CN105907177B - A kind of inkjet printing tempered glass ink and preparation method thereof - Google Patents
A kind of inkjet printing tempered glass ink and preparation method thereof Download PDFInfo
- Publication number
- CN105907177B CN105907177B CN201610315821.3A CN201610315821A CN105907177B CN 105907177 B CN105907177 B CN 105907177B CN 201610315821 A CN201610315821 A CN 201610315821A CN 105907177 B CN105907177 B CN 105907177B
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- tempered glass
- solvent
- inkjet printing
- ink
- low temperature
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Abstract
The invention discloses a kind of inkjet printing tempered glass ink and preparation method thereof, and ink is by low temperature frit, inorganic pigment, dispersing agent, resin, levelling agent and solvent composition；Inkjet printing of the invention is good with tempered glass ink stability, it can save for a long time, and there is good Ink Jet Printing Performance, and the viscosity of ink is low, particle diameter distribution is uniform, and the viscosity of ink is between 10.0~40.0 mPas and controllable, and surface tension is 25~35 mN/m, average grain diameter is 200~400 nm, and maximum particle diameter is less than 1 micron.Ink firing temperature prepared by the present invention is low, good with glass associativity, and the surface resistance to acid and alkali after firing is strong and anti-ultraviolet radiation.
Description
Technical field
The present invention relates to a kind of special ink, in particular to a kind of inkjet printing tempered glass ink and its preparation side
Method.
Background technique
Colored glazed glass is that ink made by inorganic glaze is printed onto glass surface, then drying, tempering or thermalization
Glaze is permanently sintered in glass surface and obtains a kind of wear-resisting, acid and alkali-resistance decorative glasses product by working process.Colored glaze glass
Glass usually passes through the techniques such as silk-screen printing or roller printing for inorganic glaze decoration in glass surface, is passing through drying, heat treatment,
Finally permanent firm glaze layer is formed in glass surface.But it is lacked by silk-screen printing or roller printing mode there is many
Point: 1) color of texture and pattern are single, it is difficult to make complicated pattern product；2) the inorganic glaze utilization rate of traditional handicraft is low,
Raw materials consumption and environmental pollution are huge, and high production cost is required with energy-saving and environment-friendly trend is not met；3) it needs to make in production
Piece shines net, the cumbersome process such as cut blocks for printing, and the production cycle is long, and yield rate is low.
Inkjet printing technology is a kind of contactless digital printing technologies, is a kind of glass decoration skill of great potential
Art.Opposite Conventional printing process, has abandoned the cumbersome of Conventional decal mode, product individuality may be implemented in the precision for improving stamp
Metaplasia produces, and image appearance is finer and smoother true, and no version is efficient, is advantageously implemented rich in color, multiple patterns small lot glass
Glass production of articles.Inkjet printing technology is the preparation of glass ink in the key application of glass decoration, and glass ink is by low
Warm frit, inorganic pigment, solvent, dispersing agent, link stuff and other auxiliary agents are formed, and usually require that the partial size of inorganic glaze is less than
1 micron, size distribution wants narrow, while having good suspending stabilized performance.Therefore develop that suspendability is good, print performance is excellent
Different inkjet printing tempered glass ink is of great significance to glass decoration technical level is promoted.
Summary of the invention
The purpose of the present invention is to provide a kind of inkjet printing tempered glass ink and preparation method thereof.
The technical solution used in the present invention is:
A kind of inkjet printing tempered glass ink, the component containing following mass percent: low temperature frit 20~45%,
Inorganic pigment 10~25%, dispersing agent 3~10%, resin 1~5%, levelling agent 0.1~0.2%, surplus are solvent；Wherein, low temperature is molten
Block is environmental-friendly lead-free frit, and fusing point is lower than 600 DEG C, consisting of SiO220~40%, B2O35~20%, Bi2O330~60%,
Al2O31~5%, ZrO21~4%, (K+Na)2O 0.5~2%, Li2O 1~3%.
As the further improvement of tempered glass ink of above-mentioned inkjet printing, dispersing agent is the high score containing close pigment group
Son amount dispersing agent.
As the further improvement of tempered glass ink of above-mentioned inkjet printing, resin is alkyd resin, acrylic resin
At least one of.
As the further improvement of tempered glass ink of above-mentioned inkjet printing, levelling agent is polyacrylate or polyethers
At least one of modified siloxane.
As the further improvement of tempered glass ink of above-mentioned inkjet printing, solvent be ether solvent, esters solvent or
At least one of person's ketone.
As the further improvement of tempered glass ink of above-mentioned inkjet printing, ether solvent is butyl glycol ether, diethyl
Glycol methyl ether, butyl, propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, dipropylene, 3 the third two
Alcohol methyl ether, at least one of tripropylene glycol butyl ether；Esters solvent be ethylene glycol ether acetate, propylene glycol methyl ether acetate,
At least one of propylene-glycol diacetate；Ketones solvent is cyclohexanone.
As the further improvement of tempered glass ink of above-mentioned inkjet printing, inorganic pigment is iron oxide red, cobalt aluminium is blue,
Titanium yellow, titanium chrome yellow or copper-chrome black.
A kind of ornament materials with tempered glass ink layer, ornament materials have above-mentioned inkjet printing tempered glass oil
The decorative pattern that ink is formed by curing.
A kind of inkjet printing preparation method of tempered glass ink, includes the following steps:
1) preparation of low temperature frit: selecting corresponding raw material to mix in proportion by the composition of oxide, then 800~
It is sintered into frit at 1400 DEG C, is then broken to 300 mesh or less；
2) preparation of micro-nano low temperature glaze slip: solvent, dispersing agent and low temperature frit are mixed, is uniformly dispersed, fills frit
It shares in the benefit wet；Scattered material is ground using sand mill, the partial size of zirconium pearl is ground between 0.3~1.0mm, controls material
Average grain diameter is 200~400 nm, and maximum particle diameter obtains micro-nano low temperature glaze slip less than 1 micron；
3) preparation of micro-nano mill base: solvent, dispersing agent and inorganic pigment are mixed, is uniformly dispersed, moistens pigment sufficiently
It is wet；Scattered material is further crushed, the average grain diameter for controlling material is 200~400 nm, and maximum particle diameter is micro- less than 1
Rice, obtains micro-nano mill base；
4) it is put in proportion into glaze slip and mill base, levelling agent, resin and residual solvent is added, stirs, it is micro- using 1
Rice filter element filtering, obtains inkjet printing tempered glass ink；
Wherein, inkjet printing is as described above with tempered glass ink.
The beneficial effects of the present invention are:
Inkjet printing of the invention is good with tempered glass ink stability, can save for a long time, and has good ink-jet
Print performance, and the viscosity of ink is low, particle diameter distribution is uniform, and the viscosity of ink is between 10.0~40.0 mPas and can
Regulation, surface tension are 25~35 mN/m, and average grain diameter is 200~400 nm, and maximum particle diameter is less than 1 micron.Present invention preparation
Ink firing temperature it is low, good with glass associativity, surface resistance to acid and alkali after firing is strong and anti-ultraviolet radiation.
Specific embodiment
Below with reference to specific embodiment, the present invention is further illustrated, but is not so limited.
Embodiment 1
。
Embodiment 2
。
Embodiment 3
。
Embodiment 4
。
Embodiment 5
。
The inkjet printing of the above embodiments preparation method of tempered glass ink, includes the following steps:
(1) preparation of low temperature frit: corresponding raw material is selected to mix in proportion by the composition of low temperature frit, then 800
Frit is sintered at~1400 DEG C, then by below ball mill crushing to 300 mesh；
(2) preparation of micro-nano low temperature glaze slip: solvent, dispersing agent and low temperature frit are mixed, is uniformly dispersed, fills frit
It shares in the benefit wet；Scattered material is ground using sand mill, the partial size of zirconium pearl is ground between 0.3~1.0mm, controls material
Average grain diameter is 200~400 nm, and maximum particle diameter obtains micro-nano low temperature glaze slip less than 1 micron；
(3) preparation of micro-nano mill base: solvent, dispersing agent and inorganic pigment are mixed, is uniformly dispersed, moistens pigment sufficiently
It is wet；Scattered material is ground using sand mill, the partial size of zirconium pearl controls the average grain diameter of material between 0.3~1.0mm
For 200~400 nm, maximum particle diameter obtains micro-nano mill base less than 1 micron；
(4) it is put in proportion into glaze slip and mill base, levelling agent, resin and residual solvent is added, stirs, utilizes 1
Micron filter element filtering, obtains inkjet printing tempered glass ink.
Ink viscosity prepared by the present invention is 10.0~40.0 mPas, and surface tension is in 25~35 mN/m, partial size
It is evenly distributed, average grain diameter is between 200~400 nm, and maximum particle diameter is less than 1 micron, and stability is good, has good
Ink Jet Printing Performance and glass binding performance.
The tempered glass ink print that Examples 1 to 5 is prepared is printed upon respectively on different plate glass, later
Firing.Testing result surface ink is tightly combined with glass, not peelable.
Claims (4)
1. a kind of inkjet printing tempered glass ink, the component containing following mass percent: low temperature frit 20~45%, nothing
Machine pigment 10~25%, dispersing agent 3~10%, resin 1~5%, levelling agent 0.1~0.2%, surplus are solvent；Wherein, low temperature frit
For environmental-friendly lead-free frit, fusing point is lower than 600 DEG C, consisting of SiO220~40%, B2O35~20%, Bi2O330~60%,
Al2O31~5%, ZrO21~4%, (K+Na)2O 0.5~2%, Li2O 1~3%；Wherein, resin is alkyd resin, acrylic acid tree
At least one of rouge；
Dispersing agent is the high molecular weight dispersant containing close pigment group；
Levelling agent is at least one of polyacrylate or polyether modified siloxane；
Solvent is at least one of ether solvent, esters solvent or ketone, and ether solvent is butyl glycol ether, diethylene glycol
Methyl ether, butyl, propylene glycol monomethyl ether, dipropylene glycol methyl ether, propandiol butyl ether, dipropylene, tripropylene glycol first
Ether, at least one of tripropylene glycol butyl ether；Esters solvent is ethylene glycol ether acetate, propylene glycol methyl ether acetate, the third two
At least one of alcohol diacetate esters；Ketones solvent is cyclohexanone.
2. inkjet printing according to claim 1 tempered glass ink, it is characterised in that: inorganic pigment is iron oxide
Red, cobalt aluminium indigo plant, titanium yellow, titanium chrome yellow or copper-chrome black.
3. a kind of ornament materials with tempered glass ink layer, it is characterised in that: ornament materials has claims 1 or 2 institute
State the decorative pattern of inkjet printing tempered glass ink solidification formation.
4. a kind of inkjet printing preparation method of tempered glass ink, includes the following steps:
1) preparation of low temperature frit: corresponding raw material is selected to mix in proportion by the composition of low temperature frit, then 800~1400
It is sintered into frit at DEG C, is then broken to 300 mesh or less；
2) preparation of micro-nano low temperature glaze slip: solvent, dispersing agent and low temperature frit are mixed, is uniformly dispersed, moistens frit sufficiently
It is wet；Scattered material is ground using sand mill, the partial size of zirconium pearl is ground between 0.3~1.0mm, controls being averaged for material
Partial size is 200~400 nm, and maximum particle diameter obtains micro-nano low temperature glaze slip less than 1 micron；
3) preparation of micro-nano mill base: solvent, dispersing agent and inorganic pigment are mixed, is uniformly dispersed, soaks pigment sufficiently；It will
Scattered material is further crushed, and the average grain diameter for controlling material is 200~400 nm, and maximum particle diameter obtains micro- less than 1 micron
Nano color paste；
4) it is put in proportion into glaze slip and mill base, levelling agent, resin and residual solvent is added, stirs, is filtered using 1 micron
Core filtering, obtains inkjet printing tempered glass ink；
Wherein, inkjet printing is as claimed in claim 1 or 2 with tempered glass ink.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510979373 | 2015-12-23 | ||
| CN2015109793732 | 2015-12-23 |
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| Publication Number | Publication Date |
|---|---|
| CN105907177A CN105907177A (en) | 2016-08-31 |
| CN105907177B true CN105907177B (en) | 2019-04-30 |
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| CN201610315821.3A Active CN105907177B (en) | 2015-12-23 | 2016-05-13 | A kind of inkjet printing tempered glass ink and preparation method thereof |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912836A (en) * | 2018-07-04 | 2018-11-30 | 山东汇龙色釉新材料科技有限公司 | A kind of inkjet printing glass ink and its preparation process |
| CN110894380A (en) * | 2018-09-12 | 2020-03-20 | 广州精陶机电设备有限公司 | Printing ink, preparation method thereof and printer |
| CN110511616A (en) * | 2019-08-15 | 2019-11-29 | 深圳市百柔新材料技术有限公司 | Rear reflector glaze ink and the method for making photovoltaic glass panel with it |
| CN111977967A (en) * | 2020-08-13 | 2020-11-24 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Environment-friendly high-corrosion-resistance low-temperature special automobile glass black fusing agent and preparation method and application thereof |
| CN114163872A (en) * | 2022-01-14 | 2022-03-11 | 英辉（大厂）自动化技术有限公司 | Low-viscosity automobile glass printing ink and preparation method thereof |
| CN114751647B (en) * | 2022-03-29 | 2023-06-20 | 华南理工大学 | Glass frit easy to grind and preparation method and application thereof |
| CN114963268A (en) * | 2022-06-16 | 2022-08-30 | 杭州老板电器股份有限公司 | Smoke machine panel and preparation method and application thereof |
| CN115466541A (en) * | 2022-08-03 | 2022-12-13 | 佛山市兴洲玻璃科技有限公司 | Method for cutting tempered ink glass in different places |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153809A (en) * | 2015-09-22 | 2015-12-16 | 东莞市贝特利新材料有限公司 | Glass ink-jet printing ink |
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- 2016-05-13 CN CN201610315821.3A patent/CN105907177B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153809A (en) * | 2015-09-22 | 2015-12-16 | 东莞市贝特利新材料有限公司 | Glass ink-jet printing ink |
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Effective date of registration: 20211222 Address after: 529400 Room 102, 1f, Daoshi technology complex building, Sanlian fozi'ao, Shengtang Town, Enping City, Jiangmen City, Guangdong Province Patentee after: Guangdong Dow ceramic materials Co.,Ltd. Address before: 529441 Sanlian fo Tsao, Enping, Guangdong, Jiangmen Patentee before: GUANGDONG DOWSTONE TECHNOLOGY Co.,Ltd. |
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