CN108276830A - A kind of ceramic ink jet printing water-based ink and preparation method thereof - Google Patents
A kind of ceramic ink jet printing water-based ink and preparation method thereof Download PDFInfo
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- CN108276830A CN108276830A CN201810072808.9A CN201810072808A CN108276830A CN 108276830 A CN108276830 A CN 108276830A CN 201810072808 A CN201810072808 A CN 201810072808A CN 108276830 A CN108276830 A CN 108276830A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of ceramic ink jet printing water-based inks, are prepared by the raw material including lower parts by weight：20~50 parts of ceramic pigment, 2~7 parts of dispersant, 2~5 parts of surfactant, 2~3 parts of resinoid bond, 2~6 parts of conditioning agent, 0.1~0.5 part of auxiliary agent, water supplies 100 parts.Water-based ink of the present invention reaches certain physical and chemical index without virose organic solvent by mechanical dispersion process, and high comprehensive performance, cost is relatively low, highly practical, can adapt to most of ink-jet printers on the market.
Description
Technical field
The present invention relates to ceramic ink jet printing technical fields, and in particular to the ink used in a kind of ceramic ink jet printing.
Background technology
With the development of market economy and computer technology, existing traditional ceramics decorative means have been unable to meet market and need
It wants.The introducing of modernization of computer technological means is the inexorable trend of design of ceramic products developing direction from now on.It is presently used for
The new process inkjet printing technology of mould-free forming just becomes worldwide research hotspot, matched various ceramic inks
Expose one after another.Inkjet printing is a kind of decoration technique of great potential, and this method is that multi-color ink is made for making pottery in colorant
Multi-color ink is directly printed to ceramic surface and decorated by porcelain incrustation, the printer controlled by computer.
One of the key of ceramic ink jet technology is the development of ceramic ink, and the solvent type ceramic ink of existing mainstream applications is more
For esters, hydro carbons etc., there are production cost height, contain volatile toxic substance, there is certain harm to environment.And water-based ink is
Belong to environmentally friendly ink without volatility, virose organic solvent using water as the carrier of pigment granules, meet ceramics
The development trend in ink future, and cost can be reduced, enhance product competitiveness.And existing aqueous ink is due to formula and technique
Etc. reasons, after printing to glaze, center is different from surrounding rate of drying, ink of spreading and sinking in occurs, and causes pattern resolution and colour generation uniform
Degree reduces.
Invention content
The object of the present invention is to provide a kind of ceramic ink jet printing water-based inks, by the raw material system for including following parts by weight
It is standby to form：20~50 parts of ceramic pigment, 2~7 parts of dispersant, 2~5 parts of surfactant, 2~3 parts of resinoid bond, conditioning agent
2~6 parts, 0.1~0.5 part of auxiliary agent, water supplies 100 parts.
Using the produced ceramic ink of the above formula, volatile toxic substance is free of, environmentally friendly ink, cost are belonged to
It is relatively low, solve water-based ink spread and sink in the application ink and low, poor in color uniformity pattern resolution the problems such as, and color development is strong, surely
It is qualitative good.
Preferably, the ceramic pigment is cobalt blue, reddish brown, cobalt black, praseodymium yellow, package is yellow, wraps up red or zirconium-iron pink pigment；
It is further preferred that the ceramic pigment is prepared by hydro-thermal method, the precipitation method or solid phase method.
Preferably, the dispersant is total for addition product, polyethylenimine derivates, the acrylic acid of aliphatic acid and ethylene oxide
One or more of polymers ammonium salt or polyacrylamide；Preferably (GA40 sends this to acrylic copolymer ammonium salt purchased from Supreme Being
Dispex)。
Preferably, neopelex, α-sodium olefin sulfonate or sodium sulfate of polyethenoxy ether of fatty alcohol
Preferably, the resinoid bond is water soluble propene's acid modified resin；Optimization styrene modified acrylic acid emulsion
Or epoxy resin modification acrylate.
Preferably, the conditioning agent is 1,2-PD and diethylene glycol (DEG) by volume 1：0.5~5 preparation being mixed to get.
Preferably, the amount of auxiliary is one or more of antifoaming agent, conductivity conditioning agent, preservative.
As a preferred option, water-based ink of the invention is prepared by the raw material of following parts by weight：
35~42 parts of ceramic pigment, 3.5~4.6 parts of dispersant, 3.7~4.5 parts of surfactant, resinoid bond 2.3
~2.8 parts, 4.4~5.5 parts of conditioning agent, 0.2~0.4 part of auxiliary agent, water supplies 100 parts；
The ceramic pigment be the cobalt blue being prepared by hydro-thermal method, the precipitation method or solid phase method, reddish brown, cobalt black, praseodymium yellow,
Package is yellow, wraps up red or zirconium-iron pink pigment, and the dispersant is acrylic copolymer ammonium salt, and the surfactant is dodecane
Base benzene sulfonic acid sodium salt, α-sodium olefin sulfonate or sodium sulfate of polyethenoxy ether of fatty alcohol, the resinoid bond are phenylethene modified third
Olefin(e) acid lotion or epoxy resin modification acrylate；The conditioning agent is 1,2- propylene glycol and diethylene glycol (DEG) by volume 1：1.5~
3.3 preparations being mixed to get；The auxiliary agent is one or more of antifoaming agent, conductivity conditioning agent, preservative.
The present invention also provides the preparation methods of herein described water-based ink, include the following steps：
1) dispersant is added to the water and is stirred evenly, ceramic pigment is then added and stirs evenly, adds surface-active
Agent, resinoid bond and conditioning agent, using ball mill pre-grinding 2-5 hour after stirring evenly, mill is situated between for zirconia ball, size between
Then 3mm-5mm is ground using horizontal sand mill, it is zirconia ball that mill, which is situated between, and between 0.3mm-1.5mm, mill is situated between to be filled out size
Degree of filling is ground to granularity D50 between 0.30-0.70 between 50%-80%, cooling water circulation between controlling 30 DEG C -55 DEG C of temperature
Between μm, D100 is less than 1.5 μm；
2) auxiliary agent is added into the mixed liquor after above-mentioned grinding, adjusts the solid content 20-50wt% of mixed liquor, viscosity 16-
24mPas (40 DEG C), conductivity is more than 100ms/m, surface tension 20-30mN/m, pH7-9, through filter core level-one-three-stage filtration,
Up to the water-based ink.
The ink prepared using above-mentioned technique, narrow particle size distribution, no bulky grain, stability of ink is good, ink jet printing process
It is smooth, greatly reduce in ink jet process nozzle block, bracing wire the problems such as.
Water-based ink of the present invention has the advantages that：
Water-based ink of the present invention is free of virose organic solvent.Its ingredient includes ceramic pigment, dispersant, table
Face activating agent, conductivity conditioning agent, antifoaming agent, pure water etc..By mechanical dispersion process, the physical chemistry for reaching certain refers to
Mark, stability is good, and color development is strong, solve water-based ink spread and sink in the application ink and pattern resolution it is low, asked in color uniformity difference etc.
Topic, ink narrow particle size distribution, stability is good, and color development ability is strong, and cost is relatively low, can adapt to most of inkjet printings on the market
Machine.
Specific implementation mode
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Embodiment 1
The present embodiment is related to a kind of ceramic ink jet printing water-based ink, is prepared by the raw material of following parts by weight：
40 parts of praseodymium yellow ceramic pigment, 4.6 parts of dispersant acrylic copolymer ammonium salt (GA40), surfactant sodium dodecyl base
3.7 parts of benzene sulfonic acid sodium salt, 2.8 parts of resinoid bond styrenated acrylic lotion, 4.4 parts of conditioning agent, the conditioning agent by 1,
2- propylene glycol and diethylene glycol (DEG) by volume 1：1.5 be mixed into and, 0.3 part of auxiliary agent, auxiliary agent is by antifoaming agent (dimethicone), conductance
Rate conditioning agent (1% metabisulfite solution), preservative (Nordes C15 sterilization antiseptics) are by weight 2:1:3 mix, water
Supply 100 parts.
Water-based ink described in the present embodiment is prepared by the following method：
1) dispersant is added to the water and is stirred evenly, ceramic pigment is then added and stirs evenly, adds surface-active
Agent, resinoid bond and conditioning agent, using ball mill pre-grinding 3 hours after stirring evenly, it is zirconia ball that mill, which is situated between, size 3mm, so
It is ground afterwards using horizontal sand mill, it is zirconia ball that mill, which is situated between, and size 0.6mm, between 60%, cooling water follows mill Jie's compactedness
Ring, between controlling 30 DEG C -55 DEG C of temperature, it is 0.45 μm to be ground to granularity D50, and D100 is 0.9 μm；
2) auxiliary agent is added into the mixed liquor after above-mentioned grinding, the viscosity for adjusting mixed liquor is 19mPas (40 DEG C), electricity
Conductance 1320ms/m, surface tension 24mN/m, pH=7.9, through three-stage filtration to get the water-based ink.
The water-based ink stability that the present embodiment is prepared is good, energy normal print, and ink of not spreading and sinking in calcines 1130 DEG C into stove,
Heat preservation 30 minutes, pattern resolution are high, and chromatic value L=90.34, a=-13.35, b=58.9, color development is good, and to environment without
Harm, cost are relatively low.
Embodiment 2
35 parts of cobalt blue ceramic pigment, 3.5 parts of dispersant acrylic copolymer ammonium salt (GA40), surfactant α-alkenyl sulphur
4.5 parts of sour sodium, 2.3 parts of resinoid bond styrenated acrylic lotion, 5.5 parts of conditioning agent, conditioning agent is by 1,2-PD
With diethylene glycol (DEG) by volume 1：2 are mixed into and 0.3 part of auxiliary agent, and auxiliary agent is by antifoaming agent (dimethicone), preservative (Nordes
C15 sterilization antiseptics) by weight 2:3 mix, and water supplies 100 parts.
Water-based ink described in the present embodiment is prepared by the following method：
1) dispersant is added to the water and is stirred evenly, ceramic pigment is then added and stirs evenly, adds surface-active
Agent, resinoid bond and conditioning agent, using ball mill pre-grinding 2.5 hours after stirring evenly, it is zirconia ball that mill, which is situated between, size 3mm,
Then it is ground using horizontal sand mill, it is zirconia ball that mill, which is situated between, and size 0.3mm, mill Jie's compactedness is between 60%, cooling water
Cycle, between controlling 30 DEG C -55 DEG C of temperature, it is 0.45 μm to be ground to granularity D50, and D100 is 0.9 μm；
2) auxiliary agent is added into the mixed liquor after above-mentioned grinding, the viscosity for adjusting mixed liquor is 21mPas (40 DEG C), electricity
Conductance 1220ms/m, surface tension 27mN/m, pH=7.8, through filter core by-pass filtration to get the water-based ink.
The water-based ink stability that the present embodiment is prepared is good, energy normal print, and ink of not spreading and sinking in calcines 1130 DEG C into stove,
Heat preservation 30 minutes, pattern resolution are high, and chromatic value L=40.54, a=12.51, b=-34.20, color development is good, and to environment without
Harm, cost are relatively low.
Embodiment 3
The present embodiment is related to a kind of ceramic ink jet printing water-based ink, is prepared by the raw material of following parts by weight：
Wrap up 42 parts of red pottery porcelain color, 4.2 parts of dispersant acrylic copolymer ammonium salt (GA40), surfactant fatty alcohol
3.7 parts of polyethenoxy ether sodium sulfate, 2.8 parts of resinoid bond epoxy resin modification acrylic emulsion, 4.8 parts of conditioning agent are adjusted
Agent is by 1,2- propylene glycol and diethylene glycol (DEG) by volume 1：3.3 mix, and 0.3 part of auxiliary agent, auxiliary agent is by antifoaming agent (dimethyl-silicon
Oil), preservative (Nordes C15 sterilization antiseptics) by weight be 1:2 mix, and water supplies 100 parts.
Water-based ink described in the present embodiment is prepared by the following method：
1) dispersant is added to the water and is stirred evenly, ceramic pigment is then added and stirs evenly, adds surface-active
Agent, resinoid bond and conditioning agent, using ball mill pre-grinding 3 hours after stirring evenly, it is zirconia ball that mill, which is situated between, and size 3mm crouches
Formula sand mill is ground, and it is zirconia ball, size 0.3mm, mill Jie compactedness 60%, cooling water circulation, control temperature that mill, which is situated between,
Between 30 DEG C -55 DEG C, it is 0.63 μm to be ground to granularity D50, and D100 is 1.2 μm；
2) auxiliary agent is added into the mixed liquor after above-mentioned grinding, adjusts viscosity of mixed liquid 21mPas (40 DEG C), conductivity
1460ms/m, surface tension 26mN/m, pH=8.1 filter to get the water-based ink.Then 1130 DEG C are calcined into stove, heat preservation
30 minutes.
The water-based ink stability that the present embodiment is prepared is preferable, not blocking sprayer, not bracing wire, and energy normal print is not spread and sunk in
Ink, pattern resolution is high, and chromatic value L=60.62, a=38.43, b=36.09, color development is good, and non-hazardous to environment, cost
It is relatively low.
Comparative example 1
The present embodiment is related to a kind of ceramic ink jet printing water-based ink, and compared with Example 1, difference lies in described
Dispersant is polyethylene glycol 200, and the water-based ink stability that the present embodiment is prepared is general, not blocking sprayer, energy normal print,
But there is black phenomenon of spreading and sinking in, pattern resolution is relatively low, chromatic value L=92.65, a=-13.15, b=46.32, and color development is poor.
Comparative example 2
The present embodiment is related to a kind of ceramic ink jet printing water-based ink, and compared with Example 1, difference lies in described
Conditioning agent is glycerine, and the water-based ink stability that the present embodiment is prepared is poor, there is slight black phenomenon of spreading and sinking in, chromatic value L==
90.73, a=-13.21, b=54.36.
Comparative example 3
The present embodiment is related to a kind of the present embodiment and is related to a kind of ceramic ink jet printing water-based ink, compared with Example 1,
Difference lies in preparation method is directly to be ground using horizontal sand mill after stirring evenly, and it is zirconia ball, ruler that mill, which is situated between, for it
Very little 0.3mm, mill Jie compactedness 65%, the stability of ink of preparation is general, there is blocking sprayer and bracing wire situation, chromatic value L==
90.81, a=-13.19, b=57.36.
Although above having used general explanation, specific implementation mode and experiment, the present invention is made to retouch in detail
It states, but on the basis of the present invention, it can be made some modifications or improvements, this is apparent to those skilled in the art
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed
Range.
Claims (9)
1. a kind of ceramic ink jet printing water-based ink, which is characterized in that be prepared by the raw material including following parts by weight：Pottery
20~50 parts of porcelain color, 2~7 parts of dispersant, 2~5 parts of surfactant, 2~3 parts of resinoid bond, 2~6 parts of conditioning agent help
0.1~0.5 part of agent, water supplies 100 parts.
2. water-based ink according to claim 1, which is characterized in that the ceramic pigment is cobalt blue, reddish brown, cobalt black, praseodymium
Yellow, package Huang, the red or zirconium-iron pink pigment of package；Preferably, the ceramic pigment is prepared by hydro-thermal method, the precipitation method or solid phase method
It obtains.
3. water-based ink according to claim 1 or 2, which is characterized in that the dispersant is aliphatic acid and ethylene oxide
One or more of addition product, polyethylenimine derivates, acrylic copolymer ammonium salt or polyacrylamide；Preferably third
Olefin(e) acid copolymer ammonium salt.
4. water-based ink according to claim 1 or 3, which is characterized in that the surfactant is detergent alkylate sulphur
Sour sodium, α-sodium olefin sulfonate or sodium sulfate of polyethenoxy ether of fatty alcohol.
5. water-based ink according to claim 1 or 4, which is characterized in that the resinoid bond is water-soluble acrylic
Modified resin；Optimization styrene modified acrylic acid emulsion or epoxy resin modification acrylate.
6. water-based ink according to claim 1 or 5, which is characterized in that the conditioning agent is sweet by 1,2-PD and two
Alcohol by volume 1：0.5~5 preparation being mixed to get.
7. water-based ink according to claim 1 or 6, which is characterized in that the amount of auxiliary is antifoaming agent, conductivity adjusting
One or more of agent, preservative.
8. according to claim 1~7 any one of them water-based ink, which is characterized in that by including as follows by following parts by weight
Raw material be prepared：35~42 parts of ceramic pigment, 3.5~4.6 parts of dispersant, 3.7~4.5 parts of surfactant, resin knot
2.3~2.8 parts of mixture, 4.4~5.5 parts of conditioning agent, 0.2~0.4 part of auxiliary agent, water supplies 100 parts；
The ceramic pigment is the cobalt blue being prepared by hydro-thermal method, the precipitation method or solid phase method, reddish brown, cobalt black, praseodymium yellow, package
Yellow, the red or zirconium-iron pink pigment of package, the dispersant are acrylic copolymer ammonium salt, and the surfactant is detergent alkylate
Sodium sulfonate, α-sodium olefin sulfonate or sodium sulfate of polyethenoxy ether of fatty alcohol, the resinoid bond are styrenated acrylic
Lotion or epoxy resin modification acrylate；The conditioning agent is 1,2- propylene glycol and diethylene glycol (DEG) by volume 1：1.5~3.3 is mixed
Close obtained preparation；The auxiliary agent is one or more of antifoaming agent, conductivity conditioning agent, preservative.
9. the preparation method of any one of claim 1~8 water-based ink, which is characterized in that include the following steps：
1) dispersant is added to the water and is stirred evenly, ceramic pigment is then added and stirs evenly, add surfactant, tree
Fat bonding agent and conditioning agent, using ball mill pre-grinding 2-5 hours after stirring evenly, it is zirconia ball that mill, which is situated between, and size is between 3mm-
5mm；Then it is ground using horizontal sand mill, it is zirconia ball that mill, which is situated between, and size grinds Jie's compactedness between 0.3mm-1.5mm
Between 50%-80%, cooling water circulation, between controlling 30 DEG C -55 DEG C of temperature, be ground to granularity D50 between 0.30-0.70 μm it
Between, D100 is less than 1.5 μm；
2) auxiliary agent is added into the mixed liquor after above-mentioned grinding, adjusts the solid content 20-50wt% of mixed liquor, viscosity 16-
24mPas40 DEG C, conductivity is more than 100ms/m, surface tension 20-30mN/m, pH7-9, filters to get the aqueous ink
Water.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337446A (en) * | 2018-10-15 | 2019-02-15 | 湖南斯多孚节能科技有限公司 | A kind of ink and coloring process for the coloring of powder number |
| CN109852142A (en) * | 2018-12-28 | 2019-06-07 | 佛山市道氏科技有限公司 | A kind of preparation method of small particle ceramic ink jet printing package ink |
| CN111253803A (en) * | 2020-02-26 | 2020-06-09 | 武汉理工大学 | Water-based yellow ceramic ink for ink-jet printing and preparation method thereof |
| CN112457717A (en) * | 2021-02-01 | 2021-03-09 | 佛山市三水区康立泰无机合成材料有限公司 | Water-based ceramic ink for ink-jet printing and preparation method and application thereof |
| CN113402928A (en) * | 2021-07-02 | 2021-09-17 | 山东陶正新材料科技有限公司 | Ink formula and production process |
| CN116161987A (en) * | 2023-04-21 | 2023-05-26 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
| CN116814113B (en) * | 2023-06-30 | 2024-04-26 | 东莞市唯美陶瓷工业园有限公司 | Preparation method of green ceramic ink and green ceramic ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337446A (en) * | 2018-10-15 | 2019-02-15 | 湖南斯多孚节能科技有限公司 | A kind of ink and coloring process for the coloring of powder number |
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| CN111253803A (en) * | 2020-02-26 | 2020-06-09 | 武汉理工大学 | Water-based yellow ceramic ink for ink-jet printing and preparation method thereof |
| CN111253803B (en) * | 2020-02-26 | 2021-08-17 | 武汉理工大学 | Water-based yellow ceramic ink for ink-jet printing and preparation method thereof |
| CN112457717A (en) * | 2021-02-01 | 2021-03-09 | 佛山市三水区康立泰无机合成材料有限公司 | Water-based ceramic ink for ink-jet printing and preparation method and application thereof |
| CN113402928A (en) * | 2021-07-02 | 2021-09-17 | 山东陶正新材料科技有限公司 | Ink formula and production process |
| CN116161987A (en) * | 2023-04-21 | 2023-05-26 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
| CN116161987B (en) * | 2023-04-21 | 2024-01-05 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
| CN116814113B (en) * | 2023-06-30 | 2024-04-26 | 东莞市唯美陶瓷工业园有限公司 | Preparation method of green ceramic ink and green ceramic ink |
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Application publication date: 20180713 |
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