CN106634394A - Waterborne transparent fireproof paint for historic buildings and preparation method of waterborne transparent fireproof paint - Google Patents
Waterborne transparent fireproof paint for historic buildings and preparation method of waterborne transparent fireproof paint Download PDFInfo
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- CN106634394A CN106634394A CN201610889080.XA CN201610889080A CN106634394A CN 106634394 A CN106634394 A CN 106634394A CN 201610889080 A CN201610889080 A CN 201610889080A CN 106634394 A CN106634394 A CN 106634394A
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- phosphonate ester
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses waterborne transparent fireproof paint for historic buildings and a preparation method of the waterborne transparent fireproof paint. The paint is prepared from, by weight, 25-30 parts of amino resin, 1-3 parts of waterborne polyvinyl alcohol powder, 3-5 parts of ethylene-vinyl acetate copolymer, 5-10 parts of polysiloxane, 18.5-34.5 parts of fire retardant, 10-15 parts of pentaerythritol, 1-5 parts of phytic acid, 0.5-1.5 parts of triethanolamine, 2.1-3.5 parts of additives, 5-10 parts of a wood stabilizer and 10-29 parts of water. The method includes steps of raw material weighing, primary mixing and secondary mixing. By condensation polymerization of active polysiloxane emulsion and active phosphonate, fireproof performance of the paint is improved, coating transparency is realized, original appearances of materials can be kept, and the paint is less prone to cracking and excellent in weather resistance; since a main component of the paint is dry powder, storage life of the paint is effectively prolonged; due to addition of the waterborne wood stabilizer and the phytic acid in the fireproof paint, rotten and deformed wood materials are protected effectively.
Description
Technical field
The invention belongs to architectural fireproof paint technical field, and in particular to a kind of aqueous transparent old architecture survey coating and its
Preparation method.
Background technology
The Chinese nation possesses the bright civilization of 5,000-year and down, and history culture is long to spread.Ancient building, ancient houses are long
The art rarity of history, indicates the civilization degree of a country, is the witness of human history, is also the common treasured of the whole mankind
Your wealth.But because its some characteristic for mostly being wooden structures makes its anti-flammability poor, the ancient building of China various places, ancient houses are normal
There is fire, these National Treasures once catch fire just never again, deposit fire prevention situation very severe.
Due to lacking effective " active " salvo, therefore major part takes the spray of " passive type ", fire water
The methods such as bolt, i.e. neither one effectively prevent the method that fire occurs, and can only select quickly to be gone out as far as possible after fire occurs
Fire." modern times " fireproofing technique and the measures such as some thermal sensation warnings, to text object belly breaking is protected, and ancient customs difficulty is deposited, " repaiied with ancient building
It is old as usual " theory be even more differ greatly.Therefore a kind of transparent fire retarding wood protection coating is the research heat of domestic and international researcher
Point, but at present most of research all enters that " a kind of good flame retardation effect, coating transparent is poor, easy to crack；It is ornamental good fire-retardant
Property it is poor " endless loop, simultaneously because ancient building timber material, corrosion rate of decay are not quite similar, further increase development ancient
The difficulty of architectural fireproof paint.How to develop a kind of excellent fire protecting performance, coating transparent, weatherability good, timber can be kept again
Old architecture survey coating that is stable, reducing deformation, is still a difficult problem for domestic and international researcher's urgent need to resolve.
The content of the invention
It is an object of the invention to provide a kind of aqueous transparent old architecture survey coating and preparation method thereof, solves existing anti-
Fiery coating is difficult to while be applied on the ancient buildings of unlike material and different corrosion rate of decay, and anti-flaming dope anti-flammability and
Dicoration is difficult to the problem for getting both.
To solve above-mentioned technical problem, the invention provides a kind of aqueous transparent old architecture survey coating, by weight
Including：Amino resins 25-30 parts, polyvinyl alcohol 1-3 parts, ethylene-vinyl acetate copolymer 3-5 parts, polysiloxanes 5-10 parts, resistance
Combustion agent 18.5-34.5 parts, tetramethylolmethane 10-15 parts, phytic acid 1-5 parts, triethanolamine 0.5-1.5 parts, additive 2.1-3.5 parts,
Wood stabilizer 5-10 part and water 10-29 parts.
Used as preferred, the fire retardant presses fireproof coating gross weight ratio including phosphonate ester 5-10 parts, phosphorus nitrogen phosphonate ester 10-
15 parts, phosphoguanidine 3-8 parts and boric acid zirconium 0.5-1.5 parts.
Used as preferred, the additive presses fireproof coating gross weight ratio including thickening advection agent 0.3-0.5 part, ultraviolet
Absorbent 0.3-0.5 parts, UV absorbent 0.3-0.5 part, Ricinate 0.3-0.5 parts, coalescents 0.3-0.5 parts,
Water paint coalescents 0.3-0.5 parts and defoamer 0.3-0.5 parts.
As preferred, include by weight：Amino resins 27-28.7 parts, polyvinyl alcohol 1.8-2.6 parts, ethylene-vinyl
Acetate copolymer 3.7-4.3 parts, polysiloxanes 8-9.3 parts, phosphorus nitrogen phosphonate ester 11.2-12.3 parts, phosphonate ester 6.7-7.8 parts, phosphorus
Sour guanidine 5.2-6.3 parts, tetramethylolmethane 11.8-12.8 parts, boric acid zirconium 0.53-0.6 parts, phytic acid 4.2-4.7 parts, triethanolamine 0.8-
1.2 parts, thickening advection agent 0.39-0.43 part, UV absorbent 0.72-0.84 part, Ricinate SP-7620.33-
0.36 part, coalescents 0.34-0.47 parts, water paint coalescents 0.36-0.48 parts, defoamer 0.32-0.4 parts, timber
Stabilizer 5.3-5.7 parts and water 12-20 parts.
Used as preferred, the amino resins are powdex, purity >=99.0%；The polyvinyl alcohol is powder, pure
Degree >=99.0%, the degree of polymerization is less than 100；The ethylene-vinyl acetate copolymer is water miscible；The purity of the tetramethylolmethane
>=95.0%, fineness is more than 2000 mesh；The boric acid zirconium fineness is more than 2000 mesh；Phytic acid purity >=50%.
Used as preferred, the polysiloxanes, phosphonate ester are respectively provided with reactive terminal-the OH ,-H that can carry out polycondensation reaction
Or-NH3。
The present invention also provides a kind of preparation method of aqueous transparent old architecture survey coating, it is characterised in that include：
Mix for the first time：By water, defoamer A203E, dispersant, phosphorus nitrogen phosphonate ester, phosphonate ester, polysiloxanes, phosphoguanidine,
Tetramethylolmethane, boric acid zirconium, phytic acid, triethanolamine add and are stirred in container, grind and obtain mixture A；
Mix for second：Coalescents PPH, amino resins, polyvinyl alcohol, ethylene-vinyl acetate copolymer are added in A
With defoamer, thickening advection agent, water paint coalescents, UV absorbent and wood stabilizer, stir to mix homogeneously
Afterwards, the old architecture survey coating is obtained final product.
Used as preferred, the first time mixing is after 1500-2000r/min stirring 20-30min, then to grind 2-3h；
Mixing speed is 500-800r/min in mixing for second.
Used as preferred, the aqueous transparent old architecture survey coating for obtaining includes by weight：Amino resins 27-28.7
Part, polyvinyl alcohol 1.8-2.6 parts, ethylene-vinyl acetate copolymer 3.7-4.3 parts, polysiloxanes 8-9.3 parts, phosphorus nitrogen phosphonate ester
11.2-12.3 parts, phosphonate ester 6.7-7.8 parts, phosphoguanidine 5.2-6.3 parts, tetramethylolmethane 11.8-12.8 parts, boric acid zirconium 0.53-
0.6 part, phytic acid 4.2-4.7 parts, triethanolamine 0.8-1.2 parts, thickening advection agent 0.39-0.43 part, UV absorbent 0.72-
0.84 part, Ricinate SP-7620.33-0.36 parts, coalescents 0.34-0.47 parts, water paint coalescents 0.36-
0.48 part, defoamer 0.32-0.4 parts, aqueous wood stabilizer 5.3-5.7 parts and water 12-20 parts.
As preferred, the defoamer of 0.16-0.2 weight portions, second mixing is added to add when the first time mixes
The defoamer of remaining 0.16-0.2 weight portions.
Ethylene-vinyl acetate copolymer and low polymerization degree polyvinyl alcohol soluble in water used in the present invention, can play
Increase the effect of paint film flexibility；Phosphorus nitrogen phosphate ester is the phosphate ester with phosphorus and nitrogen functional group, is used in the present invention
Be phosphorus nitrogen phosphate ester soluble in water, can be expansibility flame-proof agent as fire retardant, phosphoguanidine, boric acid zirconium is used as fire-retardant enhancing
Agent and play suppression cigarette effect.Phosphorus nitrogen phosphate ester, phosphoguanidine, boric acid zirconium triplicity get up to play good fire-retardant effect
Really, triethanolamine plays a part of to adjust acid-base balance, and can be coupled with other components, strengthens paint stability.
Thickening advection agent, Ricinate, coalescents PPH, water paint coalescents in the present invention, defoamer can
To strengthen the film property and mobility of coating, UV absorbent, wood stabilizer etc. equivalent to building applied one layer it is " anti-
Shine frost ", strengthen the protection to heritage buildings, light, the heat stability of building are improved, meanwhile, also improve stablizing for coating itself
Property.
A kind of mixing of the preparation method raw material of the aqueous transparent old architecture survey coating in the present invention is divided into two steps, first
That film forming main component is dissolved in into water, due to solid-liquid mix it is more difficult, therefore stir speed and the time it is all long, it is high in addition
Fast whipping process easily bubbles, it is therefore desirable to add defoamer；Then liquid added again, liquid liquid mixed phase is to being easier to one
A bit, rotating speed is reduced, rapid transit energy consumption.
Boric acid zirconium and tetramethylolmethane fineness in the present invention is all higher than 2000 mesh, can be with stable existence, granularity in coating
The little coating that do not interfere with strengthens the feature of environmental protection of coating into film strength using the tetramethylolmethane of environmental protection.
Compared with prior art, beneficial effects of the present invention are at least one of following：
1) present invention can occur under certain condition polycondensation reaction using polysiloxanes and phosphonate ester, formed after reaction and handed over
The backbone of fork network structure, is effectively coated paint ingredient, while many siloxanes unique in polysiloxanes
Chain, hydrogen bond, ehter bond etc. make it have the good compatibility with amino resins, and the polarity of its various functional group is different also so that not
The fire retardant and tetramethylolmethane of same polarity can preferably disperse so that the old architecture survey coating Combination of the present invention, stable
Property high, fire protecting performance it is good, coating transparent, material original appearance can be kept, and not easy to crack, weatherability is good.
2) bulk composition of fireproof coating of the invention is dry powder, just adds water when needing to use and is prepared, and is effectively prolonged
The pot-life of coating is grown.
3) wood stabilizer MJB-TF soluble in water is added in fireproof coating, effectively the timber of deformation of rotting is carried out
Protection, prevents the further deformation of timber from rotting, ftractureing, and effectively extends ancient building, the protection period of ancient houses.
4) plant extract element phytic acid is added in fireproof coating, can prevents decay of wood from aoxidizing, take from plant, be used for
Plant, health environment-friendly.
Description of the drawings
Fig. 1 illustrates for the small-shape combustibility test of the aqueous transparent old architecture survey coating of the embodiment of the present invention 1 or 2
Figure.
Fig. 2 is the aqueous transparent old architecture survey coating entity fire of conventional acrylic paint and embodiments of the invention 1 or 2
The comparison diagram of calamity simulation test.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to only to explain the present invention
Limit the present invention.
Embodiment 1：
Present embodiments provide a kind of aqueous transparent old architecture survey coating, including amino resins 28.7%, polyvinyl alcohol
2.6%th, ethylene-vinyl acetate copolymer 4.3%, polysiloxanes 9.3%, phosphorus nitrogen phosphonate ester 12.3%, phosphonate ester 7.8%, phosphorus
Sour guanidine 6.3%, tetramethylolmethane 12.8%, boric acid zirconium 0.6%, phytic acid 4.7%, triethanolamine 1.2%, thickening advection agent XS-167
0.43%th, UV absorbent UV1130 0.37%, UV absorbent UV292 0.47%, Ricinate SP-762
0.36%th, coalescents PPH 0.47%, water paint coalescents XS-12 0.48%, defoamer A203E 0.4%, timber
The water of stabilizer MJB-TF5.7% and surplus.
Embodiment 2：
The present embodiment provides a kind of preparation method of aqueous transparent old architecture survey coating described in embodiment 1, specifically includes
The following steps.
(1) each component is weighed by the formula of embodiment 1；
(2) by water, the defoamer A203E for accounting for coating gross weight 0.2%, dispersant, phosphorus nitrogen phosphonate ester, phosphonate ester, poly- silica
Alkane, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid, triethanolamine are sequentially added in agitating device, 1500-2000r/min stirrings
After 20-30min, then it is placed in three-roll grinder grinding 2-3h；
(3) speed of dispersion machine is down to into 500-800r/min, continuously adds coalescents PPH, amino resins, polyethylene
Alcohol, ethylene-vinyl acetate copolymer and account for the defoamer A203E of coating gross weight 0.2%, thickening advection agent XS-167, aqueouss and apply
Material coalescents XS-12, UV absorbent UV1130 and UV absorbent UV292, wood stabilizer MJB-TF, mixing is equal
After even, the old architecture survey coating is obtained final product.
Ancient building transparent fire-resisting paint obtained by the present embodiment is carried out into sample preparation and performance test, it is specific as follows：
(1) small-shape combustibility test
Test substrate selects the old plank of ancient building, and its size is 200mm × 100mm × (10 ± 0.2) mm.Before brushing model
Old plank spot, oil stain are cleaned up with clear water, is dried to moisture content below 20%.Applied with the old architecture survey of the present embodiment
Material is brushed in three times to model, and wet coating amount is 500g/ ㎡.Test plate (panel) coating fireproof coating after should in temperature (23 ± 2) DEG C,
Dry under conditions of relative humidity (50 ± 5) % to constant mass, that is, be separated by the mass change weighed twice before and after 24h and be not more than
0.5%, old plank does not affect outward appearance appearance after brushing fireproof coating.The combustion good sample of status adjustment being placed on shown in Fig. 1
Tested in burning rack, the temperature for testing Flame is 900 to 1100 degrees Celsius, and fireproof coating expands rapidly after on-test
Foaming, forms cellular fine and close layer of charcoal, layer of charcoal expansion ratio between 50-100 times, the effectively propagation of obstruct flame and heat, 3
Base material is not compromised in minute.
(2) made old architecture survey coating is carried out entirely in Sichuan Fire Research Station by standard GB/T/T12441-2005
Performance detection, testing result is as shown in the table.
National Fire building materials quality Supervision Test Center assay summary sheet
Report number：201670071
As can be seen from the above table, the indices of the fireproof coating that the present embodiment is obtained are superior to, are even far superior to
National standard, fire protecting performance is good.
(3) entity fire smoldering test is carried out to made old architecture survey coating.The comparison diagram of this experiment as shown in Fig. 2
First we build ground 4*4m, two miniature log cabins of the high 4m of eaves, left side log cabin plank top layer according to GB 50005-2012
Old architecture survey coating prepared by brushing the present embodiment, coating weight be 500g/ ㎡, right side log cabin conventional acrylic paint into
Row is brushed, and coating weight is 500g/ ㎡.Build be completed after, to two ridge roll rooms be simulated fire test, i.e., two ridge roll rooms it
Between 1.5m passage in, spread appropriate amount wood shavings, two ridge roll rooms are ignited.Without fireproof coating after burning 20min
The log cabin of protection is surrounded by raging flames, has the log cabin for applying fireproof coating also not ignite.After burning 60min, scribble anti-
The log cabin of fiery coating protection is substantially lossless, without the basic after-flame of log cabin that fireproof coating is protected.After off-test, scribble fire prevention and apply
The log cabin only board surface of material protection has slight carbonization, can repair after brushing fireproof coating as new.
(4) it is ancient in Guizhou Southeast Guizhou Miao-Dong Autonomous Prefecture Shibing County Niu great Chang towns to prepared old architecture survey coating
The village Gu people carry out scene protection test, and old architecture survey coating application of the present invention is easy, and timber structure ancient houses brushing ancient architecture
After building fireproof coating, the antique of ancient houses is not only maintained, reaches ancient building, the effect of ancient houses " restoring the old as the old ",
And the fire protection flame retarding of ancient houses is realized, therefore the achievement in research of the present invention asks the fire prevention for solving timber structure ancient houses conscientiously
Topic, benefits popularization and application.
Embodiment 3：
Present embodiments provide a kind of aqueous transparent old architecture survey coating, including amino resins 26.7%, polyvinyl alcohol
2.6%th, ethylene-vinyl acetate copolymer 4.3%, polysiloxanes 7.3%, phosphorus nitrogen phosphonate ester 14.3%, phosphonate ester 8.8%, phosphorus
Sour guanidine 6.3%, tetramethylolmethane 12.8%, boric acid zirconium 0.6%, phytic acid 4.7%, triethanolamine 1.2%, thickening advection agent XS-167
0.43%th, UV absorbent UV1130 0.37%, UV absorbent UV292 0.47%, Ricinate SP-762
0.36%th, coalescents PPH 0.47%, water paint coalescents XS-12 0.48%, defoamer A203E 0.4%, timber
The water of stabilizer MJB-TF5.7% and surplus.
Embodiment 4：
The present embodiment provides a kind of preparation method of aqueous transparent old architecture survey coating described in embodiment 3, specifically includes
The following steps.
(1) each component is weighed by the formula of embodiment 3；
(2) by water, the defoamer A203E for accounting for coating gross weight 0.2%, dispersant, phosphorus nitrogen phosphonate ester, phosphonate ester, poly- silica
Alkane, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid, triethanolamine are sequentially added in agitating device, 1500-2000r/min stirrings
After 20-30min, then it is placed in three-roll grinder grinding 2-3h；
(3) speed of dispersion machine is down to into 500-800r/min, continuously adds coalescents PPH, amino resins, polyethylene
Alcohol, ethylene-vinyl acetate copolymer and the remaining defoamer A203E for accounting for coating gross weight 0.2%, thickening advection agent XS-167,
Water paint coalescents XS-12, UV absorbent UV1130 and UV absorbent UV292, wood stabilizer MJB-TF,
After mix homogeneously, the old architecture survey coating is obtained final product.
Embodiment 5：
Present embodiments provide a kind of aqueous transparent old architecture survey coating, including amino resins 27.7%, polyvinyl alcohol
1.6%th, ethylene-vinyl acetate copolymer 3.3%, polysiloxanes 8.3%, phosphorus nitrogen phosphonate ester 13.3%, phosphonate ester 7.8%, phosphorus
Sour guanidine 7.3%, tetramethylolmethane 12.8%, boric acid zirconium 0.6%, phytic acid 4.7%, triethanolamine 1.2%, thickening advection agent XS-167
0.43%th, UV absorbent UV1130 0.37%, UV absorbent UV292 0.47%, Ricinate SP-762
0.36%th, coalescents PPH 0.47%, water paint coalescents XS-12 0.48%, defoamer A203E 0.4%, timber
The water of stabilizer MJB-TF7.7% and surplus.
Embodiment 6：
The present embodiment provides a kind of preparation method of aqueous transparent old architecture survey coating described in embodiment 5, specifically includes
The following steps.
(1) each component is weighed by the formula of embodiment 5；
(2) by water, the defoamer A203E for accounting for coating gross weight 0.2%, dispersant, phosphorus nitrogen phosphonate ester, phosphonate ester, poly- silica
Alkane, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid, triethanolamine are sequentially added in agitating device, 1500-2000r/min stirrings
After 20-30min, then it is placed in three-roll grinder grinding 2-3h；
(3) speed of dispersion machine is down to into 500-800r/min, continuously adds coalescents PPH, amino resins, polyethylene
Alcohol, ethylene-vinyl acetate copolymer and the remaining defoamer A203E for accounting for coating gross weight 0.2%, thickening advection agent XS-167,
Water paint coalescents XS-12, UV absorbent UV1130 and UV absorbent UV292, wood stabilizer MJB-TF,
After mix homogeneously, the old architecture survey coating is obtained final product.
Embodiment 7：
A kind of aqueous transparent old architecture survey coating is present embodiments provided, is included by weight：It is 25 parts of amino resins, poly-
1 part of vinyl alcohol, 3 parts of ethylene-vinyl acetate copolymer, 5 parts of polysiloxanes, 10 parts of phosphorus nitrogen phosphonate ester, 5 parts of phosphonate ester, phosphoguanidine 3
Part, 10 parts of tetramethylolmethane, 0.5 part of boric acid zirconium, 5 parts of phytic acid, 5 parts of triethanolamine, 0.3 part of thickening advection agent XS-167, ultraviolet
0.3 part of absorbent UV1130,0.3 part of UV absorbent UV292,0.3 part of Ricinate SP-762, coalescents PPH
0.3 part, 0.3 part of water paint coalescents XS-12,0.3 part of defoamer A203E, 5 parts of wood stabilizer MJB-TF and water
10 parts.
Embodiment 8：
A kind of aqueous transparent old architecture survey coating is present embodiments provided, is included by weight：It is 30 parts of amino resins, poly-
3 parts of vinyl alcohol, 5 parts of ethylene-vinyl acetate copolymer, 10 parts of polysiloxanes, 15 parts of phosphorus nitrogen phosphonate ester, 10 parts of phosphonate ester, phosphoric acid
8 parts of guanidine, 15 parts of tetramethylolmethane, 1.5 parts of boric acid zirconium, phytic acid 5-10 parts, 10 parts of triethanolamine, thickening advection agent XS-167 0.5
Part, 0.5 part of UV absorbent UV1130,0.5 part of UV absorbent UV292, Ricinate SP-7620.5 parts, into
0.5 part of film auxiliary agent PPH, 0.5 part of water paint coalescents XS-12,0.5 part of defoamer A203E, wood stabilizer MJB-
29 parts of 10 parts of TF and water.
Embodiment 9：
A kind of aqueous transparent old architecture survey coating is present embodiments provided, is included by weight：It is 27 parts of amino resins, poly-
1.8 parts of vinyl alcohol, 3.7 parts of ethylene-vinyl acetate copolymer, 8 parts of polysiloxanes, 11.2 parts of phosphorus nitrogen phosphonate ester, phosphonate ester 6.7
Part, 5.2 parts of phosphoguanidine, 11.8 parts of tetramethylolmethane, 0.53 part of boric acid zirconium, 4.2 parts of phytic acid, 0.8 part of triethanolamine, thickening advection agent
0.39 part of XS-167,0.35 part of UV absorbent UV1130,0.37 part of UV absorbent UV292, Ricinate
0.33 part of SP-762,0.34 part of coalescents PPH, 0.36 part of water paint coalescents XS-12, defoamer A203E
12 parts of 0.32 part, 5.3 parts of wood stabilizer MJB-TF and water.
Embodiment 10：
A kind of aqueous transparent old architecture survey coating is present embodiments provided, is included by weight：28.7 parts of amino resins,
2.6 parts of polyvinyl alcohol, 4.3 parts of ethylene-vinyl acetate copolymer, 9.3 parts of polysiloxanes, 12.3 parts of phosphorus nitrogen phosphonate ester, phosphonate ester
7.8 parts, 6.3 parts of phosphoguanidine, 12.8 parts of tetramethylolmethane, 0.6 part of boric acid zirconium, 4.7 parts of phytic acid, 1.2 parts of triethanolamine, thickening advection
0.43 part of agent XS-167,0.37 part of UV absorbent UV1130,0.47 part of UV absorbent UV292, Ricinate
0.36 part of SP-762,0.47 part of coalescents PPH, 0.48 part of water paint coalescents XS-12, defoamer A203E 0.4
20 parts of part, 5.7 parts of wood stabilizer MJB-TF and water.
The fireproof coating that 1,3,5,7,8,9 and 10 7 embodiments of comparative example are obtained carries out entity fire disaster simulation examination
Test, the coating flameproof effect that embodiment 1,10 is obtained is best.
Embodiment 11：
A kind of preparation method of old architecture survey coating is present embodiments provided, including：
Raw material is weighed, 28.7 parts of amino resins, 2.6 parts of polyvinyl alcohol, 4.3 parts of ethylene-vinyl acetate copolymer, poly- are weighed
9.3 parts of siloxanes, 12.3 parts of phosphorus nitrogen phosphonate ester, 7.8 parts of phosphonate ester, 6.3 parts of phosphoguanidine, 12.8 parts of tetramethylolmethane, boric acid zirconium 0.6
Part, 4.7 parts of phytic acid, 1.2 parts of triethanolamine, 0.43 part of thickening advection agent XS-167, UV absorbent UV11300.37 part,
0.47 part of UV absorbent UV292,0.36 part of Ricinate SP-762,0.47 part of coalescents PPH, water paint
12 parts of 0.48 part of coalescents XS-12,0.4 part of defoamer A203E, wood stabilizer MJB-TF5.7 part and water；
Mix for the first time：By 0.2 part of defoamer A203E, be added to the water again by the dispersant for weighing, phosphorus nitrogen phosphonate ester,
Phosphonate ester, polysiloxanes, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid and triethanolamine are sequentially added in container in 2000r/
After min stirring 30min, then grind 3h and obtain mixture A；
Mix for second：Coalescents PPH, amino resins, polyvinyl alcohol, ethylene-vinyl acetate copolymer are added in A
With remaining defoamer A203E, thickening advection agent XS-167, water paint coalescents XS-12, UV absorbent UV1130
With UV absorbent UV292, wood stabilizer MJB-TF, stir to mix homogeneously under the conditions of 500r/min, obtain final product institute
State old architecture survey coating.
Embodiment 12：
A kind of preparation method of old architecture survey coating is present embodiments provided, including：
Raw material is weighed, 28.7 parts of amino resins, 2.6 parts of polyvinyl alcohol, 4.3 parts of ethylene-vinyl acetate copolymer, poly- are weighed
9.3 parts of siloxanes, 12.3 parts of phosphorus nitrogen phosphonate ester, 7.8 parts of phosphonate ester, 6.3 parts of phosphoguanidine, 12.8 parts of tetramethylolmethane, boric acid zirconium 0.6
Part, 4.7 parts of phytic acid, 1.2 parts of triethanolamine, 0.43 part of thickening advection agent XS-167, UV absorbent UV11300.37 part,
0.47 part of UV absorbent UV292,0.36 part of Ricinate SP-762,0.47 part of coalescents PPH, water paint
12 parts of 0.48 part of coalescents XS-12,0.4 part of defoamer A203E, wood stabilizer MJB-TF5.7 part and water；
Mix for the first time：By 0.2 part of defoamer A203E, be added to the water again by the dispersant for weighing, phosphorus nitrogen phosphonate ester,
Phosphonate ester, polysiloxanes, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid and triethanolamine are sequentially added in container in 1500r/
After min stirring 20min, then grind 2h and obtain mixture A；
Mix for second：Coalescents PPH, amino resins, polyvinyl alcohol, ethylene-vinyl acetate copolymer are added in A
With remaining defoamer A203E, thickening advection agent XS-167, water paint coalescents XS-12, UV absorbent UV1130
With UV absorbent UV292, wood stabilizer MJB-TF, stir to mix homogeneously under the conditions of 800r/min, obtain final product institute
State old architecture survey coating.
Embodiment 13：
A kind of preparation method of old architecture survey coating is present embodiments provided, including：
Raw material is weighed, 28.7 parts of amino resins, 2.6 parts of polyvinyl alcohol, 4.3 parts of ethylene-vinyl acetate copolymer, poly- are weighed
9.3 parts of siloxanes, 12.3 parts of phosphorus nitrogen phosphonate ester, 7.8 parts of phosphonate ester, 6.3 parts of phosphoguanidine, 12.8 parts of tetramethylolmethane, boric acid zirconium 0.6
Part, 4.7 parts of phytic acid, 1.2 parts of triethanolamine, 0.43 part of thickening advection agent XS-167, UV absorbent UV11300.37 part,
0.47 part of UV absorbent UV292,0.36 part of Ricinate SP-762,0.47 part of coalescents PPH, water paint
12 parts of 0.48 part of coalescents XS-12,0.4 part of defoamer A203E, wood stabilizer MJB-TF5.7 part and water；
Mix for the first time：By 0.2 part of defoamer A203E, be added to the water again by the dispersant for weighing, phosphorus nitrogen phosphonate ester,
Phosphonate ester, polysiloxanes, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid and triethanolamine are sequentially added in container in 1800r/
After min stirring 25min, then grind 2.5h and obtain mixture A；
Mix for second：Coalescents PPH, amino resins, polyvinyl alcohol, ethylene-vinyl acetate copolymer are added in A
With remaining defoamer A203E, thickening advection agent XS-167, water paint coalescents XS-12, UV absorbent UV1130
With UV absorbent UV292, wood stabilizer MJB-TF, stir to mix homogeneously under the conditions of 600r/min, obtain final product institute
State old architecture survey coating.
11,12 and 13 3 embodiments of embodiment utilize identical raw material, optimize technique prepared by fireproof coating of the present invention,
The fireproof coating for obtaining carries out entity fire smoldering test, and coating fire protecting performance prepared by the method for embodiment 12 is better than embodiment 11
With embodiment 13, but difference is little.But when the fire protecting performance for continuing to reduce or raise mixing speed coating can be greatly reduced,
And extend mixing time and do not have too much influence to the performance for improving coating, it is contemplated that to reducing energy consumption, improving plus work efficiency
Rate, have selected and first stir 20-30min in 1500-2000r/min, grind 2-3h；Then stirred to mixed with 500-800r/min again
Close uniform.When some compositions aggregate into larger particles and can affect the performance of coating in mixture, so grind after mixing for the first time,
Then second mixing is carried out again.
Embodiment 14：
A kind of preparation method of old architecture survey coating is present embodiments provided, including：
Raw material is weighed, 27 parts of amino resins, 1.8 parts of polyvinyl alcohol, 3.7 parts of ethylene-vinyl acetate copolymer, poly- silicon is weighed
8 parts of oxygen alkane, 11.2 parts of phosphorus nitrogen phosphonate ester, 6.7 parts of phosphonate ester, 5.2 parts of phosphoguanidine, 11.8 parts of tetramethylolmethane, 0.53 part of boric acid zirconium,
It is 4.2 parts of phytic acid, 0.8 part of triethanolamine, 0.39 part of thickening advection agent XS-167, UV absorbent UV11300.35 part, ultraviolet
0.37 part of light absorbers UV292,0.33 part of Ricinate SP-762,0.34 part of coalescents PPH, water paint film forming
12 parts of 0.36 part of auxiliary agent XS-12,0.32 part of defoamer A203E, 5.3 parts of wood stabilizer MJB-TF and water；
Mix for the first time：By 0.16 part of defoamer A203E, be added to the water again by the dispersant for weighing, phosphorus nitrogen phosphonate ester,
Phosphonate ester, polysiloxanes, phosphoguanidine, tetramethylolmethane, boric acid zirconium, phytic acid and triethanolamine are sequentially added in container in 1800r/
After min stirring 25min, then grind 2.5h and obtain mixture A；
Mix for second：Coalescents PPH, amino resins, polyvinyl alcohol, ethylene-vinyl acetate copolymer are added in A
With remaining 0.16 part of defoamer A203E, thickening advection agent XS-167, water paint coalescents XS-12, UV absorbent
UV1130 and UV absorbent UV292, wood stabilizer MJB-TF, stir to mix homogeneously under the conditions of 600r/min,
Obtain final product the old architecture survey coating.
Thickening advection agent, UV absorbent, Ricinate, coalescents used in embodiments of the invention,
Water paint coalescents, defoamer, wood stabilizer are respectively：Thickening advection agent XS-167, UV absorbent UV1130,
UV absorbent UV292, Ricinate SP-762, coalescents PPH, water paint coalescents XS-12, defoamer
A203E, wood stabilizer MJB-TF, but the preparation of the aqueous transparent old architecture survey coating of high-quality is not limited in embodiment
The model for using, those skilled in the art can select the raw material of other models to prepare fireproof coating according to Professional knowledge, this
Should be in the scope of protection of the invention.
Although reference be made herein to invention has been described for multiple explanatory embodiments of the invention, however, it is to be understood that
Those skilled in the art can be designed that a lot of other modification and embodiment, and these modifications and embodiment will fall in this Shen
Please be within disclosed spirit and spirit.More specifically, in the range of disclosure and claim, can be to master
The building block and/or layout of topic composite configuration carries out various modifications and improvement.Except what is carried out to building block and/or layout
Deformation and improvement are outer, and to those skilled in the art, other purposes also will be apparent.
Claims (10)
1. a kind of aqueous transparent old architecture survey coating, it is characterised in that include by weight：Amino resins 25-30 parts, poly- second
Enol 1-3 parts, ethylene-vinyl acetate copolymer 3-5 parts, polysiloxanes 5-10 parts, fire retardant 18.5-34.5 parts, tetramethylolmethane
10-15 parts, phytic acid 1-5 parts, triethanolamine 0.5-1.5 parts, additive 2.1-3.5 parts, wood stabilizer MJB-TF 5-10 parts and
Water 10-29 parts.
2. a kind of aqueous transparent old architecture survey coating according to claim 1, it is characterised in that the fire retardant is by anti-
Fiery coating gross weight ratio includes phosphonate ester 5-10 parts, phosphorus nitrogen phosphonate ester 10-15 parts, phosphoguanidine 3-8 parts and boric acid zirconium 0.5-1.5
Part.
3. a kind of aqueous transparent old architecture survey coating according to claim 1, it is characterised in that the additive is by anti-
Fiery coating gross weight ratio includes thickening advection agent 0.3-0.5 part, UV absorbent 0.6-1 part, Ricinate 0.3-0.5
Part, coalescents 0.3-0.5 parts, water paint coalescents 0.3-0.5 parts and defoamer 0.3-0.5 parts.
4. a kind of aqueous transparent old architecture survey coating according to claim 1, it is characterised in that include by weight：
Amino resins 27-28.7 parts, polyvinyl alcohol 1.8-2.6 parts, ethylene-vinyl acetate copolymer 3.7-4.3 parts, polysiloxanes 8-
9.3 parts, phosphorus nitrogen phosphonate ester 11.2-12.3 parts, phosphonate ester 6.7-7.8 parts, phosphoguanidine 5.2-6.3 parts, tetramethylolmethane 11.8-12.8
Part, boric acid zirconium 0.53-0.6 parts, phytic acid 4.2-4.7 parts, triethanolamine 0.8-1.2 parts, thickening advection agent 0.39-0.43 part, purple
Ultraviolet absorbers 0.72-0.84 parts, Ricinate SP-762 0.33-0.36 parts, coalescents 0.34-0.47 parts, aqueouss are applied
Material coalescents 0.36-0.48 parts, defoamer 0.32-0.4 parts,
Aqueous wood stabilizer 5.3-5.7 parts and water 12-20 parts.
5. a kind of aqueous transparent old architecture survey coating according to Claims 1-4 any one, it is characterised in that institute
Amino resins are stated for powdex, purity >=99.0%；The polyvinyl alcohol is powder, and purity >=99.0%, the degree of polymerization is less than
100；The ethylene-vinyl acetate copolymer is water miscible；Purity >=95.0% of the tetramethylolmethane, fineness is more than 2000
Mesh；The boric acid zirconium fineness is more than 2000 mesh；Phytic acid purity >=50%.
6. a kind of aqueous transparent old architecture survey coating according to Claims 1-4 any one, it is characterised in that institute
State polysiloxanes, phosphonate ester and be respectively provided with reactive terminal-the OH ,-H or-NH that can carry out polycondensation reaction3。
7. a kind of preparation method of aqueous transparent old architecture survey coating, it is characterised in that include：
Mix for the first time：By deionized water, defoamer, dispersant, phosphorus nitrogen phosphonate ester, phosphonate ester, polysiloxanes, phosphoguanidine, season
Penta tetrol, boric acid zirconium, phytic acid, triethanolamine add and are stirred in container, grind and obtain mixture A；
Mix for second：Coalescents PPH, amino resins, polyvinyl alcohol, ethylene-vinyl acetate copolymer are added in A and is disappeared
Infusion, thickening advection agent, water paint coalescents, wood stabilizer and UV absorbent, stir to mix homogeneously, i.e.,
Obtain the old architecture survey coating.
8. the preparation method of a kind of aqueous transparent old architecture survey coating according to claim 7, it is characterised in that described
For the first time mixing is after 1500-2000r/min stirring 20-30min, then to grind 2-3h；Mixing speed is in mixing for second
500-800r/min。
9. the preparation method of a kind of aqueous transparent old architecture survey coating according to claim 7, it is characterised in that obtain
Aqueous transparent old architecture survey coating include by weight：Amino resins 27-28.7 parts, polyvinyl alcohol 1.8-2.6 parts, second
Alkene-ethylene vinyl acetate copolymer 3.7-4.3 parts, polysiloxanes 8-9.3 parts, phosphorus nitrogen phosphonate ester 11.2-12.3 parts, phosphonate ester 6.7-
7.8 parts, phosphoguanidine 5.2-6.3 parts, tetramethylolmethane 11.8-12.8 parts, boric acid zirconium 0.53-0.6 parts,
Phytic acid 4.2-4.7 parts, triethanolamine 0.8-1.2 parts, thickening advection agent 0.39-0.43 part, UV absorbent 0.72-
0.84 part, Ricinate SP-762 0.33-0.36 parts, coalescents 0.34-0.47 parts, water paint coalescents 0.36-
0.48 part, defoamer 0.32-0.4 parts, aqueous wood stabilizer 5.3-5.7 parts and water 12-20 parts.
10. a kind of preparation method of aqueous transparent old architecture survey coating according to claim 9, it is characterised in that institute
The defoamer of 0.16-0.2 weight portions, second mixing is added to add disappearing for remaining 0.16-0.2 weight portions when stating mixing for the first time
Infusion.
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104650676A (en) * | 2013-11-22 | 2015-05-27 | 高天红 | High-efficient aqueous expansion fireproof coating and preparation method thereof |
-
2016
- 2016-10-12 CN CN201610889080.XA patent/CN106634394B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104650676A (en) * | 2013-11-22 | 2015-05-27 | 高天红 | High-efficient aqueous expansion fireproof coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王国建: "《防火涂料科学与技术》", 31 December 2007 * |
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Address after: 610000 Jinke South Road, Jinniu District, Chengdu, Sichuan 69 Co-patentee after: Fujian Zhangping Zhong Zhi fire prevention and Technology Co., Ltd. Patentee after: Sichuan Fire Fighting Inst., Ministry of Public Safety Address before: 610000 Jinke South Road, Jinniu District, Chengdu, Sichuan 69 Co-patentee before: Xiamen universal Chemical Technology Co., Ltd. Patentee before: Sichuan Fire Fighting Inst., Ministry of Public Safety |