CN110218482A - A kind of plastic rotogravure printing ink - Google Patents
A kind of plastic rotogravure printing ink Download PDFInfo
- Publication number
- CN110218482A CN110218482A CN201910628841.XA CN201910628841A CN110218482A CN 110218482 A CN110218482 A CN 110218482A CN 201910628841 A CN201910628841 A CN 201910628841A CN 110218482 A CN110218482 A CN 110218482A
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- parts
- printing ink
- rotogravure printing
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- adjuvant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of plastic rotogravure printing ink, it is related to printing technical field of ink.The present invention is mainly made of the component of following parts by weight: 10-20 parts of polyamide, 20-23 parts of nitrocellulose, 15-22 parts of chlorinated polypropylene, 20-30 parts of polyurethane resin, 10-18 parts of polyacrylate dispersion, 15-18 parts of inorganic pigment, 10-15 parts of butyl acetate, 10-15 parts of ethyl alcohol, 1-15 parts of water, 1-15 parts of adjuvant.Ink of the present invention has the advantages that epithelium intensity and heat-resist, various kinds of resin and plasticizer have preferable intersolubility, while adhesive force is strong, make the good dispersion of pigment, good luster, and have good adhesive force, acid and alkali resistance to a variety of printable fabrics, ink asepsis environment-protecting, with good application prospect.
Description
Technical field
The invention belongs to print technical field of ink, more particularly to a kind of plastic rotogravure printing ink.
Background technique
Intaglio printing is as one of numerous mode of printings, thick and solid, the bright-colored, saturation degree with its printing product layer of ink
Many merits are in printing packaging and picture and text publishing area occupies and its consequence for high, print quality stabilization etc..From application
From the point of view of situation, at abroad, gravure is mainly used for the fine publication such as magazine, catalogue, in addition, being also applied to ornament materials more
Equal special dimensions；At home, gravure is mainly used in packages printing, with the development of Chinese gravure techniques, in sheet package, wood
Line decoration, leather substance, gravure has also been widely used on Key works Drug packing.
Current existing its viscosity of the ink requirements suitable for intaglio printing, tinting strength, tinting power, attachment fastness and heat resistance etc. are more
Parameter meets commonly used environment and needs, this will be that the application range of the ink is limited to, to expand intaglio printing
The application range of ink, the requirement for multiple parameters such as the viscosity of such ink, tinting strength, tinting power, adhesion and heat resistances constantly mention
Height, therefore, the performance for further improving gravure ink is still the field technical issues that need to address.
Summary of the invention
The purpose of the present invention is to provide a kind of plastic rotogravure printing inks, have preferable heat resistance, acid and alkali resistance
Property, the good dispersion of pigment, good luster, and have good adhesive force, environment-protecting and non-poisonous advantage to a variety of printable fabrics.
The present invention is achieved by the following technical solutions:
The present invention is a kind of plastic rotogravure printing ink, is mainly made of the component of following parts by weight:
10-20 parts of polyamide, 20-23 parts of nitrocellulose, 15-22 parts of chlorinated polypropylene, polyurethane resin
20-30 parts, 10-18 parts of polyacrylate dispersion, 15-18 parts of inorganic pigment, 10-15 parts of butyl acetate, 10-15 parts of ethyl alcohol, water
1-15 parts, 1-15 parts of adjuvant.
Further, a kind of plastic rotogravure printing ink, is mainly made of the component of following parts by weight:
15 parts of polyamide, 22 parts of nitrocellulose, 19 parts of chlorinated polypropylene, 25 parts of polyurethane resin, poly- third
14 parts of olefin(e) acid ester lotion, 17 parts of inorganic pigment, 13 parts of butyl acetate, 12 parts of ethyl alcohol, 8 parts of water, 7 parts of adjuvant.
Further, the production method of the ink includes the following steps:
(1), butyl acetate, ethyl alcohol, water are added in reaction kettle and are uniformly mixed, mixed solvent is made；
(2), by acrylate, polyenoid acrylate, initiator, wherein the deionized water of 25-40% mixes in a reservoir
After uniformly, it is added drop-wise in the reaction kettle equipped with remaining deionized water and alkaline acrylic acid solution, time for adding is 4-5 hours, instead
Answering temperature is 70-90 DEG C, is added dropwise to complete subsequent continuous insulation reaction 1-2 hours, cooling discharge, and obtaining solid content is 25-30%'s
Polyacrylate dispersion；
(3), polyamide, nitrocellulose, chlorinated polypropylene, polyurethane resin are added in reaction kettle and are mixed
Bonding solvent mixing, is warming up to 65-80 DEG C, and stir 0.5-1h；
(4), polyacrylate dispersion, inorganic pigment and adjuvant are added in stirred tank, stirring 1-2h, cooling discharge,
Sand mill is added mixture into again is ground to material size lower than 20 microns hereinafter, finished product ink.
Further, the adjuvant is one of antistatic agent, surfactant, defoaming agent, diluent, plasticizer
Or it is several.
Further, the inorganic pigment can be one of copper powder, carbon black, titanium white, chrome yellow, iron oxide red, manganese violet or several
Kind.
Further, the initiator is one or more of ammonium persulfate, potassium peroxydisulfate, sodium peroxydisulfate.
The invention has the following advantages:
Ink of the present invention has the advantages that epithelium intensity and heat-resist, and various kinds of resin and plasticizer, which have, preferably to dissolve each other
Property, while adhesive force is strong, make the good dispersion of pigment, good luster, and have good attachment to a variety of printable fabrics
Power, acid and alkali resistance, ink asepsis environment-protecting, with good application prospect.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Embodiment one
A kind of plastic rotogravure printing ink of the invention, is mainly made of the component of following parts by weight:
10 parts of polyamide, 20 parts of nitrocellulose, 15 parts of chlorinated polypropylene, 20 parts of polyurethane resin, poly- third
10 parts of olefin(e) acid ester lotion, (wherein, inorganic pigment can be copper powder, carbon black, titanium white, chrome yellow, iron oxide red, manganese violet to 15 parts of inorganic pigment
One or more of), 10 parts of butyl acetate, 10 parts of ethyl alcohol, 1 part of water, 1 part of adjuvant (wherein, adjuvant be antistatic agent,
One or more of surfactant, defoaming agent, diluent, plasticizer).
Further, the production method of ink includes the following steps:
(1), butyl acetate, ethyl alcohol, water are added in reaction kettle and are uniformly mixed, mixed solvent is made；
(2), by acrylate, polyenoid acrylate, initiator, (wherein, initiator is ammonium persulfate, potassium peroxydisulfate, mistake
One or more of sodium sulphate), wherein 25-40% deionized water in a reservoir after mixing, be added drop-wise to equipped with residue
In the reaction kettle of deionized water and alkaline acrylic acid solution, time for adding is 4-5 hours, and reaction temperature is 70-90 DEG C, is dripped
At subsequent continuous insulation reaction 1-2 hours, cooling discharge obtained the polyacrylate dispersion that solid content is 25-30%；
(3), polyamide, nitrocellulose, chlorinated polypropylene, polyurethane resin are added in reaction kettle and are mixed
Bonding solvent mixing, is warming up to 65-80 DEG C, and stir 0.5-1h；
(4), polyacrylate dispersion, inorganic pigment and adjuvant are added in stirred tank, stirring 1-2h, cooling discharge,
Sand mill is added mixture into again is ground to material size lower than 20 microns hereinafter, finished product ink.
Embodiment two
A kind of plastic rotogravure printing ink of the invention, is mainly made of the component of following parts by weight:
15 parts of polyamide, 22 parts of nitrocellulose, 19 parts of chlorinated polypropylene, 25 parts of polyurethane resin, poly- third
14 parts of olefin(e) acid ester lotion, (wherein, inorganic pigment can be copper powder, carbon black, titanium white, chrome yellow, iron oxide red, manganese violet to 17 parts of inorganic pigment
One or more of), 13 parts of butyl acetate, 12 parts of ethyl alcohol, 8 parts of water, 7 parts of adjuvant (wherein, adjuvant be antistatic agent,
One or more of surfactant, defoaming agent, diluent, plasticizer).
Further, the production method of ink includes the following steps:
(1), butyl acetate, ethyl alcohol, water are added in reaction kettle and are uniformly mixed, mixed solvent is made；
(2), by acrylate, polyenoid acrylate, initiator, (wherein, initiator is ammonium persulfate, potassium peroxydisulfate, mistake
One or more of sodium sulphate), wherein 25-40% deionized water in a reservoir after mixing, be added drop-wise to equipped with residue
In the reaction kettle of deionized water and alkaline acrylic acid solution, time for adding is 4-5 hours, and reaction temperature is 70-90 DEG C, is dripped
At subsequent continuous insulation reaction 1-2 hours, cooling discharge obtained the polyacrylate dispersion that solid content is 25-30%；
(3), polyamide, nitrocellulose, chlorinated polypropylene, polyurethane resin are added in reaction kettle and are mixed
Bonding solvent mixing, is warming up to 65-80 DEG C, and stir 0.5-1h；
(4), polyacrylate dispersion, inorganic pigment and adjuvant are added in stirred tank, stirring 1-2h, cooling discharge,
Sand mill is added mixture into again is ground to material size lower than 20 microns hereinafter, finished product ink.
Embodiment three
A kind of plastic rotogravure printing ink of the invention, is mainly made of the component of following parts by weight:
20 parts of polyamide, 23 parts of nitrocellulose, 22 parts of chlorinated polypropylene, 30 parts of polyurethane resin, poly- third
18 parts of olefin(e) acid ester lotion, (wherein, inorganic pigment can be copper powder, carbon black, titanium white, chrome yellow, iron oxide red, manganese violet to 18 parts of inorganic pigment
One or more of), 15 parts of butyl acetate, 15 parts of ethyl alcohol, 15 parts of water, (wherein, adjuvant is antistatic to 15 parts of adjuvant
One or more of agent, surfactant, defoaming agent, diluent, plasticizer).
Further, the production method of ink includes the following steps:
(1), butyl acetate, ethyl alcohol, water are added in reaction kettle and are uniformly mixed, mixed solvent is made；
(2), by acrylate, polyenoid acrylate, initiator, (wherein, initiator is ammonium persulfate, potassium peroxydisulfate, mistake
One or more of sodium sulphate), wherein 25-40% deionized water in a reservoir after mixing, be added drop-wise to equipped with residue
In the reaction kettle of deionized water and alkaline acrylic acid solution, time for adding is 4-5 hours, and reaction temperature is 70-90 DEG C, is dripped
At subsequent continuous insulation reaction 1-2 hours, cooling discharge obtained the polyacrylate dispersion that solid content is 25-30%；
(3), polyamide, nitrocellulose, chlorinated polypropylene, polyurethane resin are added in reaction kettle and are mixed
Bonding solvent mixing, is warming up to 65-80 DEG C, and stir 0.5-1h；
(4), polyacrylate dispersion, inorganic pigment and adjuvant are added in stirred tank, stirring 1-2h, cooling discharge,
Sand mill is added mixture into again is ground to material size lower than 20 microns hereinafter, finished product ink.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment
All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification,
It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention
Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only
It is limited by claims and its full scope and equivalent.
Claims (6)
1. a kind of plastic rotogravure printing ink, which is characterized in that be mainly made of the component of following parts by weight:
10-20 parts of polyamide, 20-23 parts of nitrocellulose, 15-22 parts of chlorinated polypropylene, polyurethane resin 20-30
Part, 10-18 parts of polyacrylate dispersion, 15-18 parts of inorganic pigment, 10-15 parts of butyl acetate, 10-15 parts of ethyl alcohol, water 1-15
Part, 1-15 parts of adjuvant.
2. a kind of plastic rotogravure printing ink according to claim 1, which is characterized in that mainly by following parts by weight
Component is made:
15 parts of polyamide, 22 parts of nitrocellulose, 19 parts of chlorinated polypropylene, 25 parts of polyurethane resin, polyacrylic acid
14 parts of ester lotion, 17 parts of inorganic pigment, 13 parts of butyl acetate, 12 parts of ethyl alcohol, 8 parts of water, 7 parts of adjuvant.
3. a kind of plastic rotogravure printing ink according to claim 1 or 2, which is characterized in that the production of the ink
Method includes the following steps:
(1), butyl acetate, ethyl alcohol, water are added in reaction kettle and are uniformly mixed, mixed solvent is made；
(2), by acrylate, polyenoid acrylate, initiator, wherein the deionized water of 25-40% is uniformly mixed in a reservoir
Afterwards, it is added drop-wise in the reaction kettle equipped with remaining deionized water and alkaline acrylic acid solution, time for adding is 4-5 hours, reaction temperature
Degree is 70-90 DEG C, is added dropwise to complete subsequent continuous insulation reaction 1-2 hours, cooling discharge, and poly- third that solid content is 25-30% is obtained
Olefin(e) acid ester lotion；
(3), by polyamide, nitrocellulose, chlorinated polypropylene, polyurethane resin be added reaction kettle in mix it is molten
Agent mixing, is warming up to 65-80 DEG C, and stir 0.5-1h；
(4), polyacrylate dispersion, inorganic pigment and adjuvant are added in stirred tank, stirring 1-2h, cooling discharge, then will
Mixture is added sand mill and is ground to material size lower than 20 microns hereinafter, finished product ink.
4. a kind of plastic rotogravure printing ink according to claim 1 or 2, which is characterized in that the adjuvant is anti-
One or more of electrostatic agent, surfactant, defoaming agent, diluent, plasticizer.
5. a kind of plastic rotogravure printing ink according to claim 1 or 2, which is characterized in that the inorganic pigment can
Think one or more of copper powder, carbon black, titanium white, chrome yellow, iron oxide red, manganese violet.
6. a kind of plastic rotogravure printing ink according to claim 3, which is characterized in that the initiator is persulfuric acid
One or more of ammonium, potassium peroxydisulfate, sodium peroxydisulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910628841.XA CN110218482A (en) | 2019-07-12 | 2019-07-12 | A kind of plastic rotogravure printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910628841.XA CN110218482A (en) | 2019-07-12 | 2019-07-12 | A kind of plastic rotogravure printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110218482A true CN110218482A (en) | 2019-09-10 |
Family
ID=67813325
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910628841.XA Pending CN110218482A (en) | 2019-07-12 | 2019-07-12 | A kind of plastic rotogravure printing ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN110218482A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303691A (en) * | 2020-03-24 | 2020-06-19 | 佛山市恺盛印务有限公司 | Environment-friendly plastic printing ink |
| CN112874193A (en) * | 2021-01-08 | 2021-06-01 | 海赢印务科技(上海)有限公司 | Plastic film-based gravure efficient printing process |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774496A (en) * | 2015-04-22 | 2015-07-15 | 中国科学院化学研究所 | Universal water-based gravure composite printing ink and preparation method thereof |
-
2019
- 2019-07-12 CN CN201910628841.XA patent/CN110218482A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774496A (en) * | 2015-04-22 | 2015-07-15 | 中国科学院化学研究所 | Universal water-based gravure composite printing ink and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 何炜德: "《塑料印刷入门》", 29 February 2000, 浙江科学技术出版社 * |
| 钟泽辉等: "《凹印制版技术》", 31 July 2006, 印刷工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303691A (en) * | 2020-03-24 | 2020-06-19 | 佛山市恺盛印务有限公司 | Environment-friendly plastic printing ink |
| CN112874193A (en) * | 2021-01-08 | 2021-06-01 | 海赢印务科技(上海)有限公司 | Plastic film-based gravure efficient printing process |
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Application publication date: 20190910 |