CN109852142A - A kind of preparation method of small particle ceramic ink jet printing package ink - Google Patents
A kind of preparation method of small particle ceramic ink jet printing package ink Download PDFInfo
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- CN109852142A CN109852142A CN201811617766.9A CN201811617766A CN109852142A CN 109852142 A CN109852142 A CN 109852142A CN 201811617766 A CN201811617766 A CN 201811617766A CN 109852142 A CN109852142 A CN 109852142A
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Abstract
The invention discloses a kind of small particle ceramic ink jet printing preparation methods of package ink.By using the abrasive media classified grinding of different-grain diameter, the occlusion pigment suitable for ceramic ink jet printing is successfully prepared.The method of the present invention is easy to operate efficiently, the preparation suitable for a variety of package inks.In the ceramic ink being prepared, pigment granules are uniform, and size distribution is narrow, average grain diameter is 500~600nm, and maximum particle diameter is no more than 1 μm, and package ink color development after 1000~1300 DEG C of high temperature firings is full bright-coloured, it can be used for tile production, it can also be used to Antique Imitation Tiles field.Solve the excessive easy precipitating of ink fineness and blocking sprayer, the problem of the too small color development difference of ink fineness.Particles of ink size distribution concentrates the storage stability for improving package ink, prints fluency, avoids the stability that colorant is improved color development by random destruction.Abundant tile product design is greatly simplified ceramic tile production process by the use for wrapping up ink, saves enterprise's production cost.
Description
Technical field
The present invention relates to a kind of preparation method of ceramic ink, in particular to a kind of ceramic ink jet printing package ink
Preparation method.
Background technique
In recent years, ceramic ink jet printing technology is with its high the degree of automation and production stability, replace rapidly silk screen,
Roll printing technology becomes most popular surface decoration technique, is known as china industry third time decoration technique revolution.With pottery
The all-round popularization application of porcelain inkjet printing technology, the ceramic ink demand as ceramic surface ornament materials are growing day by day.
Ceramic ink is generally made of colorant, resin, dispersing agent, levelling agent, defoaming agent, anti-settling agent and solvent.Ink-jet is beaten
Print needs to grind in colorant with ink, dispersion is prepared into ink, the necessary fine of the colorant in ink to sub-micron, Nano grade
It is just able to achieve inkjet printing, otherwise just not can guarantee the smoothness of inkjet printing, or even spray head can be blocked.For common non-package
For type colorant, reach specified partial size as long as colorant grinding is crushed, so that it may guarantee its hair color effect.Colorant grinding is broken
Particle shape afterwards does not have particular/special requirement, can be any form.Such as in the prior art, the ink such as praseodymium yellow, reddish brown, cobalt blue, cobalt black
Water is usually to pass through level-one grinding distribution to be prepared.
Different colors can be generated in red, yellow, primary colors after being overlapped mutually, currently, Red ceramic ink is mainly with powder
It is especially reddish brown based on red, reddish brown, but reddish brown ink color development is shallower, darker, and the tile product color produced is not fresh enough
Gorgeous, color is not abundant enough, dull image, easily distortion, it usually needs increase screen printing process after inkjet printing, it is therefore an objective to
Complementary color is carried out to product with the fancy glaze for containing package Red pigment to solve the problems, such as.But this not only adds production operations
Complexity also adds manually and equipment cost.
Bright red and package rheum officinale ink is wrapped up, bright-colored pure, full color, saturation degree are high, can be with other colors
Ink is superimposed out more wide gamut range, is greatly enriched the type of ceramic ink colour system, so that tile product pattern,
The performance of pattern is more rich and varied.The transmission electron microscope picture of exemplary package colorant is as shown in Figure 1, in coated color in ceramic ink
In material, chromogen is wrapped in the inside of pigment.If the shell (such as zirconium silicate shell) outside chromogen is destroyed, chromogen will be complete
It is naked to be exposed in air, be oxidized decomposition at high temperature, cause its can not color development or color it is dim, extreme influence hair color effect.
But particle is generally large, and further micronization processes is needed to can be only used for ceramic ink jet printing.
In general, the particle in ceramic ink is more uniform, particle diameter distribution is narrower, is more conducive to the hair for wrapping up ink
Color.But due to the special package structure of coated colorant, there is situation of facing a difficult choice during grinding refinement, on the one hand, to protect
Its hair color effect is demonstrate,proved, cannot be by its overgrinding, in order to avoid destroy its coated structure, but the particle of colorant is too big, then ink
Storage stability is poor, easily generates precipitating;On the other hand, it and requires its particle thinner, guarantees the fluency and ink of its printing
The stability of water, but most probably because package structure is destroyed, it is difficult to color development.
The coated ceramic ink that can be used for inkjet printing is prepared, is to simplify ceramics printing production technology, reduce
The key of production cost.
Summary of the invention
It is good that it is an object of the invention to overcome the deficiencies of the prior art and provide a kind of hair color effects, is suitable for ceramic ink jet
The printing small particle ceramic ink jet printing preparation method of package ink.
The technical solution used in the present invention is:
A kind of ceramic ink jet printing preparation method of package ink, includes the following steps:
1) occlusion pigment and solvent are mixed, is uniformly dispersed, obtains to abrasive material;
2) level-one grinding will be carried out to abrasive material, the size of abrasive media is 1.0~1.5mm, is ground to the average grain of colorant
Diameter is 1.0~1.3 μm, obtains level-one abrasive;
3) level-one abrasive is subjected to secondary grinder, the size of abrasive media is 0.7~1.0mm and is less than level-one grinding
Abrasive media, the average grain diameter for being ground to colorant is 0.7~0.9 μm, obtains secondary grinder material;
4) secondary grinder material is subjected to three-level grinding, the size of abrasive media is 0.5~0.7mm and is less than secondary grinder
Abrasive media, the average grain diameter for being ground to colorant is 0.5~0.6 μm, obtains starching for the colorant of ceramic ink jet printing;
5) colorant is starched and is mixed with other auxiliary agents, obtain ceramic ink jet printing package ink.
As the further improvement of above-mentioned preparation method, the size of abrasive media that level-one grinding uses is 1.1~
1.3mm。
As the further improvement of above-mentioned preparation method, the size of the abrasive media that secondary grinder uses is 0.7~
0.9mm。
As the further improvement of above-mentioned preparation method, the size of abrasive media that three-level grinding uses is 0.5~
0.6mm。
As the further improvement of above-mentioned preparation method, the initial partial size of occlusion pigment is 1~5 μm.
As the further improvement of above-mentioned preparation method, occlusion pigment is selected from zirconium silicate package, and cadmium sulfoselenide is bright red and silicic acid
Zirconium wraps up at least one of cadmium sulfide rheum officinale.
As the further improvement of above-mentioned preparation method, the quality group of ceramic ink jet printing package ink becomes: package
Colorant 30~60%, resin 1~5%, dispersing agent 3~8%, levelling agent 0~0.5%, defoaming agent 0~0.6%, anti-settling agent 0~
0.5%, surplus is solvent.
As the further improvement of above-mentioned preparation method, resin includes in alkyd resin, acrylic resin and polyester resin
At least one.
As the further improvement of above-mentioned preparation method, by occlusion pigment, resin, dispersing agent, anti-settling agent and partial solvent
Mixing is uniformly dispersed, and obtains to abrasive material.
As the further improvement of above-mentioned preparation method, dispersing agent stands alone as polyurethane-type dispersing agent.
As the further improvement of above-mentioned preparation method, levelling agent stands alone as Levaslip8629.
As the further improvement of above-mentioned preparation method, anti-settling agent stands alone as Disparlon NS-5501 or hamming this SD-
1。
As the further improvement of above-mentioned preparation method, solvent independently includes diethylene glycol dimethyl ether, ethylene glycol ethyl ether acetic acid
At least one of ester, propylene glycol methyl ether acetate and alicyclic hydrocarbon type organic solvent.
The beneficial effects of the present invention are:
The method of the present invention is easy to operate efficiently, the preparation suitable for a variety of package inks.In the ceramic ink being prepared,
Pigment granules are uniform, and size distribution is narrow, and average grain diameter is 500~600nm, and maximum particle diameter is no more than 1 μm, and package ink passes through
Color development is full bright-coloured after 1000~1300 DEG C of high temperature firings, can be used for tile production, it can also be used to Antique Imitation Tiles field.Solves ink
The excessive easy precipitating of water fineness and blocking sprayer, the problem of the too small color development difference of ink fineness.Particles of ink size distribution, which is concentrated, to be improved
The storage stability of package ink, prints fluency, avoids colorant by random destroy and improves the stability of color development.Packet
Abundant tile product design is greatly simplified ceramic tile production process by the use for wrapping up in ink, saves enterprise's production cost.
Detailed description of the invention
Fig. 1 is the transmission electron microscope picture of exemplary package colorant;
Fig. 2 is that the ceramic ink jet printing of comparative example 1-3 and embodiment 1-4 preparation wraps up bright red, rheum officinale ink burning
Finished product photo after;
Specific embodiment
A kind of ceramic ink jet printing preparation method of package ink, includes the following steps:
1) occlusion pigment and solvent are mixed, is uniformly dispersed, obtains to abrasive material;
2) level-one grinding will be carried out to abrasive material, the size of abrasive media is 1.0~1.5mm, is ground to the average grain of colorant
Diameter is 1.0~1.3 μm, obtains level-one abrasive;
3) level-one abrasive is subjected to secondary grinder, the size of abrasive media is 0.7~1.0mm and is less than level-one grinding
Abrasive media, the average grain diameter for being ground to colorant is 0.7~0.9 μm, obtains secondary grinder material;
4) secondary grinder material is subjected to three-level grinding, the size of abrasive media is 0.5~0.7mm and is less than secondary grinder
Abrasive media, the average grain diameter for being ground to colorant is 0.5~0.6 μm, obtains starching for the colorant of ceramic ink jet printing;
5) colorant is starched and is mixed with other auxiliary agents, obtain ceramic ink jet printing package ink.
As the further improvement of above-mentioned preparation method, the size of abrasive media that level-one grinding uses is 1.1~
1.3mm。
As the further improvement of above-mentioned preparation method, the size of the abrasive media that secondary grinder uses is 0.7~
0.9mm。
As the further improvement of above-mentioned preparation method, the size of abrasive media that three-level grinding uses is 0.5~
0.6mm。
Particularly, the size for the abrasive media that level-one grinding uses is 1.1~1.3mm;The grinding medium that secondary grinder uses
The size of matter is 0.7~0.9mm;The size for the abrasive media that three-level grinding uses is 0.5~0.6mm.
As the further improvement of above-mentioned preparation method, the initial partial size of occlusion pigment is 1~5 μm.
As the further improvement of above-mentioned preparation method, occlusion pigment is selected from zirconium silicate package, and cadmium sulfoselenide is bright red and silicic acid
Zirconium wraps up at least one of cadmium sulfide rheum officinale.
Ceramic ink jet printing wraps up ink can be according to the needs of actual production, according to existing ceramic ink jet printing ink
Composition compound to obtain.As the further improvement of above-mentioned preparation method, the quality composition of ceramic ink jet printing package ink
Are as follows: occlusion pigment 30~60%, resin 1~5%, dispersing agent 3~8%, levelling agent 0~0.5%, are prevented defoaming agent 0~0.6%
Heavy agent 0~0.5%, surplus is solvent.
As the further improvement of above-mentioned preparation method, resin includes in alkyd resin, acrylic resin and polyester resin
At least one.
To simplify production technology, improve mixed effect, as the further improvement of above-mentioned preparation method, by occlusion pigment,
Resin, dispersing agent, anti-settling agent and partial solvent mixing are uniformly dispersed, and obtain to abrasive material.It grinds together later, in the process of grinding
In and component can more fully be uniformly mixed.
As the further improvement of above-mentioned preparation method, dispersing agent stands alone as polyurethane-type dispersing agent.
As the further improvement of above-mentioned preparation method, levelling agent stands alone as Levaslip8629.
As the further improvement of above-mentioned preparation method, anti-settling agent stands alone as Disparlon NS-5501 or hamming this SD-
1。
As the further improvement of above-mentioned preparation method, solvent independently includes diethylene glycol dimethyl ether, ethylene glycol ethyl ether acetic acid
At least one of ester, propylene glycol methyl ether acetate and alicyclic hydrocarbon type organic solvent.
Below with reference to embodiment, technical solution of the present invention is further illustrated.
For the sake of facilitating comparison, in following embodiment and comparative example, resin is YL-885 polyester resin, and dispersing agent is polyurethane
Type dispersing agent TR-7010, levelling agent Levaslip8629, defoaming agent are organic silicon defoamer AT-99, anti-settling agent be hamming this
SD-1, solvent are alicyclic hydrocarbon type organic solvent.
Embodiment 1
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium package cadmium sulfoselenide is bright red) 50%, resin 2%, dispersing agent 6%, levelling agent 0.1%, defoaming agent 0.1%, anti-settling agent
0.2%, surplus is solvent.
Embodiment 2
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium package cadmium sulfoselenide is bright red) 50%, resin 2.5%, dispersing agent 5.5% is levelling agent 0.1%, defoaming agent 0.1%, anti-settling
Agent 0.25%, surplus are solvent.
Embodiment 3
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium wraps up cadmium sulfide rheum officinale) 50%, resin 3%, dispersing agent 6%, levelling agent 0.1%, defoaming agent 0.2%, anti-settling agent
0.3%, surplus is solvent.
Embodiment 4
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium wraps up cadmium sulfide rheum officinale) 50%, resin 2%, dispersing agent 4.5%, levelling agent 0.2%, defoaming agent 0.2%, anti-settling agent
0.15%, surplus is solvent.
Comparative example 1
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium package cadmium sulfoselenide is bright red) 50%, resin 2%, dispersing agent 6%, levelling agent 0.1%, defoaming agent 0.1%, anti-settling agent
0.2%, surplus is solvent.
Comparative example 2
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium wraps up cadmium sulfide rheum officinale) 50%, resin 2.5%, dispersing agent 5%, levelling agent 0.1%, defoaming agent 0.2%, anti-settling agent
0.3%, surplus is solvent.
Comparative example 3
A kind of ceramic ink jet printing package ink, it is by mass percentage, composed of the following components: occlusion pigment (silicon
Sour zirconium package vulcanization cadmium crimson) 50%, resin 3%, dispersing agent 6%, levelling agent 0.1%, defoaming agent 0.2%, anti-settling agent
0.3%, surplus is solvent.
Different ceramic ink jet printings are as shown in table 1 with the preparation process of package ink, and it is flat that control final grinding obtains colorant
Equal partial size is 400~600nm.
The preparation technology parameter table of table 1, ceramic ink jet printing package ink
Performance detection:
Performance detection is carried out with package ink to the ceramic ink jet printing being prepared, test result is as shown in table 2.
The performance test results of table 2, ceramic ink jet printing package ink
Note: viscosity is obtained at 40 DEG C using rotary viscosimeter measurement;Surface tension 40 DEG C at a temperature of using dynamic
Surface tension instrument measurement obtains.
By analysis result it is found that comparative example 1~2 is uneven by the particles of ink size distribution of level-one grinding preparation,
(D90-D10)/D50 ratio size indicates the width of size distribution, and the obvious ratio 1-4's of the particle diameter distribution of comparative example 1~2 wants
Width, particle diameter distribution are easy that bimodal or multi-modal is presented, and many pigment granules fineness are too big, and ink suspension is poor, easily generate
Precipitating blocks spray head.Comparative example 3 is by secondary grinder, though ink performance can be improved compared with comparative example 1~2, but still ratio is not
The three-level grinding effect of upper example 1-4.
And ink viscosity prepared by the embodiment of the present invention 1~4 is 15.0~40.0mPas, surface tension 20~
30mN/m, particle diameter distribution is uniform, and average grain diameter is between 500~600nm, and maximum particle diameter is no more than 1 μm, and stability is good,
With good inkjet printing smoothness performance.There is not phenomena such as broken string, streak, will not wear and block spray head, printing
Pattern in detail is clear, bright-colored.This is because three-level grinding is first ground with biggish using well-regulated lapping mode step by step
Bulky grain colorant is crushed control in medium size range, then using medium sized abrasive media medium grain by grinding media
Colorant crush again, last lesser abrasive media is further ground, and final pigment granules partial size is concentrated mainly on 400
~700nm, ratio are up to 80%, this makes the color development for wrapping up ink good, and suspension stability is good.Three-level lapping mode, overcomes
The shortcomings that package reddish yellow abrasive lapping is too thin on the market at present, color development power reduces.The package ink handled by three-level grinding distribution
Water particle diameter distribution is very narrow, solves the disadvantages that package reddish yellow particles of ink is big from production technology, and bad dispersibility has very big
Market prospects.
It is as follows to wrap up ink ceramic ink jet printing Product Process production process:
Press green compact → body drying → green body water spray leaching overglaze (bell jar) → adobe surface ceramic ink jet printing →
Adobe leaching throws glaze (bell jar) → semi-finished product into 1200 DEG C of firing → finished products of kiln.
Fig. 2 is after the ceramic ink jet printing of comparative example 1-3 and embodiment 1-4 preparation wraps up bright red, rheum officinale ink firing
Finished product photo, number 1-3 in comparative example 1-3 corresponding diagram, number 4-7 in embodiment 1-4 corresponding diagram.It can be seen from the figure that
There is phenomena such as bracing wire, broken string in the easy blocking sprayer of package ink of comparative example 1-3 preparation, the pattern of printing, wherein No. 1 the tightest
Weight, followed by No. 2 and No. 3;Comparative example 2 is by adding prolonged level-one to grind, and the ink of preparation is not only without improving printing stream
Smooth property, and occlusion pigment causes pattern color development to be deteriorated instead by random serious destruction;And the ink of embodiment 1-4 preparation
Water, printing is smooth, does not occur the phenomenon that bracing wire, broken string, and 4-7 pattern color development is bright-coloured full.
Claims (10)
1. a kind of ceramic ink jet printing preparation method of package ink, includes the following steps:
1) occlusion pigment and solvent are mixed, is uniformly dispersed, obtains to abrasive material;
2) level-one grinding will be carried out to abrasive material, the size of abrasive media is 1.0~1.5mm, and the average grain diameter for being ground to colorant is
1.0~1.3 μm, obtain level-one abrasive;
3) level-one abrasive is subjected to secondary grinder, the size of abrasive media is 0.7~1.0mm and is less than the grinding of level-one grinding
Medium, the average grain diameter for being ground to colorant is 0.7~0.9 μm, obtains secondary grinder material;
4) secondary grinder material is subjected to three-level grinding, the size of abrasive media is 0.5~0.7mm and is less than the grinding of secondary grinder
Medium, the average grain diameter for being ground to colorant is 0.5~0.6 μm, obtains starching for the colorant of ceramic ink jet printing;
5) colorant is starched and is mixed with other auxiliary agents, obtain ceramic ink jet printing package ink.
2. preparation method according to claim 1, it is characterised in that: the size of abrasive media that level-one grinding uses is
1.1~1.3mm.
3. preparation method according to claim 1, it is characterised in that: the size for the abrasive media that secondary grinder uses is
0.7~0.9mm.
4. preparation method according to claim 1, it is characterised in that: the size of abrasive media that three-level grinding uses is
0.5~0.6mm.
5. preparation method according to any one of claims 1 to 4, it is characterised in that: the initial partial size of occlusion pigment be 1~
5μm。
6. preparation method according to any one of claims 1 to 4, it is characterised in that: occlusion pigment is wrapped up selected from zirconium silicate
Cadmium sulfoselenide is bright red and zirconium silicate wraps up at least one of cadmium sulfide rheum officinale.
7. preparation method according to any one of claims 1 to 4, it is characterised in that: ceramic ink jet printing package ink
Quality group become: occlusion pigment 30~60%, resin 1~5%, dispersing agent 3~8%, levelling agent 0~0.5%, defoaming agent 0
~0.6%, anti-settling agent 0~0.5%, surplus are solvent.
8. preparation method according to claim 7, it is characterised in that: resin includes alkyd resin, acrylic resin and gathers
At least one of ester resin.
9. preparation method according to claim 7, it is characterised in that: by occlusion pigment, resin, dispersing agent, anti-settling agent and
Partial solvent mixing is uniformly dispersed, and obtains to abrasive material.
10. preparation method according to claim 7, it is characterised in that: dispersing agent stands alone as polyurethane-type dispersing agent;Levelling
Agent stands alone as Levaslip8629;Anti-settling agent stands alone as Disparlon NS-5501 or hamming this SD-1;Solvent independently includes two
At least one of ethylene glycol monomethyl ether, ethylene glycol ether acetate, propylene glycol methyl ether acetate and alicyclic hydrocarbon type organic solvent.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111004038A (en) * | 2020-01-02 | 2020-04-14 | 杭州诺贝尔陶瓷有限公司 | Ultra-large specification thin porcelain plate with electric heating function and production method thereof |
CN111018543A (en) * | 2020-01-02 | 2020-04-17 | 杭州诺贝尔陶瓷有限公司 | Once-fired ultra-large specification thin porcelain plate and production method thereof |
CN113234357A (en) * | 2021-05-12 | 2021-08-10 | 闻涛 | Preparation method of environment-friendly high-performance digital ink-jet red ink |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996023032A1 (en) * | 1995-01-27 | 1996-08-01 | Toyo Ink Manufacturing Co., Ltd. | Recording fluid for ink-jet printing and process for production thereof |
CN102964920A (en) * | 2012-11-27 | 2013-03-13 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
WO2013104033A1 (en) * | 2012-01-13 | 2013-07-18 | Mineraçao Floresta Ltda | Process for obtaining a titanium dioxide pigment |
CN103466645A (en) * | 2013-09-27 | 2013-12-25 | 上海冠旗电子新材料股份有限公司 | Method for preparing nano-silica by wet grinding |
WO2014062227A1 (en) * | 2012-10-15 | 2014-04-24 | Sun Chemical Corporation | Pigment dispersions and printing inks with improved coloristic properties |
US20140186585A1 (en) * | 2012-12-31 | 2014-07-03 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive blasting media and methods of forming and using same |
CN104860720A (en) * | 2015-05-07 | 2015-08-26 | 广东宏陶陶瓷有限公司 | Ceramic decoration high-temperature bright red inkjet ink preparation method and application thereof |
CN105419394A (en) * | 2015-11-25 | 2016-03-23 | 赖清甜 | Red ceramic pigment and preparation method thereof |
CN107033672A (en) * | 2017-05-16 | 2017-08-11 | 佛山市禅信陶瓷釉料有限公司 | A kind of big red ink of refractory ceramics and preparation method thereof |
CN108178613A (en) * | 2018-01-24 | 2018-06-19 | 江西绿岛科技有限公司 | Tertiary colour imitates stone product, preparation method and its preparation system |
CN108276830A (en) * | 2018-01-25 | 2018-07-13 | 山东国瓷功能材料股份有限公司 | A kind of ceramic ink jet printing water-based ink and preparation method thereof |
-
2018
- 2018-12-28 CN CN201811617766.9A patent/CN109852142B/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996023032A1 (en) * | 1995-01-27 | 1996-08-01 | Toyo Ink Manufacturing Co., Ltd. | Recording fluid for ink-jet printing and process for production thereof |
WO2013104033A1 (en) * | 2012-01-13 | 2013-07-18 | Mineraçao Floresta Ltda | Process for obtaining a titanium dioxide pigment |
WO2014062227A1 (en) * | 2012-10-15 | 2014-04-24 | Sun Chemical Corporation | Pigment dispersions and printing inks with improved coloristic properties |
CN102964920A (en) * | 2012-11-27 | 2013-03-13 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
US20140186585A1 (en) * | 2012-12-31 | 2014-07-03 | Saint-Gobain Ceramics & Plastics, Inc. | Abrasive blasting media and methods of forming and using same |
CN103466645A (en) * | 2013-09-27 | 2013-12-25 | 上海冠旗电子新材料股份有限公司 | Method for preparing nano-silica by wet grinding |
CN104860720A (en) * | 2015-05-07 | 2015-08-26 | 广东宏陶陶瓷有限公司 | Ceramic decoration high-temperature bright red inkjet ink preparation method and application thereof |
CN105419394A (en) * | 2015-11-25 | 2016-03-23 | 赖清甜 | Red ceramic pigment and preparation method thereof |
CN107033672A (en) * | 2017-05-16 | 2017-08-11 | 佛山市禅信陶瓷釉料有限公司 | A kind of big red ink of refractory ceramics and preparation method thereof |
CN108178613A (en) * | 2018-01-24 | 2018-06-19 | 江西绿岛科技有限公司 | Tertiary colour imitates stone product, preparation method and its preparation system |
CN108276830A (en) * | 2018-01-25 | 2018-07-13 | 山东国瓷功能材料股份有限公司 | A kind of ceramic ink jet printing water-based ink and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
OKSUZOGLU, BILGE等: ""An experimental study on the ultra-fine grinding of gypsum ore in a dry ball mill"", 《POWDER TECHNOLOGY》 * |
徐研等: ""新型大红陶瓷色料的研制"", 《陶瓷》 * |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN111004038A (en) * | 2020-01-02 | 2020-04-14 | 杭州诺贝尔陶瓷有限公司 | Ultra-large specification thin porcelain plate with electric heating function and production method thereof |
CN111018543A (en) * | 2020-01-02 | 2020-04-17 | 杭州诺贝尔陶瓷有限公司 | Once-fired ultra-large specification thin porcelain plate and production method thereof |
CN111004038B (en) * | 2020-01-02 | 2022-05-03 | 杭州诺贝尔陶瓷有限公司 | Super-large-specification thin porcelain plate with electrothermal function and production method thereof |
CN113234357A (en) * | 2021-05-12 | 2021-08-10 | 闻涛 | Preparation method of environment-friendly high-performance digital ink-jet red ink |
CN113234357B (en) * | 2021-05-12 | 2023-05-05 | 闻涛 | Preparation method of environment-friendly high-performance digital inkjet red ink |
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Effective date of registration: 20221117 Address after: 529441 Room 102, 1st floor, Daoshi technology complex building, Sanlian fozai'ao, Shengtang Town, Enping City, Jiangmen City, Guangdong Province Patentee after: Guangdong Dow ceramic materials Co.,Ltd. Address before: 528031 Building 1, No. 131, Jihua West Road, Chancheng District, Foshan City, Guangdong Province Patentee before: FOSHAN DOWSTONG TECHNOLOGY Co.,Ltd. |