CN110016253A - A kind of PE//compound PE novel gravure composite inks for plastics and preparation method thereof - Google Patents
A kind of PE//compound PE novel gravure composite inks for plastics and preparation method thereof Download PDFInfo
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- CN110016253A CN110016253A CN201910393720.1A CN201910393720A CN110016253A CN 110016253 A CN110016253 A CN 110016253A CN 201910393720 A CN201910393720 A CN 201910393720A CN 110016253 A CN110016253 A CN 110016253A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of PE//compound PE novel gravure composite inks for plastics and preparation method thereof, the raw materials including following parts by weight: ethylene-vinyl acetate copolymer liquid；CLEVA liquid；Rosin modified phenolic resin liquid；Aldehyde ketone liquid；Squeeze multiple polypropylene dedicated liquid；Toner；Filler material；Ethyl acetate；Invention preparation process is simple, and the pattern that prepared product prints is smooth, smooth, fine and smooth, and printing effect is good, attachment fastness is strong, and it is non-ignitable, not quick-fried, printing effect is kept persistently, and ink film surface is smooth wrinkle resistant, printing is clear, in use, ink will not fall off, and rate of drying is fast, it adapts to use in printing ink area, improves properties of product.
Description
Technical field
The present invention relates to technical field of ink more particularly to a kind of PE//compound PE novel gravure composite inks for plastics and its
Preparation method.
Background technique
PE, Quan Mingwei polyethylene (Polyethylene) are the simplest macromolecular organic compound of structure, the world today
Most widely used high molecular material.With the continuous development of China's economy, PE film is applied more and more wider in all trades and professions
General, it has played our life very important important.Present PE//PE laminated film be widely used in glass, steel,
The industries such as electronic product, automobile, digital product are used as surface protection, can effectively prevent falling into for dust, and holding is protected
The cleaning of content is avoided losing during transportation, be abraded.
Conventional gravure plastic inner printing ink is produced with chlorinated polypropylene series plastics, and surface treated is mainly used in
BOPP film do the printing of composite packaging, contain a large amount of volatile organic solvent (accounting for about 50%) in ink.However
Toluene, butanone etc. have agent low boiling point, high volatilization, contain aromatic hydrocarbon, not only toxic but also inflammable, are the primary pollution source of environment.Tradition
Intaglio plate plastic inner printing ink is printed on PE film, because PE film is a kind of inert material, more difficult printing, after printing light resistance compared with
Difference, glossiness is poor, and adhesive force is also poor.Therefore, there is an urgent need to develop a kind of PE//compound PE novel gravure plastics compound oils
Ink is technology preparation to solve problem above.
Summary of the invention
It is of the invention that a kind of PE//compound PE novel gravure composite inks for plastics and preparation method thereof is provided.
The scheme of the invention is:
A kind of PE//compound PE novel gravure composite inks for plastics, the raw material including following parts by weight:
It is made of as a preferred technical solution, the raw material of following parts by weight:
The toner is rutile titanium white powder.
It is made of as a preferred technical solution, the raw material of following parts by weight:
The toner is environment-friendly type organic pigment.
The filler material is that calcium carbonate, bentonite, talcum powder etc. are one such or more as a preferred technical solution,
Kind, the calcium carbonate is calcene.
As a preferred technical solution, the ethylene-vinyl acetate copolymer liquid include ethylene-vinyl acetate copolymer with
The mass ratio of first solvent, the ethylene-vinyl acetate copolymer and the first solvent is 1:4, and first solvent includes ethyl ester
With n-propyl；
The CLEVA liquid includes CLEVA and the second solvent, and the mass ratio of the CLEVA and the second solvent is 1:4, described
Second solvent includes ethyl ester and n-propyl, and the CLEVA is ethylene-vinyl acetate copolymer, second used in the CLEVA liquid
The ethylene-vinyl acetate copolymer trade mark that alkene-acetate ethylene copolymer and the ethylene-vinyl acetate copolymer liquid use is not
Together；
The rosin modified phenolic resin liquid includes rosin modified phenolic resin and ethyl ester, the rosin modified phenolic resin
Mass ratio with ethyl ester is 1:1；
The polypropylene dedicated liquid again that squeezes includes squeezing multiple dedicated CPP resin and third solvent, the crowded multiple dedicated CPP resin
Mass ratio with third solvent is 1:4, and the third solvent includes ethyl ester and n-propyl；
The aldehyde ketone liquid includes CF120 aldehyde ketone and ethyl ester, and the mass ratio of the CF120 aldehyde ketone and ethyl ester is 1:1.
PE//compound PE novel gravure composite inks for plastics method, including following step are prepared the present invention also provides a kind of
It is rapid:
Step 1) respectively puts into ethylene-vinyl acetate copolymer in the first solvent, and blender stirs 120min,
CLEVA puts into the second solvent, and blender stirs 120min, and rosin modified phenolic resin puts into ethyl ester, and blender stirs 60min,
It squeezes multiple dedicated CPP resin and puts into third solution, blender stirs 60min, and CF120 aldehyde ketone puts into ethyl ester, blender stirring
60min after each liquid is uniformly dispersed, respectively obtains ethylene-vinyl acetate copolymer liquid, CLEVA liquid, rosin modified phenolic resin
Liquid squeezes multiple polypropylene dedicated liquid and aldehyde ketone liquid；
Step 2) takes step 1) in prepare 10%-20% parts by weight ethylene-vinyl acetate copolymer liquid, 10%-
The CLEVA liquid of 20% parts by weight, the rosin modified phenolic resin liquid of 4%-8% parts by weight are mixed with toner in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material made from step 2) is placed in sand mill by step 3), is ground at a temperature of 20-30 DEG C, when grinding
It is long fixed according to weight of material, mill base is prepared；
The crowded of the 15%-20% parts by weight prepared in step 1) is answered polypropylene dedicated liquid, 5%-8% parts by weight by step 4)
Aldehyde ketone liquid, the filler material after sand mill is sanded and ethyl acetate put into mill base, it is high at a temperature of 20-30 DEG C
Speed dispersion 30min is deployed into ink.
Blender revolving speed is 1000r/min in the step 1 as a preferred technical solution,.
First solution includes ethyl ester and n-propyl as a preferred technical solution, and second solution includes ethyl ester
With n-propyl, the third solution includes ethyl ester and n-propyl.
As a preferred technical solution, in the step 2 15%-25% parts by weight toner, the toner be rutile
Titanium dioxide；The filler material of 10%-15% parts by weight and the ethyl acetate of 15%-22% parts by weight put into color in the step 4
In slurry.
As a preferred technical solution, in the step 2 5%-8% parts by weight toner, the toner has for environment-friendly type
Machine pigment；The filler material of 5%-15% parts by weight and the ethyl acetate of 25%-35% parts by weight put into mill base in the step 4
In the middle.
By adopting the above-described technical solution, a kind of PE//compound PE novel gravure composite inks for plastics and its preparation side
Method, step 1) respectively put into ethylene-vinyl acetate copolymer in the first solvent, and blender stirs 120min, CLEVA investment
Second solvent, blender stir 120min, and rosin modified phenolic resin puts into ethyl ester, and blender stirs 60min, squeeze multiple dedicated
CPP resin puts into third solution, and blender stirs 60min, and CF120 aldehyde ketone puts into ethyl ester, and blender stirs 60min, each liquid
After being uniformly dispersed, respectively obtain ethylene-vinyl acetate copolymer liquid, CLEVA liquid, rosin modified phenolic resin liquid, squeeze it is multiple dedicated
Polypropylene liquid and aldehyde ketone liquid；Step 2) takes step 1) in prepare 10%-20% parts by weight ethylene-vinyl acetate copolymer
Liquid, the CLEVA liquid of 10%-20% parts by weight, 4%-8% parts by weight rosin modified phenolic resin liquid mixed with toner investment extremely
Be mixed in blender, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, system
Obtain mixed material；Mixed material made from step 2) is placed in sand mill by step 3), is ground, is ground at a temperature of 20-30 DEG C
It is fixed according to weight of material to grind duration, mill base is prepared；Step 4) is crowded multiple by the 15%-20% parts by weight prepared in step 1)
Polypropylene dedicated liquid, the aldehyde ketone liquid of 5%-8% parts by weight, the filler material after sand mill is sanded and ethyl acetate are put into
In mill base, high speed dispersion 30min is deployed into ink at a temperature of 20-30 DEG C.
Advantages of the present invention:
Firstly, key point preparation process of the invention is simple, the pattern that prepared product prints is smooth, it is smooth,
Exquisiteness, printing effect is good, and attachment fastness is strong, and non-ignitable, not quick-fried, and printing effect is kept persistently, and ink film surface is smooth wrinkle resistant, print
Brush is clear, and in use, ink will not fall off, and rate of drying is fast, adapts to use in printing ink area, improve
Properties of product, solvent is single in formula, and cost is low compared with traditional ink, and economic effect is obvious, is suitable for being widely used for market；
Secondly, the present invention can enhance the flexibility of PE film rich in caoutchouc elasticity, isolation wet steam can also be played, protects PE
Film extends the effect of storage period.It reduces costs, reduces cure shrinkage, improve peel strength.
Also, present invention employs rosin modified phenolic resin liquid.Rosin modified phenolic resin has the hard, gloss that forms a film
The feature that degree is high, light resistance is good, since it has a good ester dissolubility, viscosity is low, quick-drying and good water resistance, especially suitable
Close production gravure printing ink；Ink of the present invention made from rosin modified phenolic resin liquid has the characteristics that fast drying, brightness are high,
It can satisfy the requirement of high speed printing.
Moreover, the present invention uses filler.Filler is the substance that can be dispersed in binder, filler pigment part
Filler can reduce amount of pigment, reduce cost, and economic benefit is obvious, can also adjust the property of ink, such as mobility.This hair
The filler of bright selection is mainly calcene, and calcene is mainly characterized by fine particles, and specific surface area is larger, has
The advantages that oil absorption is big, transparency is good, stability is preferable.The calcene that the present invention uses in the ink product for showing
Excellent dispersibility, the transparency, fabulous gloss and covering power and excellent ink absorption and drying property out, therefore print
Product are fine and smooth, site is complete.
Present invention employs aldehyde ketone resin, aldehyde ketone resin is that one kind has high brightness, sunproof neutral, non-saponified type ring
Hexanone --- formaldehyde resin.Since this resin is free of ester bond in the structure, thus there is preferable water resistance, containing very on major key
More cyclohexyl, makes it have heat resistance.Aldehyde ketone resin and the ratio of solvent are 1:1, and the solid part for substantially increasing ink contains
Amount.In addition, the polarity of ketone groups and hydroxyl groups makes it have extensive dissolubility intermiscibility, water removal and petroleum ether/rouge can be dissolved in
Nearly all organic solvent outside fat hydrogen.Aldehyde ketone resin and various resin compatibles are preferable, for significantly improving in the system
Glossiness, adhesive force, levelability, quick-drying etc..With good pigment wettability and adhesive force.Therefore, aldehyde ketone resin both may be used
It is compatible with the biggish compound of polarity, and can be compatible with the lesser compound of polarity, for improving the quick-drying, light of this ink
Pool, adhesive force, mobility, the wetability of pigment and amount of solid content etc. have splendid effect.
Specific embodiment
In order to make up the above deficiency, the present invention provides a kind of PE//compound PE novel gravure composite inks for plastics and its systems
Preparation Method is to solve the problems in above-mentioned background technique.
A kind of PE//compound PE novel gravure composite inks for plastics, the raw material including following parts by weight:
It is made of the raw material of following parts by weight:
The toner is rutile titanium white powder.
It is made of the raw material of following parts by weight:
The toner is environment-friendly type organic pigment.
The filler material is that calcium carbonate, bentonite, talcum powder etc. are one such or a variety of, and the calcium carbonate is colloid carbon
Sour calcium.
The ethylene-vinyl acetate copolymer liquid includes ethylene-vinyl acetate copolymer and the first solvent, the ethylene-
The mass ratio of acetate ethylene copolymer and the first solvent is 1:4, and first solvent includes ethyl ester and n-propyl；
The CLEVA liquid includes CLEVA and the second solvent, and the mass ratio of the CLEVA and the second solvent is 1:4, described
Second solvent includes ethyl ester and n-propyl；
The rosin modified phenolic resin liquid includes rosin modified phenolic resin and ethyl ester, the rosin modified phenolic resin
Mass ratio with ethyl ester is 1:1；
The polypropylene dedicated liquid again that squeezes includes squeezing multiple dedicated CPP resin and third solvent, the crowded multiple dedicated CPP resin
Mass ratio with third solvent is 1:4, and the third solvent includes ethyl ester and n-propyl；
The aldehyde ketone liquid includes CF120 aldehyde ketone and ethyl ester, and the mass ratio of the CF120 aldehyde ketone and ethyl ester is 1:1.
PE//compound PE novel gravure composite inks for plastics method, including following step are prepared the present invention also provides a kind of
It is rapid:
Step 1) respectively puts into ethylene-vinyl acetate copolymer in the first solvent, and blender stirs 120min,
CLEVA puts into the second solvent, and blender stirs 120min, and rosin modified phenolic resin puts into ethyl ester, and blender stirs 60min,
It squeezes multiple dedicated CPP resin and puts into third solution, blender stirs 60min, and CF120 aldehyde ketone puts into ethyl ester, blender stirring
60min after each liquid is uniformly dispersed, respectively obtains ethylene-vinyl acetate copolymer liquid, CLEVA liquid, rosin modified phenolic resin
Liquid squeezes multiple polypropylene dedicated liquid and aldehyde ketone liquid；
Step 2) takes step 1) in prepare 10%-20% parts by weight ethylene-vinyl acetate copolymer liquid, 10%-
The CLEVA liquid of 20% parts by weight, the rosin modified phenolic resin liquid of 4%-8% parts by weight are mixed with toner in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material made from step 2) is placed in sand mill by step 3), is ground at a temperature of 20-30 DEG C, when grinding
It is long fixed according to weight of material, mill base is prepared；
The crowded of the 15%-20% parts by weight prepared in step 1) is answered polypropylene dedicated liquid, 5%-8% parts by weight by step 4)
Aldehyde ketone liquid, the filler material after sand mill is sanded and ethyl acetate put into mill base, it is high at a temperature of 20-30 DEG C
Speed dispersion 30min is deployed into ink.
Blender revolving speed is 1000r/min in the step 1.
First solution includes ethyl ester and n-propyl, and second solution includes ethyl ester and n-propyl, and the third is molten
Liquid includes ethyl ester and n-propyl.
The toner of 15%-25% parts by weight in the step 2, the toner are rutile titanium white powder；In the step 4
The filler material of 10%-15% parts by weight and the ethyl acetate of 15%-22% parts by weight are put into mill base.
The toner of 5%-8% parts by weight in the step 2, the toner are environment-friendly type organic pigment；In the step 4
The filler material of 5%-15% parts by weight and the ethyl acetate of 25%-35% parts by weight are put into mill base.
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1:
It is as follows to dissolve formula rate table
A, B, C, D component preparation process are identical, hard resin are put into ethyl ester, n-propyl is mixed to dissolve by upper table and is formulated
Than preparing, blender be arranged revolving speed be 1000r/min, be uniformly dispersed, be made ethylene-vinyl acetate copolymer liquid, CLEVA liquid,
Rosin modified phenolic resin liquid squeezes multiple polypropylene dedicated liquid and aldehyde ketone liquid.Resin solvent in conventional gravure composite inks for plastics
It is benzene, ketone, is all replaced now by esters solvent.
Embodiment 2:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight prepared in Example 1,10% parts by weight
Liquid, the rosin modified phenolic resin liquid of 4% parts by weight are mixed with the rutile titanium white powder of 15% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
By the crowded multiple polypropylene dedicated liquid of 15% parts by weight prepared in embodiment 1, the aldehyde ketone liquid and sand of 5% parts by weight
The filler material of 10% parts by weight and the ethyl acetate of 15% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 3:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 20% parts by weight prepared in Example 1,20% parts by weight
Liquid, the rosin modified phenolic resin liquid of 8% parts by weight are mixed with the rutile titanium white powder of 25% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 20% parts by weight prepared in Example 1
The filler material of 15% parts by weight and the ethyl acetate of 22% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 4:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight prepared in Example 1,10% parts by weight
Liquid, the rosin modified phenolic resin liquid of 6% parts by weight are mixed with the rutile titanium white powder of 20% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 6% parts by weight of 18% parts by weight prepared in Example 1
The filler material of 15% parts by weight and the ethyl acetate of 15% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 5:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight prepared in Example 1,12% parts by weight
Liquid, the rosin modified phenolic resin liquid of 5% parts by weight are mixed with the rutile titanium white powder of 18% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 6% parts by weight of 18% parts by weight prepared in Example 1
The filler material of 18% parts by weight and the ethyl acetate of 15% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 6:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight prepared in Example 1,10% parts by weight
Liquid, the rosin modified phenolic resin liquid of 5% parts by weight are mixed with the rutile titanium white powder of 18% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 6% parts by weight of 16% parts by weight prepared in Example 1
The filler material of 18% parts by weight and the ethyl acetate of 15% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 7:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 12% parts by weight prepared in Example 1,10% parts by weight
Liquid, the rosin modified phenolic resin liquid of 5% parts by weight are mixed with the rutile titanium white powder of 18% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 6% parts by weight of 16% parts by weight prepared in Example 1
The filler material of 18% parts by weight and the ethyl acetate of 15% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 8:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 12% parts by weight prepared in Example 1,10% parts by weight
Liquid, the rosin modified phenolic resin liquid of 5% parts by weight are mixed with the rutile titanium white powder of 20% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 6% parts by weight of 16% parts by weight prepared in Example 1
The filler material of 15% parts by weight and the ethyl acetate of 15% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 9:
The CLEVA of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight prepared in Example 1,12% parts by weight
Liquid, the rosin modified phenolic resin liquid of 4% parts by weight are mixed with the rutile titanium white powder of 18% parts by weight in investment to blender
Be mixed, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 5% parts by weight of 18% parts by weight prepared in Example 1
The filler material of 15% parts by weight and the ethyl acetate of 18% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 10:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight, 10% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 4% parts by weight mixed with the environment-friendly type organic pigment of 5% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 5% parts by weight of 15% parts by weight prepared by Example 1
The filler material of 5% parts by weight and the ethyl acetate of 25% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
Embodiment 11:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 20% parts by weight, 20% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 8% parts by weight mixed with the environment-friendly type organic pigment of 8% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 20% parts by weight prepared by Example 1
The filler material of 15% parts by weight and the ethyl acetate of 35% parts by weight after grinding machine sand milling are put into mill base, at 20-30 DEG C
At a temperature of high speed dispersion 30min be deployed into ink.
Embodiment 12:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 15% parts by weight, 12% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 4% parts by weight mixed with the environment-friendly type organic pigment of 8% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 18% parts by weight prepared by Example 1
The filler material of 7% parts by weight and the ethyl acetate of 28% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
Embodiment 13:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight, 17% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 4% parts by weight mixed with the environment-friendly type organic pigment of 8% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 18% parts by weight prepared by Example 1
The filler material of 7% parts by weight and the ethyl acetate of 33% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
Embodiment 14:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 12% parts by weight, 17% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 6% parts by weight mixed with the environment-friendly type organic pigment of 8% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 16% parts by weight prepared by Example 1
The filler material of 7% parts by weight and the ethyl acetate of 26% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
Embodiment 15:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 10% parts by weight, 16% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 6% parts by weight mixed with the environment-friendly type organic pigment of 6% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 18% parts by weight prepared by Example 1
The filler material of 8% parts by weight and the ethyl acetate of 33% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
Embodiment 16:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 18% parts by weight, 10% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 6% parts by weight mixed with the environment-friendly type organic pigment of 7% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 17% parts by weight prepared by Example 1
The filler material of 8% parts by weight and the ethyl acetate of 26% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
Embodiment 17:
The CLEVA liquid of the ethylene-vinyl acetate copolymer liquid of 16% parts by weight, 12% parts by weight prepared by Example 1,
The rosin modified phenolic resin liquid of 5% parts by weight mixed with the environment-friendly type organic pigment of 8% parts by weight investment in blender into
Row is mixed, and whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixture is made
Material；
Mixed material obtained is placed in sand mill, is ground at a temperature of 20-30 DEG C, grinds duration according to weight of material
It is fixed, mill base is prepared；
The crowded aldehyde ketone liquid and sand for answering polypropylene dedicated liquid, 8% parts by weight of 17% parts by weight prepared by Example 1
The filler material of 7% parts by weight and the ethyl acetate of 27% parts by weight after grinding machine sand milling are put into mill base, in 20-30 DEG C of temperature
It spends lower high speed dispersion 30min and is deployed into ink.
The above shows and describes the basic principle, main features and advantages of the invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent circle.
Claims (10)
1. a kind of PE//compound PE novel gravure composite inks for plastics, which is characterized in that the raw material including following parts by weight:
Toner；
Filler material；
Ethyl acetate.
2. a kind of PE//compound PE novel gravure composite inks for plastics as described in claim 1, feature exists, by following weight
The raw material composition of part:
The toner is rutile titanium white powder.
3. a kind of PE//compound PE novel gravure composite inks for plastics as described in claim 1, feature exists, by following weight
The raw material composition of part:
The toner is environment-friendly type organic pigment.
4. a kind of PE//compound PE novel gravure composite inks for plastics as described in claim 1,2,3, feature exist: described to fill out
Charge is that calcium carbonate, bentonite, talcum powder etc. are one such or a variety of, and the calcium carbonate is calcene.
5. a kind of PE//compound PE novel gravure composite inks for plastics as described in claim 1,2,3, feature exist:
The ethylene-vinyl acetate copolymer liquid includes ethylene-vinyl acetate copolymer and the first solvent, the ethyl vinyl acetate
The mass ratio of ethylene copolymer and the first solvent is 1:4, and first solvent includes ethyl ester and n-propyl；
The CLEVA liquid includes CLEVA and the second solvent, and the mass ratio of the CLEVA and the second solvent is 1:4, and described second
Solvent includes ethyl ester and n-propyl, and the CLEVA is ethylene-vinyl acetate copolymer；
The rosin modified phenolic resin liquid includes rosin modified phenolic resin and ethyl ester, the rosin modified phenolic resin and second
The mass ratio of ester is 1:1；
Described to squeeze multiple polypropylene dedicated liquid include squeezing multiple dedicated CPP resin and third solvent, described to squeeze multiple dedicated CPP resin and the
The mass ratio of three solvents is 1:4, and the third solvent includes ethyl ester and n-propyl；
The aldehyde ketone liquid includes CF120 aldehyde ketone and ethyl ester, and the mass ratio of the CF120 aldehyde ketone and ethyl ester is 1:1.
6. a kind of prepare PE/ as described in claims 1 to 3/compound PE novel gravure composite inks for plastics method, feature exists
In, including the following steps:
Step 1) respectively puts into ethylene-vinyl acetate copolymer in the first solvent, and blender stirs 120min, and CLEVA is thrown
Enter the second solvent, blender stirs 120min, and rosin modified phenolic resin puts into ethyl ester, and blender stirs 60min, squeezes multiple dedicated
CPP resin puts into third solution, and blender stirs 60min, and CF120 aldehyde ketone puts into ethyl ester, and blender stirs 60min, each liquid
After being uniformly dispersed, respectively obtain ethylene-vinyl acetate copolymer liquid, CLEVA liquid, rosin modified phenolic resin liquid, squeeze it is multiple dedicated
Polypropylene liquid and aldehyde ketone liquid；
Step 2) takes step 1) in prepare 10%-20% parts by weight ethylene-vinyl acetate copolymer liquid, 10%-20% weight
The rosin modified phenolic resin liquid of the CLEVA liquid, 4%-8% parts by weight of measuring part is mixed with toner to be mixed in investment to blender
Close stirring, whipping temp is 20-30 DEG C, rate of dispersion 1000r/min, when stirring a length of 30min, mixed material is made；
Mixed material made from step 2) is placed in sand mill by step 3), is ground at a temperature of 20-30 DEG C, and duration root is ground
It is fixed according to weight of material, mill base is prepared；
Step 4) is by the crowded multiple polypropylene dedicated liquid of the 15%-20% parts by weight prepared in step 1), the aldehyde of 5%-8% parts by weight
Ketone liquid, the filler material after sand mill is sanded and ethyl acetate are put into mill base, are divided at a high speed at a temperature of 20-30 DEG C
Scattered 30min is deployed into ink.
7. a kind of preparation method of PE//compound PE novel gravure composite inks for plastics as claimed in claim 6, feature exist
In: blender revolving speed is 1000r/min in the step 1.
8. a kind of preparation method of PE//compound PE novel gravure composite inks for plastics as claimed in claim 6, feature exist
In: first solution includes ethyl ester and n-propyl, and second solution includes ethyl ester and n-propyl, and the third solution includes
Ethyl ester and n-propyl.
9. a kind of preparation method of PE//compound PE novel gravure composite inks for plastics as claimed in claim 6, feature exist
In: the toner of 15%-25% parts by weight in the step 2, the toner are rutile titanium white powder；10%- in the step 4
The filler material of 15% parts by weight and the ethyl acetate of 15%-22% parts by weight are put into mill base.
10. a kind of preparation method of PE//compound PE novel gravure composite inks for plastics as claimed in claim 6, feature exist
In: the toner of 5%-8% parts by weight in the step 2, the toner are environment-friendly type organic pigment；5%- in the step 4
The filler material of 15% parts by weight and the ethyl acetate of 25%-35% parts by weight are put into mill base.
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Cited By (1)
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| CN115710449A (en) * | 2022-11-30 | 2023-02-24 | 江苏扬瑞新材料有限公司 | Amino-resin-free aqueous internal spray coating and preparation method thereof |
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