CN109267420A - A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity - Google Patents
A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity Download PDFInfo
- Publication number
- CN109267420A CN109267420A CN201810928360.6A CN201810928360A CN109267420A CN 109267420 A CN109267420 A CN 109267420A CN 201810928360 A CN201810928360 A CN 201810928360A CN 109267420 A CN109267420 A CN 109267420A
- Authority
- CN
- China
- Prior art keywords
- resin
- parts
- offset printing
- cruel
- superelevation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention proposes a kind of offset printing transferring aluminum-plating paper coatings with superelevation ink adsorption capacity, in parts by mass, it includes at least: made of 13-14 parts of cellulosic resin, 6-8 parts of polyacrylic resin, 2-3 parts of vinyl chloride-vinyl acetate resin, MS resin 0.5-1,0.1-0.2 parts of fumed silica, 0.1-0.2 parts of double amino-type functional silanes, 0.2-0.3 parts of auxiliary agent, 75-80 parts of solvent are mixed.The invention solves the problems, such as that common transfer coatings cannot directly carry out offset printing, can allow the direct offset printing of our company offset printing transfer aluminum plated paper, without oil polish before printing, reduces production process, saves production cost.
Description
Technical field
The present invention relates to a kind of offset printing transferring aluminum-plating paper coatings with superelevation ink adsorption capacity.
Background technique
Transfer aluminum plated paper is environmental-friend packing material generally acknowledged currently on the market, is widely used in various packaging industries.It
It is degradable recyclable without metal aluminum foil and the difficult high molecular material decomposed, and cost than traditional aluminum foil composite paper and is covered
Film paper more has economic advantages.In transfer aluminum plated paper production process, antifalse effect can also be reached by radium-shine or holographic technique,
Keep product more beautiful simultaneously.And coating transfer aluminum plating is a kind of special coating made to measure for it, is obtained in recent years
Promotion and application energetically.
Since common transfer coatings cannot directly carry out offset printing, need on transfer aluminum plated paper that upper one layer of adaptability is good again
Gloss oil, with guarantee with offset ink have good adhesive force, which increase production costs, also increase one of production process.
Summary of the invention
The present invention proposes a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity, solves common transfer and applies
Material cannot directly carry out the problem of offset printing, which can allow the direct offset printing of our company offset printing transfer aluminum plated paper, without printing
Oil polish before brushing, reduces production process, saves production cost.
The technical scheme of the present invention is realized as follows:
A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity includes at least in parts by mass: cellulose
13-14 parts of resinoid, 6-8 parts of polyacrylic resin, 2-3 parts of vinyl chloride-vinyl acetate resin, MS resin 0.5-1, fumed silica 0.1-0.2
Made of part, 0.1-0.2 parts of double amino-type functional silanes, 0.2-0.3 parts of auxiliary agent, 75-80 parts of solvent are mixed.
Preferably, the molecular weight of the cellulosic resin is 120,000-14 ten thousand, including cellulose acetate resin, acetic acid
Third cruel celluosic resin, the cruel celluosic resin of acetic acid fourth or viscosity are one of 18s nitrocellulose resin below or several
Kind.
Preferably, for the molecular weight of the polyacrylic resin 120,000-16 ten thousand, the monomer of polyacrylic resin is methyl
Acrylic acid first is cruel, methacrylic acid second is cruel, methacrylic acid fourth is cruel, acrylic acid first is cruel, acrylic acid second is cruel or acrylic acid fourth is cruel, gathers
Acrylic resin is one of above-mentioned monomer or a variety of homopolymers or copolymer aggregated into.
Preferably, the molecular weight of the vinyl chloride-vinyl acetate resin is 100,000-18 ten thousand, including binary vinyl chloride-vinyl acetate resin,
Trihydroxylic vinyl chloride-vinyl acetate resin or ternary carboxyl vinyl chloride-vinyl acetate resin, wherein the content of vinyl acetate be
15wt%-35wt%.
Preferably, the auxiliary agent is selected from one or more of levelling agent, plasticizer, anti scuffing agent or coalescing agent.
Preferably, the solvent includes that acetic acid second is cruel, acetic acid positive third is cruel, the positive fourth of acetic acid is cruel, acetone, butanone, propylene glycol
One or more of methyl ether, propylene-glycol ethyl ether or ethyl alcohol.
Preferably, coating surface dyne value is greater than 40.
Preferably, double amino-type functional silanes are N- (mono- aminoethyl of β)-γ-aminopropyl front three (second) oxygroup
Silane.
The present invention is the beneficial effects are as follows: the present invention can allow the direct offset printing of our company offset printing transfer aluminum plated paper, nothing
Oil polish before printing is needed, reduces production process, saves production cost.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work belongs to what the present invention protected
Range.
A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity includes at least in parts by mass: cellulose
13-14 parts of resinoid, 6-8 parts of polyacrylic resin, 2-3 parts of vinyl chloride-vinyl acetate resin, MS resin 0.5-1, fumed silica 0.1-0.2
Made of part, 0.1-0.2 parts of double amino-type functional silanes, 0.2-0.3 parts of auxiliary agent, 75-80 parts of solvent are mixed.
Preferably, the molecular weight of the cellulosic resin is 120,000-14 ten thousand, including cellulose acetate resin, acetic acid
Third cruel celluosic resin, the cruel celluosic resin of acetic acid fourth or viscosity are one of 18s nitrocellulose resin below or several
Kind.
Preferably, for the molecular weight of the polyacrylic resin 120,000-16 ten thousand, the monomer of polyacrylic resin is methyl
Acrylic acid first is cruel, methacrylic acid second is cruel, methacrylic acid fourth is cruel, acrylic acid first is cruel, acrylic acid second is cruel or acrylic acid fourth is cruel, gathers
Acrylic resin is one of above-mentioned monomer or a variety of homopolymers or copolymer aggregated into.
Preferably, the molecular weight of the vinyl chloride-vinyl acetate resin is 100,000-18 ten thousand, including binary vinyl chloride-vinyl acetate resin,
Trihydroxylic vinyl chloride-vinyl acetate resin or ternary carboxyl vinyl chloride-vinyl acetate resin, wherein the content of vinyl acetate be
15wt%-35wt%.
Preferably, the auxiliary agent is selected from one or more of levelling agent, plasticizer, anti scuffing agent or coalescing agent.
Preferably, the solvent includes that acetic acid second is cruel, acetic acid positive third is cruel, the positive fourth of acetic acid is cruel, acetone, butanone, propylene glycol
One or more of methyl ether, propylene-glycol ethyl ether or ethyl alcohol.
Preferably, coating surface dyne value is greater than 40.
Preferably, double amino-type functional silanes are N- (mono- aminoethyl of β)-γ-aminopropyl front three (second) oxygroup
Silane.
Specific production procedure is as follows: firstly, confirmation formula rate: by weight, 13-14 parts of cellulosic resin, poly- third
6-8 parts of olefin(e) acid resin, 2-3 parts of vinyl chloride-vinyl acetate resin, MS resin 0.5-1,0.1-0.2 parts of fumed silica, 0.2-0.3 parts of auxiliary agent,
75-80 parts of solvent.Secondly, first solvent is placed in reaction kettle according to formula, agitating and heating is opened, after mixing by various trees
The raw materials such as rouge component put into reaction kettle, and high-speed stirred 2-5h is completely dissolved various resin Compositions, then mistake after natural cooling
Filter, finally obtains offset printing transferring aluminum-plating paper coating.
Comprising unsaturated bond in vinyl chloride-vinyl acetate resin class in the present invention, light resistance and oxidative resistance are poor, cooperate celluosic resin
The coating of preparation has good water-fast, oil resistant, acid and alkali-resistance and salt tolerance.And celluosic resin can prevent air and hydrone from seeping
The metal surface for entering transfer aluminum plated paper entirely prevents the chemical attack of metal.
N- (mono- aminoethyl of β)-γ-aminopropyl front three (second) oxysilane is improved to resin laminate performance, and increase has
Cementability of the machine material to inorganic material；Improve bonding, improves the dry state and tensile strength and modulus, bending strength of material
With compressive strength.Double amino-type functional silanes with free amino are grafted on silica particles, prepare high score
Property and moderately good nano particle are dissipated, while the free amino being grafted can further be coupled other active materials, increases adherency
Power.
And MS resin can be hydrolyzed to silanol in the present invention, and effect forms firm silicon oxygen under catalyst appropriate
Network can quickly improve room temperature curing effect, increase the adsorption rate to ink.The silicone cross-linked system being formed simultaneously
So that polymer machinery performance, chemical-resistance and weatherability are all enhanced, the quality of product is improved.
Coating surface dyne produced by the present invention value is greater than 40, and dyne value is higher, and surface energy is more, therefore surface is also
More acceptant ink, if surface dynes value is too low, ink just can not be parched and can be peeled off.Therefore, it is further promoted to oil
The adsorption capacity of ink.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity, which is characterized in that in parts by mass, at least wrap
It includes: 13-14 parts of cellulosic resin, 6-8 parts of polyacrylic resin, 2-3 parts of vinyl chloride-vinyl acetate resin, MS resin 0.5-1, gas phase titanium dioxide
0.1-0.2 parts of silicon, 0.1-0.2 parts of double amino-type functional silanes, 0.2-0.3 parts of auxiliary agent, 75-80 parts of solvent are made through being mixed
At.
2. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
The molecular weight of the cellulosic resin be 120,000-14 ten thousand, including cellulose acetate resin, the cruel celluosic resin of acetic acid third,
The cruel celluosic resin of acetic acid fourth or viscosity are one or more of 18s nitrocellulose resin below.
3. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
For the molecular weight of the polyacrylic resin 120,000-16 ten thousand, the monomer of polyacrylic resin is that methyl methacrylate is cruel, methyl
Acrylic acid second is cruel, methacrylic acid fourth is cruel, acrylic acid first is cruel, acrylic acid second is cruel or acrylic acid fourth is cruel, on polyacrylic resin is
State one of monomer or a variety of homopolymers or copolymer aggregated into.
4. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
The molecular weight of the vinyl chloride-vinyl acetate resin is 100,000-18 ten thousand, including binary vinyl chloride-vinyl acetate resin, trihydroxylic vinyl chloride-
Vinyl acetate resin or ternary carboxyl vinyl chloride-vinyl acetate resin, wherein the content of vinyl acetate is 15wt%-35wt%.
5. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
The auxiliary agent is selected from one or more of levelling agent, plasticizer, anti scuffing agent or coalescing agent.
6. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
The solvent includes that acetic acid second is cruel, acetic acid positive third is cruel, the positive fourth of acetic acid is cruel, acetone, butanone, propylene glycol monomethyl ether, propylene-glycol ethyl ether
Or one or more of ethyl alcohol.
7. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
Coating surface dyne value is greater than 40.
8. a kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity as described in claim 1, which is characterized in that
Double amino-type functional silanes are N- (mono- aminoethyl of β)-γ-aminopropyl front three (second) oxysilane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810928360.6A CN109267420A (en) | 2018-08-15 | 2018-08-15 | A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810928360.6A CN109267420A (en) | 2018-08-15 | 2018-08-15 | A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109267420A true CN109267420A (en) | 2019-01-25 |
Family
ID=65153449
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810928360.6A Pending CN109267420A (en) | 2018-08-15 | 2018-08-15 | A kind of offset printing transferring aluminum-plating paper coating with superelevation ink adsorption capacity |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109267420A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114990926A (en) * | 2022-06-22 | 2022-09-02 | 湖北绿新环保包装科技有限公司 | Offset printing transfer coating with high scrubbing resistance and preparation method thereof |
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| CN114990926A (en) * | 2022-06-22 | 2022-09-02 | 湖北绿新环保包装科技有限公司 | Offset printing transfer coating with high scrubbing resistance and preparation method thereof |
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Application publication date: 20190125 |
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