CN106867323A - A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof - Google Patents
A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof Download PDFInfo
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- CN106867323A CN106867323A CN201710053218.7A CN201710053218A CN106867323A CN 106867323 A CN106867323 A CN 106867323A CN 201710053218 A CN201710053218 A CN 201710053218A CN 106867323 A CN106867323 A CN 106867323A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of safe environment protection type heat conduction emulsion paint and preparation method thereof, emulsion paint includes following components and weight portion content：410 430 parts of emulsion, 20 30 parts of coalescents, 24 parts of multifunction amine auxiliary agent, 25 parts of wetting agent, 78 parts of dispersant, 25 parts of defoamer, 13 parts of cellulose, 7 10 parts of thickener, 80 100 parts of pigment, 160 180 parts of heat filling, 15 20 parts of 250 270 parts of water, 24 parts of preservative, 12 parts of mould inhibitor and propane diols.Compared with prior art, emulsion paint good heat conduction effect of the present invention, it is convenient to construct, and with eager to do well in everything scrub resistance, low VOC content drops to harmful substance at least, low smell, safe and reliable, proportion is lighter, cost of transportation can be mitigated, preparation method is simple, and controllability is good, environmental protection, it is easy to industry extension production, with good application prospect.
Description
Technical field
The invention belongs to safety and environmental protection pigment and technical field of dye, be related to a kind of safe environment protection type heat conduction emulsion paint and its
Preparation method.
Background technology
Emulsion paint is being commonly called as latex paint, is born in the next period in nineteen seventies, is with acrylic ester copolymer
Emulsion is a major class scumbling type coating of representative.Emulsion paint is water-dispersible paint, and it is, with synthetic resin emulsion as base-material, to fill out
Expect the coating by adding various auxiliary agents to refine after grinding distribution.Emulsion paint possesses the crowds different from traditional wall covering
Many advantages, are such as easy to brush, dry that rapid, paint film is water-fast.
Now, as environmental protection concept is deepened constantly, in Housing Project construction, energy conservation standard is also improved constantly, respectively
Many new power-saving technologies and material are all introduced and developed to individual construction unit, and being widelyd popularize in civil buildings should
With.Country proposes new requirement within particularly 2010, seeks to be directed to current environmental protection and energy saving requirement, reduces energy resource consumption,
Mitigate atmosphere pollution, improve building thermally comfortable environment, promote the coordinated development of town and country construction, people's lives and ecological environment.But
The current building energy conservation level of China, also far below developed country.The building heating energy consumption of north cold area accounts for local full society
More than the 20% of meeting energy consumption, serious pollution is brought to environment.The consumption of the heating energy is reduced, is the emphasis of energy conservation.Section
Energy emission reduction has turned into themes of the times, and heat conduction emulsion paint arises at the historic moment, and it has very good ornamental and heat conductivility feature,
It is mainly used in northern floor heating metope, there is good dicoration and thermal conductivity, not only plays the effect of beautifying the environment, and save energy
Source.
The content of the invention
The purpose of the present invention is exactly that a kind of speed of application is provided for the defect for overcoming above-mentioned prior art to exist soon, is applied
Work cycle is short, with good ornamental and thermal conductivity, the safe environment protection type heat conduction emulsion paint of environment protecting and power-saving.
Another object of the present invention is just to provide the preparation method of above-mentioned safe environment protection type heat conduction emulsion paint.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of safe environment protection type heat conduction emulsion paint, the emulsion paint includes following components and weight portion content：Emulsion 410-430
Part, coalescents 20-30 parts, 2-4 parts of multifunction amine auxiliary agent, wetting agent 2-5 parts, dispersant 7-8 parts, defoamer 2-5 parts, fiber
It is plain 1-3 parts, thickener 7-10 parts, pigment 80-100 parts, heat filling 160-180 parts and water 250-270 parts.
Used as preferred technical scheme, described emulsion paint also includes following components and weight portion content：Preservative 2-4
Part, mould inhibitor 1-2 parts and propane diols 15-20 parts.
Described emulsion is styrene-acrylic emulsion or pure-acrylic emulsion, and described coalescents are 2,2,4- trimethyl -1,3- penta 2
Alcohol mono isobutyrate, described multifunction amine auxiliary agent is selected from commercially available AMP-95, and described wetting agent is selected from commercially available X-405 and moistens
Humectant, described dispersant is selected from commercially available H5040 dispersants, and described defoamer is selected from commercially available Mcbain131 defoamers,
Described cellulose is hydroxyethyl cellulose, and described thickener is selected from commercially available DR-72 thickeners or UH-420 thickeners
One or two, described pigment is selected from commercially available imperial boa R996 titanium dioxides.
Described emulsion is selected from commercially available BLJ838A-2 emulsions, TX-100 emulsions, 8039 emulsions or RS706T emulsions.
Described heat filling is included in heavy calcium carbonate, boron carbide powder, magnesia powder, alumina powder or oxide powder and zinc
One or more.
Used as preferred technical scheme, described heat filling is alumina powder.
Described preservative is selected from commercially available A26 preservatives, and described mould inhibitor is selected from commercially available SN-048 mould inhibitors.
The fineness of described emulsion paint is 45-75 μm, and pH value is 8-9, and viscosity is 115-116KU.
A kind of preparation method of safe environment protection type heat conduction emulsion paint, the method specifically includes following steps：
Step (1)：Got the raw materials ready by following components and weight portion content：
Liquid 410-430 parts, coalescents 20-30 parts, 2-4 parts of multifunction amine auxiliary agent, wetting agent 2-5 parts, dispersant 7-8
Part, defoamer 2-5 parts, cellulose 1-3 parts, thickener 7-10 parts, pigment 80-100 parts, heat filling 160-180 parts, water 250-
270 parts, preservative 2-4 parts, mould inhibitor 1-2 parts and propane diols 15-20 parts；
Step (2)：In under 400-500 revs/min of mixing speed, sequentially add 95-100 parts water, wetting agent and point
Powder；
Step (3)：In under 400-500 revs/min of mixing speed, cellulose is slowly put into, after finishing, in 1200-
Under 1500 revs/min of mixing speed, dispersion 5-10 minutes, treats that cellulose is completely dissolved, mixed liquor gel at a high speed；
Step (4)：Defoamer, propane diols and multifunction amine auxiliary agent are sequentially added, is uniformly mixed, then slow input
Heat filling, pigment, after finishing, under 1800-2000 revs/min of mixing speed, disperse 25-30 minutes at a high speed；
Step (5)：Rotating speed is reduced to 400-500 revs/min, emulsion, coalescents, defoamer, anti-corrosion is sequentially added
Agent, mould inhibitor and remaining water, are sufficiently stirred for, and are eventually adding thickener, and regulation is obtained described heat conduction to setting viscosity
Emulsion paint.
In heat conduction emulsion paint of the present invention, coalescents select 2,2,4- trimethyl -1, and 3- pentanediol mono isobutyrates (can be with
From commercially available TEXANOL) MFT of emulsion paint can be reduced, softening lotion particle simultaneously makes its more preferable bonding,
And then the scrub resistance of paint film is effectively improved, and the consistent of emulsion paint color can be kept in the range of wider temperature and humidity,
Improve the color developing of weatherability, cleanablity, touch-up paint and the improvement coating of emulsion paint；Emulsion paint can be made using AMP-95
PH value is very stable, while having moistening, scattered effect concurrently；The X-405 wetting agents of use can improve the colloid of emulsion polymerisation system
Stability, including ion, storage freeze thawing and thermally-stabilised；It is a kind of anion surfactant using H5040 dispersants, with Zhuo
Wetting and dispersing characteristic more, foaminess is low, can improve the mobility of paint film, the excellent properties with stable slurry viscosity.
Heat filling aspect preferably alumina powder, it is the white powder crystallization of generation under hot conditions, the knot of aluminum oxide
Crystalline flour end is numerous, but aluminum oxide for heat conduction has a ball-aluminium oxide (ZF-KQ systems), and spherical aluminum oxide (ZF-KK systems) is combined
Type aluminum oxide (ZF-KQM, KCM system) etc..Thermal conductivity factor K values are high.It has fillibility high, and its particle diameter distribution is narrow, coupling modifier is closed
Reason, therefore macromolecular material can be carried out to implement high concentration filling, the preferable mixture of low viscosity mobility is can obtain, and do not influence
Vulcanization；Meanwhile, with high thermoconductivity, because its can high concentration filling, more complete heat conduction chain can be formed, with other metal oxygens
Compound is compared, and can obtain that pyroconductivity is high, the good mixture of thermal diffusivity；Because purity is high, product is deposited with covalent compound state
It is few in, particle state impurity content, so this product has preferable electric property；With acid and alkali-resistance, high temperature resistant and surface energy
Low the characteristics of, so as to not affected to the product heat conductivility used under different condition and other physical property.
Compared with prior art, the invention has the characteristics that：
1) good heat conduction effect, it is convenient to construct, and with eager to do well in everything scrub resistance, low VOC content drops to harmful substance most
Few, low smell is safe and reliable；
2) proportion is lighter, can mitigate cost of transportation；
3) preparation method is simple, and controllability is good, environmental protection, and the technology for efficiently solving existing emulsion paint poor thermal conductivity lacks
Fall into, extend emulsion paint usage cycles, good economy performance, it is easy to industry extension production, with good application prospect.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1：
To meet《JB/T-9755-1995 synthetic emulsion exterior coating standards》Requirement.The performance of coating is mainly bonded
The influence of physical performance.
Screening contrast is carried out suitable for doing the adhesive of emulsion paint coating to the country first：
Note：Water resistance shown in upper table is that, by emulsion 100um paint films dope molding on a glass, 50 DEG C of dryings 1 are small
Shi Hou, the data of soaked 96 hours.
As can be seen from the above table, the equal composite demand of performance.Carry out next step performance test.
4 sections of emulsions are respectively prepared emulsion paint according to the following formulation：
With the finished product being made by《JB/T-9755-1995 synthetic emulsion exterior coating standards》Test comparison is carried out, is seen below
Table：
As can be seen from the above table, pure-acrylic emulsion RS-706 best performances, thus the selected RS706T of adhesive carry out follow-up reality
Test.
Improve emulsion paint heat conductivility：To improve the heat conductivility of emulsion paint, compare plateau material from thermal conductivity factor and make
It is the filler of emulsion paint.
Embodiment 2：
The present embodiment safe environment protection type heat conduction emulsion paint, should include following components and weight portion content：410 parts of emulsion, into
20 parts of film auxiliary agent, 2 parts of multifunction amine auxiliary agent, 2 parts of wetting agent, 7 parts of dispersant, 2 parts of defoamer, 1 part of cellulose, 7 parts of thickener,
15 parts of 80 parts of pigment, 160 parts of heat filling, 250 parts of water, 2 parts of preservative, 1 part of mould inhibitor and propane diols.
Wherein, emulsion is selected from commercially available BLJ838A-2 emulsions, and coalescents are 2,2,4- trimethyl -1,3- pentanediol lists
Isobutyrate, multifunction amine auxiliary agent is selected from commercially available AMP-95, and wetting agent is selected from commercially available X-405 wetting agents, and dispersant is selected from
Commercially available H5040 dispersants, defoamer is selected from commercially available Mcbain131 defoamers, and cellulose is hydroxyethyl cellulose, thickener
Selected from commercially available DR-72 thickeners, pigment is selected from commercially available imperial boa R996 titanium dioxides.Heat filling is by heavy calcium carbonate and oxygen
It is 1 to change aluminium powder in mass ratio:2 mix.Preservative is selected from commercially available A26 preservatives, and mould inhibitor is selected from commercially available SN-048
Mould inhibitor.
The fineness of the present embodiment emulsion paint is 45 μm, and pH value is 8, and viscosity is 115KU, and preparation method specifically includes following step
Suddenly：
Step (1)：Got the raw materials ready by following components and weight portion content：
410 parts of emulsion, 20 parts of coalescents, 2 parts of multifunction amine auxiliary agent, 2 parts of wetting agent, 7 parts of dispersant, 2 parts of defoamer,
1 part of cellulose, 7 parts of thickener, 80 parts of pigment, 160 parts of heat filling, 250 parts of water, 2 parts of preservative, 1 part of mould inhibitor and third
15 parts of glycol；
Step (2)：In the water, wetting agent and the dispersant that under 400 revs/min of mixing speed, sequentially add 95 parts；
Step (3)：In under 400 revs/min of mixing speed, cellulose is slowly put into, after finishing, in 1200 revs/min
Mixing speed under, at a high speed dispersion 10 minutes, treat that cellulose is completely dissolved, mixed liquor gel；
Step (4)：Defoamer, propane diols and multifunction amine auxiliary agent are sequentially added, is uniformly mixed, then slow input
Heat filling, pigment, after finishing, under 1800 revs/min of mixing speed, disperse 30 minutes at a high speed；
Step (5)：Rotating speed is reduced to 400 revs/min, emulsion, coalescents, defoamer, preservative, anti-is sequentially added
Mould dose and remaining water, are sufficiently stirred for, and are eventually adding thickener, regulation to setting viscosity, you can.
Embodiment 3：
The present embodiment safe environment protection type heat conduction emulsion paint, should include following components and weight portion content：430 parts of emulsion, into
30 parts of film auxiliary agent, 4 parts of multifunction amine auxiliary agent, 5 parts of wetting agent, 8 parts of dispersant, 5 parts of defoamer, 3 parts of cellulose, thickener 10
Part, 20 parts of 100 parts of pigment, 180 parts of heat filling, 270 parts of water, 4 parts of preservative, 2 parts of mould inhibitor and propane diols.
Wherein, emulsion is selected from commercially available TX-100 emulsions, and coalescents are 2,2,4- trimethyl -1,3- pentanediol list isobutyls
Acid esters, multifunction amine auxiliary agent is selected from commercially available AMP-95, and wetting agent is selected from commercially available X-405 wetting agents, and dispersant is selected from commercially available
H5040 dispersants, defoamer be selected from commercially available Mcbain131 defoamers, cellulose is hydroxyethyl cellulose, and thickener is selected from
Commercially available DR-72 thickeners, pigment is selected from commercially available imperial boa R996 titanium dioxides.Heat filling by magnesia powder, boron carbide powder with
Alumina powder is 1 in mass ratio:1:3 mix.Preservative is selected from commercially available A26 preservatives, and mould inhibitor is selected from commercially available SN-
048 mould inhibitor.
The fineness of the present embodiment emulsion paint is 75 μm, and pH value is 9, and viscosity is 1156KU, and preparation method specifically includes following
Step：
Step (1)：Got the raw materials ready by following components and weight portion content：
430 parts of emulsion, 30 parts of coalescents, 4 parts of multifunction amine auxiliary agent, 5 parts of wetting agent, 8 parts of dispersant, 5 parts of defoamer,
3 parts of cellulose, 10 parts of thickener, 100 parts of pigment, 180 parts of heat filling, 270 parts of water, 4 parts of preservative, 2 parts of mould inhibitor and
20 parts of propane diols；
Step (2)：In the water, wetting agent and the dispersant that under 500 revs/min of mixing speed, sequentially add 100 parts；
Step (3)：In under 500 revs/min of mixing speed, cellulose is slowly put into, after finishing, in 1500 revs/min
Mixing speed under, at a high speed dispersion 5 minutes, treat that cellulose is completely dissolved, mixed liquor gel；
Step (4)：Defoamer, propane diols and multifunction amine auxiliary agent are sequentially added, is uniformly mixed, then slow input
Heat filling, pigment, after finishing, under 2000 revs/min of mixing speed, disperse 25 minutes at a high speed；
Step (5)：Rotating speed is reduced to 500 revs/min, emulsion, coalescents, defoamer, preservative, anti-is sequentially added
Mould dose and remaining water, are sufficiently stirred for, and are eventually adding thickener, regulation to setting viscosity, you can.
The above-mentioned description to embodiment is to be understood that and use invention for ease of those skilled in the art.
Person skilled in the art obviously can easily make various modifications to these embodiments, and described herein general
Principle is applied in other embodiment without by performing creative labour.Therefore, the invention is not restricted to above-described embodiment, ability
Field technique personnel announcement of the invention, does not depart from improvement that scope made and modification all should be of the invention
Within protection domain.
Claims (8)
1. a kind of safe environment protection type heat conduction emulsion paint, it is characterised in that the emulsion paint includes following components and weight portion content：Breast
Liquid 410-430 parts, coalescents 20-30 parts, 2-4 parts of multifunction amine auxiliary agent, wetting agent 2-5 parts, dispersant 7-8 parts, defoamer
2-5 parts, cellulose 1-3 parts, thickener 7-10 parts, pigment 80-100 parts, heat filling 160-180 parts and water 250-270 parts.
2. a kind of safe environment protection type heat conduction emulsion paint according to claim 1, it is characterised in that described emulsion paint is also wrapped
Include following components and weight portion content：Preservative 2-4 parts, mould inhibitor 1-2 parts and propane diols 15-20 parts.
3. a kind of safe environment protection type heat conduction emulsion paint according to claim 2, it is characterised in that described emulsion is phenylpropyl alcohol
Emulsion or pure-acrylic emulsion, described coalescents are 2,2,4- trimethyl -1, and 3- pentanediol mono isobutyrates, described is multi-functional
Amine auxiliary agent is selected from commercially available AMP-95, and described wetting agent is selected from commercially available X-405 wetting agents, and described dispersant is selected from commercially available
H5040 dispersants, described defoamer is selected from commercially available Mcbain131 defoamers, and described cellulose is hydroxy ethyl fiber
Element, described thickener is selected from one or two in commercially available DR-72 thickeners or UH-420 thickeners, described pigment choosing
From commercially available imperial boa R996 titanium dioxides.
4. a kind of safe environment protection type heat conduction emulsion paint according to claim 3, it is characterised in that described emulsion is selected from city
BLJ838A-2 emulsions, TX-100 emulsions, 8039 emulsions or the RS706T emulsions sold.
5. a kind of safe environment protection type heat conduction emulsion paint according to claim 2, it is characterised in that described heat filling bag
Include one or more in heavy calcium carbonate, boron carbide powder, magnesia powder, alumina powder or oxide powder and zinc.
6. a kind of safe environment protection type heat conduction emulsion paint according to claim 2, it is characterised in that described preservative is selected from
Commercially available A26 preservatives, described mould inhibitor is selected from commercially available SN-048 mould inhibitors.
7. a kind of safe environment protection type heat conduction emulsion paint according to claim 2, it is characterised in that described emulsion paint it is thin
It is 45-75 μm to spend, and pH value is 8-9, and viscosity is 115-116KU.
8. a kind of preparation method of the safe environment protection type heat conduction emulsion paint as described in any one of claim 2 to 7, its feature exists
In the method specifically includes following steps：
Step (1)：Got the raw materials ready by following components and weight portion content：
Liquid 410-430 parts, coalescents 20-30 parts, 2-4 parts of multifunction amine auxiliary agent, dispersant 7-8 parts, disappears by wetting agent 2-5 parts
Infusion 2-5 parts, cellulose 1-3 parts, thickener 7-10 parts, pigment 80-100 parts, heat filling 160-180 parts, water 250-270
Part, preservative 2-4 parts, mould inhibitor 1-2 parts and propane diols 15-20 parts；
Step (2)：In the water, wetting agent and the dispersant that under 400-500 revs/min of mixing speed, sequentially add 95-100 parts；
Step (3)：In under 400-500 revs/min of mixing speed, slowly put into cellulose, after finishing, in 1200-1500 turn/
Under the mixing speed of minute, dispersion 5-10 minutes, treats that cellulose is completely dissolved, mixed liquor gel at a high speed；
Step (4)：Defoamer, propane diols and multifunction amine auxiliary agent are sequentially added, is uniformly mixed, then the heat conduction of slow input
Filler, pigment, after finishing, under 1800-2000 revs/min of mixing speed, disperse 25-30 minutes at a high speed；
Step (5)：Rotating speed is reduced to 400-500 revs/min, emulsion, coalescents, defoamer, preservative, anti-is sequentially added
Mould dose and remaining water, are sufficiently stirred for, and are eventually adding thickener, and regulation is obtained described heat conduction latex to setting viscosity
Paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710053218.7A CN106867323A (en) | 2017-01-22 | 2017-01-22 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
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| CN201710053218.7A CN106867323A (en) | 2017-01-22 | 2017-01-22 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383971A (en) * | 2017-08-31 | 2017-11-24 | 白建宏 | A kind of new indoor emulsion paint |
| CN107663392A (en) * | 2017-11-14 | 2018-02-06 | 润泰化学（泰兴）有限公司 | A kind of response type coalescents |
| CN108102493A (en) * | 2017-12-27 | 2018-06-01 | 温州市艺都装潢有限公司 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
-
2017
- 2017-01-22 CN CN201710053218.7A patent/CN106867323A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383971A (en) * | 2017-08-31 | 2017-11-24 | 白建宏 | A kind of new indoor emulsion paint |
| CN107663392A (en) * | 2017-11-14 | 2018-02-06 | 润泰化学（泰兴）有限公司 | A kind of response type coalescents |
| CN107663392B (en) * | 2017-11-14 | 2021-01-05 | 润泰化学（泰兴）有限公司 | Reactive film-forming assistant |
| CN108102493A (en) * | 2017-12-27 | 2018-06-01 | 温州市艺都装潢有限公司 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
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