CN106167647A - Environmental protection Noctilucence printing ink - Google Patents

Environmental protection Noctilucence printing ink Download PDF

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Publication number
CN106167647A
CN106167647A CN201610688888.1A CN201610688888A CN106167647A CN 106167647 A CN106167647 A CN 106167647A CN 201610688888 A CN201610688888 A CN 201610688888A CN 106167647 A CN106167647 A CN 106167647A
Authority
CN
China
Prior art keywords
alcohol
molten
environmental protection
parts
luminescent powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610688888.1A
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Chinese (zh)
Inventor
徐晓花
吕伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU BOLOIT PRINTING INK CO Ltd
Original Assignee
SUZHOU BOLOIT PRINTING INK CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU BOLOIT PRINTING INK CO Ltd filed Critical SUZHOU BOLOIT PRINTING INK CO Ltd
Priority to CN201610688888.1A priority Critical patent/CN106167647A/en
Publication of CN106167647A publication Critical patent/CN106167647A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of environmental protection Noctilucence printing ink, be made up of luminescent powder, organic resin, organic solvent and function additive;Described organic resin includes the molten modified aldehyde ketone resin of molten acrylic resin modified, the alcohol of alcohol, described organic solvent be concentration be the ethanol solution of more than 95%, described function additive includes anti-settling agent, antistatic additive and dispersant;Above-mentioned each component by mass fraction be respectively as follows: luminescent powder account for 25 50 parts, alcohol molten acrylic resin modified account for 12 22 parts, the molten modified aldehyde ketone resin of alcohol account for 10 20 parts, concentration be more than 95% ethanol solution account for 35 55 parts and function additive 2.5 9 parts.The present invention is made up of luminescent powder, organic resin, organic solvent and function additive, the use of luminescent powder makes ink be provided with in noctilucent ability, organic solvent have selected the ethanol solution that concentration is more than 95%, there is not the residual of solvent and noxious substance, serving the function of environmental protection, the antistatic additive in function additive also makes this ink be provided with certain anti-static function.

Description

Environmental protection Noctilucence printing ink
Technical field
The present invention relates to ink area, particularly relate to a kind of environmental protection Noctilucence printing ink.
Background technology
Along with development and the progress of society, people are more and more higher to the concern of quality of life and life comfort level, for print The prescription of brush product is stricter, not only needs leaflet itself to have extraordinary printing effect, and right In printing ink used, its bad harm that surrounding and the person are produced should be reduced as far as possible.It addition, in the face of high-strength The work of degree, people's outdoor activity that has no time by day plays, and increasing people selects go on a journey night, therefore, at night Carrying out advertising etc. and also can obtain bigger effect, what in advertising, usual use was most is that various printing show window is old If, decal paper, bumper guard, industrial insurance instrument, ads. on vehicle, letter raft, pictorial poster (poster), 24 inches of posters, accounts Basis, signal flag, journal surface, invitation card, outdoor advertising, cloth mark etc., the most a can night luminous leaflet certainly will be able to inhale Induce one eyeball.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of environmental protection Noctilucence printing ink, it is possible in noctilucent print Brush ink, strengthening print product in noctilucent ability, and can use the alcohol solution system of environmental-protecting performance, well protects Environment.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of environmental protection noctilucence off-set oil Ink.
In a preferred embodiment of the present invention, environmental protection Noctilucence printing ink by luminescent powder, organic resin, organic solvent and Function additive forms;Described organic resin includes molten acrylic resin modified, the molten modified aldehyde ketone resin of alcohol of alcohol, described organic solvent Being the ethanol solution of more than 95% for concentration, described function additive includes anti-settling agent, antistatic additive and dispersant;Above-mentioned each component It is respectively as follows: luminescent powder by mass fraction and accounts for that 25-50 part, alcohol are molten acrylic resin modified accounts for 12-22 part, the molten modified aldehyde ketone resin of alcohol Account for 10-20 part, concentration be more than 95% ethanol solution account for 35-55 part and function additive 2.5-9 part.
Preferably, described anti-settling agent is aerosil anti-settling agent, and mass fraction is 1-3 part.
Preferably, described antistatic additive is the molten antistatic additive of anionic alcohol, and mass fraction is 1-3 part.
Preferably, described dispersant is ethylene vinyl acetate copolymer dispersant, and mass fraction is 0.5-3 part.
Preferably, described luminescent powder is the mixture of Potassium monosulfide., barium nitrate, indium nitrate, strontium sulfate and silver nitrate.
The invention has the beneficial effects as follows: the present invention is made up of luminescent powder, organic resin, organic solvent and function additive, night The use of light powder makes ink be provided with in noctilucent ability, and it is molten that organic solvent have selected the ethanol that concentration is more than 95% , there is not the residual of solvent and noxious substance in liquid, serves the function of environmental protection, and the antistatic additive in function additive also makes this ink It is provided with certain anti-static function.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1:
Luminescent powder account for 25 parts, alcohol molten acrylic resin modified account for 22 parts, the molten modified aldehyde ketone resin of alcohol account for 20 parts, concentration be 95% with On ethanol solution account for 40 parts, aerosil anti-settling agent account for 2 parts, the molten antistatic additive of anionic alcohol account for 2 parts, ethylene vinyl acetate Copolymer dispersant accounts for 2 parts.
The preparation method of above-mentioned ink is as follows: by molten for molten for alcohol acrylic resin modified, alcohol modified aldehyde ketone resin, concentration be The ethanol solution of more than 95% is put in container, adds ethylene vinyl acetate copolymer dispersant, is stirred, depends under stirring Secondary addition aerosil anti-settling agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, directly after adding luminescent powder It is dispersed in ink to luminescent powder, filters and i.e. prepare environmental protection Noctilucence printing ink.
Embodiment 2:
Luminescent powder account for 50 parts, alcohol molten acrylic resin modified account for 12 parts, the molten modified aldehyde ketone resin of alcohol account for 10 parts, concentration be 95% with On ethanol solution account for 40 parts, aerosil anti-settling agent account for 1 part, the molten antistatic additive of anionic alcohol account for 3 parts, ethylene vinyl acetate Copolymer dispersant accounts for 2 parts.
The preparation method of above-mentioned ink is as follows: by molten for molten for alcohol acrylic resin modified, alcohol modified aldehyde ketone resin, concentration be The ethanol solution of more than 95% is put in container, adds ethylene vinyl acetate copolymer dispersant, is stirred, depends under stirring Secondary addition aerosil anti-settling agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, directly after adding luminescent powder It is dispersed in ink to luminescent powder, filters and i.e. prepare environmental protection Noctilucence printing ink.
Embodiment 3:
Luminescent powder account for 40 parts, alcohol molten acrylic resin modified account for 18 parts, the molten modified aldehyde ketone resin of alcohol account for 15 parts, concentration be 95% with On ethanol solution account for 40 parts, aerosil anti-settling agent account for 2 parts, the molten antistatic additive of anionic alcohol account for 2 parts, ethylene vinyl acetate Copolymer dispersant accounts for 1.5 parts.
The preparation method of above-mentioned ink is as follows: by molten for molten for alcohol acrylic resin modified, alcohol modified aldehyde ketone resin, concentration be The ethanol solution of more than 95% is put in container, adds ethylene vinyl acetate copolymer dispersant, is stirred, depends under stirring Secondary addition aerosil anti-settling agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, directly after adding luminescent powder It is dispersed in ink to luminescent powder, filters and i.e. prepare environmental protection Noctilucence printing ink.
Embodiment 4:
Luminescent powder account for 40 parts, alcohol molten acrylic resin modified account for 18 parts, the molten modified aldehyde ketone resin of alcohol account for 15 parts, concentration be 95% with On ethanol solution account for 35 parts, aerosil anti-settling agent account for 3 parts, the molten antistatic additive of anionic alcohol account for 1 part, ethylene vinyl acetate Copolymer dispersant accounts for 0.5 part.
The preparation method of above-mentioned ink is as follows: by molten for molten for alcohol acrylic resin modified, alcohol modified aldehyde ketone resin, concentration be The ethanol solution of more than 95% is put in container, adds ethylene vinyl acetate copolymer dispersant, is stirred, depends under stirring Secondary addition aerosil anti-settling agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, directly after adding luminescent powder It is dispersed in ink to luminescent powder, filters and i.e. prepare environmental protection Noctilucence printing ink.
Embodiment 5:
Luminescent powder account for 40 parts, alcohol molten acrylic resin modified account for 18 parts, the molten modified aldehyde ketone resin of alcohol account for 15 parts, concentration be 95% with On ethanol solution account for 55 parts, aerosil anti-settling agent account for 1.5 parts, the molten antistatic additive of anionic alcohol account for 1.5 parts, ethylene Acetate copolymer dispersant accounts for 3 parts.
The preparation method of above-mentioned ink is as follows: by molten for molten for alcohol acrylic resin modified, alcohol modified aldehyde ketone resin, concentration be The ethanol solution of more than 95% is put in container, adds ethylene vinyl acetate copolymer dispersant, is stirred, depends under stirring Secondary addition aerosil anti-settling agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, directly after adding luminescent powder It is dispersed in ink to luminescent powder, filters and i.e. prepare environmental protection Noctilucence printing ink.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (5)

1. an environmental protection Noctilucence printing ink, it is characterised in that by luminescent powder, organic resin, organic solvent and function additive group Become;Described organic resin includes molten acrylic resin modified, the molten modified aldehyde ketone resin of alcohol of alcohol, and described organic solvent is that concentration is The ethanol solution of more than 95%, described function additive includes anti-settling agent, antistatic additive and dispersant;Above-mentioned each component presses mass parts Number is respectively as follows: that luminescent powder accounts for 25-50 part, the molten modified aldehyde ketone resin of the molten acrylic resin modified 12-22 of the accounting for part of alcohol, alcohol accounts for 10-20 Part, concentration be more than 95% ethanol solution account for 35-55 part and function additive 2.5-9 part.
Environmental protection Noctilucence printing ink the most according to claim 1, it is characterised in that described anti-settling agent is aerosil Anti-settling agent, mass fraction is 1-3 part.
Environmental protection Noctilucence printing ink the most according to claim 1, it is characterised in that described antistatic additive is anionic alcohol Molten antistatic additive, mass fraction is 1-3 part.
Environmental protection Noctilucence printing ink the most according to claim 1, it is characterised in that described dispersant is ethylene vinyl acetate copolymerization Thing dispersant, mass fraction is 0.5-3 part.
Environmental protection Noctilucence printing ink the most according to claim 1, it is characterised in that described luminescent powder is Potassium monosulfide., nitric acid The mixture of barium, indium nitrate, strontium sulfate and silver nitrate.
CN201610688888.1A 2016-08-19 2016-08-19 Environmental protection Noctilucence printing ink Pending CN106167647A (en)

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CN201610688888.1A CN106167647A (en) 2016-08-19 2016-08-19 Environmental protection Noctilucence printing ink

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318024A (en) * 2016-08-23 2017-01-11 苏州中亚油墨有限公司 Wear-resistant ink applicable to elastomers
CN106810977A (en) * 2017-02-14 2017-06-09 合肥智慧龙图腾知识产权股份有限公司 A kind of functional paint for being exclusively used in landscape stone material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756403A (en) * 2014-01-23 2014-04-30 繁昌县朱氏印务有限责任公司 Luminous printing ink
CN103965682A (en) * 2014-04-16 2014-08-06 大亚科技股份有限公司 Environment-friendly water-based ink

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756403A (en) * 2014-01-23 2014-04-30 繁昌县朱氏印务有限责任公司 Luminous printing ink
CN103965682A (en) * 2014-04-16 2014-08-06 大亚科技股份有限公司 Environment-friendly water-based ink

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318024A (en) * 2016-08-23 2017-01-11 苏州中亚油墨有限公司 Wear-resistant ink applicable to elastomers
CN106810977A (en) * 2017-02-14 2017-06-09 合肥智慧龙图腾知识产权股份有限公司 A kind of functional paint for being exclusively used in landscape stone material and preparation method thereof

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Application publication date: 20161130

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