CN106189498A - A kind of ink for screen printing - Google Patents
A kind of ink for screen printing Download PDFInfo
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- CN106189498A CN106189498A CN201610751342.6A CN201610751342A CN106189498A CN 106189498 A CN106189498 A CN 106189498A CN 201610751342 A CN201610751342 A CN 201610751342A CN 106189498 A CN106189498 A CN 106189498A
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- Prior art keywords
- ink
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- screen printing
- weight ratio
- mixing composition
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of ink for screen printing, including the material of following weight portion: pigment 15 25 parts, link stuff 25 40 parts, solvent 45 70 parts, calcium carbonate 13 parts, defoamer 13 parts, levelling agent 13 parts, 27 parts of 5A molecular sieve, aerosil 13 parts, dispersant 27 parts, adhesion promoter 0.5 1.5 parts, colloid oil 25 parts, slip agent 13 parts, 14 parts of barium sulfate, brucite 13 parts, light stabilizer 13 parts.Can strengthen the adhesive force of ink in the present invention, prevent ink from ink bleed occur, changing the phenomenons such as ink, chemical stability is strong, and the storage time is long, and printing performance is stable, and anti-uv-ray and oxidation resistance are strong, abrasion-resistant.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of ink for screen printing.
Background technology
China's ink industry in 2010 produces and has reached all-time high, " China's ink industry production and marketing demand and investment
Forecast analysis report prediction " statistics, whole nation ink gross annual output amount amounts to 58.99 ten thousand tons, exceedes Germany first, Japan occupies the world
Second.Calculating according to world's ink annual production then about 4,100,000 tons, the Printing ink producing scale of China accounts for the 14% of the whole world.
Ink is the important materials for packaging material printing, and it will be wrapped in pattern, literal table present stock curing ink by printing
Including main component and auxiliary element, they mix equably and form a kind of viscosity colloidal fluid through repeat-rolling.Ink for screen printing
When referring to use screen printing mode, all of ink is referred to as ink for screen printing.But more existing ink for screen printing rate of drying mistakes
Slowly, the phenomenon such as set-off, page sticking is in press often resulted in.Also have some ink for screen printing poor adhesive force, easily produce printing
The phenomenons such as uneven, deinking, have a strong impact on printing quality, and the surface tension relationship of ink is to the transfer performance of ink and print
Mark stability on printing face, when the surface tension of ink is more more than the surface tension in printing face, trace can shrink, very
To the aperture that fish-eye shaped occurs;If printing face is close with the surface tension of ink, and the surface tension of half tone is more than printing face
Surface tension time, printing there will be network blocking phenomenon, and how reconciliation statement surface tension is the problem needing to solve in fact;Ink is imprinted on print
After brush product, owing to wearability is bad, leaflet can produce ink during transport, use and come off, and falls the phenomenons such as ink, in transport
During, excessively transmission speed is very fast, and the layer of ink of printed matter surface can affect the outward appearance of leaflet because rubbing and partial exfoliation
And quality, the storage effect of ink is also the problem merited attention simultaneously.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of ink for screen printing.
A kind of ink for screen printing that the present invention proposes, including the material of following weight portion: pigment 15-25 part, link stuff 25-40
Part, solvent 45-70 part, calcium carbonate 1-3 part, defoamer 1-3 part, levelling agent 1-3 part, 5A molecular sieve 2-7 part, aerosil
1-3 part, dispersant 2-7 part, adhesion promoter 0.5-1.5 part, colloid oil 2-5 part, slip agent 1-3 part, barium sulfate 1-4 part,
Brucite 1-3 part, light stabilizer 1-3 part.
Preferably, described slip agent is polypropylene wax.
Preferably, described link stuff is chlorinated polypropylene, polyurethane modified epoxy resin, polyketone resin and polyamide
Resin is 2:1:1:1 mixing composition according to weight ratio.
Preferably, described solvent includes isopropanol, toluene, ether, butyl acetate and butanone and is 2:3 according to weight ratio:
1:2:1 mixes composition.
Preferably, described defoamer is polyether-modified silicon.
Preferably, described levelling agent be polydimethylsiloxane and fluorinated siloxane be 2:1 mixing composition according to weight ratio.
Preferably, described adhesion promoter be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio.
Preferably, described dispersant is oleamide.
Preferably, described light stabilizer is that phenyl salicylate, Benzophenone-9 and ultraviolet absorbent uv-326 are according to weight
Form than for 1:1:2 mixing.
Preferably, described pigment is titanium white or cadmium red or chrome green.
The present invention compared with prior art, the Advantageous Effects having:
In the present invention, select polypropylene wax can float over ink pellet surface as slip agent, reduce the surface tension of ink, make oil
The coefficient of friction on second surface is reduced by ink, prevents from causing because of friction coming off, and selects oleamide permissible as dispersant
Reducing resin particle molding melting viscosity, improve mobility and have the function of slip agent simultaneously concurrently, both cooperate and can strengthen work
Use effect;Add calcium carbonate can the viscosity of ink be adjusted, it is also possible to be filled with as extender pigment, to reduce into
This;The most easily rising due to ink steep oneself-meeting impact printing quality, the polyether-modified silicon of defoamer combine polyethers with
The advantage of both organic silicon defoamers, acid and alkali resistance and inorganic salt, can be used for the froth breaking under harsh conditions, it is possible to decrease system surface
Tension force, makes oneself to be prone in the surface spreading of liquid and absorption, thus reduces liquid surface film-strength to reach froth breaking purpose;Stream
Flat agent can make ink form a film smooth, smooth, uniform during drying and forming-film, uses polydimethylsiloxane
With fluorinated siloxane according to weight ratio be 2:1 mixing composition, polydimethylsiloxane possesses good apparent condition control ability,
But shrinkage cavity can often occur, then can improve the wettability of base material after adding fluorinated siloxane, improve anti-shrinkage cavity ability;Add gas
Aerosil can play preferable anti-settling effect in ink system, but more aerosil can make ink
Levelability is deteriorated, and now adds 5A molecular sieve and can improve the stability of ink, the polarity of the silicone hydroxyl on 5A molecular sieve hole wall
Can make to have between 5A molecular sieve and polymer or polymer monomer with polar group the good compatibility so that molecule
The existence of sieve can make link stuff be coupled together with molecular sieve by chemical bond, and the supply chain network structure making ink is more perfect, improves
The storage time of ink;Link stuff uses chlorinated polypropylene, polyurethane modified epoxy resin, polyketone resin and polyamide resin
Fat is 2:1:1:1 mixing composition according to weight ratio, and chlorinated polypropylene is the one introducing chlorine atom in polypropylene molecular chain
Polar thermoplastic resin, has good one-tenth colloidality and gloss, can be used as the adhesive of bonding plastics, metal or paper, polyamides
Polyimide resin has good printing adaptability, surface rub resistance, polyurethane modified epoxy resin then make the high resiliency of polyurethane with
The good heat resistance of epoxy resin organically combines with cementability, introduces flexible ehter bond on epoxy resin, thus
Improving the toughness of epoxy resin, occur the situation of fracture after preventing ink printing, polyketone resin is remarkably improved the light of ink
Solids content in pool degree, adhesive force, wettability, case hardness and system, reduces system viscosity, prevents the product of wire drawing phenomenon
Raw, complement each other to form between different resins a kind of become colloidality is good, adhesive force compared with strong, tackness is moderate, the company of applied range
Ramming material;Solvent includes isopropanol, toluene, ether, butyl acetate and butanone and is 2:3:1:2:1 mixing composition according to weight ratio,
Amalgamation is good each other, for relatively single solvent, link stuff resin especially polyamide is had the strongest dissolving power;
Adhesion promoter be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, epoxy radicals silicone hydride is novel
Epoxy radicals coupling agent, has reaction active groups, has good yellowing resistance characteristic, and amino silane has two kinds of functional groups,
I.e. amino and ethyoxyl, wherein three hydrolyzable groups (ethyoxyl), the most first hydrolysis generates silanol, owing to silanol is unstable
Fixed, the easily hydroxy combining with inorganic matter or metal surface is dehydrated, thus combines with inorganic matter or metal, on amino with
Two active hydrogens can react with various polymer, thus by chemical bond by two kinds of diverse material tight of character
Combine, both are with the use of improving the adhesive force of resin link stuff further, prevent ink from ink bleed occur, changing ink
Etc. phenomenon;Brucite can improve the stability of ink, convenient transport and storage;Colloid oil can improve the set speed of ink
Degree, printing adaptability and good stability, can be used to adjust ink body bone and gloss;Barium sulfate can improve the set of ink further
Effect;Light stabilizer be phenyl salicylate, Benzophenone-9 and ultraviolet absorbent uv-326 be 1:1:2 mixing group according to weight ratio
Becoming, for more single light stabilizer, it has Ultraviolet Light have antioxygen property concurrently more widely, can strengthen oil
The anti-uv-ray of ink and oxidation resistance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment 1
In the present embodiment, a kind of ink for screen printing, including the material of following weight portion: pigment 15 parts, link stuff 25 parts, solvent
45 parts, calcium carbonate 1 part, defoamer 1 part, levelling agent 1 part, 2 parts of 5A molecular sieve, aerosil 1 part, dispersant 2 parts, attachment
Power accelerator 0.5 part, colloid oil 2 parts, slip agent 1 part, 1 part of barium sulfate, brucite 1 part, light stabilizer 1 part.
Slip agent is polypropylene wax, link stuff be chlorinated polypropylene, polyurethane modified epoxy resin, polyketone resin and
Polyamide is 2:1:1:1 mixing composition according to weight ratio, and solvent includes isopropanol, toluene, ether, butyl acetate and butanone
And according to weight ratio be 2:3:1:2:1 mixing composition, defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorine
Changing siloxanes according to weight ratio is 2:1 mixing composition, and adhesion promoter is that amino silane and epoxy radicals silicone hydride are according to weight ratio
For 1:2 mixing composition, dispersant is oleamide, and light stabilizer is phenyl salicylate, Benzophenone-9 and UV absorbent UV-
326 according to weight ratio be 1:1:2 mixing composition, pigment is titanium white.
Embodiment 2
In the present embodiment, a kind of ink for screen printing, including the material of following weight portion: pigment 20 parts, link stuff 32.5 parts, molten
Agent 57.5 parts, calcium carbonate 2 parts, defoamer 2 parts, levelling agent 2 parts, 4.5 parts of 5A molecular sieve, aerosil 2 parts, dispersant
4.5 parts, adhesion promoter 1 part, colloid oil 3.5 parts, slip agent 2 parts, 2.5 parts of barium sulfate, brucite 2 parts, light stabilizer 2
Part.
Slip agent is polypropylene wax, link stuff be chlorinated polypropylene, polyurethane modified epoxy resin, polyketone resin and
Polyamide is 2:1:1:1 mixing composition according to weight ratio, and solvent includes isopropanol, toluene, ether, butyl acetate and butanone
And according to weight ratio be 2:3:1:2:1 mixing composition, defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorine
Changing siloxanes according to weight ratio is 2:1 mixing composition, and adhesion promoter is that amino silane and epoxy radicals silicone hydride are according to weight ratio
For 1:2 mixing composition, dispersant is oleamide, and light stabilizer is phenyl salicylate, Benzophenone-9 and UV absorbent UV-
326 according to weight ratio be 1:1:2 mixing composition, pigment is cadmium red.
Embodiment 3
In the present embodiment, a kind of ink for screen printing, including the material of following weight portion: pigment 25 parts, link stuff 40 parts, solvent
70 parts, calcium carbonate 3 parts, defoamer 3 parts, levelling agent 3 parts, 7 parts of 5A molecular sieve, aerosil 3 parts, dispersant 7 parts, attachment
Power accelerator 1.5 parts, colloid oil 5 parts, slip agent 3 parts, 4 parts of barium sulfate, brucite 3 parts, light stabilizer 3 parts.
Slip agent is polypropylene wax, link stuff be chlorinated polypropylene, polyurethane modified epoxy resin, polyketone resin and
Polyamide is 2:1:1:1 mixing composition according to weight ratio, and solvent includes isopropanol, toluene, ether, butyl acetate and butanone
And according to weight ratio be 2:3:1:2:1 mixing composition, defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorine
Changing siloxanes according to weight ratio is 2:1 mixing composition, and adhesion promoter is that amino silane and epoxy radicals silicone hydride are according to weight ratio
For 1:2 mixing composition, dispersant is oleamide, and light stabilizer is phenyl salicylate, Benzophenone-9 and UV absorbent UV-
326 according to weight ratio be 1:1:2 mixing composition, pigment is chrome green.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (10)
1. an ink for screen printing, it is characterised in that include the material of following weight portion: pigment 15-25 part, link stuff 25-40 part,
Solvent 45-70 part, calcium carbonate 1-3 part, defoamer 1-3 part, levelling agent 1-3 part, 5A molecular sieve 2-7 part, aerosil 1-3
Part, dispersant 2-7 part, adhesion promoter 0.5-1.5 part, colloid oil 2-5 part, slip agent 1-3 part, barium sulfate 1-4 part, neatly
Stone 1-3 part, light stabilizer 1-3 part.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described slip agent is polypropylene wax.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described link stuff be chlorinated polypropylene,
Polyurethane modified epoxy resin, polyketone resin and polyamide are 2:1:1:1 mixing composition according to weight ratio.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described solvent includes isopropanol, toluene, second
Ether, butyl acetate and butanone and according to weight ratio be 2:3:1:2:1 mixing composition.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described defoamer is polyether-modified silicon.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described levelling agent be polydimethylsiloxane and
Fluorinated siloxane is 2:1 mixing composition according to weight ratio.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described adhesion promoter be amino silane and
Epoxy radicals silicone hydride is 1:2 mixing composition according to weight ratio.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described dispersant is oleamide.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described light stabilizer be phenyl salicylate, two
Benzophenone-9 and ultraviolet absorbent uv-326 are 1:1:2 mixing composition according to weight ratio.
A kind of ink for screen printing the most according to claim 1, it is characterised in that: described pigment is titanium white or cadmium red or chrome green.
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CN201610751342.6A CN106189498A (en) | 2016-08-29 | 2016-08-29 | A kind of ink for screen printing |
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CN201610751342.6A CN106189498A (en) | 2016-08-29 | 2016-08-29 | A kind of ink for screen printing |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107163678A (en) * | 2017-06-26 | 2017-09-15 | 太仓市鑫鹤印刷包装有限公司 | Strong printing-ink of a kind of adhesive force and preparation method thereof |
CN107189541A (en) * | 2017-06-26 | 2017-09-22 | 太仓市鑫鹤印刷包装有限公司 | A kind of printing process of the strong printing-ink of adhesive force |
CN107216710A (en) * | 2017-06-26 | 2017-09-29 | 太仓市鑫鹤印刷包装有限公司 | A kind of wear-resisting Noctilucence printing ink and preparation method thereof |
CN107353702A (en) * | 2017-06-26 | 2017-11-17 | 太仓市鑫鹤印刷包装有限公司 | Strong Noctilucence printing ink of a kind of adhesive force and preparation method thereof |
CN115612348A (en) * | 2022-10-28 | 2023-01-17 | 浙江龙游道明光学有限公司 | White silk-screen printing ink printed on polypropylene board and manufacturing method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107163678A (en) * | 2017-06-26 | 2017-09-15 | 太仓市鑫鹤印刷包装有限公司 | Strong printing-ink of a kind of adhesive force and preparation method thereof |
CN107189541A (en) * | 2017-06-26 | 2017-09-22 | 太仓市鑫鹤印刷包装有限公司 | A kind of printing process of the strong printing-ink of adhesive force |
CN107216710A (en) * | 2017-06-26 | 2017-09-29 | 太仓市鑫鹤印刷包装有限公司 | A kind of wear-resisting Noctilucence printing ink and preparation method thereof |
CN107353702A (en) * | 2017-06-26 | 2017-11-17 | 太仓市鑫鹤印刷包装有限公司 | Strong Noctilucence printing ink of a kind of adhesive force and preparation method thereof |
CN115612348A (en) * | 2022-10-28 | 2023-01-17 | 浙江龙游道明光学有限公司 | White silk-screen printing ink printed on polypropylene board and manufacturing method thereof |
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Application publication date: 20161207 |