CN109321045A - A kind of water paint and preparation method thereof made of conch meal - Google Patents

A kind of water paint and preparation method thereof made of conch meal Download PDF

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Publication number
CN109321045A
CN109321045A CN201811074037.3A CN201811074037A CN109321045A CN 109321045 A CN109321045 A CN 109321045A CN 201811074037 A CN201811074037 A CN 201811074037A CN 109321045 A CN109321045 A CN 109321045A
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China
Prior art keywords
conch meal
water paint
water
preparation
agent
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Pending
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CN201811074037.3A
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Chinese (zh)
Inventor
高卓彤
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Individual
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Individual
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Priority to CN201811074037.3A priority Critical patent/CN109321045A/en
Publication of CN109321045A publication Critical patent/CN109321045A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Abstract

The water paint and preparation method thereof that the present invention relates to a kind of to make of conch meal is added diatomite, calcium powder, kaolin and other auxiliary agents etc. and is mixed to form the water paint made of conch meal using conch meal as primary raw material.The invention has the benefit that the water paint produced by the present invention made of conch meal, has effects that good permeability, mould proof, decomposition and absorption noxious material, adjusting air humidity;More environmentally-friendly, all raw materials used do not contain lipid or benzene ring substance, and finished product is non-toxic and tasteless;Wearability is higher, has flame retarding function;Application property is good, and construction method is flexible, sprayable also to can be applied.

Description

A kind of water paint and preparation method thereof made of conch meal
Technical field
The invention belongs to Paint preparation technologies, and in particular to a kind of water paint and its preparation side with conch meal production Method.
Background technique
It is all with water as solvent or to make the coating of decentralized medium, it all can be described as water paint.Water paint is divided into two Major class: the natural water paint and artificial synthetic resin's water paint of natural materials or minerals.The water of artificial synthetic resin's class Property coating includes water soluble paint, water-reducible coating and water-dispersible paint.Water soluble paint be with water-soluble resin be at Film object, using polyvinyl alcohol and its various modifiers as representative, in addition to this there are also water-soluble alkyd resin, water-soluble epoxy resin and nothings Machine polymer waterborne resin etc..
Water paint or emulsion paint currently on the market is most of all airtight, and wall can be made by spraying or be applied to metope surface Face is gone mouldy, and bacterium is bred;Although harmful substance contents are in national standard hereinafter, but wherein still having the objects of a large amount of harmful human bodies Matter;But also there are the service life of product is short, it is prone to wear, not environmentally etc. problems.
Summary of the invention
In order to solve the above problems existing in the present technology, the present invention provides a kind of water paints made of conch meal And preparation method thereof.The manufactured water paint made of conch meal is ventilative, fire-retardant, environmentally friendly, and application property is good.
The technical scheme adopted by the invention is as follows: a kind of water paint made of conch meal, prepared by following raw material and At the raw material includes: diatomite 5%-10% by weight percentage;Conch meal 40%-55%;Calcium powder 5%-8%;Kaolin 3%-8%;Defoaming agent 0.5%-1%;Thickener 1%-1.5%;Lotion 10%-15%;Conditioning agent 1%-1.5%;Levelling agent 1.5%-2% and deionized water 32%-38%.
Further, the calcium powder is nanometer calcium powder.
Further, the raw material further includes dispersing agent and multifunctional assistant, and the thickener includes the thickening of alkali swelling type Agent.The additive amount of dispersing agent is 1-1.5%, and the additive amount of multifunctional assistant is 1-5%.
Further, the lotion is styrene-acrylic emulsion.Styrene-acrylic emulsion in the present invention is as carrier, and buying is from German bar Si Fu company, model ECO-502, tasteless, alkaline-resisting, elasticity is good.
A kind of water paint preparation method made of conch meal, comprising the following steps:
(1) first diatomite, conch meal, calcium powder and kaolin are uniformly mixed, pour into the 30% of deionized water total amount, mixed Uniformly, it is formed to mixed radix material;
(2) obtained to step (1) to which defoaming agent, thickener, conditioning agent and levelling agent are added in mixed radix material, and remove Other raw materials outside ionized water stir 15-25 minutes, remaining deionized water are then added, and are uniformly mixed, and form mixture;
(3) mixture that step (2) obtains is ground and is filtered, be again stirring for being uniformly mixed to get with shell The water paint of powder production.
Further, it in step (1) and step (2), is all made of high speed disperser and is stirred or mixes.
Further, it in step (1), after pouring into deionized water, first stirs at low speed 10 minutes, then high-speed stirred 10 minutes.
Further, in step (2), to which defoaming agent, thickener, conditioning agent and levelling agent are added in mixed radix material, and Other raw materials in addition to deionized water first stir at low speed 8-12 minutes, then high-speed stirred 8-12 minutes;Then remaining go is added Ionized water, then high-speed stirred 38-42 minutes is to being uniformly mixed.Further, the speed stirred at low speed be 500-800 turn/ Minute;The speed of the high-speed stirred is 1000-1500 revs/min.
Further, in step (3), it is 200-800nm that mixture, which is ground to partial size,.
It is added during raw material, solid powder will be bit by bit slowly added, and added a part stirring for a moment, waited and dissolve into it It is afterwards again plus a part of, because all pouring into the short time more difficult can be uniformly mixed.
The invention has the benefit that in preparation process of the present invention reasonable arrangement raw material addition sequence, and according to addition Raw material difference, and, can be good at merging each constituent, and do not need high energy and disappear using different mixing speed Consumption, uniformly and conveniently.
The water paint produced by the present invention made of conch meal has good permeability, mould proof, decomposition and absorption Toxic The effect of matter, adjusting air humidity.Mainly using conch meal as raw material, due to the lumen pore structure in conch meal, so that finished product With good permeability and mould proof effect;The chitin contained in conch meal also makes finished product have effects that decomposing formaldehyde.
Conch meal specific gravity is higher, and the specific gravity such as diatomite, calcium powder, kaolin difference and the original small compared with conch meal specific gravity is added Defoaming agent, thickener, conditioning agent and levelling agent etc. is added so that being uniformly dispersed after material mixing in material, can make finished product regardless of Layer, mixing more evenly, have good physical property.
The water paint produced by the present invention made of conch meal is more environmentally-friendly, and all raw materials used do not contain rouge Class or benzene ring substance, are all EU criteria environment-friendly products, and finished product is non-toxic and tasteless;
Wearability is higher, has fire-proof function.Contain higher calcium carbonate in finished product of the invention, after being combined with water hardness It is stronger, very fine and close protective layer can be formed on surface in kind, and can persistently keep stronger hardness, finished product has resistance to Mill property, anti-flammability;
Application property is good, and construction method is flexible, sprayable also to can be applied;
Have a wide range of application, the water paint produced by the present invention made of conch meal has well for different substrates Adhesive force.
Specific embodiment
Technical solutions and effects of the present invention is described in further details combined with specific embodiments below.
As illustrated without especially unexpected, each raw material used in the present invention is all industry universal raw material.Dispersing agent it is main at It is divided into Sodium Polyacrylate, purchases from Hiachuan Industry Co., Ltd., Shenzhen, model H5040;Conditioning agent is purchased from Tao Shi Chemical company, model X-405, general wetting agent, low bubble color developing is good, can effectively prevent coating floating;Defoaming agent uses two Kind, it is a kind of to purchase from Hiachuan Industry Co., Ltd., Shenzhen, model F111, there is beneficial foam inhibition effect, dispersibility Good, from Nuo Pu section of Japan, model NXZ has excellent effect of breaking bubble for another defoaming agent buying;Thickener uses Luo Menha The association thickener of this company, model TT-935 can effectively improve middle cut and paste degree, and can opening effect is good, splendid mobility And levelability, another kind are the TVA-9760 of sunrise Industry Group Co., Ltd;Sterilization antiseptic purchases the company from Suzhou, type Number be KC-10B;Levelling agent is purchased from Hiachuan Industry Co., Ltd., Shenzhen, model 620 and/or 600;Multifunctional assistant Agent buying is purchased from Dow Chemical, model AMP, styrene-acrylic emulsion from BASF Aktiengesellschaft, model ECO-502.
Embodiment 1
The technical scheme adopted by the invention is as follows: a kind of water paint made of conch meal, prepared by following raw material and At diatomite 8%;Conch meal 50%;Calcium powder 6%;Kaolin 5%;Defoaming agent 0.8%;Thickener 1.2%;Lotion 12%;It adjusts Humectant 1.3%;Levelling agent 1.8% and deionized water 36%.
Preparation method, comprising the following steps:
(1) first diatomite, conch meal, calcium powder and kaolin are uniformly mixed, pour into the 30% of deionized water total amount, mixed Uniformly, it is formed to mixed radix material;
(2) obtained to step (1) to which defoaming agent, thickener, conditioning agent and levelling agent are added in mixed radix material, and remove Other raw materials outside ionized water stir 20 minutes, remaining deionized water are then added, and are uniformly mixed, and form mixture;
(3) mixture that step (2) obtains is ground and is filtered, be again stirring for being uniformly mixed to get with shell The water paint of powder production.
Embodiment 2
The technical scheme adopted by the invention is as follows: a kind of water paint made of conch meal, prepared by following raw material and At diatomite 5%;Conch meal 55%;Nanoscale calcium powder 8%;Kaolin 8%;Defoaming agent 0.5%;Thickener 1.5%;Phenylpropyl alcohol Lotion 10%;Conditioning agent 1.5%;Levelling agent 1.5%;Dispersing agent 1.5%, sterilization antiseptic 0.1%, 5% He of multifunctional assistant Deionized water 32%.
Preparation method, comprising the following steps:
(1) first diatomite, conch meal, calcium powder and kaolin are uniformly mixed, pour into high speed disperser, then pour into deionization The 30% of water inventory, first stirred at low speed 10 minutes with 800 revs/min, then with 1000 revs/min high-speed stirred 10 minutes, mixing Uniformly, it is formed to mixed radix material;
(2) obtained to step (1) to which defoaming agent, thickener, conditioning agent and levelling agent are added in mixed radix material, and remove Other raw materials outside ionized water, first stirred at low speed 12 minutes with 500 revs/min, then with 1000 revs/min high-speed stirred 8 minutes, Then be added remaining deionized water, then with 1000 revs/min high-speed stirred 42 minutes to being uniformly mixed, form mixture;
(3) mixture that step (2) obtains is carried out being ground to partial size as 200nm and is filtered, be again stirring for equal to mixing It is even to get the water paint made of conch meal.
Embodiment 3
The technical scheme adopted by the invention is as follows: a kind of water paint made of conch meal, prepared by following raw material and At diatomite 10%;Conch meal 40%;Nanoscale calcium powder 5%;Kaolin 3%;Defoaming agent 1%;Thickener 1%;Styrene-acrylic emulsion 15%;Conditioning agent 1%;Levelling agent 2%;Dispersing agent 1%, sterilization antiseptic 0.5%, multifunctional assistant 1% and deionized water 38%.
Preparation method, comprising the following steps:
(1) first diatomite, conch meal, calcium powder and kaolin are uniformly mixed, pour into high speed disperser, then pour into deionization The 30% of water inventory, first stirred at low speed 10 minutes with 500 revs/min, further accelerate to 1500 revs/min high-speed stirred 10 minutes, It is uniformly mixed, is formed to mixed radix material;
(2) obtained to step (1) to which defoaming agent, thickener, conditioning agent and levelling agent are added in mixed radix material, and remove Other raw materials outside ionized water, first stirred at low speed 8 minutes with 800 revs/min, then with 1000 revs/min high-speed stirred 12 minutes, Then be added remaining deionized water, then with 1500 revs/min high-speed stirred 38 minutes to being uniformly mixed, form mixture;
(3) mixture that step (2) obtains is carried out being ground to partial size as 800nm and is filtered, be again stirring for equal to mixing It is even to get the water paint made of conch meal.
The present invention is not limited to above-mentioned preferred forms, anyone can show that other are various under the inspiration of the present invention The product of form, however, make any variation in its shape or structure, it is all that there is skill identical or similar to the present application Art scheme, is within the scope of the present invention.

Claims (10)

1. a kind of water paint made of conch meal, which is characterized in that be prepared from the following materials, the raw material is by weight Percentage includes: diatomite 5%-10%;Conch meal 40%-55%;Calcium powder 5%-8%;Kaolin 3%-8%;Defoaming agent 0.5%-1%;Thickener 1%-1.5%;Lotion 10%-15%;Conditioning agent 1%-1.5%;Levelling agent 1.5%-2% and go from Sub- water 32%-38%.
2. the water paint according to claim 1 made of conch meal, which is characterized in that the calcium powder is nanometer calcium Powder.
3. the water paint according to claim 1 made of conch meal, which is characterized in that the raw material further includes dispersion Agent and multifunctional assistant, the thickener include alkali-swelling type thickener.
4. the water paint according to claim 1 made of conch meal, which is characterized in that the lotion is phenylpropyl alcohol cream Liquid.
5. a kind of preparation method of the water paint made of conch meal as described in Claims 1-4 is any, feature exist In, comprising the following steps:
(1) first diatomite, conch meal, calcium powder and kaolin are uniformly mixed, pour into the 30% of deionized water total amount, mixing is equal It is even, it is formed to mixed radix material;
(2) obtained to step (1) to which defoaming agent, thickener, conditioning agent and levelling agent are added in mixed radix material, and remove deionization Other raw materials outside water stir 15-25 minutes, remaining deionized water are then added, and are uniformly mixed, and form mixture;
(3) mixture that step (2) obtains is ground and is filtered, be again stirring for being uniformly mixed to get with conch meal system The water paint of work.
6. the preparation method of the water paint according to claim 5 made of conch meal, which is characterized in that step (1) In step (2), it is all made of high speed disperser and is stirred or mixes.
7. the preparation method of the water paint according to claim 5 made of conch meal, which is characterized in that step (1) In, it after pouring into deionized water, first stirs at low speed 10 minutes, then high-speed stirred 10 minutes.
8. the preparation method of the water paint according to claim 5 made of conch meal, which is characterized in that step (2) In, to which defoaming agent, thickener, conditioning agent and levelling agent, and other raw materials in addition to deionized water, elder generation are added in mixed radix material It stirs at low speed 8-12 minutes, then high-speed stirred 8-12 minutes;Then remaining deionized water, then high-speed stirred 38-42 points are added Clock to be uniformly mixed.
9. the preparation method of the water paint according to claim 7 or 8 made of conch meal, which is characterized in that described The speed stirred at low speed is 500-800 revs/min;The speed of the high-speed stirred is 1000-1500 revs/min.
10. the preparation method of the water paint according to claim 5 made of conch meal, which is characterized in that step (3) In, it is 200-800nm that mixture, which is ground to partial size,.
CN201811074037.3A 2018-09-14 2018-09-14 A kind of water paint and preparation method thereof made of conch meal Pending CN109321045A (en)

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CN201811074037.3A CN109321045A (en) 2018-09-14 2018-09-14 A kind of water paint and preparation method thereof made of conch meal

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109929281A (en) * 2019-03-25 2019-06-25 秦皇岛美博士新型材料科技有限公司 A kind of conch meal water soluble paint and preparation method thereof quickly removing formaldehyde
CN111234573A (en) * 2020-03-20 2020-06-05 秦皇岛美博士新型材料科技有限公司 Wear-resistant and water-resistant shell powder coating and preparation method thereof
CN114316760A (en) * 2021-12-31 2022-04-12 三棵树(上海)新材料研究有限公司 Shell powder coating with high bio-based content and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR880002242B1 (en) * 1985-08-08 1988-10-20 박진우 Composition of aqueous paints
CN107383946A (en) * 2016-05-16 2017-11-24 天津引领未来科技有限公司 A kind of wall covering for interior wall
CN107459933A (en) * 2017-08-25 2017-12-12 秦皇岛美博士新型材料科技有限公司 A kind of liquid shell powder paint and preparation method thereof
CN108299881A (en) * 2018-02-13 2018-07-20 青岛宏赛环保科技有限公司 A kind of the diatomite paint formula and its bullet painting technique of surface-stable
CN108300039A (en) * 2017-09-18 2018-07-20 白山市和硅藻科技有限公司 A kind of thermal insulation coatings of containing diatomite and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR880002242B1 (en) * 1985-08-08 1988-10-20 박진우 Composition of aqueous paints
CN107383946A (en) * 2016-05-16 2017-11-24 天津引领未来科技有限公司 A kind of wall covering for interior wall
CN107459933A (en) * 2017-08-25 2017-12-12 秦皇岛美博士新型材料科技有限公司 A kind of liquid shell powder paint and preparation method thereof
CN108300039A (en) * 2017-09-18 2018-07-20 白山市和硅藻科技有限公司 A kind of thermal insulation coatings of containing diatomite and preparation method thereof
CN108299881A (en) * 2018-02-13 2018-07-20 青岛宏赛环保科技有限公司 A kind of the diatomite paint formula and its bullet painting technique of surface-stable

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109929281A (en) * 2019-03-25 2019-06-25 秦皇岛美博士新型材料科技有限公司 A kind of conch meal water soluble paint and preparation method thereof quickly removing formaldehyde
CN111234573A (en) * 2020-03-20 2020-06-05 秦皇岛美博士新型材料科技有限公司 Wear-resistant and water-resistant shell powder coating and preparation method thereof
CN114316760A (en) * 2021-12-31 2022-04-12 三棵树(上海)新材料研究有限公司 Shell powder coating with high bio-based content and preparation method thereof

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Application publication date: 20190212

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