CN105907177A - Tempered glass ink for ink-jet printing and preparation method thereof - Google Patents
Tempered glass ink for ink-jet printing and preparation method thereof Download PDFInfo
- Publication number
- CN105907177A CN105907177A CN201610315821.3A CN201610315821A CN105907177A CN 105907177 A CN105907177 A CN 105907177A CN 201610315821 A CN201610315821 A CN 201610315821A CN 105907177 A CN105907177 A CN 105907177A
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- ink
- safety glass
- inkjet printing
- solvent
- glass ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a tempered glass ink for ink-jet printing and a preparation method thereof. The ink is prepared from low-temperature frit, inorganic pigments, a dispersant, resin, a flatting agent and a solvent. The tempered glass ink for ink-jet printing has good stability, favorable ink-jet printing performance, low viscosity which ranges from 10.0 to 40.0mPa.s and can be regulated, uniform particle size distribution, the surface tension of 25 to 35mN/m, an average particle size of 200 to 400 nm and a maximum particle size of less than 1 micrometers, and can be stored for a long time. The ink prepared by the preparation method disclosed by the invention has low sintering temperature and can be well combined with glass. The sintered surface is strongly resistant to acid, alkaline and ultraviolet radiation.
Description
Technical field
The present invention relates to a kind of special ink, particularly to a kind of inkjet printing safety glass ink and preparation side thereof
Method.
Background technology
Colored glazed glass is by the ink made by inorganic glaze, is printed onto glass surface, then drying, tempering or thermalization
Working process, is forever sintered in glass surface by glaze and obtains a kind of wear-resisting, decorative glasses product of acid and alkali-resistance.Colored glaze glass
Inorganic glaze is generally decorated at glass surface by the technique such as serigraphy or roller printing by glass, is passing through drying, is being heat-treated,
Finally form permanent firm glaze layer at glass surface.But there is many lacking by serigraphy or roller printing mode
Point: 1) color of texture is single with pattern, it is difficult to make the pattern product of complexity；2) traditional handicraft inorganic glaze utilization rate is low,
Raw materials consumption and environmental pollution are huge, production cost height and the trend requirement not meeting energy-conserving and environment-protective；3) system is needed in producing
Sheet, shining net, the cumbersome process such as cut blocks for printing, the production cycle is long, and yield rate is low.
Inkjet technology is a kind of contactless digital printing technologies, is the glass decoration skill of a kind of great potential
Art.Relatively conventional typography, has abandoned the loaded down with trivial details of Conventional decal mode, and the precision that improve stamp can realize product individuality
Metaplasia is produced, and image appearance is the finest and the smoothest truly, efficient without version, is advantageously implemented the small lot glass of rich color, multiple patterns
Glass production of articles.Inkjet technology is the preparation of glass ink at the key application of glass decoration, and glass ink is by low
Temperature frit, inorganic pigment, solvent, dispersant, link stuff and other auxiliary agent are formed, and usually require that the particle diameter of inorganic glaze is less than
1 micron, Size Distribution is narrow, has good suspending stabilized performance simultaneously.Therefore develop that suspendability is good, print performance is excellent
Different inkjet printing safety glass ink is significant to promoting glass decoration technical merit.
Summary of the invention
It is an object of the invention to provide a kind of inkjet printing safety glass ink and preparation method thereof.
The technical solution used in the present invention is:
A kind of inkjet printing safety glass ink, containing the component of following mass percent: low temperature frit 20～45%, inorganic
Pigment 10～25%, dispersant 3～10%, resin 1～5%, levelling agent 0.1～0.2%, surplus is solvent；Wherein, low temperature frit is
Environmental-friendly lead-free frit, fusing point is less than 600 DEG C, consisting of SiO220～40%, B2O35～20%, Bi2O330～60%, Al2O3
1～5%, ZrO21～4%, (K+Na)2O 0.5～2%, Li2O 1～3%.
As the further improvement of above-mentioned inkjet printing safety glass ink, dispersant is the high score containing parent's pigment group
Son amount dispersant.
As the further improvement of above-mentioned inkjet printing safety glass ink, resin is alkyd resin, acrylic resin
In at least one.
As the further improvement of above-mentioned inkjet printing safety glass ink, levelling agent is polyacrylate or polyethers
At least one in modified siloxane.
As the further improvement of above-mentioned inkjet printing safety glass ink, solvent be ether solvent, esters solvent or
At least one in person's ketone.
As the further improvement of above-mentioned inkjet printing safety glass ink, ether solvent is butyl glycol ether, diethyl
Glycol methyl ether, butyl, propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, dipropylene, 3 the third two
Alcohol methyl ether, at least one in tripropylene glycol butyl ether；Esters solvent be ethylene glycol ether acetate, propylene glycol methyl ether acetate,
At least one in propylene-glycol diacetate；Ketones solvent is cyclohexanone.
As the further improvement of above-mentioned inkjet printing safety glass ink, inorganic pigment be iron oxide red, cobalt aluminium blue,
Titanium yellow, titanium chrome yellow or copper-chrome black.
A kind of ornament materials with safety glass ink layer, ornament materials has above-mentioned inkjet printing safety glass oil
The decorative pattern that ink solidify to form.
The preparation method of a kind of inkjet printing safety glass ink, comprises the steps:
1) preparation of low temperature frit: select corresponding raw material to mix in proportion, then at 800～1400 DEG C by the composition of oxide
Under be sintered into frit, be then broken to below 300 mesh；
2) preparation of micro-nano low temperature glaze slip: solvent, dispersant and low-temperature glaze are mixed, is uniformly dispersed, makes glaze fully moisten
Wet；Utilizing sand mill to grind scattered material, the particle diameter of grinding zirconium pearl, between 0.3～1.0mm, controls the average of material
Particle diameter is 200～400 nm, and maximum particle diameter is less than 1 micron, obtains micro-nano low temperature glaze slip；
3) preparation of micro-nano mill base: solvent, dispersant and inorganic pigment are mixed, is uniformly dispersed, makes pigment fully soak；Will
Scattered material crushes further, and the average grain diameter controlling material is 200～400 nm, and maximum particle diameter is less than 1 micron, obtains micro-
Nano color paste；
4) put in proportion glaze will and mill base, add levelling agent, resin and residual solvent, stir, utilize 1 micron of filter
Core filters, and obtains inkjet printing safety glass ink；
Wherein, inkjet printing safety glass ink is described above.
The invention has the beneficial effects as follows:
The inkjet printing safety glass ink stability of the present invention is good, can preserve for a long time, and have good inkjet printing
Performance, and the viscosity of ink is low, even particle size distribution, the viscosity of ink between 10.0～40.0 mPa s and controllable,
Surface tension is 25～35 mN/m, and average grain diameter is 200～400 nm, and maximum particle diameter is less than 1 micron.Oil prepared by the present invention
Ink firing temperature is low, good with glass associativity, and surface resistance to acids and bases after burning till is strong and anti-ultraviolet radiation.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated, but limitation is not such.
Embodiment 1
Embodiment 2
Embodiment 3
Embodiment 4
Embodiment 5
The inkjet printing of the above example preparation method of safety glass ink, comprises the steps: (1) low-temperature glaze
Preparation: by oxide composition select corresponding raw material mix in proportion, then at 800～1400 DEG C, be sintered into frit,
It is then passed through ball mill crushing to below 300 mesh；(2) preparation of micro-nano low temperature glaze slip: solvent, dispersant and low-temperature glaze are mixed
Close, be uniformly dispersed, make glaze fully soak；Utilize sand mill to grind scattered material, grind the particle diameter of zirconium pearl 0.3～
Between 1.0mm, the average grain diameter controlling material is 200～400 nm, and maximum particle diameter is less than 1 micron, obtains micro-nano low temperature glaze slip；
(3) preparation of micro-nano mill base: solvent, dispersant and inorganic pigment are mixed, is uniformly dispersed, makes pigment fully soak；To divide
The material dissipated utilizes sand mill to grind, the particle diameter of zirconium pearl between 0.3～1.0mm, control material average grain diameter be 200～
400 nm, maximum particle diameter is less than 1 micron, obtains micro-nano mill base；(4) in proportion put into glaze will and mill base, add levelling agent, resin
And residual solvent, stir, utilize 1 micron of filter element filtering, obtain inkjet printing safety glass ink.
The performance test results of the safety glass ink of table 1 embodiment 1～5 preparation
Ink viscosity prepared by the present invention is 10.0～40.0 mPa s, and surface tension is distributed at 25～35 mN/m, particle diameter
Uniformly, average grain diameter is between 200～400 nm, and maximum particle diameter is less than 1 micron, and good stability, there is good ink-jet
Print performance and glass binding ability.
The safety glass ink print that embodiment 1～5 prepares is printed upon on different plate glass respectively, afterwards
Burn till.Testing result surface ink is tightly combined with glass, the most peelable.
Claims (9)
1. an inkjet printing safety glass ink, containing the component of following mass percent: low temperature frit 20～45%, nothing
Machine pigment 10～25%, dispersant 3～10%, resin 1～5%, levelling agent 0.1～0.2%, surplus is solvent；Wherein, low temperature frit
For environmental-friendly lead-free frit, fusing point is less than 600 DEG C, consisting of SiO220～40%, B2O35～20%, Bi2O330～60%,
Al2O31～5%, ZrO21～4%, (K+Na)2O 0.5～2%, Li2O 1～3%.
Inkjet printing safety glass ink the most according to claim 1, it is characterised in that: dispersant is for containing parent's pigment base
The high molecular weight dispersant of group.
Inkjet printing safety glass ink the most according to claim 1, it is characterised in that: resin be alkyd resin, third
At least one in olefin(e) acid resin.
Inkjet printing safety glass ink the most according to claim 1, it is characterised in that: levelling agent is polyacrylate
Or at least one in polyether modified siloxane.
Inkjet printing safety glass ink the most according to claim 1, it is characterised in that: solvent is ether solvent, ester
At least one in kind solvent or ketone.
Inkjet printing safety glass ink the most according to claim 5, it is characterised in that: ether solvent is ethylene glycol fourth
Ether, diethylene glycol dimethyl ether, butyl, propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, dipropylene,
Tripropylene glycol methyl ether, at least one in tripropylene glycol butyl ether；Esters solvent is ethylene glycol ether acetate, propylene glycol monomethyl ether vinegar
At least one in acid esters, propylene-glycol diacetate；Ketones solvent is cyclohexanone.
Inkjet printing safety glass ink the most according to claim 1, it is characterised in that: inorganic pigment is iron oxide
Red, cobalt aluminium indigo plant, titanium yellow, titanium chrome yellow or copper-chrome black.
8. an ornament materials with safety glass ink layer, it is characterised in that: ornament materials has claim 1～7
The decorative pattern that a described inkjet printing safety glass ink solidification of anticipating is formed.
9. an inkjet printing preparation method for safety glass ink, comprises the steps:
1) preparation of low temperature frit: select corresponding raw material to mix in proportion, then at 800～1400 DEG C by the composition of oxide
Under be sintered into frit, be then broken to below 300 mesh；
2) preparation of micro-nano low temperature glaze slip: solvent, dispersant and low-temperature glaze are mixed, is uniformly dispersed, makes glaze fully moisten
Wet；Utilizing sand mill to grind scattered material, the particle diameter of grinding zirconium pearl, between 0.3～1.0mm, controls the average of material
Particle diameter is 200～400 nm, and maximum particle diameter is less than 1 micron, obtains micro-nano low temperature glaze slip；
3) preparation of micro-nano mill base: solvent, dispersant and inorganic pigment are mixed, is uniformly dispersed, makes pigment fully soak；Will
Scattered material crushes further, and the average grain diameter controlling material is 200～400 nm, and maximum particle diameter is less than 1 micron, obtains micro-
Nano color paste；
4) put in proportion glaze will and mill base, add levelling agent, resin and residual solvent, stir, utilize 1 micron of filter
Core filters, and obtains inkjet printing safety glass ink；
Wherein, inkjet printing with safety glass ink as described in claim 1～7 any one.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510979373 | 2015-12-23 | ||
| CN2015109793732 | 2015-12-23 |
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| Publication Number | Publication Date |
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| CN105907177A true CN105907177A (en) | 2016-08-31 |
| CN105907177B CN105907177B (en) | 2019-04-30 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912836A (en) * | 2018-07-04 | 2018-11-30 | 山东汇龙色釉新材料科技有限公司 | A kind of inkjet printing glass ink and its preparation process |
| CN110511616A (en) * | 2019-08-15 | 2019-11-29 | 深圳市百柔新材料技术有限公司 | Rear reflector glaze ink and the method for making photovoltaic glass panel with it |
| CN110894380A (en) * | 2018-09-12 | 2020-03-20 | 广州精陶机电设备有限公司 | Printing ink, preparation method thereof and printer |
| CN111977967A (en) * | 2020-08-13 | 2020-11-24 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Environment-friendly high-corrosion-resistance low-temperature special automobile glass black fusing agent and preparation method and application thereof |
| CN114163872A (en) * | 2022-01-14 | 2022-03-11 | 英辉（大厂）自动化技术有限公司 | Low-viscosity automobile glass printing ink and preparation method thereof |
| CN114751647A (en) * | 2022-03-29 | 2022-07-15 | 华南理工大学 | Glass frit easy to grind and preparation method and application thereof |
| CN114963268A (en) * | 2022-06-16 | 2022-08-30 | 杭州老板电器股份有限公司 | Smoke machine panel and preparation method and application thereof |
| CN115466541A (en) * | 2022-08-03 | 2022-12-13 | 佛山市兴洲玻璃科技有限公司 | Method for cutting tempered ink glass in different places |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153809A (en) * | 2015-09-22 | 2015-12-16 | 东莞市贝特利新材料有限公司 | Glass ink-jet printing ink |
-
2016
- 2016-05-13 CN CN201610315821.3A patent/CN105907177B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153809A (en) * | 2015-09-22 | 2015-12-16 | 东莞市贝特利新材料有限公司 | Glass ink-jet printing ink |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912836A (en) * | 2018-07-04 | 2018-11-30 | 山东汇龙色釉新材料科技有限公司 | A kind of inkjet printing glass ink and its preparation process |
| CN110894380A (en) * | 2018-09-12 | 2020-03-20 | 广州精陶机电设备有限公司 | Printing ink, preparation method thereof and printer |
| CN110511616A (en) * | 2019-08-15 | 2019-11-29 | 深圳市百柔新材料技术有限公司 | Rear reflector glaze ink and the method for making photovoltaic glass panel with it |
| CN111977967A (en) * | 2020-08-13 | 2020-11-24 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Environment-friendly high-corrosion-resistance low-temperature special automobile glass black fusing agent and preparation method and application thereof |
| CN114163872A (en) * | 2022-01-14 | 2022-03-11 | 英辉（大厂）自动化技术有限公司 | Low-viscosity automobile glass printing ink and preparation method thereof |
| CN114751647A (en) * | 2022-03-29 | 2022-07-15 | 华南理工大学 | Glass frit easy to grind and preparation method and application thereof |
| CN114963268A (en) * | 2022-06-16 | 2022-08-30 | 杭州老板电器股份有限公司 | Smoke machine panel and preparation method and application thereof |
| CN115466541A (en) * | 2022-08-03 | 2022-12-13 | 佛山市兴洲玻璃科技有限公司 | Method for cutting tempered ink glass in different places |
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| Publication number | Publication date |
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| CN105907177B (en) | 2019-04-30 |
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Effective date of registration: 20211222 Address after: 529400 Room 102, 1f, Daoshi technology complex building, Sanlian fozi'ao, Shengtang Town, Enping City, Jiangmen City, Guangdong Province Patentee after: Guangdong Dow ceramic materials Co.,Ltd. Address before: 529441 Sanlian fo Tsao, Enping, Guangdong, Jiangmen Patentee before: GUANGDONG DOWSTONE TECHNOLOGY Co.,Ltd. |