CN107163678A - Strong printing-ink of a kind of adhesive force and preparation method thereof - Google Patents

Strong printing-ink of a kind of adhesive force and preparation method thereof Download PDF

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Publication number
CN107163678A
CN107163678A CN201710492546.7A CN201710492546A CN107163678A CN 107163678 A CN107163678 A CN 107163678A CN 201710492546 A CN201710492546 A CN 201710492546A CN 107163678 A CN107163678 A CN 107163678A
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CN
China
Prior art keywords
ink
parts
adhesive force
printing
strong printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710492546.7A
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Chinese (zh)
Inventor
蒋冬艳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Xin He Printing Packaging Co Ltd
Original Assignee
Taicang Xin He Printing Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Xin He Printing Packaging Co Ltd filed Critical Taicang Xin He Printing Packaging Co Ltd
Priority to CN201710492546.7A priority Critical patent/CN107163678A/en
Publication of CN107163678A publication Critical patent/CN107163678A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention belongs to printing technology, more particularly to a kind of strong printing-ink of adhesive force and preparation method thereof.The strong printing-ink of adhesive force of the present invention, cost of material is low, and preparation method is simple, scientific and reasonable, the ink adhesion of preparation is strong, and folding resistance is excellent, and the surface tension of ink can be reduced from the slip agents of DOW CORNING DC 51, polishing machine is improved, it is anti-to be adhered, reduce skin-friction coefficient;Ink viscosity can be adjusted for calcium carbonate, can also make to be filled organic pigment, reduce cost;Defoamer can reduce system surface tension, reduce liquid surface film-strength;Colloid oil G improves the set speed of ink, and printing adaptability and stability are good, also can adjust ink;Ethylene glycol can improve the resistance to frost of ink.

Description

Strong printing-ink of a kind of adhesive force and preparation method thereof
Technical field
The invention belongs to printing technology, more particularly to a kind of strong printing-ink of adhesive force and preparation method thereof.
Background technology
Printing is, through processes such as plate-making, Shi Mo, pressurizations, to arrive printing ink transfer by the original copy such as word, picture, photo, false proof The material surfaces such as paper, textile, plastic products, leather, the technology of batch duplicating original copy content.
The oil plant of printing is ink, is the important materials of printing, and pattern, word are shown into printing by printing or air brushing On thing.Ink includes main component and auxiliary element, and they are uniformly mixed and gluey into a kind of stickiness through repeat-rolling Fluid.It is made up of resin, pigment, filler auxiliary agent and organic solvent etc..For books and periodicals including decoration, building decoration and electric wire The various printings such as road sheet material.As social demand increases, also respective extension and the growth of various ink.
The existing usual rate of drying of printing-ink slow or adhesive force excessively is bad, easily comes off, causes time and resource Waste.
The content of the invention
Goal of the invention:In order to overcome problem above, it is an object of the invention to provide a kind of strong printing-ink of adhesive force and Its preparation method.
Technical scheme:It is an object of the present invention to provide a kind of strong printing-ink of adhesive force, including following weight The component of part:20-30 parts of organic pigment, 20-30 parts of epoxy resin, 30-40 parts of organic solvent, 1-3 parts of trbasic zinc phosphate, age resistor 8- 12 parts, 1-3 parts of defoamer, 1-3 parts of levelling agent, 4-6 parts of dispersant, 1-2 parts of adhesion promoter, 1-3 parts of slip agent, calcium carbonate 1-3 parts, 3-6 parts of colloid oil, 4-6 parts of ethylene glycol, 1-3 parts of anti-settling agent.
It is preferred that, described organic solvent is that concentration is 90% ethanol solution.
It is preferred that, described age resistor is age resistor 1010.
It is preferred that, described defoamer is organopolysiloxane or polyether-modified silicon.
It is preferred that, described levelling agent is dimethyl silicone polymer or fluorinated siloxane.
It is preferred that, described dispersant is propene carbonate or dimethicone.
It is preferred that, described adhesion promoter is that epoxy radicals silicone hydride and amino silane are 1 according to weight ratio:1 mixing and Into.
It is preferred that, described slip agent is DOW CORNING DC-51.
It is preferred that, described anti-settling agent is polyamide wax or aerosil.
It is another object of the present invention to provide the preparation method of above-mentioned printing-ink, comprise the following steps:
1)The each component for weighing the amount of formula is sequentially placed into stirred autoclave, and stir speed (S.S.) is 1600-1800r/min, is first risen Temperature then heats to 80-90 DEG C and continues stirring reaction 20-25min to 60-70 DEG C of stirring reaction 10-15min;
2)By step 1)Material after stirring reaction is placed on 15-18 DEG C of drying, then the place of closing stands 20-25min Grinding obtains 20 μm of slurries.
Above-mentioned technical proposal can be seen that the present invention and have the advantages that:The print of adhesive force of the present invention by force Brush ink, cost of material is low, and preparation method is simple, scientific and reasonable, and the ink adhesion of preparation is strong, and folding resistance is excellent, from road Healthy and free from worry DC-51 slip agents can reduce the surface tension of ink, improve polishing machine, anti-to be adhered, and reduce skin-friction coefficient;Carbonic acid Ink viscosity can be adjusted for calcium, can also make to be filled organic pigment, reduce cost;Defoamer can reduce system Surface tension, reduces liquid surface film-strength;Colloid oil G improves the set speed of ink, and printing adaptability and stability are good, It also can adjust ink;Ethylene glycol can improve the resistance to frost of ink.
Embodiment
With reference to specific embodiment, the present invention is furture elucidated.
Embodiment 1
A kind of strong printing-ink of adhesive force, includes the component of following parts by weight:20 parts of organic pigment, 20 parts of epoxy resin, have 30 parts of machine solvent, 1 part of trbasic zinc phosphate, 8 parts of age resistor, 1 part of defoamer, 1 part of levelling agent, 4 parts of dispersant, 1 part of adhesion promoter, 1 part of slip agent, 1 part of calcium carbonate, 3 parts of colloid oil, 4 parts of ethylene glycol, 1 part of anti-settling agent.
Described organic solvent is that concentration is 90% ethanol solution.
Described age resistor is age resistor 1010.
Described defoamer is organopolysiloxane.
Described levelling agent is dimethyl silicone polymer.
Described dispersant is propene carbonate.
Described adhesion promoter is that epoxy radicals silicone hydride and amino silane are 1 according to weight ratio:1 mixes.
Described slip agent is DOW CORNING DC-51.
Described anti-settling agent is polyamide wax.
The preparation method of above-mentioned printing-ink:
1)The each component for weighing the amount of formula is sequentially placed into stirred autoclave, and stir speed (S.S.) is 1600r/min, is first warming up to 60 DEG C stirring reaction 15min, then heats to 80 DEG C and continues stirring reaction 25min;
2)By step 1)Material after stirring reaction is placed on 15 DEG C of dryings, the place of closing stands 25min and then ground To 20 μm of slurries.
Embodiment 2
A kind of strong printing-ink of adhesive force, includes the component of following parts by weight:30 parts of organic pigment, 30 parts of epoxy resin, have 40 parts of machine solvent, 3 parts of trbasic zinc phosphate, 12 parts of age resistor, 3 parts of defoamer, 3 parts of levelling agent, 6 parts of dispersant, adhesion promoter 2 Part, 6 parts of 3 parts of slip agent, 3 parts of calcium carbonate, colloid oil, 6 parts of ethylene glycol, 3 parts of anti-settling agent.
Described organic solvent is that concentration is 90% ethanol solution.
Described age resistor is age resistor 1010.
Described defoamer is polyether-modified silicon.
Described levelling agent is fluorinated siloxane.
Described dispersant is dimethicone.
Described adhesion promoter is that epoxy radicals silicone hydride and amino silane are 1 according to weight ratio:1 mixes.
Described slip agent is DOW CORNING DC-51.
Described anti-settling agent is polyamide wax.
The preparation method of above-mentioned printing-ink:
1)The each component for weighing the amount of formula is sequentially placed into stirred autoclave, and stir speed (S.S.) is 1800r/min, is first warming up to 70 DEG C stirring reaction 10min, then heats to 90 DEG C and continues stirring reaction 20min;
2)By step 1)Material after stirring reaction is placed on 18 DEG C of dryings, the place of closing stands 25min and then ground To 20 μm of slurries.
Embodiment 3
A kind of strong printing-ink of adhesive force, includes the component of following parts by weight:25 parts of organic pigment, 25 parts of epoxy resin, have 35 parts of machine solvent, 2 parts of trbasic zinc phosphate, 10 parts of age resistor, 2 parts of defoamer, 2 parts of levelling agent, 5 parts of dispersant, adhesion promoter 1.5 Part, 4.5 parts of 2 parts of slip agent, 2 parts of calcium carbonate, colloid oil, 5 parts of ethylene glycol, 2 parts of anti-settling agent.
Described organic solvent is that toluene, acetone, isopropanol, ethyl acetate are 3 according to weight ratio:1:3:1 mixes.
Described age resistor is age resistor 1010.
Described defoamer is organopolysiloxane.
Described levelling agent is fluorinated siloxane.
Described dispersant is propene carbonate.
Described organic solvent is that concentration is 90% ethanol solution.
Described slip agent is DOW CORNING DC-51.
Described anti-settling agent is aerosil.
The preparation method of above-mentioned printing-ink:
1)The each component for weighing the amount of formula is sequentially placed into stirred autoclave, and stir speed (S.S.) is 1700r/min, is first warming up to 65 DEG C stirring reaction 13min, then heats to 85 DEG C and continues stirring reaction 22min;
2)By step 1)Material after stirring reaction is placed on 16 DEG C of dryings, the place of closing stands 22min and then ground To 20 μm of slurries.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as the present invention's Protection domain.

Claims (10)

1. a kind of strong printing-ink of adhesive force, it is characterised in that:Include the component of following parts by weight:20-30 parts of organic pigment, 20-30 parts of epoxy resin, 30-40 parts of organic solvent, 1-3 parts of trbasic zinc phosphate, 8-12 parts of age resistor, 1-3 parts of defoamer, levelling agent 1- 3 parts, 4-6 parts of dispersant, 1-2 parts of adhesion promoter, 1-3 parts of slip agent, 1-3 parts of calcium carbonate, 3-6 parts of colloid oil, ethylene glycol 4-6 parts, 1-3 parts of anti-settling agent.
2. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described organic solvent is dense Spend for 90% ethanol solution.
3. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described age resistor is anti-old Agent 1010.
4. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described defoamer is organic Polysiloxanes or polyether-modified silicon.
5. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described levelling agent is poly- two Methylsiloxane or fluorinated siloxane.
6. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described dispersant is carbonic acid Propylene or dimethicone.
7. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described adhesion promoter According to weight ratio it is 1 for epoxy radicals silicone hydride and amino silane:1 mixes.
8. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described slip agent is road health Peaceful DC-51.
9. a kind of strong printing-ink of adhesive force according to claim 1, it is characterised in that:Described anti-settling agent is polyamides Amine wax or aerosil.
10. a kind of preparation method of the strong printing-ink of adhesive force as described in claim any one of 1-9, it is characterised in that: Comprise the following steps:
1)The each component for weighing the amount of formula is sequentially placed into stirred autoclave, and stir speed (S.S.) is 1600-1800r/min, is first risen Temperature then heats to 80-90 DEG C and continues stirring reaction 20-25min to 60-70 DEG C of stirring reaction 10-15min;
2)By step 1)Material after stirring reaction is placed on 15-18 DEG C of drying, then the place of closing stands 20-25min Grinding obtains 20 μm of slurries.
CN201710492546.7A 2017-06-26 2017-06-26 Strong printing-ink of a kind of adhesive force and preparation method thereof Pending CN107163678A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710492546.7A CN107163678A (en) 2017-06-26 2017-06-26 Strong printing-ink of a kind of adhesive force and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710492546.7A CN107163678A (en) 2017-06-26 2017-06-26 Strong printing-ink of a kind of adhesive force and preparation method thereof

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CN107163678A true CN107163678A (en) 2017-09-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107513307A (en) * 2017-09-29 2017-12-26 马鞍山松鹤信息科技有限公司 A kind of environment-friendly type printing-ink and its preparation technology

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817881A (en) * 2015-04-28 2015-08-05 中科院广州化学有限公司南雄材料生产基地 Water removal protective ink and preparation method thereof
CN106084984A (en) * 2016-08-29 2016-11-09 苏州安洁科技股份有限公司 A kind of printing-ink
CN106189498A (en) * 2016-08-29 2016-12-07 苏州安洁科技股份有限公司 A kind of ink for screen printing
CN106590169A (en) * 2016-12-14 2017-04-26 合肥金泉印务有限公司 Oil paint for spraying printing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817881A (en) * 2015-04-28 2015-08-05 中科院广州化学有限公司南雄材料生产基地 Water removal protective ink and preparation method thereof
CN106084984A (en) * 2016-08-29 2016-11-09 苏州安洁科技股份有限公司 A kind of printing-ink
CN106189498A (en) * 2016-08-29 2016-12-07 苏州安洁科技股份有限公司 A kind of ink for screen printing
CN106590169A (en) * 2016-12-14 2017-04-26 合肥金泉印务有限公司 Oil paint for spraying printing

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107513307A (en) * 2017-09-29 2017-12-26 马鞍山松鹤信息科技有限公司 A kind of environment-friendly type printing-ink and its preparation technology

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Application publication date: 20170915

RJ01 Rejection of invention patent application after publication