CN106221376A - The wear-resisting printing-ink of environmental protection noctilucence - Google Patents

The wear-resisting printing-ink of environmental protection noctilucence Download PDF

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Publication number
CN106221376A
CN106221376A CN201610689263.7A CN201610689263A CN106221376A CN 106221376 A CN106221376 A CN 106221376A CN 201610689263 A CN201610689263 A CN 201610689263A CN 106221376 A CN106221376 A CN 106221376A
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CN
China
Prior art keywords
ink
parts
alcohol
molten
wear
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Pending
Application number
CN201610689263.7A
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Chinese (zh)
Inventor
徐晓花
吕伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU BOLOIT PRINTING INK CO Ltd
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SUZHOU BOLOIT PRINTING INK CO Ltd
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Priority to CN201610689263.7A priority Critical patent/CN106221376A/en
Publication of CN106221376A publication Critical patent/CN106221376A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of wear-resisting printing-ink of environmental protection noctilucence, be respectively as follows: the molten modified resin solution 22 42 parts of alcohol, vinyl chloride-vinyl acetate resin 4 10 parts, luminescent powder 25 50 parts, organic solvent 25 45 parts, nanometer alchlor wearproof emulsion 5 20 parts and function additive 28 parts by mass fraction each component;The molten modified resin solution of described alcohol, according to the mass fraction, alcohol molten acrylic resin modified account for 12 22 parts, the molten modified aldehyde ketone resin of alcohol account for 10 20 parts, concentration be more than 95% ethanol solution account for 10 20 parts.In the present invention, the use of luminescent powder makes ink be provided with in noctilucent ability, organic solvent have selected the ethanol solution that concentration is more than 95%, there is not the residual of solvent and noxious substance, serve the function of environmental protection, the use of wearproof emulsion makes ink be provided with wear-resisting function, and the antistatic additive in function additive also makes this ink be provided with certain anti-static function.

Description

The wear-resisting printing-ink of environmental protection noctilucence
Technical field
The present invention relates to ink area, particularly relate to a kind of wear-resisting printing-ink of environmental protection noctilucence.
Background technology
Along with development and the progress of society, people are more and more higher to the concern of quality of life and life comfort level, for print The prescription of brush product is stricter, not only needs leaflet itself to have extraordinary printing effect, and right In printing ink used, its bad harm that surrounding and the person are produced should be reduced as far as possible.It addition, in the face of high-strength The work of degree, people's outdoor activity that has no time by day plays, and increasing people selects go on a journey night, therefore, at night Carrying out advertising etc. and also can obtain bigger effect, what in advertising, usual use was most is that various printing show window is old If, decal paper, bumper guard, industrial insurance instrument, ads. on vehicle, letter raft, pictorial poster (poster), 24 inches of posters, accounts Basis, signal flag, journal surface, invitation card, outdoor advertising, cloth mark etc., the most a can night luminous leaflet certainly will be able to inhale Induce one eyeball.And, people are more and more higher to performance requirements such as the abrasion-resistant of product, ensureing that product has excellent adhesion While power, it is necessary to will have the performances such as good abrasion-resistant.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of wear-resisting printing-ink of environmental protection noctilucence, it is possible at noctilucence Printing-ink, strengthen print product can add wearproof emulsion in noctilucent ability, enhance the wear-resisting of print product Property, and use the alcohol solution system of environmental-protecting performance, well protect environment.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of wear-resisting print of environmental protection noctilucence Brush ink.
In a preferred embodiment of the present invention, the wear-resisting printing-ink of environmental protection noctilucence is respectively as follows: by mass fraction each component Alcohol molten modified resin solution 22-42 part, vinyl chloride-vinyl acetate resin 4-10 part, luminescent powder 25-50 part, organic solvent 25-45 part, nanometer three oxygen Change aluminum wearproof emulsion 5-20 part and function additive 2-8 part;The molten modified resin solution of described alcohol, according to the mass fraction, the molten modification of alcohol The ethanol solution that acrylic resin accounts for 12-22 part, the molten modified aldehyde ketone resin of alcohol accounts for 10-20 part, concentration is more than 95% accounts for 10-20 Part.
Preferably, described organic solvent be concentration be the ethanol solution of more than 95%.
Further, described function additive includes defoamer, dispersant and antistatic additive.
Preferably, described defoamer is emulsified silicone oil defoamer, and mass fraction is 0.5-2 part.
Preferably, described dispersant is ethylene vinyl acetate copolymer dispersant, and mass fraction is 0.5-3 part.
Preferably, described antistatic additive is the molten antistatic additive of anionic alcohol, and mass fraction is 1-3 part.
Preferably, described luminescent powder is the mixture of calcium sulfide, magnesium sulfate, Potassium monosulfide., barium nitrate and silver nitrate.
The invention has the beneficial effects as follows: in the present invention, the use of luminescent powder makes ink be provided with at noctilucent energy Power, organic solvent have selected the ethanol solution that concentration is more than 95%, there is not the residual of solvent and noxious substance, serve ring The function protected, the use of wearproof emulsion makes ink be provided with wear-resisting function, and the antistatic additive in function additive also makes this oil Ink is provided with certain anti-static function.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1:
The wear-resisting printing-ink of environmental protection noctilucence is respectively as follows: alcohol molten modified resin solution 22 parts, vinyl chloride-vinyl acetate resin by mass fraction each component 10 parts, luminescent powder 25 parts, concentration be more than 95% ethanol solution 45 parts, nanometer alchlor wearproof emulsion 5 parts, emulsified silicone oil Defoamer 2 parts, ethylene vinyl acetate copolymer dispersant 3 parts, 3 parts of the molten antistatic additive of anionic alcohol;The molten modified resin of described alcohol is molten Liquid, according to the mass fraction, alcohol molten acrylic resin modified account for 12 parts, the molten modified aldehyde ketone resin of alcohol account for 20 parts, concentration be more than 95% Ethanol solution account for 10 parts.
The preparation method of above-mentioned ink is as follows: by molten for alcohol acrylic resin modified, the molten modified aldehyde ketone resin of alcohol and concentration be The ethanol solution of more than 95% is put into stirring in container by a certain percentage and is obtained the molten modified resin solution of alcohol, is subsequently adding chlorine vinegar tree Fat and concentration are the ethanol solution of more than 95%, are stirred, and are sequentially added into the dispersion of ethylene vinyl acetate copolymer under stirring Agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, until luminescent powder is dispersed in ink after adding luminescent powder In, reduce rotating speed and add emulsified silicone oil defoamer and nanometer alchlor wearproof emulsion, continue to stir to being thoroughly mixed, filter I.e. prepare finished product.
Embodiment 2:
The wear-resisting printing-ink of environmental protection noctilucence is respectively as follows: alcohol molten modified resin solution 42 parts, vinyl chloride-vinyl acetate resin 4 by mass fraction each component Part, luminescent powder 50 parts, concentration are the ethanol solution 25 parts of more than 95%, nanometer alchlor wearproof emulsion 20 parts, emulsified silicone oil disappear Infusion 0.5 part, ethylene vinyl acetate copolymer dispersant 0.5 part, 1 part of the molten antistatic additive of anionic alcohol;The molten modified resin of described alcohol Solution, according to the mass fraction, alcohol molten acrylic resin modified account for 22 parts, the molten modified aldehyde ketone resin of alcohol account for 10 parts, concentration be 95% with On ethanol solution account for 20 parts.
The preparation method of above-mentioned ink is as follows: by molten for alcohol acrylic resin modified, the molten modified aldehyde ketone resin of alcohol and concentration be The ethanol solution of more than 95% is put into stirring in container by a certain percentage and is obtained the molten modified resin solution of alcohol, is subsequently adding chlorine vinegar tree Fat and concentration are the ethanol solution of more than 95%, are stirred, and are sequentially added into the dispersion of ethylene vinyl acetate copolymer under stirring Agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, until luminescent powder is dispersed in ink after adding luminescent powder In, reduce rotating speed and add emulsified silicone oil defoamer and nanometer alchlor wearproof emulsion, continue to stir to being thoroughly mixed, filter I.e. prepare finished product.
Embodiment 3:
The wear-resisting printing-ink of environmental protection noctilucence is respectively as follows: alcohol molten modified resin solution 30 parts, vinyl chloride-vinyl acetate resin 8 by mass fraction each component Part, luminescent powder 38 parts, concentration are the ethanol solution 30 parts of more than 95%, nanometer alchlor wearproof emulsion 15 parts, emulsified silicone oil disappear Infusion 1 part, ethylene vinyl acetate copolymer dispersant 1.5 parts, 1.5 parts of the molten antistatic additive of anionic alcohol;The molten modified resin of described alcohol Solution, according to the mass fraction, alcohol molten acrylic resin modified account for 18 parts, the molten modified aldehyde ketone resin of alcohol account for 15 parts, concentration be 95% with On ethanol solution account for 15 parts.
The preparation method of above-mentioned ink is as follows: by molten for alcohol acrylic resin modified, the molten modified aldehyde ketone resin of alcohol and concentration be The ethanol solution of more than 95% is put into stirring in container by a certain percentage and is obtained the molten modified resin solution of alcohol, is subsequently adding chlorine vinegar tree Fat and concentration are the ethanol solution of more than 95%, are stirred, and are sequentially added into the dispersion of ethylene vinyl acetate copolymer under stirring Agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, until luminescent powder is dispersed in ink after adding luminescent powder In, reduce rotating speed and add emulsified silicone oil defoamer and nanometer alchlor wearproof emulsion, continue to stir to being thoroughly mixed, filter I.e. prepare finished product.
Embodiment 4:
The wear-resisting printing-ink of environmental protection noctilucence is respectively as follows: alcohol molten modified resin solution 42 parts, vinyl chloride-vinyl acetate resin 8 by mass fraction each component Part, luminescent powder 25 parts, concentration are the ethanol solution 30 parts of more than 95%, nanometer alchlor wearproof emulsion 20 parts, emulsified silicone oil disappear Infusion 1 part, ethylene vinyl acetate copolymer dispersant 1.5 parts, 1.5 parts of the molten antistatic additive of anionic alcohol;The molten modified resin of described alcohol Solution, according to the mass fraction, alcohol molten acrylic resin modified account for 22 parts, the molten modified aldehyde ketone resin of alcohol account for 15 parts, concentration be 95% with On ethanol solution account for 10 parts.
The preparation method of above-mentioned ink is as follows: by molten for alcohol acrylic resin modified, the molten modified aldehyde ketone resin of alcohol and concentration be The ethanol solution of more than 95% is put into stirring in container by a certain percentage and is obtained the molten modified resin solution of alcohol, is subsequently adding chlorine vinegar tree Fat and concentration are the ethanol solution of more than 95%, are stirred, and are sequentially added into the dispersion of ethylene vinyl acetate copolymer under stirring Agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, until luminescent powder is dispersed in ink after adding luminescent powder In, reduce rotating speed and add emulsified silicone oil defoamer and nanometer alchlor wearproof emulsion, continue to stir to being thoroughly mixed, filter I.e. prepare finished product.
Embodiment 5:
The wear-resisting printing-ink of environmental protection noctilucence is respectively as follows: alcohol molten modified resin solution 30 parts, vinyl chloride-vinyl acetate resin 4 by mass fraction each component Part, luminescent powder 50 parts, concentration are the ethanol solution 45 parts of more than 95%, nanometer alchlor wearproof emulsion 15 parts, emulsified silicone oil disappear Infusion 1 part, ethylene vinyl acetate copolymer dispersant 1.5 parts, 1.5 parts of the molten antistatic additive of anionic alcohol;The molten modified resin of described alcohol Solution, according to the mass fraction, alcohol molten acrylic resin modified account for 18 parts, the molten modified aldehyde ketone resin of alcohol account for 20 parts, concentration be 95% with On ethanol solution account for 15 parts.
The preparation method of above-mentioned ink is as follows: by molten for alcohol acrylic resin modified, the molten modified aldehyde ketone resin of alcohol and concentration be The ethanol solution of more than 95% is put into stirring in container by a certain percentage and is obtained the molten modified resin solution of alcohol, is subsequently adding chlorine vinegar tree Fat and concentration are the ethanol solution of more than 95%, are stirred, and are sequentially added into the dispersion of ethylene vinyl acetate copolymer under stirring Agent, the molten antistatic additive of anionic alcohol and luminescent powder;Rotating speed is improved, until luminescent powder is dispersed in ink after adding luminescent powder In, reduce rotating speed and add emulsified silicone oil defoamer and nanometer alchlor wearproof emulsion, continue to stir to being thoroughly mixed, filter I.e. prepare finished product.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (7)

1. the wear-resisting printing-ink of environmental protection noctilucence, it is characterised in that be respectively as follows: the molten modified resin of alcohol by mass fraction each component Solution 22-42 part, vinyl chloride-vinyl acetate resin 4-10 part, luminescent powder 25-50 part, organic solvent 25-45 part, nanometer alchlor wearproof emulsion 5-20 part and function additive 2-8 part;The molten modified resin solution of described alcohol, according to the mass fraction, alcohol is molten acrylic resin modified to be accounted for The ethanol solution that 12-22 part, the molten modified aldehyde ketone resin of alcohol account for 10-20 part, concentration is more than 95% accounts for 10-20 part.
The wear-resisting printing-ink of environmental protection noctilucence the most according to claim 1, it is characterised in that described organic solvent is that concentration is The ethanol solution of more than 95%.
The wear-resisting printing-ink of environmental protection noctilucence the most according to claim 1, it is characterised in that described function additive includes froth breaking Agent, dispersant and antistatic additive.
The wear-resisting printing-ink of environmental protection noctilucence the most according to claim 3, it is characterised in that described defoamer is emulsified silicone oil Defoamer, mass fraction is 0.5-2 part.
The wear-resisting printing-ink of environmental protection noctilucence the most according to claim 3, it is characterised in that described dispersant is ethylene vinyl acetate Copolymer dispersant, mass fraction is 0.5-3 part.
The wear-resisting printing-ink of environmental protection noctilucence the most according to claim 3, it is characterised in that described antistatic additive is anion The molten antistatic additive of type alcohol, mass fraction is 1-3 part.
The wear-resisting printing-ink of environmental protection noctilucence the most according to claim 1, described luminescent powder is calcium sulfide, magnesium sulfate, sulfuration The mixture of potassium, barium nitrate and silver nitrate.
CN201610689263.7A 2016-08-19 2016-08-19 The wear-resisting printing-ink of environmental protection noctilucence Pending CN106221376A (en)

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CN201610689263.7A CN106221376A (en) 2016-08-19 2016-08-19 The wear-resisting printing-ink of environmental protection noctilucence

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955465A (en) * 2017-11-03 2018-04-24 苏州梅香雅筑工艺品有限公司 A kind of covering of the fan of the spontaneous light pattern of band
CN108166310A (en) * 2017-11-27 2018-06-15 苏州梅香雅筑工艺品有限公司 A kind of self-luminous covering of the fan
CN112143383A (en) * 2020-09-29 2020-12-29 昆山星脉特种绳带有限公司 Processing technology of wear-resistant isolation belt

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103740173A (en) * 2014-01-17 2014-04-23 苏州昭奇凯虹精细化工有限公司 Ink
CN103756403A (en) * 2014-01-23 2014-04-30 繁昌县朱氏印务有限责任公司 Luminous printing ink
CN103965682A (en) * 2014-04-16 2014-08-06 大亚科技股份有限公司 Environment-friendly water-based ink

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103740173A (en) * 2014-01-17 2014-04-23 苏州昭奇凯虹精细化工有限公司 Ink
CN103756403A (en) * 2014-01-23 2014-04-30 繁昌县朱氏印务有限责任公司 Luminous printing ink
CN103965682A (en) * 2014-04-16 2014-08-06 大亚科技股份有限公司 Environment-friendly water-based ink

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955465A (en) * 2017-11-03 2018-04-24 苏州梅香雅筑工艺品有限公司 A kind of covering of the fan of the spontaneous light pattern of band
CN108166310A (en) * 2017-11-27 2018-06-15 苏州梅香雅筑工艺品有限公司 A kind of self-luminous covering of the fan
CN112143383A (en) * 2020-09-29 2020-12-29 昆山星脉特种绳带有限公司 Processing technology of wear-resistant isolation belt

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