CN106118233A - A kind of fluorescent ink - Google Patents
A kind of fluorescent ink Download PDFInfo
- Publication number
- CN106118233A CN106118233A CN201610755223.8A CN201610755223A CN106118233A CN 106118233 A CN106118233 A CN 106118233A CN 201610755223 A CN201610755223 A CN 201610755223A CN 106118233 A CN106118233 A CN 106118233A
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- parts
- ink
- fluorescent ink
- weight ratio
- mixing composition
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of fluorescent ink, including the material of following weight portion: fluorescent pigment 15 30 parts, link stuff 25 50 parts, solvent 45 80 parts, defoamer 14 parts, levelling agent 14 parts, 27 parts of 5A molecular sieve, aerosil 13 parts, dispersant 27 parts, adhesion promoter 0.5 1.5 parts, colloid oil 25 parts, 14 parts of barium sulfate, brucite 13 parts, dioctyl phthalate 7 15 parts, 13 parts of antioxidant.Can strengthen the adhesive force of ink in the present invention, prevent ink from ink bleed occur, changing the phenomenons such as ink, chemical stability is strong, and the storage time is long, and printing performance is stable, and oxidation resistance is strong, abrasion-resistant.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of fluorescent ink.
Background technology
Fluorescent ink is Application comparison one of ink widely in modern packaging printing and anti-counterfeit printing, is suitable for for public affairs
Literary composition, marketable securities, certificate, profit are the name brands packages printings such as envelope, invitation card and senior cigarette, wine, medicine, cosmetics.Fluoroleum
In ink, main component is fluorescent pigment, fluorescent pigment function of dominant luminous pigment, when natural light (containing ultraviolet light) irradiates, permissible
By ultraviolet shortwave being converted to longer visible ray, thus reflect more gorgeous color.Fluorescent pigment and high score subtree
Fat binder, solvent and additive compound are ground prepares fluorescent ink, can use the modes such as wire mark version, intaglio plate or hectograph to print.
But more existing fluorescent ink poor adhesive force, easily produce phenomenons such as printing uneven, deinking, have a strong impact on printing quality
Amount, and the surface tension relationship of ink is to the transfer performance of ink and trace stability on printing face, when the table of ink
When surface tension is more more than the surface tension in printing face, trace can shrink, and the aperture of fish-eye shaped even occurs；If printing face and oil
The surface tension of ink is close, and the surface tension of half tone more than the surface tension in printing face time, printing there will be network blocking phenomenon,
How reconciliation statement surface tension is the problem needing to solve in fact；After ink is imprinted on leaflet, owing to wearability is bad, leaflet is in fortune
Defeated, use during can produce ink and come off, fall the phenomenons such as ink, in transportation, excessively transmission speed is very fast, leaflet table
The layer of ink in face can affect outward appearance and the quality of leaflet because rubbing and partial exfoliation, and the storage effect of ink is also value simultaneously
The problem that must pay close attention to.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of fluorescent ink.
A kind of fluorescent ink that the present invention proposes, including the material of following weight portion: fluorescent pigment 15-30 part, link stuff
25-50 part, solvent 45-80 part, defoamer 1-4 part, levelling agent 1-4 part, 5A molecular sieve 2-7 part, aerosil 1-3 part,
Dispersant 2-7 part, adhesion promoter 0.5-1.5 part, colloid oil 2-5 part, barium sulfate 1-4 part, brucite 1-3 part, phthalandione two
Monooctyl ester 7-15 part, antioxidant 1-3 part.
Preferably, described link stuff is chlorinated polypropylene, polyurethane modified epoxy resin, chlorine vinegar copolymerization PVC paste tree
Fat and polyamide are 1:1:2:1 mixing composition according to weight ratio.
Preferably, described solvent includes isopropanol, toluene, Petroleum, butyl acetate and butanone and is 1 according to weight ratio:
2:3:2:1 mixes composition.
Preferably, described defoamer is polyether-modified silicon.
Preferably, described levelling agent be polydimethylsiloxane and fluorinated siloxane be 1:2 mixing composition according to weight ratio.
Preferably, described adhesion promoter be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio.
Preferably, described dispersant is oleamide.
Preferably, described antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-and double (3,5-tri-grades of butyl-4-hydroxy benzeness
Base) thioether according to weight ratio be 2:1 mixing composition.
The present invention compared with prior art, the Advantageous Effects having:
In the present invention, select oleamide can reduce resin particle molding melting viscosity as dispersant, improve flowing
Property has the function of slip agent concurrently simultaneously, and both cooperate can potentiation effect；Owing to ink the most easily rises
The quality that impact of steeping oneself-meeting is printed, the polyether-modified silicon of defoamer combines polyethers with the advantage of both organic silicon defoamers, acid and alkali resistance
And inorganic salt, can be used for the froth breaking under harsh conditions, it is possible to decrease diagram of system surface tension, make oneself to be prone to the surface spreading at liquid
And absorption, thus reduce liquid surface film-strength to reach froth breaking purpose；Levelling agent can make ink during drying and forming-film
Forming a film smooth, smooth, uniform, using polydimethylsiloxane and fluorinated siloxane is that 1:2 mixes according to weight ratio
Being combined into, polydimethylsiloxane possesses good apparent condition control ability, but shrinkage cavity can often occurs, adds fluorination silica
Then can improve the wettability of base material after alkane, improve anti-shrinkage cavity ability；Add aerosil to play in ink system
Preferably anti-settling effect, but the levelability that more aerosil can make ink is deteriorated, and now adds 5A molecular sieve
Can improve the stability of ink, the polarity of the silicone hydroxyl on 5A molecular sieve hole wall can make 5A molecular sieve and with polar group
Polymer or polymer monomer between there is the good compatibility so that the existence of molecular sieve can make link stuff pass through chemistry
Key couples together with molecular sieve, and the supply chain network structure making ink is more perfect, improves the storage time of ink；Link stuff uses chlorination
Acrylic resin, polyurethane modified epoxy resin, chlorine vinegar copolymerization PVC paste resin and polyamide are 1:1:2 according to weight ratio:
1 mixing composition, chlorinated polypropylene is a kind of polar thermoplastic resin introducing chlorine atom in polypropylene molecular chain, has good
Good one-tenth colloidality and gloss, can be used as the adhesive of bonding plastics, metal or paper, and polyamide has good printing and fits
Ying Xing, surface rub resistance, polyurethane modified epoxy resin then make the good heat resistance of the high resiliency of polyurethane and epoxy resin with
Cementability organically combines, and introduces flexible ehter bond, thus improves the toughness of epoxy resin, prevent on epoxy resin
The situation of fracture occurs after ink printing, chlorine vinegar copolymerization PVC paste molecular resin chain introduces vinyl acetate groups, improve
The dissolution velocity of resin, enhances the bonding force of resin and various adhesive substrate material, can plastify completely at 120 DEG C-130 DEG C,
Avoid printing material due to the adverse consequences such as high-temperature baking after-contraction, deformation, variable color, foaming, feel be hardening, except low temperature gel
Change outside characteristic, also there is the good transparency, of light color, flexibility, cementability, low odor profiles and stability, different resins it
Between complement each other to form a kind of become colloidality is good, adhesive force compared with strong, tackness is moderate, the link stuff of applied range；Solvent includes
Isopropanol, toluene, Petroleum, butyl acetate and butanone and according to weight ratio be 1:2:3:2:1 mixing composition, merge each other
Property is good, for relatively single solvent, link stuff resin especially polyamide is had the strongest dissolving power；Adhesion promoter
Be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, epoxy radicals silicone hydride is novel epoxy radicals coupling agent,
Having reaction active groups, have good yellowing resistance characteristic, amino silane has two kinds of functional groups, i.e. amino and ethoxy
Base, wherein three hydrolyzable groups (ethyoxyl), the most first hydrolysis generates silanol, owing to silanol is unstable, easily with nothing
The hydroxy combining dehydration of machine thing or metal surface, thus combine with inorganic matter or metal, with two active hydrogens on amino
Can react with various polymer, thus by chemical bond, the combination of two kinds of diverse material tight of character be risen
Coming, both are with the use of improving the adhesive force of resin link stuff further, prevent ink from ink bleed occur, changing the phenomenons such as ink；
Brucite can improve the stability of ink, convenient transport and storage；Colloid oil can improve the set speed of ink, and printing is suitable
Answering property and good stability, can be used to adjust ink body bone and gloss；Barium sulfate can improve the anchor effect of ink further；Antioxygen
Agent is 2, and tri-grades of butyl-4-methylphenols of 6-and double (3,5-tri-grades of butyl-4-hydroxy phenyls) thioether are that 2:1 mixes according to weight ratio
Being combined into, it has antioxygenic property more widely, and dioctyl phthalate is the plasticizer of chlorine vinegar copolymerization PVC paste resin.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment 1
In the present embodiment, a kind of fluorescent ink, including the material of following weight portion: fluorescent pigment 15 parts, link stuff 25 parts,
Solvent 45 parts, defoamer 1 part, levelling agent 1 part, 2 parts of 5A molecular sieve, aerosil 1 part, dispersant 2 parts, adhesive force promotes
Agent 0.5 part, colloid oil 2 parts, 1 part of barium sulfate, brucite 1 part, dioctyl phthalate 7 parts, 1 part of antioxidant.
Link stuff is chlorinated polypropylene, polyurethane modified epoxy resin, chlorine vinegar copolymerization PVC paste resin and polyamide resin
Fat according to weight ratio be 1:1:2:1 mixing composition, solvent include isopropanol, toluene, Petroleum, butyl acetate and butanone and according to
Weight ratio is 1:2:3:2:1 mixing composition, and defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorination silica
Alkane is 1:2 mixing composition according to weight ratio, adhesion promoter be amino silane and epoxy radicals silicone hydride be that 1:2 mixes according to weight ratio
Being combined into, dispersant is oleamide, and antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-and double (3,5-tri-grades of butyl-4-hydroxyls
Base phenyl) thioether according to weight ratio be 2:1 mixing composition.
Embodiment 2
In the present embodiment, a kind of fluorescent ink, including the material of following weight portion: fluorescent pigment 22.5 parts, link stuff
37.5 parts, solvent 62.5 parts, defoamer 2.5 parts, levelling agent 2.5 parts, 4.5 parts of 5A molecular sieve, aerosil 2 parts, dispersion
Agent 4.5 parts, adhesion promoter 1 part, colloid oil 3.5 parts, 2.5 parts of barium sulfate, brucite 2 parts, dioctyl phthalate 11 parts, antioxygen
Agent 2 parts.
Link stuff is chlorinated polypropylene, polyurethane modified epoxy resin, chlorine vinegar copolymerization PVC paste resin and polyamide resin
Fat according to weight ratio be 1:1:2:1 mixing composition, solvent include isopropanol, toluene, Petroleum, butyl acetate and butanone and according to
Weight ratio is 1:2:3:2:1 mixing composition, and defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorination silica
Alkane is 1:2 mixing composition according to weight ratio, adhesion promoter be amino silane and epoxy radicals silicone hydride be that 1:2 mixes according to weight ratio
Being combined into, dispersant is oleamide, and antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-and double (3,5-tri-grades of butyl-4-hydroxyls
Base phenyl) thioether according to weight ratio be 2:1 mixing composition.
Embodiment 3
In the present embodiment, a kind of fluorescent ink, including the material of following weight portion: fluorescent pigment 30 parts, link stuff 50 parts,
Solvent 80 parts, defoamer 4 parts, levelling agent 4 parts, 7 parts of 5A molecular sieve, aerosil 3 parts, dispersant 7 parts, adhesive force promotes
Agent 1.5 parts, colloid oil 5 parts, 4 parts of barium sulfate, brucite 3 parts, dioctyl phthalate 15 parts, 3 parts of antioxidant.
Link stuff is chlorinated polypropylene, polyurethane modified epoxy resin, chlorine vinegar copolymerization PVC paste resin and polyamide resin
Fat according to weight ratio be 1:1:2:1 mixing composition, solvent include isopropanol, toluene, Petroleum, butyl acetate and butanone and according to
Weight ratio is 1:2:3:2:1 mixing composition, and defoamer is polyether-modified silicon, and levelling agent is polydimethylsiloxane and fluorination silica
Alkane is 1:2 mixing composition according to weight ratio, adhesion promoter be amino silane and epoxy radicals silicone hydride be that 1:2 mixes according to weight ratio
Being combined into, dispersant is oleamide, and antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-and double (3,5-tri-grades of butyl-4-hydroxyls
Base phenyl) thioether according to weight ratio be 2:1 mixing composition.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (8)
1. a fluorescent ink, it is characterised in that include the material of following weight portion: fluorescent pigment 15-30 part, link stuff 25-
50 parts, solvent 45-80 part, defoamer 1-4 part, levelling agent 1-4 part, 5A molecular sieve 2-7 part, aerosil 1-3 part, dispersion
Agent 2-7 part, adhesion promoter 0.5-1.5 part, colloid oil 2-5 part, barium sulfate 1-4 part, brucite 1-3 part, dioctyl phthalate
7-15 part, antioxidant 1-3 part.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described link stuff be chlorinated polypropylene,
Polyurethane modified epoxy resin, chlorine vinegar copolymerization PVC paste resin and polyamide are 1:1:2:1 mixing composition according to weight ratio.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described solvent includes isopropanol, toluene, stone brain
Oil, butyl acetate and butanone be 1:2:3:2:1 mixing composition according to weight ratio.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described defoamer is polyether-modified silicon.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described levelling agent be polydimethylsiloxane and
Fluorinated siloxane is 1:2 mixing composition according to weight ratio.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described adhesion promoter be amino silane and
Epoxy radicals silicone hydride is 1:2 mixing composition according to weight ratio.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described dispersant is oleamide.
A kind of fluorescent ink the most according to claim 1, it is characterised in that: described antioxidant is 2, tri-grades of butyl-4-of 6-
Methylphenol and double (3,5-tri-grades of butyl-4-hydroxy phenyls) thioether are 2:1 mixing composition according to weight ratio.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610755223.8A CN106118233A (en) | 2016-08-29 | 2016-08-29 | A kind of fluorescent ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610755223.8A CN106118233A (en) | 2016-08-29 | 2016-08-29 | A kind of fluorescent ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106118233A true CN106118233A (en) | 2016-11-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610755223.8A Pending CN106118233A (en) | 2016-08-29 | 2016-08-29 | A kind of fluorescent ink |
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| CN (1) | CN106118233A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659613A (en) * | 2018-06-11 | 2018-10-16 | 江苏海田电子材料有限公司 | A kind of fluorescent ink and preparation method thereof |
| CN109267420A (en) * | 2018-08-15 | 2019-01-25 | 湖北绿新环保包装科技有限公司 | A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity |
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| CN101984008A (en) * | 2010-10-29 | 2011-03-09 | 沈阳化工大学 | Organic nano anti-corrosion coating and preparation method thereof |
| CN103436079A (en) * | 2013-07-23 | 2013-12-11 | 王景泉 | Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof |
| CN104804537A (en) * | 2015-04-22 | 2015-07-29 | 黎司华 | Low-temperature curing silk-screen printing ink for polypropylene materials |
| CN105348920A (en) * | 2015-11-12 | 2016-02-24 | 成都普瑞斯特新材料有限公司 | Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610755223.8A patent/CN106118233A/en active Pending
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| CN101984008A (en) * | 2010-10-29 | 2011-03-09 | 沈阳化工大学 | Organic nano anti-corrosion coating and preparation method thereof |
| CN103436079A (en) * | 2013-07-23 | 2013-12-11 | 王景泉 | Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof |
| CN104804537A (en) * | 2015-04-22 | 2015-07-29 | 黎司华 | Low-temperature curing silk-screen printing ink for polypropylene materials |
| CN105348920A (en) * | 2015-11-12 | 2016-02-24 | 成都普瑞斯特新材料有限公司 | Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659613A (en) * | 2018-06-11 | 2018-10-16 | 江苏海田电子材料有限公司 | A kind of fluorescent ink and preparation method thereof |
| CN109267420A (en) * | 2018-08-15 | 2019-01-25 | 湖北绿新环保包装科技有限公司 | A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity |
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Application publication date: 20161116 |