CN108102493A - A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof - Google Patents
A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof Download PDFInfo
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- CN108102493A CN108102493A CN201711446223.0A CN201711446223A CN108102493A CN 108102493 A CN108102493 A CN 108102493A CN 201711446223 A CN201711446223 A CN 201711446223A CN 108102493 A CN108102493 A CN 108102493A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of safe environment protection type heat conduction emulsion paints and preparation method thereof, it is related to technical field of coatings, compared with emulsion paint of the prior art, invention increases the heat conductivilitys of film, there is good bacteria resistance energy and Anti-mildew capability simultaneously, its key points of the technical solution are that：A kind of safe environment protection type heat conduction emulsion paint, according to the mass fraction, including following components：420 430 parts of lotion, 25 30 parts of coalescents, 10 15 parts of multifunction amine auxiliary agent, 25 parts of wetting agent, 25 parts of antifoaming agent, 12 16 parts of dispersant, 8 12 parts of thickener, 200 220 parts of ceramic, 50 70 parts of silicon carbide powder, 250 270 parts of water, 13 parts of o-phenyl phenol.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of safe environment protection type heat conduction emulsion paint and preparation method thereof.
Background technology
With deepening constantly for environmentally protective concept, in Housing Project construction, energy conservation standard is also continuously improved, Ge Gejian
If unit in charge of construction all introduces and develops many new energy-saving materials and technology, and widelys popularize application in various buildings.
Wherein, emulsion paint is using synthetic resin emulsion as base-material, and filler adds in the breast that various auxiliary agents refine after grinding distribution
Glue coating possesses many merits different from traditional coating, such as is easy to brush, dries that rapid, paint film is water-fast, therefore wide
It is general to be applied on floor.
Floor heating would generally be set in the building of north cold area, the heating agent of floor heating by floor by heat from the bottom to top
It is conducted, and then being dissipated into even heat in room.However the existing usual thermal conductivity factor of emulsion paint is relatively low, ground HVAC
Cross that the heat that floor is transferred in room is generally less, so that the household temperature of people is relatively low.
The content of the invention
First purpose of the present invention is to provide a kind of safe environment protection type heat conduction emulsion paint, has good heat conductivility,
So that floor heating is increased by the heat on floor.
The present invention above-mentioned technical purpose technical scheme is that：
A kind of safe environment protection type heat conduction emulsion paint, according to the mass fraction, including following components：420-430 parts of lotion, coalescents
25-30 parts, 10-15 parts of multifunction amine auxiliary agent, 2-5 parts of wetting agent, 2-5 parts of antifoaming agent, 12-16 parts of dispersant, thickener 8-12
Part, 200-220 parts of ceramic, 50-70 parts of silicon carbide powder, 250-270 parts of water, 1-3 parts of o-phenyl phenol.
Further preferably：The safe environment protection type heat conduction emulsion paint according to the mass fraction, including following components：Lotion
425 parts, 28 parts of coalescents, 12 parts of multifunction amine auxiliary agent, 4 parts of wetting agent, 3 parts of antifoaming agent, 14 parts of dispersant, thickener 10
Part, 210 parts of ceramic, 60 parts of carborundum powder, 260 parts of water, 2 parts of o-phenyl phenol.
Using the above program, carborundum phase has higher thermal conductivity factor for heat fillings such as magnesia, aluminium oxide
(120-180W/m.k) adds the heat conductivility of emulsion paint so that floor heating is increased by the heat on floor；Carborundum particle
The impurity such as hydrophobic free carbon, hydrocarbon are contained on surface, these impurity can be efficiently removed in alkaline conditions, be made
Obtaining the mutual active force of carborundum particle increases, so that carborundum particle is uniformly dispersed, and the pH value of lotion usually exists
Between 7-9, in alkalescent, lotion can be maintained alkalescent state by multifunction amine auxiliary agent, so that carborundum is uniform
It is scattered in emulsion paint, avoids heat conductivility difference of the paint film of emulsion paint formation on different parts excessive；It is in addition, multi-functional
- OH the groups of amine auxiliary agent can also form hydrogen bond, and carborundum particle can attract each other again under the action of hydrogen bond, so as to reduce carbon
Spacing between SiClx particle so that the content of emulsion paint carborundum particle in unit volume increases, and paint film is improved with this
Heat conductivility；O-phenyl phenol can effectively inhibit the growth of bacterium and mould, more work(under the environment of alkalescence
Energy amine auxiliary agent enables o-phenyl phenol persistently to play a role, and then improves the bacteria resistance energy and Anti-mildew capability of paint film.
Further preferably：The lotion is pure-acrylic emulsion or silicone acrylic emulsion.
Using the above program, lotion mainly has phenylpropyl alcohol, pure third and the third three types of silicon, wherein, styrene-acrylic emulsion is by benzene second
Alkene and acrylate monomer are copolymerized through emulsifier, and the impurity such as emulsifier are usually left in the product of styrene-acrylic emulsion, and
It is difficult to eliminate completely, and the presence of emulsifier adds the viscosity of lotion, prevents the relative motion between emulsion particle, in addition, also
Interparticle charge repulsion can be increased, be not easy to the close to each other of particle so that interparticle moisture film contraction slows down, and reduces breast
The rate of film build of liquid, therefore preferably pure-acrylic emulsion and silicone acrylic emulsion.
Further preferably：The coalescents are in diethylene glycol monomethyl ether, diethylene glycol monobutyl ether and propylene glycol
One or more of mixtures.
Using the above program, coalescents provide enough free volumes in emulsion paint film forming procedure, so that polymer
Particle deforms and polymer molecule segment spreads, winds and be fused into continuous film.Wherein, diethylene glycol monomethyl ether, diethyl two
Alcohol monobutyl ether and propylene glycol are the strong solvents of polymer, can adsorb on the surface of emulsion particle after adding in lotion, have with this
Good compatibility so that the surface of paint film is more smooth, smooth.
Further preferably：The multifunction amine auxiliary agent is AMP-95.
Using the above program, when-OH the groups in AMP-95 molecules can effectively be adsorbed in ceramic surface, and making pottery
Porcelain micro mist surface forms NH3 +Charge, and then the equipotential of ceramic is improved, ceramic solution is made to flocculate, increases ceramic
Dispersion effect so that paint film uniform color, surface more flat smooth after the film forming of emulsion paint；In addition, it is waved in AMP-95
The incrementss of hair property organic compound (VOC) are few, reduce the content of harmful substance, have the characteristics that safe and reliable.
Further preferably：The dispersant is polyethylene glycol.
Using the above program, the O-H keys of polyethylene glycol can form hydrogen bond and make to be connected with each other or be connected with other groups, because
This is with good compatibility；Under the conditions of lotion is weakly alkaline, one layer of OH of the adsorption of carborundum particle-With poly- second two
Alcohol strand, and OH-It can further be connected with each other under the action of hydrogen bond again with peg molecule chain, therefore in carbonization silicon grain
Sublist face forms one layer of organic matter shell, prevents carborundum particle from reuniting when doing Brownian movement, promotes carborundum particle equal
Even is scattered in lotion so that the heat conductivility difference of different parts is smaller on paint film.
Further preferably：The thickener is hydroxyethyl cellulose.
Using the above program, hydroxyethyl cellulose has large range of dissolubility and viscosity, can be with other water solubilitys altogether
Polymers preferably coexists, and has preferable flow adjustment, can play a protective role to the colloidal particle in lotion.
Second object of the present invention is to provide a kind of preparation method of safe environment protection type heat conduction emulsion paint, increases emulsion paint
Film-formation result.
The present invention above-mentioned technical purpose technical scheme is that：
A kind of preparation method of safe environment protection type heat conduction emulsion paint, each component is added by above-mentioned quality, including making as follows
Standby step：S1, the water that 100-110 parts are added in into mixer, add in wetting agent, control mixing speed as 550-600r/min,
Stirring is to being completely dissolved；
S2, antifoaming agent, dispersant and multifunction amine auxiliary agent are sequentially added into the mixer of S1, it is 550- to control mixing speed
600r/min is stirred to uniformly mixed；
S3, after being slowly added to ceramic and carborundum powder into the mixer of S2, mixing speed is controlled as 1500-1700r/
Min stirs 30-40min；
S4, by the mixer reduction of speed of S3 to 400-500r/min, sequentially add lotion, coalescents, o-phenyl phenol and surplus
Remaining water is stirred to uniformly mixed；
S5, thickener is slow added into the mixer of S4, controls mixing speed as 400-500r/min, stirring is equal to mixing
It is even to get the emulsion paint.
Using the above program, first wetting agent is dissolved alone in water, to ensure the compatible stability of emulsion paint each component,
Active balance amphiphilic performance so that antifoaming agent, dispersant and multifunction amine auxiliary agent are preferably dispersed in water；Then pottery is added again
Porcelain micro mist and carborundum powder, multifunction amine auxiliary agent promote ceramic and carborundum powder to be dispersed in solution, are eventually adding
Each component, is uniformly mixed by lotion, coalescents and o-phenyl phenol with this so that the paint film that emulsion paint is formed is more smooth
It is fine and smooth.
Further preferably：Ceramic and carborundum powder in S3 are first positioned over ultrasonic activation before mixer is added in
It is sieved in sieve, the powder sieved by ultrasonic activation is weighed by above-mentioned quality.
The situation of caking, ceramics after screening are commonly present when using the above program, in ceramic and carborundum powder
Micro mist and carborundum powder uniform particle sizes, and then make emulsion paint finer and smoother.
In conclusion the invention has the advantages that：
1st, the addition that emulsion paint of the invention passes through carborundum powder and multifunction amine auxiliary agent so that lotion maintains weak basic condition
Under, the impurity of carborundum molecular surface is removed so that carborundum is uniformly scattered in lotion, while adds emulsion paint list
The content of carborundum in the volume of position improves the heat conductivility of emulsion paint with this；
2nd, o-phenyl phenol is added in the environment of latex alkalescent so that emulsion paint has good bacteria resistance energy and anti-mildew
Bacterium performance, multifunction amine auxiliary agent maintain the pH of emulsion paint under weakly alkaline environment so that o-phenyl phenol can continue to play to make
With extending the usage time of film；
3rd, preparation method is simple, easy to operate, is easy to industry extension production, has a good application prospect.
Specific embodiment
Mixer elects the high-speed mixer of the prosperous mechanical model HRS-100 of Dongguan ring as；
Ultrasonic activation screening is sieved for the MT ultrasonic activations of Xinxiang Ming Yang sieving machines；
Wetting agent elects the wetting agent of the model X-405 of Guangzhou perseverance space chemical industry as；
Antifoaming agent elects the antifoaming agent of the W159 series of chemical industry in the dimension of Zhengzhou as, in addition can also be 131 antifoaming agent of Mcbain
Deng other antifoaming agent；
Dispersant is preferably commercially available polyethylene glycol, in addition can also be other dispersants such as sodium pyrophosphate, sodium disilicate；
Multifunction amine auxiliary agent is preferably commercially available AMP-95, in addition can also be other multifunction amine auxiliary agents such as AN130；
Lotion is preferably commercially available pure-acrylic emulsion or silicone acrylic emulsion, and in addition styrene-acrylic emulsion can also be used；
Coalescents are preferably one or more of commercially available diethylene glycol monomethyl ether, diethylene glycol monobutyl ether and propylene glycol
Mixture；O-phenyl phenol is directly purchased for Shanghai sea Qu Huagong；
Thickener is preferably commercially available hydroxyethyl ether cellulose, in addition can also be DR-72 thickeners, UN-450VF thickenings
Agent etc..
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
S1, the water that 105kg is added in into mixer, add in wetting agent 4kg, and mixing speed is controlled to be stirred for 580r/min to complete
Fully dissolved；
S2, the AMP-95 that the antifoaming agent of 3kg, the polyethylene glycol of 14kg and 12kg are sequentially added into the mixer of S1, control are stirred
Speed is mixed as 580r/min, is stirred to uniformly mixed；
S3, ceramic and carborundum powder using ultrasonic activation are sieved respectively, weighs the ceramic after screening
210kg and carborundum powder 60kg is slowly added to ceramic and carborundum powder after sieving weighs, control into the mixer of S2
Mixing speed is 1600r/min, stirs 35min；
S4, by the mixer reduction of speed of S3 to 450r/min, sequentially add the lotion of 425kg, 28kg diethylene glycol monomethyl ether,
The o-phenyl phenol of 2kg and the water of 155kg are stirred to uniformly mixed；
S5, the hydroxyethyl ether cellulose that 10kg is slow added into the mixer of S4 control mixing speed to be stirred for 450r/min
It mixes to uniformly mixed to get emulsion paint finished product.
Embodiment 2- embodiments 5 and comparative example 1
Embodiment 2- embodiments 5 and comparative example 1 are on the method and technology of embodiment 1, to the component and each group of emulsion paint
The quality divided is made adjustment, mass unit kg；
The component of the emulsion paint of embodiment 1- embodiments 5 and comparative example 1 and the quality such as following table of each component：
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 |
| Silicone acrylic emulsion | 425 | 420 | 422 | 428 | 430 | 425 |
| Diethylene glycol monobutyl ether | 28 | 25 | 26 | 29 | 30 | 28 |
| AMP-95 | 12 | 10 | 12 | 14 | 15 | 12 |
| Wetting agent | 4 | 2 | 3 | 5 | 5 | 4 |
| Antifoaming agent | 3 | 2 | 2 | 4 | 5 | 3 |
| Polyethylene glycol | 14 | 12 | 12 | 15 | 16 | 14 |
| Hydroxyethyl cellulose | 10 | 8 | 8 | 11 | 12 | 10 |
| Ceramic | 210 | 200 | 205 | 215 | 220 | 210 |
| Carborundum powder | 60 | 50 | 55 | 65 | 70 | / |
| Water | 260 | 250 | 256 | 265 | 270 | 260 |
| O-phenyl phenol | 2 | 1 | 2 | 3 | 3 | / |
Using emulsion paint made from above-described embodiment 1 to embodiment 5 as experimental subjects, following performance detection experiment is carried out：
1st, pH value：Commercially available pH meter is selected to be measured；
2nd, drying time：It is carried out by the regulation of second method in GB/T 1728-1979；
3rd, heat conductivility：It is carried out by the regulation of GB/T 14907-94；
4th, bacteria resistance energy：It is carried out by the regulation of GB/T 21866-2008；
5th, Anti-mildew capability：It is carried out by the regulation of GB/T 1741-2007；
Testing result such as following table：
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Standard |
| PH value | 8.75 | 8.72 | 8.69 | 8.82 | 8.66 | 8.68 | 8-9 |
| Drying time (h) | 1.0 | 1.7 | 1.4 | 1.3 | 1.6 | 1.2 | ≤2 |
| Thermal conductivity factor (W/m.k) | 19.7 | 15.3 | 17.9 | 19.6 | 19.7 | 0.18 | ≥0.15 |
| Bacteria resistance energy (%) | 99.98 | 99.27 | 99.79 | 99.63 | 99.89 | 0.53 | ≥99 |
| Anti-mildew capability (grade) | 0 | 1 | 1 | 0 | 0 | 5 | 0-5 |
As seen from the above table, the emulsion paint prepared by embodiment 1 to embodiment 5 meets examination criteria.
Comparative example 1 and embodiment 1- embodiments 5 are compared, it can be deduced that：The addition of carborundum powder can be carried effectively
The heat conductivility of high emulsion paint in addition, the addition of o-phenyl phenol can effectively inhibit bacteria the growth with mould, improves film
Bacteria resistance energy and Anti-mildew capability；
Embodiment 1- embodiments 5 are compared, it can be deduced that：With the increase of carborundum powder quality, the heat conduction system of emulsion paint
Number is in the situation for first rising and tending to be steady afterwards；With the increase of the quality of o-phenyl phenol, the anti-microbial property and anti-mildew of emulsion paint
Performance is equally in the situation for first rising and tending to be steady afterwards.Wherein, the emulsion paint prepared by embodiment 1 is compared with other four implementations
The emulsion paint of example, drying time is shorter, has better thermal conductivity, anti-microbial property and Anti-mildew capability, therefore is preferably real
Apply example 1 as the presently preferred embodiments.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, people in the art
Member can as needed make the present embodiment the modification of no creative contribution after this specification is read, but as long as at this
It is all protected in the protection domain of invention be subject to Patent Law.
Claims (9)
1. a kind of safe environment protection type heat conduction emulsion paint, according to the mass fraction, including following components：420-430 parts of lotion, film forming help
25-30 parts of agent, 10-15 parts of multifunction amine auxiliary agent, 2-5 parts of wetting agent, 2-5 parts of antifoaming agent, 12-16 parts of dispersant, thickener 8-
12 parts, 200-220 parts of ceramic, 50-70 parts of silicon carbide powder, 250-270 parts of water, 1-3 parts of o-phenyl phenol.
2. a kind of safe environment protection type heat conduction emulsion paint according to claim 1, it is characterised in that：The safe environment protection type is led
Hot emulsion paint according to the mass fraction, including following components：425 parts of lotion, 28 parts of coalescents, 12 parts of multifunction amine auxiliary agent, profit
4 parts of humectant, 3 parts of antifoaming agent, 14 parts of dispersant, 10 parts of thickener, 210 parts of ceramic, 60 parts of carborundum powder, 260 parts of water, neighbour
2 parts of phenylphenol.
3. a kind of safe environment protection type heat conduction emulsion paint according to claim 1 or 2, it is characterised in that：The lotion is pure
Acrylic emulsion or silicone acrylic emulsion.
4. a kind of safe environment protection type heat conduction emulsion paint according to claim 1 or 2, it is characterised in that：The coalescents
For the mixture of one or more of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether and propylene glycol.
5. a kind of safe environment protection type heat conduction emulsion paint according to claim 1 or 2, it is characterised in that：The multifunction amine
Auxiliary agent is AMP-95.
6. a kind of safe environment protection type heat conduction emulsion paint according to claim 1 or 2, it is characterised in that：The dispersant is
Polyethylene glycol.
7. a kind of safe environment protection type heat conduction emulsion paint according to claim 1 or 2, it is characterised in that：The thickener is
Hydroxyethyl cellulose.
8. a kind of preparation of safe environment protection type heat conduction emulsion paint according to any one claim in claim 1 to 7
Method, each component are added by above-mentioned quality, including following preparation process：
S1, the water that 100-110 parts are added in into mixer, add in wetting agent, control mixing speed as 550-600r/min, stirring
To being completely dissolved；
S2, antifoaming agent, dispersant and multifunction amine auxiliary agent are sequentially added into the mixer of S1, it is 550- to control mixing speed
600r/min is stirred to uniformly mixed；
S3, after being slowly added to ceramic and carborundum powder into the mixer of S2, mixing speed is controlled as 1500-1700r/
Min stirs 30-40min；
S4, by the mixer reduction of speed of S3 to 400-500r/min, sequentially add lotion, coalescents, o-phenyl phenol and surplus
Remaining water is stirred to uniformly mixed；
S5, thickener is slow added into the mixer of S4, controls mixing speed as 400-500r/min, stirring is equal to mixing
It is even to get the emulsion paint.
9. a kind of preparation method of safe environment protection type heat conduction emulsion paint according to claim 8, it is characterised in that：In S3
Ceramic and carborundum powder are sieved in ultrasonic activation sieve is first positioned over before adding in mixer, are weighed by above-mentioned quality
The powder sieved by ultrasonic activation.
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| CN201711446223.0A CN108102493A (en) | 2017-12-27 | 2017-12-27 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
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| CN201711446223.0A CN108102493A (en) | 2017-12-27 | 2017-12-27 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113061374A (en) * | 2020-01-02 | 2021-07-02 | 苏州皇冠涂料科技发展有限公司 | Nano ceramic material modified emulsion paint and preparation method thereof |
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| CN101230216A (en) * | 2007-12-29 | 2008-07-30 | 天津市职业大学 | Method for preparing antibiotic coating of computer keyboard |
| CN106867323A (en) * | 2017-01-22 | 2017-06-20 | 铂恩塞尔新材料（上海）股份有限公司 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
-
2017
- 2017-12-27 CN CN201711446223.0A patent/CN108102493A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230216A (en) * | 2007-12-29 | 2008-07-30 | 天津市职业大学 | Method for preparing antibiotic coating of computer keyboard |
| CN106867323A (en) * | 2017-01-22 | 2017-06-20 | 铂恩塞尔新材料（上海）股份有限公司 | A kind of safe environment protection type heat conduction emulsion paint and preparation method thereof |
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| 周文英等: "《导热高分子材料》", 30 April 2014, 国防工业出版社 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113061374A (en) * | 2020-01-02 | 2021-07-02 | 苏州皇冠涂料科技发展有限公司 | Nano ceramic material modified emulsion paint and preparation method thereof |
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Application publication date: 20180601 |