CN104804565A - Pottery sand stone-like coating and preparation method thereof - Google Patents
Pottery sand stone-like coating and preparation method thereof Download PDFInfo
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- CN104804565A CN104804565A CN201510196855.0A CN201510196855A CN104804565A CN 104804565 A CN104804565 A CN 104804565A CN 201510196855 A CN201510196855 A CN 201510196855A CN 104804565 A CN104804565 A CN 104804565A
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- pottery sand
- mineral varnish
- true mineral
- pottery
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Abstract
The invention discloses a pottery sand stone-like coating. The pottery sand stone-like coating is prepared by the following steps: weighting the following components in parts by weight: 20-260 parts of water, 2-5 parts of a multifunctional additive, 3-5 parts of a fungicide, 2-6 parts of cellulose, 2-10 parts of a dispersant, 1-8 parts of a wetting agent, 1-8 parts of a foam killer, 6-10 parts of a film-forming additive, and 20-200 parts of a styrene-acrylic emulsion, stirring to enable the components to be mixed to obtain a binder, adding 1-750 parts of pottery sand by weight and 1-750 parts of quartz sand by weight into the binder, mixing and stirring to obtain the pottery sand stone-like coating. According to the pottery sand stone-like coating added with pottery sand, the heat insulation and thermal insulation performance of the stone-like coating is well; as the fungicide is added into the stone-like coating, the pottery sand stone-like coating is antibacterial and bactericidal; the pottery sand stone-like coating provided by the invention is heat-insulated, thermal-insulated, antibacterial and bactericidal. In addition, the pottery sand stone-like coating provided by the invention is simple in preparation method, convenient to construction, safe and environment-friendly.
Description
Technical field
The invention belongs to true mineral varnish field, be specifically related to true mineral varnish of a kind of pottery sand and preparation method thereof.
Background technology
True mineral varnish is that a kind of decorative effect exactly likes marble, granitic coating, and the main natural stone-powder of shades of colour that adopts is formulated.Buildings after true mineral varnish finishing, has natural real natural colour, gives elegance, harmony, serious aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings, particularly decorate on curved-surface building thing, can receive vivid, effect of back to nature.True mineral varnish has fire prevention, waterproof, acid and alkali-resistance, anti-pollution.The features such as nontoxic, tasteless, bonding force is strong, will never fade, can stop extraneous severe environment to corrode buildings effectively, extend the life-span of buildings, because true mineral varnish possesses good sticking power and freeze-thaw resistance property, are therefore particularly suitable for using in cold district.True mineral varnish easy construction, easily dryly saves time, the advantages such as easy construction.
Chinese patent CN104402301A discloses the true mineral varnish of a kind of light haydite and preparation method, with the addition of pottery sand and natural sliver in its raw material, by adding natural sliver, makes true mineral varnish simulated effect better, but its heat preservation and insulation and antibacterial ability poor.
Summary of the invention
For the deficiencies in the prior art, an object of the present invention is to provide a kind of pottery sand true mineral varnish, and the true mineral varnish of this pottery sand has effect of heat-insulation and heat-preservation, antibiotic and sterilizing.
For reaching this object, the present invention by the following technical solutions:
The true mineral varnish of a kind of pottery sand, comprises following raw material by mass parts:
Pottery sand 1-750 part, such as 1 part, 10 parts, 20 parts, 50 parts, 100 parts, 120 parts, 150 parts, 160 parts, 180 parts, 200 parts, 250 parts, 300 parts, 350 parts, 400 parts, 430 parts, 480 parts, 500 parts, 550 parts, 600 parts, 650 parts, 700 parts, 750 parts;
Quartz sand 1-750 part, such as 1 part, 10 parts, 20 parts, 50 parts, 100 parts, 120 parts, 150 parts, 160 parts, 180 parts, 200 parts, 250 parts, 300 parts, 350 parts, 400 parts, 430 parts, 480 parts, 500 parts, 550 parts, 600 parts, 650 parts, 700 parts, 750 parts;
Benzene emulsion 20-200 part, such as 20 parts, 30 parts, 50 parts, 60 parts, 80 parts, 100 parts, 140 parts, 160 parts, 180 parts, 200 parts;
Ethylene glycol 2-20 part, such as 2 parts, 4 parts, 6 parts, 8 parts, 10 parts, 13 parts, 15 parts, 17 parts, 20 parts;
Multifunctional assistant 1-10 part, such as 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts;
Sterilant 1-8 part, such as 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts;
Mierocrystalline cellulose 1-10 part, such as 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts;
Dispersion agent 1-20 part, such as 1 part, 2 parts, 4 parts, 6 parts, 8 parts, 10 parts, 13 parts, 15 parts, 17 parts, 20 parts;
Wetting agent 1-15 part, such as 1 part, 2 parts, 4 parts, 6 parts, 8 parts, 10 parts, 13 parts, 15 parts;
Defoamer 1-20 part, such as 1 part, 2 parts, 4 parts, 6 parts, 8 parts, 10 parts, 13 parts, 15 parts, 17 parts, 20 parts;
Film coalescence aid 5-30 part, such as 5 parts, 6 parts, 8 parts, 10 parts, 13 parts, 15 parts, 17 parts, 20 parts, 23 parts, 25 parts, 27 parts, 29 parts, 30 parts;
Water 20-260 part, such as 20 parts, 40 parts, 50 parts, 60 parts, 70 parts, 80 parts, 90 parts, 100 parts, 120 parts, 140 parts, 150 parts, 170 parts, 190 parts, 200 parts, 220 parts, 240 parts, 260 parts.
Haydite is the particle of ceramic, and thinner is referred to as sand of making pottery.Pottery sand utilizes the plurality of raw materials such as all kinds of clay, slate, shale, coal gangue and industrial solid castoff, forms through ceramic post sintering, is generally used to replace the rubble in concrete and cobble.The many merits such as pottery sand has that density is low, heat insulating, impervious excellent, alkali resistant aggregate reaction is excellent, water-intake rate is low, anti-freezing property and excellent in durability.
Quartz sand is the quartz particles that quartzite processes through fragmentation, also known as silica, is that a kind of quality is hard, wear-resisting, the silicates mineral of stable chemical nature.Exist with quartzose sandstone, quartzite and vein quartz at occurring in nature.Quartzose sandstone is the chip rock of consolidation, quartz grains content reaches more than 95%, quartz sand is a kind of silicate minerals of hard, wear-resisting, stable chemical performance, its main mineral constituent is SiO2, the color of quartz sand is oyster white or semi-transparent clear shape, Mohs' hardness 7, quartz sand is important industrial mineral raw material, non-chemically hazardous substance, are widely used in the industry such as glass, casting, pottery and refractory materials, smelting duriron, flux for metallurgy, metallurgy, building, chemical industry, plastics, rubber, abrasive material, filtrate.
Wherein, pottery sand is 150-220 order, such as 150 orders, 160 orders, 170 orders, 180 orders, 190 orders, 200 orders, 210 orders, 220 orders; Quartz sand is 50-200 order, such as 50 orders, 80 orders, 90 orders, 100 orders, 120 orders, 150 orders, 160 orders, 170 orders, 180 orders, 190 orders, 200 orders.
Benzene emulsion (styrene-acrylate emulsion) is obtained through emulsion copolymerization by vinylbenzene and acrylate monomer.It is water-fast, alkaline-resisting, scrub resistance can be good, and resistance to outdoor aging is widely used in the field such as tackiness agent, coating.Preferably, benzene emulsion is benzene emulsion 992.
Filmogen in coating can dissolve or be separated into uniform liquid state by ethylene glycol, in addition can also as frostproofer.
The effect of Mierocrystalline cellulose in coating is have good thickening, suspension, dispersion, emulsification, bonding, film forming, protection moisture and provide protective colloid etc., and Mierocrystalline cellulose can be selected from lignocellulose, hydroxypropylcellulose, carboxymethyl cellulose, sodium benzene emulsion, Polyanionic Cellulose, polyvinyl alcohol propylene glycol, sodium polyacrylate ethyl cellulose, Natvosol etc.Preferably, Mierocrystalline cellulose is Natvosol 100,000.
Sterilant, dispersion agent, wetting agent, defoamer, film coalescence aid and multifunctional assistant are commercially available usual auxiliaries.
Preferably, described multifunctional assistant is multifunctional assistant AMP-95; Multifunctional assistant AMP-95 contains the moisture content-2-amino-2-methyl-1-propanol of 5%, is that current minority has one of lower molecular weight and overbasic industrial amine.AMP-95 as the multifunctional assistant of all kinds emulsion paint, can be divided into powder with AMP-95 as brute force and can prevent pigment from re-uniting in formula.Meanwhile, all properties of multifunctional assistant AMP-95 to enamelled coating contributes significant superiority.
Preferably, described sterilant is sterilant LXZ.
Dispersion agent is a kind of interfacial agent simultaneously in molecule with lipophilicity and wetting ability two kinds of opposite nature, can homogeneous dispersion and be insoluble in the solid particulate of inorganic, the pigment dyestuff of liquid, also can prevent sedimentation and the cohesion of solid particulate simultaneously, form stable medicament needed for suspension.In coating, use pigment dispersing agent, the gloss of film can be increased, improve levelling property, improve the painted and opacifying power of coating, prevent loose colour, sedimentation, enhance productivity and the package stability of coating.Preferably, described dispersion agent is dispersion agent PDA.
Preferably, described wetting agent is wetting agent 486;
Preferably, described defoamer is defoamer NXZ;
Preferably, described film coalescence aid is film coalescence aid C-12.
Two of object of the present invention is the preparation method providing the true mineral varnish of a kind of sand of making pottery, comprise the steps:, by mass parts, take 20-260 part water, 2-5 part multifunctional assistant, 3-5 part sterilant, 2-6 part Mierocrystalline cellulose, 2-10 part dispersion agent, 1-8 part wetting agent, 1-8 part defoamer, 6-10 part film coalescence aid, 20-200 part benzene emulsion be uniformly mixed into base-material, then in base-material, add 1-750 part pottery sand, 1-750 part quartz sand mix and blend, obtain the true mineral varnish of described pottery sand.
Compared with prior art, beneficial effect of the present invention is: the true mineral varnish of a kind of pottery sand, by mass parts, take 20-260 part water, 2-5 part multifunctional assistant, 3-5 part sterilant, 2-6 part Mierocrystalline cellulose, 2-10 part dispersion agent, 1-8 part wetting agent, 1-8 part defoamer, 6-10 part film coalescence aid, 20-200 part benzene emulsion be uniformly mixed into base-material, then in base-material, add 1-750 part pottery sand, 1-750 part quartz sand mix and blend, obtain the true mineral varnish of described pottery sand.The present invention's true mineral varnish of sand of making pottery adds pottery sand, makes the heat preservation and insulation of true mineral varnish good; In true mineral varnish, with the addition of sterilant, make pottery sand true mineral varnish energy antibiotic and sterilizing.The true mineral varnish heat-insulation and heat-preservation of pottery sand of the present invention, antibiotic and sterilizing.In addition, the true mineral varnish preparation method of pottery sand of the present invention is simple, easy construction, safety and environmental protection.
Embodiment
Technical scheme of the present invention is further illustrated below by embodiment.
As no specific instructions, various raw material of the present invention all can commercially availablely be buied, or prepares according to the ordinary method of this area.
Embodiment 1
Take 200 parts of water, 4 parts of multifunctional assistant AMP-95,5 parts of sterilant LXZ, 5 parts of Natvosols, 100,000,8 parts of dispersion agent PDA, 3 parts of wetting agents, 486,4 parts of defoamer NXZ, 7 parts of film coalescence aid C-12,100 part of 992 benzene emulsion are uniformly mixed into base-material, then in base-material, add 500 parts, 200 order pottery sand, 150 order, 500 parts of quartz sand mix and blends, obtain the true mineral varnish of pottery sand, the true mineral varnish condition in container obtained is normal, and application property is good.
Embodiment 2
Take 100 parts of water, 5 parts of multifunctional assistant AMP-95,3 parts of sterilant LXZ, 2 parts of Natvosols, 100,000,5 parts of dispersion agent PDA, 2 parts of wetting agents, 486,6 parts of defoamer NXZ, 6 parts of film coalescence aid C-12,150 part of 992 benzene emulsion are uniformly mixed into base-material, then in base-material, add 450 parts, 160 order pottery sand, 200 order, 500 parts of quartz sand mix and blends, obtain the true mineral varnish of pottery sand, the true mineral varnish condition in container obtained is normal, and application property is good.
Embodiment 3
Take 240 parts of water, 2 parts of multifunctional assistant AMP-95,4 parts of sterilant LXZ, 3 parts of Natvosols, 100,000,3 parts of dispersion agent PDA, 6 parts of wetting agents, 486,3 parts of defoamer NXZ, 8 parts of film coalescence aid C-12,80 part of 992 benzene emulsion are uniformly mixed into base-material, then in base-material, add 200 parts, 220 order pottery sand, 100 order, 300 parts of quartz sand mix and blends, obtain the true mineral varnish of pottery sand, the true mineral varnish condition in container obtained is normal, and application property is good.
Above embodiment is only used for method detailed of the present invention is described, the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of ancillary component, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (10)
1. the true mineral varnish of pottery sand, is characterized in that, comprise following raw material by mass parts:
2. the true mineral varnish of one pottery sand according to claim 1, is characterized in that, comprise following raw material by mass parts:
3. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, described pottery sand is 150-220 order, and described quartz sand is 50-200 order.
4. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, described benzene emulsion is 992 benzene emulsions.
5. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, described multifunctional assistant is multifunctional assistant AMP-95.
6. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, sterilant is sterilant LXZ.
7. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, described Mierocrystalline cellulose is Natvosol 100,000.
8. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, described dispersion agent is dispersion agent PDA.
9. the true mineral varnish of one pottery sand according to claim 1, it is characterized in that, described wetting agent is wetting agent 486;
Preferably, described defoamer is defoamer NXZ;
Preferably, described film coalescence aid is film coalescence aid C-12.
10. the preparation method of the true mineral varnish of a kind of sand of making pottery as claimed in claim 1, it is characterized in that, comprise the steps: by mass parts, take 20-260 part water, 2-5 part multifunctional assistant, 3-5 part sterilant, 2-6 part Mierocrystalline cellulose, 2-10 part dispersion agent, 1-8 part wetting agent, 1-8 part defoamer, 6-10 part film coalescence aid, 20-200 part benzene emulsion be uniformly mixed into base-material, then in base-material, add 1-750 part pottery sand, 1-750 part quartz sand mix and blend, obtain the true mineral varnish of described pottery sand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510196855.0A CN104804565A (en) | 2015-04-23 | 2015-04-23 | Pottery sand stone-like coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510196855.0A CN104804565A (en) | 2015-04-23 | 2015-04-23 | Pottery sand stone-like coating and preparation method thereof |
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| CN104804565A true CN104804565A (en) | 2015-07-29 |
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| CN201510196855.0A Pending CN104804565A (en) | 2015-04-23 | 2015-04-23 | Pottery sand stone-like coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
| CN109912261A (en) * | 2019-03-22 | 2019-06-21 | 浙江曼得丽涂料有限公司 | A kind of pure C light granules dazzle rock lacquer and preparation method thereof |
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| CN103555082A (en) * | 2013-11-08 | 2014-02-05 | 西北永新涂料有限公司 | Real stone paint and preparation method thereof |
| CN104293056A (en) * | 2014-10-08 | 2015-01-21 | 杭州潮头建材有限公司 | Water-based colorful real stone-type stone-like coating and production process thereof |
| CN104402301A (en) * | 2014-11-11 | 2015-03-11 | 黄美忠 | Lightweight pottery sand stone-like paint and preparation method thereof |
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2015
- 2015-04-23 CN CN201510196855.0A patent/CN104804565A/en active Pending
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| DE4211208A1 (en) * | 1992-04-03 | 1993-10-07 | Henkel Kgaa | Wash- and abrasion-resistant aq. emulsion paints - comprising polymer dispersion binder, mono:ether cpds. of dicyclopentadiene as coalescing agent and usual additives |
| CN103555082A (en) * | 2013-11-08 | 2014-02-05 | 西北永新涂料有限公司 | Real stone paint and preparation method thereof |
| CN104293056A (en) * | 2014-10-08 | 2015-01-21 | 杭州潮头建材有限公司 | Water-based colorful real stone-type stone-like coating and production process thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
| CN109912261A (en) * | 2019-03-22 | 2019-06-21 | 浙江曼得丽涂料有限公司 | A kind of pure C light granules dazzle rock lacquer and preparation method thereof |
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Application publication date: 20150729 |