CN105753465A - Method of making ceramic super-flat mirror art mural and product made thereby - Google Patents
Method of making ceramic super-flat mirror art mural and product made thereby Download PDFInfo
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- CN105753465A CN105753465A CN201610043338.4A CN201610043338A CN105753465A CN 105753465 A CN105753465 A CN 105753465A CN 201610043338 A CN201610043338 A CN 201610043338A CN 105753465 A CN105753465 A CN 105753465A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/19—Alkali metal aluminosilicates, e.g. spodumene
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
- C04B41/90—Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being a metal
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Abstract
The invention relates to a method of making a ceramic super-flat mirror art mural, comprising the following steps: roll-forming a base material to form a green body, drying the green body, applying an engobe coating and a transparent matte glaze layer to the green body, and firing in a kiln to obtain a ceramic tile; printing a zirconium white ground glaze layer to the surface of the ceramic tile by means of silk-screen printing technology, drying at high temperature and decorating by colored drawing, printing a color fixation glaze layer and a polished crystal dry powder layer to the colored drawing decorative layer, and firing in the kiln to obtain an art ceramic tile; decorating the art ceramic tile by gilding process or schreinering process, and carrying out edging and polishing processes to obtain the ceramic super-flat mirror art mural product.The ceramic mural good in performance and quality is made via two-stage firing by using ceramic ink-jet printing technology and the traditional silk-screen printing and manual colored drawing process, and the product is delicate, graphically rich and fine in texture, is widely applicable to decorating for airports, stations, home decoration and office buildings and has a promising application prospect.
Description
Technical field
The invention belongs to Inorganic Non-metallic Materials (pottery) field, be specifically related to the manufacture method of the super flat minute surface art mural of a kind of porcelain and prepared product thereof.
Background technology
At present, on market, art porcelain plate painter's skill is numerous and diverse, and such as UV paints picture (this product is not environmentally), also has based on powder enamel (five colours), blue and white with copper red colors series of products, subject matter mostly is scenery with hills and waters, as: the high-grade ceramic board pictures such as snow scenes, birds and flowers, personage, substantially by technique great master manual drawing in person, it mostly is original product, every secondary picture creative time cycle is long, quantity is very limited, and expensive, how more than tens thousand of units.
Low and middle-grade ceramic board pictures are mostly the manual works copied of general skilled worker, mostly lack value of art appreciation, though every width works are inexpensive, but also are difficult to enter other life common；Adopting the porcelain plate product of silk screen printing or decal paper explained hereafter, low price, but lack individuality, picture lacks artistic effect, and the water absorption rate of existing market porcelain plate own is high, and brick is unstable, and time length is easy to crack.In sum, the preparation method of mural painting can not meet consumer demand in the market, seriously hinders the development prospect of art mural.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of porcelain, technique is simple, stable performance, low raw-material cost, the manufacture method of the super flat minute surface art mural of porcelain of good decorating effect and prepared product thereof
For solving above technical problem, the technical scheme is that the manufacture method of the super flat minute surface art mural of a kind of porcelain, it is characterised in that comprise the following steps:
Step one: prepare blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, the fixing glaze of pattern, to throw brilliant dry powder standby；
Step 2: by roll-forming, blank is prepared into adobe, first executes cosmetic soil layer after drying in adobe, then executes transparent suboptical glaze layer, then enters kiln through 120～150 minutes, is fired into ceramic tile at 1180～1200 DEG C；
Step 3: the ceramic tile surface printing zirconium white ground glaze layer prepared in step 2 by silk-screen printing technique, painted decoration is carried out after high temperature drying, then on painted decoration layer, print the fixing glaze layer of pattern, on the fixing glaze layer of pattern, brilliant dry powder layer is thrown in printing again, then enter kiln through 75～110 minutes, be fired into artistic ceramic tile at 1020～1100 DEG C；
Step 4: adopt craft of gilding or schreinering to decorate on the artistic ceramic tile that step 3 prepares, prepare the super flat minute surface art mural product of porcelain again through edging, glossing.
The percentage by weight of described blank and cosmetic soil formula consists of:
Blank: black mud 15～20%, calcined kaolin 10～20%, potassium albite 40～50%, high temperature sand 10～20%, magnesium soil 1～3%；
Cosmetic soil: potassium albite 20～30%, quartz 20～30%, calcined kaolin 5～10%, burning Talcum 15～20%, aluminum chloride 1～5%, frit one 5～10%, air knife soil 5～8%.
The percentage by weight of the fixing glaze formula of described transparent suboptical glaze, zirconium white ground-coat enamel, pattern consists of:
Transparent suboptical glaze: potassium albite 20～30%, quartz 15～20%, Talcum 10～15%, calcined kaolin 10～15%, aluminium oxide 3～6%, zinc oxide 1～4%, calcite 10～15%, frit one 10～20%, Kaolin 5～8%, air knife soil 5～8%；
Zirconium white ground-coat enamel: Creamy white frit 60～70%, Zirconium orthosilicate. 10～15%, calcined kaolin 5～10%, aluminium oxide 5～10%, burning Talcum 8～10%, additional ethylene glycol 10～20%, print cream 60～80%；
Pattern fixes glaze: frit 2 20～40%, dry powder one 30～40%, dry powder 2 30～40%, additional ethylene glycol 10～25%, print cream 80～100%.
The described percentage by weight throwing brilliant dry powder consists of: dry powder one 30%, dry powder 2 70%.
In described step 2 cosmetic the thickness of the layer be 0.2～0.25mm, transparent suboptical glaze thickness to be 0.25～0.3mm, adobe water absorption rate be 1～3%, ceramic tile glacing flatness is 0.2～0.3mm.
The logical mesh number printing zirconium white ground glaze layer in described step 3 is 80～120 orders, and thickness is 0.55mm；The logical mesh number of the fixing glaze layer of printing pattern is 80～120 orders, and thickness is 0.8mm；It is 40 orders that the logical mesh number of brilliant dry powder layer is thrown in printing, and thickness is 1.6～1.8mm.
KZ-867 Creamy white frit that KT-1411 Creamy white frit that described frit one is sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., frit two are sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., dry powder one are the LC-759 dry granular sold of dragon dollar Ceramic Material company limited of Foshan Sihui City, dry powder two be the LC-750 dry granular of dragon dollar Ceramic Material company limited of Foshan Sihui City sale.
Described print cream forms with the ratio of cellulose CMC, glycerol, ethylene glycol, water 0.5:1.5:3:5 by weight percentage.
Described painted decoration operation includes one or more decorating method combination in screen printing, inkjet printing, hand painting, pigment used by described screen printing, inkjet printing is that inorganic pigment mixes with stamp-pad ink and ointment, wherein inorganic pigment, stamp-pad ink, ointment weight ratio be 3:5:2, pigment used by described hand painting is inorganic pigment and Olibanum oil and Oleum Camphora mix, wherein inorganic pigment, Olibanum oil, Oleum Camphora weight ratio be 7:1:2.
The product that above-mentioned manufacture method prepares, it is characterized in that: described product is of a size of 600 × 600mm or 800 × 800mm or 1000 × 1000mm, glossiness is 100～105, the depth of parallelism, the error of perpendicularity are less than 0.3mm, the physical function parameter of product is: frost resistance :-4～4 DEG C, 80 circulations, flawless is without peeling；Heat stability: heat to 180 DEG C and be incubated after half an hour, then put in 25 DEG C of water and do not split for three times；Chemical resistance: ammonium chloride 100g/L:GA level, potassium hydroxide 30g/L:GLA level, hydrochloric acid 18%V/V:GHA level；Stain resistance: iron oxide red: 4 grades, iodine tincture: 5 grades, olive oil: 5 grades；Radioactivity: photograph index 0.7, outer photograph index 0.8 in Ra, Th, K.
The present invention adopts natural mineral raw and industrial pure material, stable performance has been prepared by double-firing process, the super flat minute surface art mural of superior in quality porcelain, simultaneously, in conjunction with international up-to-date ceramic ink jet printing technology and traditional silk screen printing and hand painting technique, famous calligraphy and painting of all times is fabricated to super flat minute surface art mural, this product quality is exquisite, picture enriches, pattern is rich in texture and anima, it is provided simultaneously with light-weight environment-friendly, invariant color, stay-in-grade feature, the level of consumption that can meet modern people and the demand that artistic product is appreciated, and meet the industry policy that national energy-saving reduces discharging, as long as this product can be decorated in the place having wall, therefore there is vast potential for future development.
Detailed description of the invention
Implement row one:
A kind of super flat minute surface art mural of porcelain, it is characterised in that comprise the following steps:
Step one: prepare blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, the fixing glaze of pattern, throw brilliant dry powder；
Wherein the preparation process of blank is: weigh black mud 16% by formulation weight percentage ratio, calcined kaolin 13%, potassium albite 50%, high temperature sand 19%, magnesium soil 2%, ball milling is carried out after being mixed by above raw material, Ball-milling Time is 15 hours, ball milling slurry fineness crosses 250 mesh sieves, tail over less than 3%, mud speed rate is in the 30L/ second, slurry is made, through spray tower, the powder that water content is 7%, strictly control grain composition, less than 5% below 20 orders, 20～40 orders are 25～45%, 40～60 orders 45～65%, 100 orders powder less than 5%, the good powder of pelletize store 48 hours standby；
Wherein the preparation process of cosmetic soil is: weighs potassium albite 23%, quartz 30%, calcined kaolin 10% by formulation weight percentage ratio, burns Talcum 20%, aluminum chloride 3%, frit one 6%, air knife soil 8%, by above raw material mixing laggard enter ball grinder grind standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.8 grams/cm3, and flow velocity is the 30L/ second；
Wherein the preparation process of transparent suboptical glaze is: weigh potassium albite 20%, quartz 10%, Talcum 12%, calcined kaolin 15%, aluminium oxide 3%, zinc oxide 4%, calcite 13%, frit one 10%, Kaolin 8%, air knife soil 5% by formulation weight percentage ratio, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.8 grams/cm3, and flow velocity is the 30L/ second；
Wherein the preparation process of zirconium white ground-coat enamel is: weighs Creamy white frit 60%, Zirconium orthosilicate. 15%, calcined kaolin 8%, aluminium oxide 8% by formulation weight percentage ratio, burns Talcum 9%, additional ethylene glycol 10%, print cream 60%, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.6 grams/cm3, and flow velocity is the 30L/ second；
Wherein the preparation process of the fixing glaze of pattern is: weigh frit 2 20%, dry powder one 40%, dry powder 2 40% by formulation weight percentage ratio, additional ethylene glycol 10%, print cream 80%, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness of grinding was 325 mesh sieves, and tailing over is 0；
The preparation process wherein throwing brilliant dry powder is: weigh dry powder one 30%, dry powder 2 70% mix homogeneously by formulation weight percentage ratio standby；
Described print cream forms with the ratio of cellulose CMC, glycerol, ethylene glycol, water 0.5:1.5:3:5 by weight percentage.
KZ-867 Creamy white frit that KT-1411 Creamy white frit that described frit one is sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., frit two are sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., dry powder one are the LC-759 dry granular sold of dragon dollar Ceramic Material company limited of Foshan Sihui City, dry powder two be the LC-750 dry granular of dragon dollar Ceramic Material company limited of Foshan Sihui City sale.
Step 2: by blank powder by the punching press 600 × 600mm adobe respectively of 3200 tons of roll squeezers, stamping pressure 300bar/cm3, in adobe, the cosmetic soil layer of 0.2mm is first spooned after drying through 180 DEG C, spoon the transparent suboptical glaze layer of 0.25mm again, then enter kiln through 120 minutes, be fired into, at 1180 DEG C, the ceramic tile that glacing flatness is below 0.3mm；
Step 3: carry out the zirconium white ground glaze layer that print thickness is 0.55mm with on the logical net ceramic tile after burning till of 80～120 purposes, 100 DEG C of drying are carried out after printing, on zirconium white ground glaze layer, pattern printing is carried out again with the logical net of 80 purposes, dry subsequently in the baking ovens of 100 DEG C, glaze layer is fixed for 0.8mm pattern after print on silk screen printing pattern with the logical net of 80 purposes again, fixing print thickness on glaze layer with the logical net of 40 purposes at pattern again is the throwing crystalline substance dry powder layer of 1.6mm, then enter kiln through 75 minutes, be fired into artistic ceramic tile at 1020 DEG C；
Step 4: adopt craft of gilding to decorate on the artistic ceramic tile that step 3 prepares, prepares, again through edging, glossing, the super flat minute surface art mural product of porcelain that glossiness is 100.
Pigment used by described pattern printing is inorganic pigment and stamp-pad ink and ointment mix, wherein inorganic pigment, stamp-pad ink, ointment weight ratio be 3:5:2.
Implement row two:
A kind of super flat minute surface art mural of porcelain, it is characterised in that comprise the following steps:
Step one: prepare blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, the fixing glaze of pattern, throw brilliant dry powder；
Wherein the preparation process of blank is: weigh black mud 18% by formulation weight percentage ratio, calcined kaolin 20%, potassium albite 41%, high temperature sand 18%, magnesium soil 3%, ball milling is carried out after being mixed by above raw material, Ball-milling Time is 15 hours, ball milling slurry fineness crosses 250 mesh sieves, tail over less than 3%, mud speed rate is in the 40L/ second, slurry is made, through spray tower, the powder that water content is 7%, strictly control grain composition, less than 5% below 20 orders, 20～40 orders are 25～45%, 40～60 orders 45～65%, 100 orders powder less than 5%, the good powder of pelletize store 48 hours standby；
Wherein the preparation process of cosmetic soil is: weighs potassium albite 30%, quartz 23%, calcined kaolin 8% by formulation weight percentage ratio, burns Talcum 17%, aluminum chloride 5%, frit one 9%, air knife soil 8%, by above raw material mixing laggard enter ball grinder grind standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.8 grams/cm3, and flow velocity is the 40L/ second；
Wherein the preparation process of transparent suboptical glaze is: weigh potassium albite 18%, quartz 12%, Talcum 13%, calcined kaolin 13%, aluminium oxide 4%, zinc oxide 2%, calcite 14%, frit one 12%, Kaolin 6%, air knife soil 6% by formulation weight percentage ratio, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.8 grams/cm3, and flow velocity is the 40L/ second；
Wherein the preparation process of zirconium white ground-coat enamel is: weighs Creamy white frit 60%, Zirconium orthosilicate. 15%, calcined kaolin 8%, aluminium oxide 8% by formulation weight percentage ratio, burns Talcum 9%, additional ethylene glycol 10%, print cream 60%, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.6 grams/cm3, and flow velocity is the 40L/ second；
Wherein the preparation process of the fixing glaze of pattern is: weigh frit 2 20%, dry powder one 40%, dry powder 2 40% by formulation weight percentage ratio, additional ethylene glycol 10%, print cream 80%, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness of grinding was 325 mesh sieves, and tailing over is 0；
The preparation process wherein throwing brilliant dry powder is: weigh dry powder one 30%, dry powder 2 70% mix homogeneously by formulation weight percentage ratio standby；
Described print cream forms with the ratio of cellulose CMC, glycerol, ethylene glycol, water 0.5:1.5:3:5 by weight percentage.
KZ-867 Creamy white frit that KT-1411 Creamy white frit that described frit one is sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., frit two are sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., dry powder one are the LC-759 dry granular sold of dragon dollar Ceramic Material company limited of Foshan Sihui City, dry powder two be the LC-750 dry granular of dragon dollar Ceramic Material company limited of Foshan Sihui City sale.
Step 2: by blank powder by the punching press 1000 × 1000mm adobe respectively of 3200 tons of roll squeezers, stamping pressure 300bar/cm3, in adobe, the cosmetic soil layer of 0.22mm is first spooned after drying through 190 DEG C, spoon the transparent suboptical glaze layer of 0.27mm again, then enter kiln through 130 minutes, be fired into, at 1190 DEG C, the ceramic tile that glacing flatness is below 0.3mm；
Step 3: carry out the zirconium white ground glaze layer that print thickness is 0.55mm with on the logical net ceramic tile after burning till of 100 purposes, 100 DEG C of drying are carried out after printing, on zirconium white ground glaze layer, inkjet printing pattern is carried out again with the logical net of 100 purposes, dry subsequently in the baking ovens of 100 DEG C, glaze layer is fixed for 0.8mm pattern after print on inkjet printing pattern with the logical net of 100 purposes again, fixing print thickness on glaze layer with the logical net of 40 purposes at pattern again is the throwing crystalline substance dry powder layer of 1.7mm, then enter kiln through 90 minutes, be fired into artistic ceramic tile at 1060 DEG C；
Step 4: adopt schreinering to decorate on the artistic ceramic tile that step 3 prepares, prepares, again through edging, glossing, the super flat minute surface art mural product of porcelain that glossiness is 102.
Pigment used by described inkjet printing is inorganic pigment and stamp-pad ink and ointment mix, wherein inorganic pigment, stamp-pad ink, ointment weight ratio be 3:5:2.
Implement row three:
A kind of super flat minute surface art mural of porcelain, it is characterised in that comprise the following steps:
Step one: prepare blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, the fixing glaze of pattern, throw brilliant dry powder；
Wherein the preparation process of blank is: weigh black mud 20% by formulation weight percentage ratio, calcined kaolin 18%, potassium albite 46%, high temperature sand 13%, magnesium soil 3%, ball milling is carried out after being mixed by above raw material, Ball-milling Time is 15 hours, ball milling slurry fineness crosses 250 mesh sieves, tail over less than 3%, mud speed rate is in the 50L/ second, slurry is made, through spray tower, the powder that water content is 6%, strictly control grain composition, less than 5% below 20 orders, 20～40 orders are 25～45%, 40～60 orders 45～65%, 100 orders powder less than 5%, the good powder of pelletize store 48 hours standby；
Wherein the preparation process of cosmetic soil is: weighs potassium albite 26%, quartz 27%, calcined kaolin 7% by formulation weight percentage ratio, burns Talcum 19%, aluminum chloride 5%, frit one 10%, air knife soil 6%, by above raw material mixing laggard enter ball grinder grind standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.8 grams/cm3, and flow velocity is the 50L/ second；
Wherein the preparation process of transparent suboptical glaze is: weigh potassium albite 18%, quartz 12%, Talcum 13%, calcined kaolin 13%, aluminium oxide 4%, zinc oxide 2%, calcite 14%, frit one 12%, Kaolin 6%, air knife soil 6% by formulation weight percentage ratio, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.8 grams/cm3, and flow velocity is the 50L/ second；
Wherein the preparation process of zirconium white ground-coat enamel is: weighs Creamy white frit 60%, Zirconium orthosilicate. 15%, calcined kaolin 8%, aluminium oxide 8% by formulation weight percentage ratio, burns Talcum 9%, additional ethylene glycol 10%, print cream 60%, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness ground was 325 mesh sieves, tail over as less than 0.8%, proportion is 1.6 grams/cm3, and flow velocity is the 50L/ second；
Wherein the preparation process of the fixing glaze of pattern is: weigh frit 2 40%, dry powder one 30%, dry powder 2 30% by formulation weight percentage ratio, additional ethylene glycol 25%, print cream 100%, by above raw material mixing laggard enter grinding in ball grinder standby, the fineness of grinding was 325 mesh sieves, and tailing over is 0；
The preparation process wherein throwing brilliant dry powder is: weigh dry powder one 30%, dry powder 2 70% mix homogeneously by formulation weight percentage ratio standby；
Described print cream forms with the ratio of cellulose CMC, glycerol, ethylene glycol, water 0.5:1.5:3:5 by weight percentage.
KZ-867 Creamy white frit that KT-1411 Creamy white frit that described frit one is sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., frit two are sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., dry powder one are the LC-759 dry granular sold of dragon dollar Ceramic Material company limited of Foshan Sihui City, dry powder two be the LC-750 dry granular of dragon dollar Ceramic Material company limited of Foshan Sihui City sale.
Step 2: by blank powder by the punching press 800 × 800mm adobe respectively of 3200 tons of roll squeezers, stamping pressure 300bar/cm3, in adobe, the cosmetic soil layer of 0.25mm is first spooned after drying through 200 DEG C, spoon the transparent suboptical glaze layer of 0.3mm again, then enter kiln through 150 minutes, be fired into, at 1200 DEG C, the ceramic tile that glacing flatness is below 0.3mm；
Step 3: carry out the zirconium white ground glaze layer that print thickness is 0.55mm with on the logical net ceramic tile after burning till of 120 purposes, 100 DEG C of drying are carried out after printing, on zirconium white ground glaze layer, painted decoration is carried out again with the logical net of 120 purposes, dry subsequently in the baking ovens of 100 DEG C, glaze layer is fixed for 0.8mm pattern after print in painted decoration with the logical net of 120 purposes again, fixing print thickness on glaze layer with the logical net of 40 purposes at pattern again is the throwing crystalline substance dry powder layer of 1.8mm, then enter kiln through 110 minutes, be fired into artistic ceramic tile at 1100 DEG C；
Step 4: adopt craft of gilding to decorate on the artistic ceramic tile that step 3 prepares, prepares, again through edging, glossing, the super flat minute surface art mural product of porcelain that glossiness is 105.
Painted decoration is that inkjet printing adds hand painting, and pigment used by inkjet printing is inorganic pigment and stamp-pad ink and print cream and mix, wherein inorganic pigment, stamp-pad ink, print cream weight ratio be 3:5:2；
Pigment used by hand painting is inorganic pigment and Olibanum oil and Oleum Camphora mix, wherein inorganic pigment, Olibanum oil, Oleum Camphora weight ratio be 7:1:2.
The physical function parameter that embodiment 1～3 prepares product is: frost resistance :-4～4 DEG C, and 80 circulations, flawless is without peeling；Heat stability: heat to 180 DEG C and be incubated after half an hour, then put in 25 DEG C of water and do not split for three times；Chemical resistance: ammonium chloride 100g/L:GA level, potassium hydroxide 30g/L:GLA level, hydrochloric acid 18%V/V:GHA level；Stain resistance: iron oxide red: 4 grades, iodine tincture: 5 grades, olive oil: 5 grades；Radioactivity: photograph index 0.7, outer photograph index 0.8 in Ra, Th, K.
600 × 600mm that above-described embodiment prepares or the super flat minute surface art mural product of porcelain of 800 × 800mm or 1000 × 1000mm, be suitable for any place by free splicing, combination, the decoration of environment uses.
Claims (10)
1. the manufacture method of the super flat minute surface art mural of porcelain, it is characterised in that comprise the following steps:
Step one: prepare blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, the fixing glaze of pattern, to throw brilliant dry powder standby；
Step 2: by roll-forming, blank is prepared into adobe, first executes cosmetic soil layer after drying in adobe, then executes transparent suboptical glaze layer, then enters kiln through 120～150 minutes, is fired into ceramic tile at 1180～1200 DEG C；
Step 3: the ceramic tile surface printing zirconium white ground glaze layer prepared in step 2 by silk-screen printing technique, painted decoration is carried out after high temperature drying, then on painted decoration layer, print the fixing glaze layer of pattern, on the fixing glaze layer of pattern, brilliant dry powder layer is thrown in printing again, then enter kiln through 75～110 minutes, be fired into artistic ceramic tile at 1020～1100 DEG C；
Step 4: adopt craft of gilding or schreinering to decorate on the artistic ceramic tile that step 3 prepares, prepare the super flat minute surface art mural product of porcelain again through edging, glossing.
2. manufacture method according to claim 1, it is characterised in that: the percentage by weight of described blank and cosmetic soil formula consists of:
Blank: black mud 15～20%, calcined kaolin 10～20%, potassium albite 40～50%, high temperature sand 10～20%, magnesium soil 1～3%；
Cosmetic soil: potassium albite 20～30%, quartz 20～30%, calcined kaolin 5～10%, burning Talcum 15～20%, aluminum chloride 1～5%, frit one 5～10%, air knife soil 5～8%.
3. manufacture method according to claim 1, it is characterised in that: the percentage by weight of the fixing glaze formula of described transparent suboptical glaze, zirconium white ground-coat enamel, pattern consists of:
Transparent suboptical glaze: potassium albite 15～20%, quartz 10～15%, Talcum 10～15%, calcined kaolin 10～15%, aluminium oxide 3～6%, zinc oxide 1～4%, calcite 10～15%, frit one 10～15%, Kaolin 5～8%, air knife soil 5～8%；
Zirconium white ground-coat enamel: Creamy white frit 60～70%, Zirconium orthosilicate. 10～15%, calcined kaolin 5～10%, aluminium oxide 5～10%, burning Talcum 8～10%, additional ethylene glycol 10～20%, print cream 60～80%；
Pattern fixes glaze: frit 2 20～40%, dry powder one 30～40%, dry powder 2 30～40%, additional ethylene glycol 10～25%, print cream 80～100%.
4. manufacture method according to claim 1, it is characterised in that: the described percentage by weight throwing brilliant dry powder consists of: dry powder one 30%, dry powder 2 70%.
5. manufacture method according to claim 1, it is characterised in that: in described step 2 cosmetic the thickness of the layer be 0.2～0.25mm, transparent suboptical glaze thickness to be 0.25～0.3mm, adobe water absorption rate be 1～3%, ceramic tile glacing flatness is 0.2～0.3mm.
6. manufacture method according to claim 1, it is characterised in that: the logical mesh number printing zirconium white ground glaze layer in described step 3 is 80～120 orders, and thickness is 0.55mm；The logical mesh number of the fixing glaze layer of printing pattern is 80～120 orders, and thickness is 0.8mm；It is 40 orders that the logical mesh number of brilliant dry powder layer is thrown in printing, and thickness is 1.6～1.8mm.
7. manufacture method according to claim 1, it is characterised in that: KZ-867 Creamy white frit that KT-1411 Creamy white frit that described frit one is sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., frit two are sold for Guangdong Sanshui Dahong Glaze Making Co., Ltd., dry powder one are the LC-759 dry granular sold of dragon dollar Ceramic Material company limited of Foshan Sihui City, dry powder two be the LC-750 dry granular of dragon dollar Ceramic Material company limited of Foshan Sihui City sale.
8. manufacture method according to claim 1, it is characterised in that: described print cream forms with the ratio of cellulose CMC, glycerol, ethylene glycol, water 0.5:1.5:3:5 by weight percentage.
9. manufacture method according to claim 1, it is characterized in that: one or more decorating method combination that described painted decoration operation includes in screen printing, inkjet printing, hand painting, pigment used by described screen printing, inkjet printing is that inorganic pigment mixes with stamp-pad ink and ointment, wherein inorganic pigment, stamp-pad ink, ointment weight ratio be 3:5:2, pigment used by described hand painting is inorganic pigment and Olibanum oil and Oleum Camphora mix, wherein inorganic pigment, Olibanum oil, Oleum Camphora weight ratio be 7:1:2.
10. the product that manufacture method prepares according to claim 1, it is characterized in that: described product is of a size of 600 × 600mm or 800 × 800mm or 1000 × 1000mm, glossiness is 100～105, the depth of parallelism, the error of perpendicularity are less than 0.3mm, the physical function parameter of product is: frost resistance :-4～4 DEG C, 80 circulations, flawless is without peeling；Heat stability: heat to 180 DEG C and be incubated after half an hour, then put in 25 DEG C of water and do not split for three times；Chemical resistance: ammonium chloride 100g/L:GA level, potassium hydroxide 30g/L:GLA level, hydrochloric acid 18%V/V:GHA level；Stain resistance: iron oxide red: 4 grades, iodine tincture: 5 grades, olive oil: 5 grades；Radioactivity: photograph index 0.7, outer photograph index 0.8 in Ra, Th, K.
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Cited By (6)
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| CN108033676A (en) * | 2017-12-06 | 2018-05-15 | 厦门万仟堂艺术品有限公司 | A kind of dumb light clear frit and preparation method thereof |
| CN109382898A (en) * | 2017-08-12 | 2019-02-26 | 主父春霖 | A kind of production technology of spun gold marble tile product |
| CN111620703A (en) * | 2020-06-09 | 2020-09-04 | 广东富强陶瓷有限公司 | Preparation method of soft light gold-plated ceramic tile and product thereof |
| CN111848119A (en) * | 2020-07-17 | 2020-10-30 | 怀化市小康瓷砖厂 | Reduction sintering process for double-sided matte glaze green tile |
| CN112194911A (en) * | 2019-07-08 | 2021-01-08 | 谌国星 | Novel color aluminum tube pigment on ceramic glaze and preparation method thereof |
| CN117682766A (en) * | 2024-02-04 | 2024-03-12 | 蒙娜丽莎集团股份有限公司 | Spot art colored glaze ceramic plate combining half-number glaze and preparation method thereof |
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| CN104150966A (en) * | 2014-08-11 | 2014-11-19 | 景德镇市精业陶瓷有限公司 | Preparation method of snowflake enamel decorative domestic ceramic and manufactured product thereof |
| KR20150073496A (en) * | 2013-12-23 | 2015-07-01 | 강동하 | Method for Decorating a surface of Ceramics and Ceramics produced by the method |
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| KR20150073496A (en) * | 2013-12-23 | 2015-07-01 | 강동하 | Method for Decorating a surface of Ceramics and Ceramics produced by the method |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109382898A (en) * | 2017-08-12 | 2019-02-26 | 主父春霖 | A kind of production technology of spun gold marble tile product |
| CN108033676A (en) * | 2017-12-06 | 2018-05-15 | 厦门万仟堂艺术品有限公司 | A kind of dumb light clear frit and preparation method thereof |
| CN112194911A (en) * | 2019-07-08 | 2021-01-08 | 谌国星 | Novel color aluminum tube pigment on ceramic glaze and preparation method thereof |
| CN111620703A (en) * | 2020-06-09 | 2020-09-04 | 广东富强陶瓷有限公司 | Preparation method of soft light gold-plated ceramic tile and product thereof |
| CN111848119A (en) * | 2020-07-17 | 2020-10-30 | 怀化市小康瓷砖厂 | Reduction sintering process for double-sided matte glaze green tile |
| CN117682766A (en) * | 2024-02-04 | 2024-03-12 | 蒙娜丽莎集团股份有限公司 | Spot art colored glaze ceramic plate combining half-number glaze and preparation method thereof |
| CN117682766B (en) * | 2024-02-04 | 2024-05-17 | 蒙娜丽莎集团股份有限公司 | Spot art colored glaze ceramic plate combining half-number glaze and preparation method thereof |
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