, Semen sesami nigrum, nutgall are mixed in proportion, cold water soak, after 2 hours, adds and boils, and boils 2 hours, filters and obtains clear liquid;
(2) green vitriol, water-soluble molysite, water-soluble ferrous salt, azone and hydroxyethylcellulose are dissolved in 40 DEG C of warm water in proportion, stir 18 hours, mix, add clear liquid described in step (1), stir 2 hours, cold filtration, is black Chinese medicine slurry;
(3) by sand mill, product in step (2) is carried out to fine grinding, be less than 10 microns to fineness;
(4) water-borne acrylic resin, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion to dispersed with stirring 36 hours in homogenizer;
(5) cooling rear test package, obtains black Environmental-protection water-based ink.
Embodiment 2:
A kind of black Environmental-protection water-based ink, is made up of the raw material of following weight portion:
Water-borne acrylic resin emulsion 15, ethanol 3, black Chinese medicine slurry 25, deionized water 5.
Preparation process is substantially the same manner as Example 1.
Embodiment 3:
A kind of black Environmental-protection water-based ink, is made up of the raw material of following weight portion:
Water-borne acrylic resin emulsion 20, ethanol 3, black Chinese medicine slurry 25, deionized water 5.
Preparation process is substantially the same manner as Example 1.
Claims (3)
1. a black Environmental-protection water-based ink, is characterized in that, is made up of the raw material of following weight portion:
Water-borne acrylic resin emulsion 5 ~ 15, ethanol 1 ~ 5, black Chinese medicine slurry 15 ~ 30, deionized water 1 ~ 10;
Wherein, described black Chinese medicine slurry is made up of the raw material of following weight portion:
Cloves 2 ~ 6, Chinese gall 3 ~ 10, Ke Zi 2 ~ 6, mulberries 1 ~ 4, Semen sesami nigrum 2 ~ 6, nutgall 1 ~ 4, green vitriol 0.5 ~ 2, water-soluble molysite 0.1 ~ 1, water-soluble ferrous salt 0.1 ~ 1, azone 0.1 ~ 1, hydroxyethylcellulose 0.01 ~ 0.1; Described water-soluble ferrous salt is at least one in frerrous chloride, ferrous nitrate;
The preparation method of this black Environmental-protection water-based ink is as follows:
(1) cloves, Chinese gall, Ke Zi, mulberries, Semen sesami nigrum, nutgall are mixed in proportion, cold water soak, after 2 ~ 6 hours, adds and boils, and boils 1 ~ 3 hour, filters and obtains clear liquid;
(2) green vitriol, water-soluble molysite, water-soluble ferrous salt, azone and hydroxyethylcellulose are dissolved in 30 ~ 50 DEG C of warm water in proportion, stir 12 ~ 24 hours, mix, add clear liquid described in step (1), stir 1 ~ 3 hour, cold filtration, is black Chinese medicine slurry;
(3) by sand mill, product in step (2) is carried out to fine grinding, be less than 10 microns to fineness;
(4) water-borne acrylic resin emulsion, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion to dispersed with stirring 24 ~ 48 hours in homogenizer;
(5) cooling rear test package, obtains black Environmental-protection water-based ink.
2. a kind of black Environmental-protection water-based ink as claimed in claim 1, is characterized in that, described water-soluble molysite is at least one in iron chloride, ferric sulfate, ferric nitrate.
3. a preparation method for black Environmental-protection water-based ink claimed in claim 1, is characterized in that, step is as follows:
(1) cloves, Chinese gall, Ke Zi, mulberries, Semen sesami nigrum, nutgall are mixed in proportion, cold water soak, after 2 ~ 6 hours, adds and boils, and boils 1 ~ 3 hour, filters and obtains clear liquid;
(2) green vitriol, water-soluble molysite, water-soluble ferrous salt, azone and hydroxyethylcellulose are dissolved in 30 ~ 50 DEG C of warm water in proportion, stir 12 ~ 24 hours, mix, add clear liquid described in step (1), stir 1 ~ 3 hour, cold filtration, is black Chinese medicine slurry;
(3) by sand mill, product in step (2) is carried out to fine grinding, be less than 10 microns to fineness;
(4) water-borne acrylic resin emulsion, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion to dispersed with stirring 24 ~ 48 hours in homogenizer;
(5) cooling rear test package, obtains black Environmental-protection water-based ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410454723.9A CN104327589B (en) | 2014-09-09 | 2014-09-09 | A kind of black Environmental-protection water-based ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410454723.9A CN104327589B (en) | 2014-09-09 | 2014-09-09 | A kind of black Environmental-protection water-based ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104327589A CN104327589A (en) | 2015-02-04 |
| CN104327589B true CN104327589B (en) | 2016-05-25 |
Family
ID=52402401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410454723.9A Expired - Fee Related CN104327589B (en) | 2014-09-09 | 2014-09-09 | A kind of black Environmental-protection water-based ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104327589B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106121153A (en) * | 2016-06-30 | 2016-11-16 | 卓达新材料科技集团威海股份有限公司 | A kind of black natural anticorrosion decorative panel and preparation technology thereof |
| CN106189497A (en) * | 2016-08-29 | 2016-12-07 | 苏州安洁科技股份有限公司 | A kind of spacetabs type fragrance water color ink |
| CN115418138B (en) * | 2022-08-16 | 2023-07-18 | 四川大学华西医院 | Positioning pen ink special for radiotherapy and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001192599A (en) * | 2000-01-13 | 2001-07-17 | Mitsubishi Pencil Co Ltd | Ink composition for oily ballpoint pen |
| CN102492328A (en) * | 2011-11-28 | 2012-06-13 | 天津市中源装饰材料有限公司 | Bright environment-friendly water-based printing ink and preparation method thereof |
| CN103642311A (en) * | 2013-11-19 | 2014-03-19 | 张家港市威迪森油墨有限公司 | Aqueous black ink |
-
2014
- 2014-09-09 CN CN201410454723.9A patent/CN104327589B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104327589A (en) | 2015-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102153909B (en) | Water-based ink for plastic table printing | |
| CN102382515B (en) | Environment-friendly, strong acid-resistant, strong base-resistant and steaming-resistant ink and preparation method | |
| CN102153910B (en) | Composite special water-based ink for plastic inner printing | |
| CN107828277A (en) | A kind of environment-friendly type aqueous ink and preparation method thereof | |
| CN104327589B (en) | A kind of black Environmental-protection water-based ink and preparation method thereof | |
| CN103254683B (en) | Water-based color paste binder, and preparation method and application thereof | |
| CN102952431A (en) | Cigarette tipping paper water-based ink and preparation method | |
| CN101665639B (en) | Aqueous ink | |
| CN103923524A (en) | Aqueous pearlescent printing ink for web gravure printing | |
| CN104708933A (en) | Novel new-formula fragrance microcapsule printing ink | |
| CN103788762B (en) | BOPP pearl film environment-friendlyink ink and preparation method thereof | |
| CN104449030A (en) | Solvent type gravure pearlescent ink and preparation method thereof | |
| CN105504974A (en) | Water-based lottery printing ink for flexography and preparing method thereof | |
| CN104403414A (en) | Water-soluble woven bag printing ink with high abrasion resistance and making method thereof | |
| CN109554022A (en) | A kind of cork paper and its preparation process with metal-like | |
| CN104987773A (en) | Environment-friendly water-based printing ink and preparation method thereof | |
| CN104845452A (en) | Waterproof dye-based ink for ink-jet printing and preparation method thereof | |
| CN104312279A (en) | Printing ink with high heat resistance | |
| CN103819962B (en) | High resolving power water-based flexographic ink and preparation method thereof | |
| DE60112452D1 (en) | INK CONTAINS AN ORANGE AZOLACKPIGMENT COMPOSITION | |
| CN105153795A (en) | Nanometer antibacterial water-based ink and preparation method thereof | |
| CN104164133A (en) | Soybean oil base offset ink | |
| CN104059429B (en) | Water-soluble inner print composite plastic ink | |
| CN103694798A (en) | Reversible pressure-sensitive-discoloration anti-counterfeiting ink and preparation method thereof | |
| CN110343421A (en) | A kind of water-based ink and preparation method thereof with anti-microbial property |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| CB02 | Change of applicant information |
Address after: Chen Industrial Park 313106 Zhejiang city of Huzhou province Changxing County Hong Qiao Zhen Applicant after: CHANGXING AIFEITE PLASTIC TECHNOLOGY CO.,LTD. Address before: Chen Industrial Park 313106 Zhejiang city of Huzhou province Changxing County Hong Qiao Zhen Applicant before: CHANGXING AIFEITE PLASTIC TECHNOLOGY CO.,LTD. |
|
| COR | Change of bibliographic data | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a black environment-friendly water-based ink and a preparation method thereof Effective date of registration: 20210630 Granted publication date: 20160525 Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd. Pledgor: CHANGXING AIFEITE PLASTIC TECHNOLOGY Co.,Ltd. Registration number: Y2021330000728 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220307 Granted publication date: 20160525 Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd. Pledgor: CHANGXING AIFEITE PLASTIC TECHNOLOGY CO.,LTD. Registration number: Y2021330000728 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160525 Termination date: 20210909 |