CN106380979A - Silicone-acrylic weather-resistant reflective heat-insulation natural stone paint and preparation method thereof - Google Patents
Silicone-acrylic weather-resistant reflective heat-insulation natural stone paint and preparation method thereof Download PDFInfo
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- CN106380979A CN106380979A CN201610848964.0A CN201610848964A CN106380979A CN 106380979 A CN106380979 A CN 106380979A CN 201610848964 A CN201610848964 A CN 201610848964A CN 106380979 A CN106380979 A CN 106380979A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a silicone-acrylic weather-resistant reflective heat-insulation natural stone paint which comprises a component A used as a base material and a component B used as natural colored sand. The component A used as the base paint is prepared from water, cellulose ether, a dispersing agent, an infrared reflection pigment, a heat-insulation filler, a film forming material, a film forming aid, wetting agent, a defoaming agent, a thickener, a pH value regulator and a bactericide. The infrared reflection pigment of the component A is W210 ceramic, the heat-insulation filler is 3M hollow glass microspheres, and the film forming material is a pure acrylic silicon emulsion. The invention also discloses a preparation method of the silicone-acrylic weather-resistant reflective heat-insulation natural stone paint. The reflection and heat insulation functions are added to the paint, and the decorative effect of marble is formed; and thus, the paint has very high decorative property. The component A base material has the reflection and heat insulation functions; the mixture of the component A base material and natural colored sand has favorable heat insulation effects on the wall, and thus, belongs to a green energy-saving product.
Description
Technical field
The present invention relates to building coating field, particularly to a kind of weather-proof reflective insulation natural real stone paint of silicon third and its preparation
Method.
Background technology
Natural real stone paint is product type very popular in building coating industry these years, and product with acrylic emulsion is
Based on master is equipped with natural colour coloured silk sand, the natural colorful sand grains of shades of colour is joined according to different levels and combines acrylic emulsion
Form with additive compound, this product has the texture effect of lithotome, film durability is excellent, colour-fast, splitting resistance is strong,
Decorative effect is attractive in appearance, this product also exactly one of popular decoration system currently on the market.
Natural real stone paint technical research comparative maturity, mainly does the improvement of the weather resistance of product at present, but
In terms of energy-conservation or the same with common exterior wall product, there is no reflective insulation function, still could not meet national energy-saving environmental protection
Require.
Content of the invention
An object of the present invention is exactly to provide a kind of silicon third weather-proof reflective insulation natural real stone paint, this weather-proof reflection of silicon third
Heat-insulated true mineral varnish is mainly applied to building wall, is a exterior coating with decorative effect very attractive in appearance, simultaneously
Base material A component has functions that to reflect external light and heat, is not affecting paint film appearance effect, this product also has reflective insulation
Effect, meet national environmental protection heat preservation energy-saving requirement, weatherability is greatly improved simultaneously, accords with the demands of the market.
The two of the object of the invention are exactly the preparation method providing the weather-proof reflective insulation natural real stone paint of above-mentioned silicon third.
The object of the present invention is achieved like this：
A kind of weather-proof reflective insulation natural real stone paint of silicon third, is prepared from the following ingredients in percentage by and is prepared from：
Component A as base-material：44%～50%；
B component as natural colour sand：50%～56%；
Based on wherein said, the component A of paint is prepared from by the raw material of following mass percent：
The B component of described natural colour sand：
Natural colour sand 100%；
The cellulose ether of described component A is methyl cellulose ether, cellulose ether, hydroxymethyl cellulose ether, ethoxy
Cellulose ether, hydroxypropylcelluloether ether, TYLOSE 30000 or methylhydroxypropylcellulose ether.
The dispersant of described component A is polyacrylic acid dipersant.
The infrared reflecting paint W210 pottery of described component A, they are with properties of infrared reflection, durable in use.
The thermal insulating filling of described component A is the hollow glass micro-ball of 3M, due to its glass material, has preferable infrared barrier
Effect, glass also has stronger reflex for sunshine, and its hollow-core construction is used in coating in addition has preferable reduction to lead
The effect of hot coefficient.
The film forming matter of described component A is pure acrylic acid silicon emulsion, has preferably weather-proof, stain resistance.
The film forming matter auxiliary agent of described component A is alcohol ester 12.
The wetting agent of described component A is Shanghai grid trade Co., Ltd 399.
The defoamer of described component A is the compounding of siloxane-based defoamer or siloxane-based defoamer.
The thickener of described component A is polyurethane-type thickener or alkali swollen thickener.
The pH adjusting agent of described component A is sodium hydrate aqueous solution or ammoniacal liquor.
The bactericide of described component A is selected from isothiazoline alcohol/ketone mixtures or imdazole derivatives.
The B component of described natural colour sand, from Hebei Shijiazhuang Jin Yuan mining industry natural colour sand.
The preparation method of the weather-proof reflective insulation natural real stone paint of above-mentioned silicon third, comprises the steps：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, is subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mixing, adds thereafter red W210 pottery, 3M hollow glass micro-ball according to this,
Disperse at a high speed, until being uniformly dispersed, then put into silicone acrylic emulsion, coalescents, wetting agent, thickener, and be uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put into stirring in the middle of produced component A on request
Uniformly obtain final product.
The present invention and the advantage of existing system product, present invention employs film forming matter based on silicon emulsion, improve routine
True mineral varnish is weather-proof, contaminated resistance, increased the function of reflective insulation, forms marmorean decorative effect, has and decorate by force very much
Property.The component A base-material of the present invention has reflective insulation function, and after mixing natural colour sand construction, body of wall is served with heat-insulated effect very well
Really, belong to green energy conservation product.The present invention has good environmental-protecting performance, and paint film has the peculiar function of reflective insulation, construction
Simply.
Specific embodiment：
Embodiment 1
A kind of weather-proof reflective insulation natural real stone paint of silicon third, the component containing following weight percents：Based on paint A
Component 45%, as the B component 55% of natural colour sand,
The B component of described natural colour sand：55%
The preparation method of the weather-proof reflective insulation natural real stone paint of silicon third of this embodiment, its step is as follows：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, is subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mixing, adds thereafter red W210 pottery, 3M hollow glass micro-ball according to this,
Disperse at a high speed, until being uniformly dispersed, then put into silicone acrylic emulsion, coalescents, wetting agent, thickener, and be uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put into stirring in the middle of produced component A on request
Uniformly；
Above-described embodiment presses " JG/T 24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS (W type) " and " JG/T 235-
The standard of 2008 architectural reflective heat-insulation paints " carries out the detection of various indexs, and partial results are as shown in table 1 below：
Table 1
Embodiment 2
A kind of weather-proof reflective insulation natural real stone paint of silicon third, the component containing following weight percents：Based on paint A
Component 50%, as the B component 50% of natural colour sand,
The B component of described natural colour sand：50%.
The preparation method of the weather-proof reflective insulation natural real stone paint of silicon third of this embodiment, its step is as follows：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, is subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mixing, adds thereafter red W210 pottery, 3M hollow glass micro-ball according to this,
Disperse at a high speed, until being uniformly dispersed, then put into silicone acrylic emulsion, coalescents, wetting agent, thickener, and be uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put into stirring in the middle of produced component A on request
Uniformly；
Above-described embodiment presses " JG/T 24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS (W type) " and " JG/T 235-
The standard of 2008 architectural reflective heat-insulation paints " carries out the detection of various indexs, and partial results are as shown in table 2 below：
Table 2
Embodiment 3
A kind of weather-proof reflective insulation natural real stone paint of silicon third, the component containing following weight percents：Based on paint A
Component 37%, as the B component 63% of natural colour sand,
The B component of described natural colour sand：63%.
The preparation method of the weather-proof reflective insulation natural real stone paint of silicon third of this embodiment, its step is as follows：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, is subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mixing, adds thereafter red W210 pottery, 3M hollow glass micro-ball according to this,
Disperse at a high speed, until being uniformly dispersed, then put into silicone acrylic emulsion, coalescents, wetting agent, thickener, and be uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put into stirring in the middle of produced component A on request
Uniformly；
Above-described embodiment presses " JG/T 24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS (W type) " and " JG/T 235-
The standard of 2008 architectural reflective heat-insulation paints " carries out the detection of various indexs, and partial results are as shown in table 3 below：
Table 3
Embodiment 4
A kind of weather-proof reflective insulation natural real stone paint of silicon third, the component containing following weight percents：Based on paint A
Component 41%, as the B component 59% of natural colour sand,
The B component of described natural colour sand：59%.
The preparation method of the weather-proof reflective insulation natural real stone paint of silicon third of this embodiment, its step is as follows：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, is subsequently adding dispersion
Agent, pH value regulator, defoamer, stirring, until mixing, adds thereafter red W210 pottery, 3M hollow glass micro-ball according to this,
Disperse at a high speed, until being uniformly dispersed, then put into silicone acrylic emulsion, coalescents, wetting agent, thickener, and be uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put into stirring in the middle of produced component A on request
Uniformly；
Above-described embodiment presses " JG/T 24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS (W type) " and " JG/T 235-
The standard of 2008 architectural reflective heat-insulation paints " carries out the detection of various indexs, and partial results are as shown in table 4 below：
Table 4
Comparative example 1
Common natural real stone paint, the component containing following weight percents：Based on paint component A 25%, as sky
So B component 75% of color sand,
The B component of described natural colour sand：75%.
The preparation method of the weather-proof reflective insulation natural real stone paint of silicon third of this embodiment, its step is as follows：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, is subsequently adding pH value
Conditioning agent, defoamer, stirring is until mix, then puts into silicone acrylic emulsion, coalescents, thickener, and is uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put into stirring in the middle of produced component A on request
Uniformly；
Above-described embodiment presses " JG/T 24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS (W type) " and " JG/T 235-
The standard of 2008 architectural reflective heat-insulation paints " carries out the detection of various indexs, and partial results are as shown in table 1 below：
Table 1
General principle, principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry
, it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and specification is originally for personnel
Invention principle, without departing from the spirit and scope of the present invention the present invention also have various changes and modifications, these change
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and its
Equivalent defines.
Claims (10)
1. a kind of weather-proof reflective insulation natural real stone paint of silicon third it is characterised in that be prepared from the following ingredients in percentage by preparation and
Become：
Component A as base-material：44%～50%；
B component as natural colour sand：50%～56%；
Based on wherein said, the component A of paint is prepared from by the raw material of following mass percent：
The B component of described natural colour sand：
Natural colour sand 100%；
The infrared reflecting paint W210 pottery of described component A, the thermal insulating filling of described component A is the hollow glass micro-ball of 3M, institute
The film forming matter stating component A is pure acrylic acid silicon emulsion.
2. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the fiber of described component A
Plain ether be methyl cellulose ether, cellulose ether, hydroxymethyl cellulose ether, hydroxyethyl ether cellulose, hydroxypropylcelluloether ether,
TYLOSE 30000 or methylhydroxypropylcellulose ether.
3. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the dispersion of described component A
Agent is polyacrylic acid dipersant.
4. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the film forming of described component A
Thing auxiliary agent is alcohol ester 12.
5. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the wetting of described component A
Agent is Shanghai grid trade Co., Ltd 399.
6. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the froth breaking of described component A
Agent is the compounding of siloxane-based defoamer or siloxane-based defoamer.
7. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the thickening of described component A
Agent is polyurethane-type thickener or alkali swollen thickener.
8. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the pH of described component A adjusts
Section agent is sodium hydrate aqueous solution or ammoniacal liquor.
9. the weather-proof reflective insulation natural real stone paint of silicon third as claimed in claim 1 is it is characterised in that the sterilization of described component A
Agent is selected from isothiazoline alcohol/ketone mixtures or imdazole derivatives.
10. the weather-proof reflective insulation natural real stone paint of silicon third described in claim 1 preparation method it is characterised in that include as
Lower step：
(1) prepare component A：Cellulose ether is added to the water, with dispersion machine moderate-speed mixer until dissolving, be subsequently adding dispersant,
PH value regulator, defoamer, stirring, until mixing, adds thereafter red W210 pottery, 3M hollow glass micro-ball, at a high speed according to this
Dispersion, until being uniformly dispersed, then puts into silicone acrylic emulsion, coalescents, wetting agent, thickener, and is uniformly mixed；
(2) color and level are matched the B component natural colour sand preparing and put on request and stir in the middle of produced component A
Obtain final product.
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| CN201610848964.0A CN106380979A (en) | 2016-09-23 | 2016-09-23 | Silicone-acrylic weather-resistant reflective heat-insulation natural stone paint and preparation method thereof |
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| CN201610848964.0A CN106380979A (en) | 2016-09-23 | 2016-09-23 | Silicone-acrylic weather-resistant reflective heat-insulation natural stone paint and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107572922A (en) * | 2017-09-21 | 2018-01-12 | 苏州振振好新型建材科技有限公司 | A kind of colorful true mineral varnish of inorganic thermal insulation |
| CN107857511A (en) * | 2017-11-13 | 2018-03-30 | 鳄鱼制漆(上海)有限公司 | A kind of weather-proof batch of scratch-type natural real stone paint of organosilicon and preparation method thereof |
| CN109337482A (en) * | 2018-10-24 | 2019-02-15 | 宿松汉邦新型建材有限公司 | A kind of snowflake white sand lacquer and preparation method thereof |
| CN109503026A (en) * | 2017-11-13 | 2019-03-22 | 天津德普威涂料有限公司 | A kind of colorful water burnt-in sand coating of high durable and preparation method thereof |
| CN110016268A (en) * | 2019-04-28 | 2019-07-16 | 河北晨阳工贸集团有限公司 | A kind of reflective insulation lacquer and preparation method thereof |
| CN111892852A (en) * | 2020-07-28 | 2020-11-06 | 浙江志强涂料有限公司 | Corrosion-resistant epoxy modified silicon-acrylic stone paint |
| CN112521816A (en) * | 2020-11-24 | 2021-03-19 | 上海三棵树防水技术有限公司 | Medium and low brightness reflective heat insulation stone-like paint and preparation method thereof |
| CN112778803A (en) * | 2020-12-30 | 2021-05-11 | 郝艳敏 | Natural stone paint and preparation method thereof |
| CN113583531A (en) * | 2021-08-16 | 2021-11-02 | 广东涂百年新型材料有限公司 | Reflective heat-insulation real stone paint material and preparation method thereof |
| CN113604166A (en) * | 2021-08-31 | 2021-11-05 | 李生贵 | Preparation method and application of self-adhesive waterproof soft porcelain |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107572922A (en) * | 2017-09-21 | 2018-01-12 | 苏州振振好新型建材科技有限公司 | A kind of colorful true mineral varnish of inorganic thermal insulation |
| CN107857511A (en) * | 2017-11-13 | 2018-03-30 | 鳄鱼制漆(上海)有限公司 | A kind of weather-proof batch of scratch-type natural real stone paint of organosilicon and preparation method thereof |
| CN109503026A (en) * | 2017-11-13 | 2019-03-22 | 天津德普威涂料有限公司 | A kind of colorful water burnt-in sand coating of high durable and preparation method thereof |
| CN109503026B (en) * | 2017-11-13 | 2021-01-08 | 天津德普威涂料有限公司 | High-weather-resistance colorful sand-in-water coating and preparation method thereof |
| CN109337482A (en) * | 2018-10-24 | 2019-02-15 | 宿松汉邦新型建材有限公司 | A kind of snowflake white sand lacquer and preparation method thereof |
| CN110016268A (en) * | 2019-04-28 | 2019-07-16 | 河北晨阳工贸集团有限公司 | A kind of reflective insulation lacquer and preparation method thereof |
| CN111892852A (en) * | 2020-07-28 | 2020-11-06 | 浙江志强涂料有限公司 | Corrosion-resistant epoxy modified silicon-acrylic stone paint |
| CN112521816A (en) * | 2020-11-24 | 2021-03-19 | 上海三棵树防水技术有限公司 | Medium and low brightness reflective heat insulation stone-like paint and preparation method thereof |
| CN112778803A (en) * | 2020-12-30 | 2021-05-11 | 郝艳敏 | Natural stone paint and preparation method thereof |
| CN113583531A (en) * | 2021-08-16 | 2021-11-02 | 广东涂百年新型材料有限公司 | Reflective heat-insulation real stone paint material and preparation method thereof |
| CN113604166A (en) * | 2021-08-31 | 2021-11-05 | 李生贵 | Preparation method and application of self-adhesive waterproof soft porcelain |
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