CN103756403A - Luminous printing ink - Google Patents

Luminous printing ink Download PDF

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Publication number
CN103756403A
CN103756403A CN201410031276.6A CN201410031276A CN103756403A CN 103756403 A CN103756403 A CN 103756403A CN 201410031276 A CN201410031276 A CN 201410031276A CN 103756403 A CN103756403 A CN 103756403A
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CN
China
Prior art keywords
printing ink
ink
luminous
noctilucence
resin
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Granted
Application number
CN201410031276.6A
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Chinese (zh)
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CN103756403B (en
Inventor
朱家昆
朱晓珍
刘瑞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Wanna Package Technology Co., Ltd.
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Zhu Shi Yin Wu Of Fanchang County LLC
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Priority to CN201410031276.6A priority Critical patent/CN103756403B/en
Publication of CN103756403A publication Critical patent/CN103756403A/en
Application granted granted Critical
Publication of CN103756403B publication Critical patent/CN103756403B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention relates to luminous printing ink consisting of the following components in percentage by mass: 25-50% of luminous powder, 10-40% of organic resin, 5-30% of an organic solvent, 0.5-5% of a dispersing agent and 0.5-3% of an anti-settling agent. A preparation method of the ink comprises the steps of adding the organic resin and the organic solvent to a container, adding the dispersing agent, stirring, and simultaneously adding the anti-settling agent and the luminous powder sequentially; increasing rotating speed after adding the luminous powder until the luminous powder is uniformly dispersed in the ink, and filtering to obtain the luminous printing ink. The luminous printing ink prepared by the technology disclosed by the invention is greatly enhanced in luminous power after being printed on a light color base material, thus the glowing effect in the night is obviously improved and glowing lifetime is prolonged; the luminous printing ink is excellent in artistic appreciation effect and reminding ability, and is suitable for popularization and application.

Description

A kind of Noctilucence printing ink
Technical field
The present invention relates to a kind of Noctilucence printing ink, belong to printing technology.
Background technology
In recent years, the fluorescent ink that more and more can be used for fine screen-printing constantly occurs.The main term of fluorescent ink printing window display, decal paper, collision bumper bib, industrial insurance instrument, ads. on vehicle, letter raft, pictorial poster (placard), 24 inches of placards, notepad, signalling pennant, journal surface, invitation card, outdoor advertising, cloth mark etc.Due to the huge difference between fluorescent ink and common ink color, make fluorescent ink take on key player in the open air of silk screen printing and indoor advertisement.
Fluorescent ink is luminescent material, is can radiative material.This material absorbs the energy storage of solar radiation under the irradiation of sunlight, then with hot form, show, or photochemical reaction occurs, or energy comes out with the form of visible ray.The radiating capacity absorbing is than the energy waves length of distributing.People are the light that absorbs different colours, and the phenomenon then coming out is called fluorescence.After absorb light in dark surrounds luminous phenomenon call phosphorescence.The phosphorescence that is not both of the two absorbs natural light or artificial light, luminous in the dark surrounds light is removed after, and fluorescence must just can be luminous under light existence after absorb light.Fluorescent ink also can be luminous in the situation that of " noctilucence " or purple light existence.But it is not luminous in the situation that dark is unglazed.Fluorescent ink not only can show his color own, and has the ability of absorb light and change light intensity, and the color that it is showed has stronger light intensity, but form and aspect (or color) are constant.
Common ink or dyestuff carry out Show Color by reflected light, and the wavelength of every kind of ink colors is also different with output energy, and for example reflection to red light is red, absorbs other colors.And fluorescent red not only has the redness of part reflection, and other colors (green, blueness and purple) converted to red wavelength as redness, come out, thus this look seem from interior of articles, radiate the same.This luminous attribute makes this ink be called as fluorescent ink just.Printer uses fluorescent ink printing can obtain 4 times of brightness to common ink and visibility.Fluorescent ink, under dim light, such as dusk and at the crack of dawn, seems very bright.
The reflectance signature of common ink color and fluorescent ink color is different, and its unit of measure is dust.Fluorescent ink converts long wavelength light to and the generation fluorescence that superposes short-wavelength light, by changing and superposeing, forms a kind of have special brightness and the fluorescence color of visibility.
Summary of the invention
The object of the present invention is to provide a kind of Noctilucence printing ink, can be at noctilucent printing-ink to prepare, strengthening print product can be in noctilucent ability.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of Noctilucence printing ink, luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, consist of, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 25~50%, organic resin accounts for 10~40%, organic solvent accounts for 5~30%, dispersion agent accounts for 0.5~5%, anti-settling agent accounts for 0.5~3%.
Further, described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.
Further, described organic resin be the alkyd varnish of epoxy resin, urethane resin, amino varnish, vibrin, acrylic resin, Hydroxylated acrylic resin, acroleic acid polyurethane varnish, color and luster money, one or several in fluoro-resin.
Further, described organic solvent is one or several in ethanol, propylene glycol monomethyl ether, diethylene glycol monobutyl ether, dipropylene glycol dme.
Further, described dispersion agent is one or several in methyl-silicone oil xylene soluble liquid, homopolymer, oxidized homopolymer, ethylene acrylic acid co polymer, ethene acetate copolymer, low molecule ionomer.
Further, described anti-settling agent is one or several in the N-Methyl pyrrolidone solution of aerosil, polyolefin-wax particulate, polyamide wax, modification polyureas.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, add dispersion agent, stir, add successively anti-settling agent, luminescent powder under whipped state; After adding luminescent powder, improve rotating speed, until luminescent powder is dispersed in ink, filters and make Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed with thinner.(2) in order to obtain the good printed patterns of illumination effect, select 80~120 object silk screens to carry out Plate making printing, due to the silk screen printing of using compared with low mesh number, China ink layer is thicker, can obtain the comparatively desirable pattern of illumination effect.(3) under luminescent coating, use white substrate be printed directly on white or light base material on, can improve brightness and the fluorescent lifetime of institute's impression case.(4) for obtaining the good goods of illumination effect, luminous printing ink layer thickness should be more than 150um.(5) adopt the mode of chromaticity printing.(6) in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
This beneficial effect of the invention is: utilize the technology of the present invention to prepare the Noctilucence printing ink of gained, after on being printed on light base material, its luminous power strengthens greatly, at noctilucence successful, extended its fluorescent lifetime, there is good effect of art appreciation and prompting ability, be applicable to applying.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, to better understand the present invention.
embodiment 1:
The Noctilucence printing ink of the present embodiment, luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, consist of, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 25%, organic resin accounts for 40%, organic solvent accounts for 30%, dispersion agent accounts for 2%, anti-settling agent accounts for 3%.Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.Described organic resin is epoxy resin, urethane resin, amino varnish mixture.Described organic solvent is ethanol, propylene glycol monomethyl ether mixture.Described dispersion agent is methyl-silicone oil xylene soluble liquid.Described anti-settling agent is aerosil.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, add dispersion agent, stir, add successively anti-settling agent, luminescent powder under whipped state; After adding luminescent powder, improve rotating speed, until luminescent powder is dispersed in ink, filters and make Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed with thinner.(2) select 80 object silk screens to carry out Plate making printing.(3) use white substrate be printed directly on white or light base material on.(4) luminous printing ink layer thickness is 155um.(5) adopt the mode of chromaticity printing.(6) in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
embodiment 2:
The Noctilucence printing ink of the present embodiment, luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, consist of, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 50%, organic resin accounts for 20%, organic solvent accounts for 25%, dispersion agent accounts for 4%, anti-settling agent accounts for 1%.Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.Described organic resin is amino varnish, vibrin, acrylic resin mixture.Described organic solvent is diethylene glycol monobutyl ether, dipropylene glycol dme mixture.Described dispersion agent is oxidized homopolymer, ethylene acrylic acid co polymer mixture.Described anti-settling agent is the N-Methyl pyrrolidone solution mixture of polyamide wax, modification polyureas.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, add dispersion agent, stir, add successively anti-settling agent, luminescent powder under whipped state; After adding luminescent powder, improve rotating speed, until luminescent powder is dispersed in ink, filters and make Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed with thinner.(2) select 120 object silk screens to carry out Plate making printing.(3) under luminescent coating, use white substrate be printed directly on white or light base material on.(4) luminous printing ink layer thickness is 170um.(5) adopt the mode of chromaticity printing.(6) in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
embodiment 3:
The Noctilucence printing ink of the present embodiment, luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, consist of, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 40%, organic resin accounts for 30%, organic solvent accounts for 28%, dispersion agent accounts for 1%, anti-settling agent accounts for 1%.Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.Described organic resin is Hydroxylated acrylic resin, acroleic acid polyurethane varnish, the alkyd varnish of color and luster money, fluoro-resin mixture.Described organic solvent is propylene glycol monomethyl ether, diethylene glycol monobutyl ether, dipropylene glycol dme mixture.Described dispersion agent is ethylene acrylic acid co polymer, ethene acetate copolymer, low molecule ionomer mixture.Described anti-settling agent is the N-Methyl pyrrolidone solution mixture of gas phase polyamide wax, modification polyureas.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, add dispersion agent, stir, add successively anti-settling agent, luminescent powder under whipped state; After adding luminescent powder, improve rotating speed, until luminescent powder is dispersed in ink, filters and make Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed with thinner.(2) select 100 object silk screens to carry out Plate making printing.(3) under luminescent coating, use white substrate be printed directly on white or light base material on.(4) luminous printing ink layer thickness is 160um.(5) adopt the mode of chromaticity printing.(6) in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (8)

1. a Noctilucence printing ink, it is characterized in that: luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, consist of, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 25~50%, organic resin accounts for 10~40%, organic solvent accounts for 5~30%, dispersion agent accounts for 0.5~5%, anti-settling agent accounts for 0.5~3%.
2. a kind of Noctilucence printing ink according to claim 1, is characterized in that: described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.
3. a kind of Noctilucence printing ink according to claim 1, is characterized in that: described organic resin is the alkyd varnish of epoxy resin, urethane resin, amino varnish, vibrin, acrylic resin, Hydroxylated acrylic resin, acroleic acid polyurethane varnish, color and luster money, one or several in fluoro-resin.
4. a kind of Noctilucence printing ink according to claim 1, is characterized in that: described organic solvent is one or several in ethanol, propylene glycol monomethyl ether, diethylene glycol monobutyl ether, dipropylene glycol dme.
5. a kind of Noctilucence printing ink according to claim 1, is characterized in that: described dispersion agent is one or several in methyl-silicone oil xylene soluble liquid, homopolymer, oxidized homopolymer, ethylene acrylic acid co polymer, ethene acetate copolymer, low molecule ionomer.
6. a kind of Noctilucence printing ink according to claim 1, is characterized in that: described anti-settling agent is one or several in the N-Methyl pyrrolidone solution of aerosil, polyolefin-wax particulate, polyamide wax, modification polyureas.
7. according to a kind of Noctilucence printing ink described in claim 1 to 6, it is characterized in that: the preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, add dispersion agent, stir, under whipped state, add successively anti-settling agent, luminescent powder; After adding luminescent powder, improve rotating speed, until luminescent powder is dispersed in ink, filters and make Noctilucence printing ink.
8. according to a kind of Noctilucence printing ink described in claim 1 to 7, it is characterized in that: the print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed with thinner; (2) select 80~120 object silk screens to carry out Plate making printing; (3) use white substrate be printed directly on white or light base material on; (4) luminous printing ink layer thickness should be more than 150um; (5) adopt the mode of chromaticity printing; (6) in the process of printing, whole system keeps dry; (7) luminous printing ink must stir before using, and uses rear sealing, is stored in shady and cool dry place.
CN201410031276.6A 2014-01-23 2014-01-23 A kind of Noctilucence printing ink Expired - Fee Related CN103756403B (en)

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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263081A (en) * 2014-10-21 2015-01-07 苏州中亚油墨有限公司 Preparation method for environment-friendly long-acting luminous printing ink
CN104774495A (en) * 2015-03-28 2015-07-15 安徽美翔塑业有限公司 Environmentally friendly ink for film printing
CN105273489A (en) * 2014-07-24 2016-01-27 李俞坤 Noctilucent ink and spray-coating method thereof
CN105348905A (en) * 2015-12-18 2016-02-24 陈荣芳 Red-light luminous ink and preparation method thereof
CN105348920A (en) * 2015-11-12 2016-02-24 成都普瑞斯特新材料有限公司 Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof
CN105368148A (en) * 2015-12-28 2016-03-02 李栋军 Quickly-cured luminous printing ink
CN105368132A (en) * 2015-12-18 2016-03-02 陈荣芳 Noctilucent printing ink and preparation method thereof
CN105419478A (en) * 2015-12-18 2016-03-23 陈荣芳 Luminous printing ink and preparation method thereof
CN105504962A (en) * 2015-12-18 2016-04-20 陈荣芳 Red-light luminous ink and preparation method thereof
CN106009908A (en) * 2016-07-28 2016-10-12 桐城市人和包装有限公司 Luminous printing ink and preparation method thereof
CN106167648A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 Ink
CN106167645A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 The wear-resisting ink of noctilucence
CN106167647A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 Environmental protection Noctilucence printing ink
CN106167649A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 Environment-friendlywear-resistant wear-resistant ink
CN106183488A (en) * 2016-07-11 2016-12-07 鹏码实业(上海)有限公司 A kind of for false proof magnetic thermal Transfer ribbon and preparation method thereof
CN106189492A (en) * 2016-08-23 2016-12-07 苏州中亚油墨有限公司 A kind of printing-ink
CN106221376A (en) * 2016-08-19 2016-12-14 苏州市博来特油墨有限公司 The wear-resisting printing-ink of environmental protection noctilucence
CN106280699A (en) * 2016-08-10 2017-01-04 苏州中亚油墨有限公司 A kind of UV printed ink
CN107880768A (en) * 2017-11-29 2018-04-06 张家港宝视特影视器材有限公司 A kind of coating material for plastics curtain and preparation method thereof
CN108299949A (en) * 2018-01-22 2018-07-20 中国石油天然气股份有限公司长庆油田分公司技术监测中心 A kind of field pressure dial plate luminous printing ink making and printing process
CN108342125A (en) * 2018-02-11 2018-07-31 安徽省中彩印务有限公司 A kind of control method and printing ink of printing ink
CN110239248A (en) * 2019-06-25 2019-09-17 厦门欣维发实业有限公司 Reflecting at night screen printing method
CN112181156A (en) * 2020-09-10 2021-01-05 深圳市蓝晨科技股份有限公司 Fluorescent keyboard, printing method thereof and fluorescent UV gloss oil applied to fluorescent keyboard
CN112694788A (en) * 2021-01-21 2021-04-23 江阴市永乐印务有限公司 Noctilucent printing ink and preparation method thereof
CN115651558A (en) * 2022-09-09 2023-01-31 明新梅诺卡(江苏)新材料有限公司 Noctilucent starry sky-top PVC film and preparation method thereof
CN115960381A (en) * 2023-01-10 2023-04-14 河北金悦能源科技开发有限公司 Preparation method of composite luminous piece

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CN102133977A (en) * 2010-12-31 2011-07-27 深圳市华熙生物科技有限公司 Food and beverage outer package printed with luminescent patterns

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Publication number Priority date Publication date Assignee Title
CN102133977A (en) * 2010-12-31 2011-07-27 深圳市华熙生物科技有限公司 Food and beverage outer package printed with luminescent patterns

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105273489A (en) * 2014-07-24 2016-01-27 李俞坤 Noctilucent ink and spray-coating method thereof
CN104263081A (en) * 2014-10-21 2015-01-07 苏州中亚油墨有限公司 Preparation method for environment-friendly long-acting luminous printing ink
CN104774495A (en) * 2015-03-28 2015-07-15 安徽美翔塑业有限公司 Environmentally friendly ink for film printing
CN105348920A (en) * 2015-11-12 2016-02-24 成都普瑞斯特新材料有限公司 Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof
CN105348905A (en) * 2015-12-18 2016-02-24 陈荣芳 Red-light luminous ink and preparation method thereof
CN105368132A (en) * 2015-12-18 2016-03-02 陈荣芳 Noctilucent printing ink and preparation method thereof
CN105419478A (en) * 2015-12-18 2016-03-23 陈荣芳 Luminous printing ink and preparation method thereof
CN105504962A (en) * 2015-12-18 2016-04-20 陈荣芳 Red-light luminous ink and preparation method thereof
CN105368148A (en) * 2015-12-28 2016-03-02 李栋军 Quickly-cured luminous printing ink
CN106183488A (en) * 2016-07-11 2016-12-07 鹏码实业(上海)有限公司 A kind of for false proof magnetic thermal Transfer ribbon and preparation method thereof
CN106009908A (en) * 2016-07-28 2016-10-12 桐城市人和包装有限公司 Luminous printing ink and preparation method thereof
CN106280699A (en) * 2016-08-10 2017-01-04 苏州中亚油墨有限公司 A kind of UV printed ink
CN106167647A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 Environmental protection Noctilucence printing ink
CN106167649A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 Environment-friendlywear-resistant wear-resistant ink
CN106167645A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 The wear-resisting ink of noctilucence
CN106221376A (en) * 2016-08-19 2016-12-14 苏州市博来特油墨有限公司 The wear-resisting printing-ink of environmental protection noctilucence
CN106167648A (en) * 2016-08-19 2016-11-30 苏州市博来特油墨有限公司 Ink
CN106189492A (en) * 2016-08-23 2016-12-07 苏州中亚油墨有限公司 A kind of printing-ink
CN107880768A (en) * 2017-11-29 2018-04-06 张家港宝视特影视器材有限公司 A kind of coating material for plastics curtain and preparation method thereof
CN108299949A (en) * 2018-01-22 2018-07-20 中国石油天然气股份有限公司长庆油田分公司技术监测中心 A kind of field pressure dial plate luminous printing ink making and printing process
CN108342125A (en) * 2018-02-11 2018-07-31 安徽省中彩印务有限公司 A kind of control method and printing ink of printing ink
CN110239248A (en) * 2019-06-25 2019-09-17 厦门欣维发实业有限公司 Reflecting at night screen printing method
CN112181156A (en) * 2020-09-10 2021-01-05 深圳市蓝晨科技股份有限公司 Fluorescent keyboard, printing method thereof and fluorescent UV gloss oil applied to fluorescent keyboard
CN112694788A (en) * 2021-01-21 2021-04-23 江阴市永乐印务有限公司 Noctilucent printing ink and preparation method thereof
CN115651558A (en) * 2022-09-09 2023-01-31 明新梅诺卡(江苏)新材料有限公司 Noctilucent starry sky-top PVC film and preparation method thereof
CN115960381A (en) * 2023-01-10 2023-04-14 河北金悦能源科技开发有限公司 Preparation method of composite luminous piece

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