CN106121153A - A kind of black natural anticorrosion decorative panel and preparation technology thereof - Google Patents
A kind of black natural anticorrosion decorative panel and preparation technology thereof Download PDFInfo
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- CN106121153A CN106121153A CN201610506874.3A CN201610506874A CN106121153A CN 106121153 A CN106121153 A CN 106121153A CN 201610506874 A CN201610506874 A CN 201610506874A CN 106121153 A CN106121153 A CN 106121153A
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- black
- water
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Classifications
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of black natural anticorrosion decorative panel, be made up of base material and black natural aqueous dope layer, wherein the natural water paint of black is by water-borne acrylic resin emulsion, ethanol, black Chinese medicine slurry, and deionized water composition, wherein black Chinese medicine slurry is by Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Fructus Mori, Semen Sesami Nigrum, Galla Turcica (Galla Helepensis), water solublity iron salt, water solublity ferrous salt, azone, hydroxyethyl cellulose and Melanteritum composition;The present invention discloses the preparation technology of a kind of black natural anticorrosion decorative panel, step includes that Chinese crude drug decocts, and stirs into slurry, sand milling, stirring, roller coat, cutting maintenance etc..The beneficial effects of the present invention is, meet building mechanical property, durability, simultaneously without Harmful chemicals content, non-volatility pollutes, and natural faint scent is with low cost.
Description
Technical field
The present invention relates to decoration material field, particularly relate to a kind of black natural anticorrosion decorative panel and preparation technology thereof.
Background technology
Outdoor finishing always people have a bad headache, and outdoor environment is easy to be corroded, and makes dirty.Although also having portion at present
Point technology can make external wall decorative material reach antiseptical effect, but is much through crossing preservative processing, and preservative pair
Human body is harmful.Anticorrosive wood in early days uses CCA C, B timber preservative, and this preservative has the biggest toxicity.
Although having occurred in that ACQ D, C, B timber preservative now, through the anticorrosive wood that this preservative is processed, it is to pass through environmental protection
Standard, but as outdoor decoration material for, self expand with heat and contract with cold not through special control, therefore can deform tight
Weight.
Existing corrosion-resistanting decoration material uses timber preservative mostly, and it has certain toxicity, to human body physical and mental health meeting
Cause certain impact.On market existing decorative panel have a problem in that following some: 1, at present most of decoration materials the most on the market are all
Containing formaldehyde, such as lumber core (core-board), plywood, fibre board, particieboard, and compound by these board making
Plate, furniture etc..The resin glue that formaldehyde uses during mostling come from these board making, formaldehyde belongs to poisonous and harmful substance,
Hang up one's hat and can have a strong impact on the physical and mental health of people.2, the adding of paint, coating and various paint that house decoration uses
Add agent and diluent all contains harmful substance benzene.3, stone materials finishing material such as granite, marble, plasterboard, ceramic tile etc., contains
There is a kind of harmful substance being called radon, one of 19 kinds of environmental carcinogenesis materials that Dong Shi World Health Organization (WHO) announces, it is only second to smoking
Second pulmonary carcinoma cause a disease because of.
Summary of the invention
In order to solve decorative panel not environmentally, not anticorrosion, the problem that noxious substance release is many, we have proposed a kind of black sky
So corrosion-resistanting decoration plate and preparation technology thereof, uses the present invention can reach building performance requirement, more has natural environment affine
Power, anticorrosion extends the life-span, and has nature delicate fragrance.
The present invention is achieved by the following technical solutions:
For achieving the above object, the present invention provides a kind of black natural anticorrosion decorative panel, and decorative panel is by base material, and black is natural
Water paint layer forms;The natural water paint of black is made up of the raw material of following weight portion: water-borne acrylic resin emulsion: 4-16
Part;Ethanol: 0.5-6.5 part;Black Chinese medicine slurry: 10-30 part;Deionized water: 1-10 part;Chinese medicine slurry is used to replace froth breaking
The chemicals such as agent, dispersant, effect is obvious, without chemicals content, without volatilizable pollutant.With traditional solvent based coating phase
Ratio, water paint has that price is low, use safety, saves resource and the energy, reduces the advantage such as environmental pollution and public hazards.
Wherein black Chinese medicine slurry is made up of the raw material of following weight portion: Flos Caryophylli: 1-6 part;Galla Chinensis: 2-12 part;Fructus Chebulae:
1-6 part;Fructus Mori: 0.5-5 part;Semen Sesami Nigrum: 1-6 part;Galla Turcica (Galla Helepensis): 1-4 part;Water solublity iron salt: 0.1-1.5 part;Water solublity is ferrous
Salt: 0.1-1 part;Azone: 0.1-1 part;Hydroxyethyl cellulose: 0.01-0.1 part;Melanteritum: 0.5-3 part;Wherein Flos Caryophylli is infiltration
Agent, infiltrates through pigment molecule whole coating system, does not use chemicals;Galla Chinensis, Fructus Chebulae, Fructus Mori, Semen Sesami Nigrum and no food
Son is pigment and nutritional labeling, and this pigment agent formula can obtain the black of natural in color, and pigment can be the most bright-coloured glossy simultaneously;Green
Vitriol is developer, is aggregated into the pigment macromole of black by Melanteritum and Chinese medicine pigment composition, it is ensured that its stablizing on base material
Property.Water solublity iron salt and water solublity ferrous salt play coloration equally, can obtain the black of natural in color;The addition of azone is permissible
Improve wearability, it is ensured that in its life-span on base material, be difficult to fade;Hydroxyethyl cellulose is thickening agent, improves the thickness of coating
Severe.
Preferably, above-mentioned base material is glass magnesium board, magnesium oxysulfide plate, the one in calcium silicate board or cement fibrolite plate.
Preferably, above-mentioned glass magnesium board density is: 1-1.5t/m3, moisture content≤8%, contract with dry rate≤0.3%, bulking factor≤
0.3%;Described magnesium oxysulfide plate density is: 600-1500kg/m3, moisture content≤8%, contract with dry rate≤0.3%, bulking factor≤
0.3%;Described calcium silicate board density is 1200-1900kg/m3, moisture content 8-10%, contract with dry rate≤0.5%, bulking factor≤
0.5%;Described cement fibrolite plate density is 900-2000kg/m3, moisture content≤8%, contract with dry rate≤0.3%, bulking factor≤
0.3%.
Preferably, above-mentioned water solublity iron salt is at least one in iron chloride, iron sulfate, ferric nitrate.
Preferably, above-mentioned water solublity ferrous salt is at least one in ferrous chloride, ferrous sulfate, ferrous nitrate.
Present invention simultaneously provides the preparation technology of a kind of black natural anticorrosion decorative panel, step is as follows:
(1) Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Fructus Mori, Semen Sesami Nigrum, Galla Turcica (Galla Helepensis) are mixed in proportion, after cold water soak 2-6 hour,
Addition is boiled, and boils 1-3 hour, is filtrated to get clear liquid;Chinese medicinal material is dry product mostly, uses cold water soak before boiling,
Effective ingredient decocting rate can be improved.
(2) Melanteritum, water solublity iron salt, water solublity ferrous salt, azone and hydroxyethyl cellulose are dissolved in 30-50 in proportion
In DEG C warm water, stir 12-24 hour, mix homogeneously, add clear liquid described in step (1), stir 1-3 hour, cold filtration, i.e.
For black Chinese medicine slurry.
(3) by sand mill, product in step (2) is carried out fine grinding, to fineness less than 10 microns.
(4) water-borne acrylic resin, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion, in high-speed stirred
Dispersed with stirring 24-48 hour in machine.
(5) directly carrying out roller coat at substrate surface after cooling, roller coat amount is 15-30g/m2。
(6) wet plate cutting: complete wet plate by automatic cutting saw and cut, enters dress wooden handcart.
(7) maintenance: control curing kilns temperature (35-45 DEG C), humidity (>=85%), carry out maintenance 2-3 days.
(8) detection, packaging, dispatch from the factory.
Compared with prior art, the beneficial effects of the present invention is:
Not only meet building mechanical property, use function and the requirement of durability, without Harmful chemicals content, without waving
Sending out contact scar, color is the most bright-coloured not to fade, and has natural faint scent, with low cost.
Accompanying drawing explanation
Fig. 1: the product appearance schematic diagram of black natural anticorrosion decorative panel of the present invention.
Detailed description of the invention
Below in conjunction with embodiment, further illustrate present disclosure.Should be appreciated that the enforcement of the present invention is not limited to
In the following examples, any pro forma accommodation or the change of being made the present invention both fall within scope;Under and
State the method in embodiment, if no special instructions, be the conventional method of this area.
Embodiment 1:
A kind of black natural anticorrosion decorative panel, it is characterised in that decorative panel by base material, black natural aqueous dope layer group
Become;The natural water paint of black is made up of the raw material of following weight portion: water-borne acrylic resin emulsion: 4 parts;Ethanol: 1 part;Black
Color Chinese medicine slurry: 20 parts;Deionized water: 10 parts.
Wherein black Chinese medicine slurry is made up of the raw material of following weight portion: Flos Caryophylli: 4 parts;Galla Chinensis: 6 parts;Fructus Chebulae: 4 parts;
Fructus Mori: 2 parts;Semen Sesami Nigrum: 4 parts;Galla Turcica (Galla Helepensis): 2 parts;0.2 part of iron chloride;Ferrous chloride 0.2 part;Azone: 0.2 part;Ethoxy is fine
Dimension element: 0.05 part;Melanteritum: 1 part.
A kind of preparation technology of black natural anticorrosion decorative panel, step is as follows:
(1) Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Fructus Mori, Semen Sesami Nigrum, Galla Turcica (Galla Helepensis) being mixed in proportion, cold water soak, after 2 hours, adds
Enter to boil, boil 2 hours, be filtrated to get clear liquid.
(2) Melanteritum, iron chloride, ferrous chloride, azone and hydroxyethyl cellulose are dissolved in 40 DEG C of warm water in proportion, stir
Mix 18 hours, mix homogeneously, add clear liquid described in step (1), stir 2 hours, cold filtration, be black Chinese medicine slurry.
(3) by sand mill, product in step (2) is carried out fine grinding, to fineness less than 10 microns.
(4) water-borne acrylic resin, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion, in high-speed stirred
Dispersed with stirring 36 hours in machine.
(5) directly carrying out roller coat at substrate surface after cooling, roller coat amount is 25g/m2。
(6) wet plate cutting: complete wet plate by automatic cutting saw and cut, enters dress wooden handcart.
(7) maintenance: control curing kilns temperature (40 DEG C), humidity (>=85%), carry out maintenance 2 days.
(8) detection is with reference to national standard, and key property test result is as shown in table 1, environmental-protecting performance test result such as table 2 institute
Show.
Embodiment 2:
A kind of black natural anticorrosion decorative panel, it is characterised in that decorative panel by base material, black natural aqueous dope layer group
Become;The natural water paint of black is made up of the raw material of following weight portion: water-borne acrylic resin emulsion: 10 parts;Ethanol: 3 parts;Black
Color Chinese medicine slurry: 20 parts;Deionized water: 5 parts.
Wherein black Chinese medicine slurry is made up of the raw material of following weight portion: Flos Caryophylli: 4 parts;Galla Chinensis: 6 parts;Fructus Chebulae: 4 parts;
Fructus Mori: 2 parts;Semen Sesami Nigrum: 4 parts;Galla Turcica (Galla Helepensis): 2 parts;0.2 part of iron chloride;Ferrous chloride 0.2 part;Azone: 0.2 part;Ethoxy is fine
Dimension element: 0.05 part;Melanteritum: 1 part.
Production stage is substantially the same manner as Example 1, and detection method is the most substantially the same manner as Example 1, key property test knot
As shown in table 1, environmental-protecting performance test result is as shown in table 2 for fruit.
Embodiment 3:
A kind of black natural anticorrosion decorative panel, it is characterised in that decorative panel by base material, black natural aqueous dope layer group
Become;The natural water paint of black is made up of the raw material of following weight portion: water-borne acrylic resin emulsion: 16 parts;Ethanol: 6 parts;Black
Color Chinese medicine slurry: 30 parts;Deionized water: 2 parts.
Wherein black Chinese medicine slurry is made up of the raw material of following weight portion: Flos Caryophylli: 4 parts;Galla Chinensis: 6 parts;Fructus Chebulae: 4 parts;
Fructus Mori: 2 parts;Semen Sesami Nigrum: 4 parts;Galla Turcica (Galla Helepensis): 2 parts;0.2 part of iron chloride;Ferrous chloride 0.2 part;Azone: 0.2 part;Ethoxy is fine
Dimension element: 0.05 part;Melanteritum: 1 part.
Production stage is substantially the same manner as Example 1, and detection method is the most substantially the same manner as Example 1, key property test knot
As shown in table 1, environmental-protecting performance test result is as shown in table 2 for fruit.
Comparative example 1:
The non-clad plate of base material.
Comparative example 2:
Commercial common decorative.
Table 1: properties is tested
Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Method of testing |
Alkali resistance | 192h is without exception | 96h is without exception | 192h is without exception | GB/T9265-1988 |
Resistance to water | 192h is without exception | 96h is without exception | 192h is without exception | GB/T1733-1993 |
Weatherability | 1000h is without exception | 500h is without exception | 1000h is without exception | GB/T1865-1997 |
Stain resistance (5 circulations) | ≤1 | ≤1 | ≤1 | GB/T9780-1988 |
Table 2: environmental-protecting performance is tested
From Tables 1 and 2, the decorative panel that the present invention makes, on the basis of ensure that the original physical property of decorative panel,
There is no the release of any harmful substance, human body will not be damaged.
Claims (6)
1. a black natural anticorrosion decorative panel, it is characterised in that decorative panel is by base material, and black natural aqueous dope layer forms;
The natural water paint of described black is made up of the raw material of following weight portion:
Water-borne acrylic resin emulsion: 4-16 part;
Ethanol: 0.5-6.5 part;
Black Chinese medicine slurry: 10-30 part;
Deionized water: 1-10 part;
Described black Chinese medicine slurry is made up of the raw material of following weight portion:
Flos Caryophylli: 1-6 part;
Galla Chinensis: 2-12 part;
Fructus Chebulae: 1-6 part;
Fructus Mori: 0.5-5 part;
Semen Sesami Nigrum: 1-6 part;
Galla Turcica (Galla Helepensis): 1-4 part;
Water solublity iron salt: 0.1-1.5 part;
Water solublity ferrous salt: 0.1-1 part;
Azone: 0.1-1 part;
Hydroxyethyl cellulose: 0.01-0.1 part;
Melanteritum: 0.5-3 part.
2. a kind of black natural anticorrosion decorative panel as claimed in claim 1, it is characterised in that described base material is glass magnesium board, sulfur
Oxygen magnesium plate, the one in calcium silicate board or cement fibrolite plate.
3. a kind of black natural anticorrosion decorative panel as claimed in claim 1, it is characterised in that described glass magnesium board density is: 1-
1.5t/m3, moisture content≤8%, contract with dry rate≤0.3%, bulking factor≤0.3%;Described magnesium oxysulfide plate density is: 600-
1500kg/m3, moisture content≤8%, contract with dry rate≤0.3%, bulking factor≤0.3%;Described calcium silicate board density is 1200-
1900kg/m3, moisture content 8-10%, contract with dry rate≤0.5%, bulking factor≤0.5%;Described cement fibrolite plate density is 900-
2000kg/m3, moisture content≤8%, contract with dry rate≤0.3%, bulking factor≤0.3%.
4. a kind of black natural anticorrosion decorative panel as claimed in claim 1, it is characterised in that described water solublity iron salt is chlorination
At least one in ferrum, iron sulfate, ferric nitrate.
5. a kind of black natural anticorrosion decorative panel as claimed in claim 1, it is characterised in that described water solublity ferrous salt is chlorine
Change at least one in ferrous iron, ferrous sulfate, ferrous nitrate.
6. the preparation technology of a black natural anticorrosion decorative panel, it is characterised in that step is as follows:
(1) Flos Caryophylli, Galla Chinensis, Fructus Chebulae, Fructus Mori, Semen Sesami Nigrum, Galla Turcica (Galla Helepensis) are mixed in proportion, after cold water soak 2-6 hour, add
Boil, boil 1-3 hour, be filtrated to get clear liquid;
(2) Melanteritum, water solublity iron salt, water solublity ferrous salt, azone and hydroxyethyl cellulose are dissolved in 30-50 DEG C of temperature in proportion
In water, stir 12-24 hour, mix homogeneously, add clear liquid described in step (1), stir 1-3 hour, cold filtration, be black
Color Chinese medicine slurry;
(3) by sand mill, product in step (2) is carried out fine grinding, to fineness less than 10 microns;
(4) water-borne acrylic resin, ethanol, black Chinese medicine slurry and deionized water are mixed in proportion, in homogenizer
Dispersed with stirring 24-48 hour;
(5) directly carrying out roller coat at substrate surface after cooling, roller coat amount is 15-30g/m2;
(6) wet plate cutting: complete wet plate by automatic cutting saw and cut, enters dress wooden handcart;
(7) maintenance: control curing kilns temperature (35-45 DEG C), humidity (>=85%), carry out maintenance 2-3 days;
(8) detection, packaging, dispatch from the factory.
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CN201610506874.3A CN106121153A (en) | 2016-06-30 | 2016-06-30 | A kind of black natural anticorrosion decorative panel and preparation technology thereof |
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CN201610506874.3A CN106121153A (en) | 2016-06-30 | 2016-06-30 | A kind of black natural anticorrosion decorative panel and preparation technology thereof |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008156573A (en) * | 2006-12-26 | 2008-07-10 | Dainippon Printing Co Ltd | Sheet for building material being improved in environmental safety and adhesion between layers |
CN201531092U (en) * | 2009-09-21 | 2010-07-21 | 河南欧亚保温材料有限公司 | Light flexible decorative board |
JP2010194462A (en) * | 2009-02-25 | 2010-09-09 | Seiren Co Ltd | Method of manufacturing construction board |
CN203891394U (en) * | 2014-05-30 | 2014-10-22 | 孔德峰 | Water-based colorful stone decorating plate |
CN104327589A (en) * | 2014-09-09 | 2015-02-04 | 长兴艾飞特塑料科技有限公司 | Black environmentally-friendly aqueous ink and its preparation method |
CN105625666A (en) * | 2015-12-29 | 2016-06-01 | 卓达新材料科技集团有限公司 | Sand beach shell decorative sheet and manufacturing method thereof |
-
2016
- 2016-06-30 CN CN201610506874.3A patent/CN106121153A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008156573A (en) * | 2006-12-26 | 2008-07-10 | Dainippon Printing Co Ltd | Sheet for building material being improved in environmental safety and adhesion between layers |
JP2010194462A (en) * | 2009-02-25 | 2010-09-09 | Seiren Co Ltd | Method of manufacturing construction board |
CN201531092U (en) * | 2009-09-21 | 2010-07-21 | 河南欧亚保温材料有限公司 | Light flexible decorative board |
CN203891394U (en) * | 2014-05-30 | 2014-10-22 | 孔德峰 | Water-based colorful stone decorating plate |
CN104327589A (en) * | 2014-09-09 | 2015-02-04 | 长兴艾飞特塑料科技有限公司 | Black environmentally-friendly aqueous ink and its preparation method |
CN105625666A (en) * | 2015-12-29 | 2016-06-01 | 卓达新材料科技集团有限公司 | Sand beach shell decorative sheet and manufacturing method thereof |
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Application publication date: 20161116 |