CN108342125A - A kind of control method and printing ink of printing ink - Google Patents
A kind of control method and printing ink of printing ink Download PDFInfo
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- CN108342125A CN108342125A CN201810138794.6A CN201810138794A CN108342125A CN 108342125 A CN108342125 A CN 108342125A CN 201810138794 A CN201810138794 A CN 201810138794A CN 108342125 A CN108342125 A CN 108342125A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
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- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of control method of printing ink and printing ink, are related to ink-printing techniques field, which includes following raw material：Water-soluble saturated polyester resin, modified terpene resin, modified complex emulsions, laruyl alcohol oleate, isopropanol, bauxite, titanium dioxide, talcum powder, hindered phenol, 2-Butoxyethyl acetate, dibutyl maleate, dispersant, initiator, crosslinking agent and plasticizer.The printing ink of the present invention prepares it is simple and convenient, it is environmentally protective, have the characteristics that adhesive force greatly, high temperature resistant, glossiness height, scratch-resistant, waterproof are sun-proof and chemical-resistant reagent corrodes, service life is long, is widely used.
Description
Technical field
The present invention relates to ink-printing techniques fields, and in particular to a kind of control method and printing ink of printing ink.
Background technology
Currently, there are two types of most commonly used food packaging gravure printing inks：One is polyamide (PA) resins to be
The flexible package ink of binder, such ink are using benzene class as primary solvent；It is connection that another kind, which is with polyurethane resin,
The compound oil ink of material, such as more dual-component polyurethane compound oil ink is applied at present, host agent component A is the poly- ammonia of hydroxyl
Ester oil ink, curing agent B is the polyurethane oligomer containing isocyanate groups, since component A is needed through its polyurethane molecular chain
Institute is hydroxyl to react with B component, so if containing hydroxyl solvent (alcohols or water) in system, can significantly affect solidification
Effect, so component A ink is usually using the higher benzene class of toxicity or ketones solvent, and the isocyanate groups in component B
Make it have prodigious toxicity.Above two ink solvent for use all has larger irritation and toxicity, not only for environment
Strong influence is caused, but also huge threat is generated for the health and safety of human body, and easy tos produce dissolvent residual；Separately
Outside, two kinds of ink high temperature resistance when being handled through heat-sealing or other high-temperature technologies is bad, causes ink adhesion that can reduce, reaches
Less than corresponding technology requirement in the market.
Invention content
For problems of the prior art, the present invention provides a kind of control methods and off-set oil of printing ink
Ink, this kind printing ink prepare simple and convenient, environmentally protective, big, high temperature resistant, glossiness height, scratch-resistant, waterproof with adhesive force
The features such as sun-proof and chemical-resistant reagent corrodes, service life is long, is widely used.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of printing ink, including the following raw material counted in parts by weight：Water-soluble saturated polyester resin 20-30 parts, change
Property 15-25 parts of terpene resin, modified 20-30 parts of complex emulsions, 3-5 parts of laruyl alcohol oleate, 8-12 parts of isopropanol, bauxite 4-
6 parts, 8-10 parts of titanium dioxide, 3-5 parts of talcum powder, 1-2 parts of hindered phenol, 4-8 parts of 2-Butoxyethyl acetate, dibutyl maleate 1-
1-3 parts of 3 parts, 5-7 parts of dispersant, 1-3 parts of initiator, 2-4 parts of crosslinking agent and plasticizer；
Above-mentioned modified terpene resin is dissolved made of terpene resin solid polyadipate hexylene glycol ester and normal propyl alcohol,
Three's mass ratio is terpene resin:Polyadipate hexylene glycol ester:Normal propyl alcohol=5:1:2；
Above-mentioned modification complex emulsions are made by following steps：
(1) the following ingredient counted in parts by weight is taken：6-8 parts of methyl methacrylate, 3-5 parts of butyl acrylate, methyl
2-3 parts of acrylic acid, 1-2 parts of nano silicon dioxide, 0.4-0.6 parts of hydroxypropyl methyl cellulose, 0.8-1.2 parts of Lignosite,
7-9 parts of 1-2 parts of alkyl phenol polyoxyethylene ether, 1-1.5 parts of calcium hydroxide and deionized water；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and one
The deionized water of half amount is added in container, is heated to 40-50 DEG C, magnetic agitation 70-80min, then with ultrasonic wave decentralized processing
30-35min obtains batch mixing A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, nitrogen atmosphere condition
Lower addition alkyl phenol polyoxyethylene ether stirs 10-15min, and whipping temp is 70-80 DEG C, mixing speed 300-500r/min,
Obtain mixed material B；
(4) the batch mixing A and mixed material B being added in reaction vessel, heating water bath stirs 40-50min to 60-70 DEG C,
Speed of agitator is not less than 800r/min, and stirring terminates to obtain the final product.
Further, above-mentioned printing ink includes the following raw material counted in parts by weight：Water-soluble saturated polyester resin
25 parts, 20 parts of modified terpene resin, modified 25 parts of complex emulsions, 4 parts of laruyl alcohol oleate, 10 parts of isopropanol, 5 parts of bauxite,
9 parts of titanium dioxide, 4 parts of talcum powder, 1.5 parts of hindered phenol, 6 parts of 2-Butoxyethyl acetate, 2 parts of dibutyl maleate, dispersant 6
Part, 2 parts of initiator, 3 parts of crosslinking agent and 2 parts of plasticizer.
Further, above-mentioned modification complex emulsions are made by following steps：
(1) the following ingredient counted in parts by weight is taken：7 parts of methyl methacrylate, 4 parts of butyl acrylate, metering system
2.5 parts of acid, 1.5 parts of nano silicon dioxide, 0.5 part of hydroxypropyl methyl cellulose, 1 part of Lignosite, alkylphenol-polyethenoxy
8 parts of 1.5 parts of ether, 1.25 parts of calcium hydroxide and deionized water；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and one
The deionized water of half amount is added in container, is heated to 45 DEG C, magnetic agitation 75min, then with ultrasonic wave decentralized processing 32min,
Obtain batch mixing A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, nitrogen atmosphere condition
Lower addition alkyl phenol polyoxyethylene ether stirs 12min, and whipping temp is 75 DEG C, and mixing speed 400r/min obtains mixed material B；
(4) the batch mixing A and mixed material B are added in reaction vessel, heating water bath stirs 45min to 65 DEG C, and stirring turns
Speed is 1000r/min, and stirring terminates to obtain the final product.
Preferably, above-mentioned dispersant uses polyacrylamide or lauryl sodium sulfate.
Preferably, above-mentioned initiator uses ammonium persulfate or potassium peroxydisulfate.
Preferably, above-mentioned crosslinking agent is using any one of pentaerythrite, dipentaerythritol or trimethylolpropane.
Preferably, above-mentioned plasticizer uses methyl pentachlorostearate or chlorinated paraffin.
The preparation method of above-mentioned printing ink is that 4-5h, speed of agitator will be dispersed with stirring in all feedstock transportations to a mixing bowl
For 300-500r/min, whipping temp is 42-46 DEG C, material is delivered in colloid mill equipment later, grinding material to fineness
Less than or equal to 20 μm.
A kind of control method of above-mentioned printing ink, includes the following steps：
Step 1：Print speed printing speed is adjusted according to ink viscosity；
Step 2：The printing ink is using silk screen come Plate making printing；
Step 3：Using white substrate or it is printed directly on white or light-colored base material；
Step 4：Printing ink layer thickness should be at 100 μm or more；
Step 5：By the way of chromaticity printing；
Step 6：During printing, whole system keeps drying；
Step 7：Luminous printing ink is sealed using preceding stirring evenly after, is stored at shady and cool drying；
In above-mentioned step 1, ink viscosity and print speed printing speed are inversely；In step 2, meshcount 90-110；
In step 4, printing ink layer thickness should be maintained at 120 ± 10 μm；In step 7, before use, heating ink temperature is to 52 ± 2 DEG C.
The present invention has following advantageous effect：
(1) printing ink of the invention is prepared simple and convenient, and raw material availability is high, and toxic, irritation object is free of in ingredient
Matter, it is environmentally protective, it will not cause damages to human body and environment, suitable for industrialized production, be worthy of popularization；
(2) printing ink of the invention is big to the adhesive force of stock, and rate of drying is fast, the glossiness of ink after printing
Height, smooth surface have the characteristics that scratch-resistant, waterproof are sun-proof and chemical-resistant reagent corrodes, after long-time use, are not easy to fade；
(3) printing ink good heat stability of the invention, high temperature resistant, envelope heat do not fade, and flame retardant property is good, using wide
It is general；
(4) control method of printing ink of the invention can improve the attachment stability of ink on the substrate, extend
Service life.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of printing ink, weighs following raw material：Water-soluble saturated polyester resin 20kg, modified terpene resin 15kg, change
Property complex emulsions 20kg, laruyl alcohol oleate 3kg, isopropanol 8kg, bauxite 4kg, titanium dioxide 8kg, talcum powder 3kg, hindered phenol
1kg, 2-Butoxyethyl acetate 4kg, dibutyl maleate 1kg, polyacrylamide amine dispersant 5kg, ammonium persulfate initiator
1kg, pentaerythrite crosslinking agent 2kg and methyl pentachlorostearate plasticizer 1kg；
Above-mentioned modified terpene resin is dissolved made of terpene resin solid polyadipate hexylene glycol ester and normal propyl alcohol,
Three's mass ratio is terpene resin:Polyadipate hexylene glycol ester:Normal propyl alcohol=5:1:2；
Above-mentioned modification complex emulsions are made by following steps：
(1) following component is taken：Methyl methacrylate 6kg, butyl acrylate 3kg, methacrylic acid 2kg, nano-silica
SiClx 1kg, hydroxypropyl methyl cellulose 0.4kg, Lignosite 0.8kg, alkyl phenol polyoxyethylene ether 1kg, calcium hydroxide 1kg
With deionized water 7kg；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and one
The deionized water of half amount is added in container, is heated to 40 DEG C, magnetic agitation 70min, then with ultrasonic wave decentralized processing 30min,
Obtain batch mixing A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, nitrogen atmosphere condition
Lower addition alkyl phenol polyoxyethylene ether stirs 10min, and whipping temp is 70 DEG C, and mixing speed 300r/min obtains mixed material B；
(4) the batch mixing A and mixed material B are added in reaction vessel, heating water bath stirs 40min to 60 DEG C, and stirring turns
Speed is 800r/min, and stirring terminates to obtain the final product.
Print the preparation of ink：It will be dispersed with stirring 4h, speed of agitator in the above-mentioned all feedstock transportations to a mixing bowl weighed
For 300r/min, whipping temp is 42 DEG C, material is delivered in colloid mill equipment later, grinding material to fineness is less than or equal to
20 μm.
A kind of control method of above-mentioned printing ink, includes the following steps：
Step 1：Print speed printing speed is adjusted according to ink viscosity, and ink viscosity and print speed printing speed are inversely；
Step 2：The printing ink is using the silk screen of 90 mesh come Plate making printing；
Step 3：Use white substrate；
Step 4：Printing ink layer thickness should be maintained at 110 μm；
Step 5：By the way of chromaticity printing；
Step 6：During printing, whole system keeps drying；
Step 7：Luminous printing ink heats ink temperature to 50 DEG C using preceding stirring evenly, and is sealed after, is stored in cool place
At dry.
Embodiment 2
A kind of printing ink, weighs following raw material：Water-soluble saturated polyester resin 25kg, modified terpene resin 20kg, change
Property complex emulsions 25kg, it laruyl alcohol oleate 4kg, isopropanol 10kg, bauxite 5kg, titanium dioxide 9kg, talcum powder 4kg, is obstructed
Phenol 1.5kg, 2-Butoxyethyl acetate 6kg, dibutyl maleate 2kg, lauryl sodium sulfate dispersant 6kg, potassium peroxydisulfate
Initiator 2kg, dipentaerythritol crosslinking agent 3kg and chlorinated paraffin plasticizer 2kg；
Above-mentioned modified terpene resin is dissolved made of terpene resin solid polyadipate hexylene glycol ester and normal propyl alcohol,
Three's mass ratio is terpene resin:Polyadipate hexylene glycol ester:Normal propyl alcohol=5:1:2；
Above-mentioned modification complex emulsions are made by following steps：
(1) following component is taken：Methyl methacrylate 7kg, butyl acrylate 4kg, methacrylic acid 2.5kg, nanometer two
Silica 1.5kg, hydroxypropyl methyl cellulose 0.5kg, Lignosite 1kg, alkyl phenol polyoxyethylene ether 1.5kg, hydroxide
Calcium 1.25kg and deionized water 8kg；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and one
The deionized water of half amount is added in container, is heated to 45 DEG C, magnetic agitation 75min, then with ultrasonic wave decentralized processing 32min,
Obtain batch mixing A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, nitrogen atmosphere condition
Lower addition alkyl phenol polyoxyethylene ether stirs 12min, and whipping temp is 75 DEG C, and mixing speed 400r/min obtains mixed material B；
(4) the batch mixing A and mixed material B are added in reaction vessel, heating water bath stirs 45min to 65 DEG C, and stirring turns
Speed is 1000r/min, and stirring terminates to obtain the final product.
Print the preparation of ink：4.5h will be dispersed with stirring in the above-mentioned all feedstock transportations to a mixing bowl weighed, stirring turns
Speed is 400r/min, and whipping temp is 44 DEG C, and material is delivered in colloid mill equipment later, and grinding material to fineness is less than etc.
In 20 μm.
A kind of control method of above-mentioned printing ink, includes the following steps：
Step 1：Print speed printing speed is adjusted according to ink viscosity, and ink viscosity and print speed printing speed are inversely；
Step 2：The printing ink is using the silk screen of 100 mesh come Plate making printing；
Step 3：It is printed directly in white substrate；
Step 4：Printing ink layer thickness should be maintained at 120 μm；
Step 5：By the way of chromaticity printing；
Step 6：During printing, whole system keeps drying；
Step 7：Luminous printing ink heats ink temperature to 52 DEG C using preceding stirring evenly, and is sealed after, is stored in cool place
At dry.
Embodiment 3
A kind of printing ink, weighs following raw material：Water-soluble saturated polyester resin 30kg, modified terpene resin 25kg, change
Property complex emulsions 30kg, it laruyl alcohol oleate 5kg, isopropanol 12kg, bauxite 6kg, titanium dioxide 10kg, talcum powder 5kg, is obstructed
Phenol 2kg, 2-Butoxyethyl acetate 8kg, dibutyl maleate 3kg, polyacrylamide amine dispersant 7kg, ammonium persulfate initiator
3kg, trimethylolpropane crosslinking agent 4kg and methyl pentachlorostearate plasticizer 3kg；
Above-mentioned modified terpene resin is dissolved made of terpene resin solid polyadipate hexylene glycol ester and normal propyl alcohol,
Three's mass ratio is terpene resin:Polyadipate hexylene glycol ester:Normal propyl alcohol=5:1:2；
Above-mentioned modification complex emulsions are made by following steps：
(1) following component is taken：Methyl methacrylate 8kg, butyl acrylate 5kg, methacrylic acid 3kg, nano-silica
SiClx 2kg, hydroxypropyl methyl cellulose 0.6kg, Lignosite 1.2kg, alkyl phenol polyoxyethylene ether 2kg, calcium hydroxide
1.5kg and deionized water 9kg；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and one
The deionized water of half amount is added in container, is heated to 50 DEG C, magnetic agitation 80min, then with ultrasonic wave decentralized processing 35min,
Obtain batch mixing A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, nitrogen atmosphere condition
Lower addition alkyl phenol polyoxyethylene ether stirs 15min, and whipping temp is 80 DEG C, and mixing speed 500r/min obtains mixed material B；
(4) the batch mixing A and mixed material B are added in reaction vessel, heating water bath stirs 50min to 70 DEG C, and stirring turns
Speed is set as 800r/min, and stirring terminates to obtain the final product.
Print the preparation of ink：It will be dispersed with stirring 5h, speed of agitator in the above-mentioned all feedstock transportations to a mixing bowl weighed
For 500r/min, whipping temp is 46 DEG C, material is delivered in colloid mill equipment later, grinding material to fineness is less than or equal to
20 μm.
A kind of control method of above-mentioned printing ink, includes the following steps：
Step 1：Print speed printing speed is adjusted according to ink viscosity, and ink viscosity and print speed printing speed are inversely；
Step 2：The printing ink is using the silk screen of 110 mesh come Plate making printing；
Step 3：It is printed directly on light green color base material；
Step 4：Printing ink layer thickness should be maintained at 130 μm；
Step 5：By the way of chromaticity printing；
Step 6：During printing, whole system keeps drying；
Step 7：Luminous printing ink heats ink temperature to 54 DEG C using preceding stirring evenly, and is sealed after, is stored in cool place
At dry.
Carry out performance detection such as the following table 1 to printing ink made from above-described embodiment 1-3, and with common commercially available off-set oil
Ink is compared；
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (9)
1. a kind of printing ink, which is characterized in that including the following raw material counted in parts by weight：Water-soluble saturated polyester resin
20-30 parts, 15-25 parts of modified terpene resin, modified 20-30 parts of complex emulsions, 3-5 parts of laruyl alcohol oleate, isopropanol 8-12
Part, 4-6 parts of bauxite, 8-10 parts of titanium dioxide, 3-5 parts of talcum powder, 1-2 parts of hindered phenol, 4-8 parts of 2-Butoxyethyl acetate, horse
Come 1-3 parts of 1-3 parts of dibutyl phthalate, 5-7 parts of dispersant, 1-3 parts of initiator, 2-4 parts of crosslinking agent and plasticizer；
The modified terpene resin is the San Zhezhi made of polyadipate hexylene glycol ester and normal propyl alcohol dissolving terpene resin solid
Amount is than being terpene resin:Polyadipate hexylene glycol ester:Normal propyl alcohol=5:1:2；
The modified complex emulsions are made by following steps：
(1) the following ingredient counted in parts by weight is taken：6-8 parts of methyl methacrylate, 3-5 parts of butyl acrylate, metering system
2-3 parts sour, 1-2 parts of nano silicon dioxide, 0.4-0.6 parts of hydroxypropyl methyl cellulose, 0.8-1.2 parts of Lignosite, alkyl
7-9 parts of 1-2 parts of phenol polyethenoxy ether, 1-1.5 parts of calcium hydroxide and deionized water；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and half amount
Deionized water be added in container, be heated to 40-50 DEG C, magnetic agitation 70-80min, then with ultrasonic wave decentralized processing 30-
35min obtains batch mixing A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, under the conditions of nitrogen atmosphere plus
Enter alkyl phenol polyoxyethylene ether stirring 10-15min, whipping temp is 70-80 DEG C, and mixing speed 300-500r/min is obtained mixed
Expect B；
(4) the batch mixing A and mixed material B are added in reaction vessel, heating water bath stirs 40-50min, stirring to 60-70 DEG C
Rotating speed is not less than 800r/min, and stirring terminates to obtain the final product.
2. a kind of printing ink according to claim 1, which is characterized in that including the following raw material counted in parts by weight：
25 parts of water-soluble saturated polyester resin, 20 parts of modified terpene resin, modified 25 parts of complex emulsions, 4 parts of laruyl alcohol oleate, isopropyl
10 parts of alcohol, 5 parts of bauxite, 9 parts of titanium dioxide, 4 parts of talcum powder, 1.5 parts of hindered phenol, 6 parts of 2-Butoxyethyl acetate, maleic acid two
2 parts of 2 parts of butyl ester, 6 parts of dispersant, 2 parts of initiator, 3 parts of crosslinking agent and plasticizer.
3. a kind of printing ink according to claim 1, which is characterized in that the modified complex emulsions pass through following steps
It is made：
(1) the following ingredient counted in parts by weight is taken：7 parts of methyl methacrylate, 4 parts of butyl acrylate, methacrylic acid 2.5
Part, 1.5 parts of nano silicon dioxide, 0.5 part of hydroxypropyl methyl cellulose, 1 part of Lignosite, alkyl phenol polyoxyethylene ether 1.5
8 parts of part, 1.25 parts of calcium hydroxide and deionized water；
(2) by methyl methacrylate, butyl acrylate, methacrylic acid, nano silicon dioxide, Lignosite and half amount
Deionized water be added in container, be heated to 45 DEG C, magnetic agitation 75min, then with ultrasonic wave decentralized processing 32min, obtain mixed
Expect A；
(3) by the deionized water mixing of hydroxypropyl methyl cellulose, calcium hydroxide and remaining half amount, under the conditions of nitrogen atmosphere plus
Enter alkyl phenol polyoxyethylene ether stirring 12min, whipping temp is 75 DEG C, and mixing speed 400r/min obtains mixed material B；
(4) the batch mixing A and mixed material B are added in reaction vessel, heating water bath stirs 45min to 65 DEG C, and speed of agitator is
1000r/min, stirring terminate to obtain the final product.
4. a kind of printing ink according to claim 1, which is characterized in that the dispersant is polyacrylamide or 12
Sodium alkyl sulfate.
5. a kind of printing ink according to claim 1, which is characterized in that the initiator is ammonium persulfate or persulfuric acid
Potassium.
6. a kind of printing ink according to claim 1, which is characterized in that the crosslinking agent is pentaerythrite, double seasons penta
Any one of tetrol or trimethylolpropane.
7. a kind of printing ink according to claim 1, which is characterized in that the plasticizer be methyl pentachlorostearate or
Chlorinated paraffin.
8. a kind of printing ink according to claim 1, which is characterized in that the preparation method of the ink is by all originals
Material, which is delivered in a mixing bowl, is dispersed with stirring 4-5h, speed of agitator 300-500r/min, and whipping temp is 42-46 DEG C, later will
Material is delivered in colloid mill equipment, and grinding material to fineness is less than or equal to 20 μm.
9. a kind of control method of printing ink, includes the following steps：
Step 1：Print speed printing speed is adjusted according to ink viscosity；
Step 2：The printing ink is using silk screen come Plate making printing；
Step 3：Using white substrate or it is printed directly on white or light-colored base material；
Step 4：Printing ink layer thickness should be at 100 μm or more；
Step 5：By the way of chromaticity printing；
Step 6：During printing, whole system keeps drying；
Step 7：Luminous printing ink is sealed using preceding stirring evenly after, is stored at shady and cool drying；
It is characterized in that, in the step 1, ink viscosity and print speed printing speed are inversely；In step 2, meshcount 90-
110；In step 4, printing ink layer thickness should be maintained at 120 ± 10 μm；In step 7, before use, heating ink temperature to 52 ±
2℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810138794.6A CN108342125A (en) | 2018-02-11 | 2018-02-11 | A kind of control method and printing ink of printing ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810138794.6A CN108342125A (en) | 2018-02-11 | 2018-02-11 | A kind of control method and printing ink of printing ink |
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| CN108342125A true CN108342125A (en) | 2018-07-31 |
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| CN201810138794.6A Pending CN108342125A (en) | 2018-02-11 | 2018-02-11 | A kind of control method and printing ink of printing ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115627096A (en) * | 2022-11-04 | 2023-01-20 | 广东科鼎功能材料有限公司 | Hot water strippable protective ink and method for improving glass processing protective performance |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993633A (en) * | 2010-12-06 | 2011-03-30 | 上海英威喷墨科技有限公司 | Water-based pigment type ink for absorbent base material spray ink printing, preparation and printing methods thereof |
| CN103666104A (en) * | 2013-11-29 | 2014-03-26 | 当涂县科辉商贸有限公司 | Ultraviolet curing digital printing ink and preparation method thereof |
| CN103756403A (en) * | 2014-01-23 | 2014-04-30 | 繁昌县朱氏印务有限责任公司 | Luminous printing ink |
| CN104151937A (en) * | 2014-07-07 | 2014-11-19 | 杭州海维特化工科技有限公司 | Special ink jet printing machine ink for PE optical cables and cables and preparation method of special ink jet printing machine ink for PE optical cables and cables |
| CN104263069A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass printing ink and preparation method thereof |
| CN104530302A (en) * | 2014-12-11 | 2015-04-22 | 华南理工大学 | Silica sol/polyacrylic ester emulsion with high silicon content and preparation method of silica sol/polyacrylic ester emulsion |
| CN104610806A (en) * | 2015-01-15 | 2015-05-13 | 长兴艾飞特塑料科技有限公司 | Nano-silica-modified composite water-based ink and preparation method thereof |
| CN106634186A (en) * | 2016-11-21 | 2017-05-10 | 芜湖市创源新材料有限公司 | Steaming-resistant and boiling-resistant waterborne polyurethane gravure fluorescent ink and preparation method thereof |
-
2018
- 2018-02-11 CN CN201810138794.6A patent/CN108342125A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993633A (en) * | 2010-12-06 | 2011-03-30 | 上海英威喷墨科技有限公司 | Water-based pigment type ink for absorbent base material spray ink printing, preparation and printing methods thereof |
| CN103666104A (en) * | 2013-11-29 | 2014-03-26 | 当涂县科辉商贸有限公司 | Ultraviolet curing digital printing ink and preparation method thereof |
| CN103756403A (en) * | 2014-01-23 | 2014-04-30 | 繁昌县朱氏印务有限责任公司 | Luminous printing ink |
| CN104151937A (en) * | 2014-07-07 | 2014-11-19 | 杭州海维特化工科技有限公司 | Special ink jet printing machine ink for PE optical cables and cables and preparation method of special ink jet printing machine ink for PE optical cables and cables |
| CN104263069A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass printing ink and preparation method thereof |
| CN104530302A (en) * | 2014-12-11 | 2015-04-22 | 华南理工大学 | Silica sol/polyacrylic ester emulsion with high silicon content and preparation method of silica sol/polyacrylic ester emulsion |
| CN104610806A (en) * | 2015-01-15 | 2015-05-13 | 长兴艾飞特塑料科技有限公司 | Nano-silica-modified composite water-based ink and preparation method thereof |
| CN106634186A (en) * | 2016-11-21 | 2017-05-10 | 芜湖市创源新材料有限公司 | Steaming-resistant and boiling-resistant waterborne polyurethane gravure fluorescent ink and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115627096A (en) * | 2022-11-04 | 2023-01-20 | 广东科鼎功能材料有限公司 | Hot water strippable protective ink and method for improving glass processing protective performance |
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