CN104559471A - Blending modified polyacrylic ester printing ink - Google Patents

Blending modified polyacrylic ester printing ink Download PDF

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Publication number
CN104559471A
CN104559471A CN201410847443.4A CN201410847443A CN104559471A CN 104559471 A CN104559471 A CN 104559471A CN 201410847443 A CN201410847443 A CN 201410847443A CN 104559471 A CN104559471 A CN 104559471A
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CN
China
Prior art keywords
ink
emulsion
water
printing ink
blended
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410847443.4A
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Chinese (zh)
Inventor
黎晚清
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201410847443.4A priority Critical patent/CN104559471A/en
Publication of CN104559471A publication Critical patent/CN104559471A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

Abstract

The invention provides blending modified polyacrylic ester printing ink and a process thereof. The printing ink is prepared through a maleic anhydride modified polyamide emulsion, an acrylic ester emulsion, a water-based acrylic acid color paste, a wetting agent, an organosilicon foam killer, and a defined amount of water. The maleic anhydride modified polyamide emulsion and the acrylic ester emulsion are compounded, so that the compound emulsion has an excellent adhesivity and wettability, and the prepared printing ink is excellent in gloss retention and color retention.

Description

A kind of blended and modified polypropylene acid esters ink
Technical field
The present invention relates to a kind of ink, particularly a kind of esters of acrylic acid ink, belongs to ink area.
Summary of the invention
Along with social demand increases, ink kind and output is respective extension and growth also, and current domestic ink industry size just maintains sustained and rapid growth with the speed of more than 10%, emerges rapidly and becomes one of ink manufacture big country of the world.Ink is that one is mixed equably by pigment, low-melting ink vehicle and auxiliary agent etc. and forms the gluey fluid of a kind of viscosity through repeat-rolling.It by printing by pattern, literal table now on the substrate, is the important materials for packages printing.
Tradition manufacture ink is the raw material using industrial petroleum resin as ink, this not only consumes a large amount of organic solvents, but also pollute the environment, high point petroleum solvent containing 35%-40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and 3,4-benzo pyrroles, 3-nitro benzo ketone etc. are wherein also containing carcinogenic components, can endanger user's health.
Environmental consciousness due to people strengthens and people improve the security requirement that food product pack is printed, developed country launches respectively policy, the application of restriction solvent borne ink in the field such as food and medical package, in facilitating ink to form, aromatic hydrocarbon toxic volatile organic composition ratio reduces, the trend of the environment-friendly ink transfer that ink industry has occurred from traditional solvent-borne ink to such as water-based flexographic ink, Soybean Oil Ink, UV ink are such.The development and production ability of environment-friendly ink has become one of following key factor of winning victory of ink manufacturer.The research and development of China's water color ink are started late, and product exists the problems such as poor water resistance, glossiness are low, and therefore the research and development of high-grade water color ink have important economy and social value with application.
The essential distinction of water color ink and solvent type ink is to take water as solvent or dispersion medium.The stuctures and properties of waterborne polymeric is the key factor determining water color ink performance.Waterborne polymeric used for water color ink is the earliest the shellac that can be dissolved in ethanol and basic solution, modified rosin resin replaced the binder that pure natural resin becomes water color ink afterwards, improve the printability of water color ink, but be also short of to some extent in glossiness and water tolerance, the use of acrylic ester emulsion substantially increases stability and the water tolerance of water color ink, but its over-all properties and solvent type ink also have certain gap.In order to improve the performance of acrylic ester aquosity ink further, by improving the performance of resin with other latex composite compoundings, thus prepare a kind of modified polyacrylate ink of excellent combination property.
Summary of the invention
The invention provides a kind of blended and modified polypropylene acid esters ink and technique thereof, for realizing this purpose, this ink comprises the material of following weight percent:
Maleic anhydride modified polymeric amide emulsion 20-30%
Acrylic ester emulsion 30-50%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 2-3%
Water surplus.
The preparation method of this ink carries out as follows:
(1) get a container, drop into a certain proportion of maleic anhydride modified polymeric amide emulsion, acrylic ester emulsion, stir and make it composite;
(2) add water soluble acrylic acid mill base, wetting agent and silicone antifoam agent and water successively again, be uniformly mixed with dispersion machine;
(3) use metre filter, collect filtrate;
(4) finally add appropriate silicone antifoam agent, a kind of blended and modified polypropylene acid esters ink.
The present invention has following advantages and characteristic:
(1) ink tool has good wearability;
Gloss retention and tint retention good.
Embodiment
Embodiment one:
Get a container, load the maleic anhydride modified polymeric amide emulsion of 20 parts, the acrylic ester emulsion of 50 parts, stir and make it composite, add the water soluble acrylic acid mill base of 10 parts, the wetting agent of 1 part and the silicone antifoam agent of 1 part and the water of 17 parts more successively, be uniformly mixed with dispersion machine, mix rear metre filter, collect filtrate, finally add the silicone antifoam agent of 1 part, a kind of blended and modified polypropylene acid esters ink.
Embodiment two:
Get a container, load the maleic anhydride modified polymeric amide emulsion of 30 parts, the acrylic ester emulsion of 40 parts, stir and make it composite, add the water soluble acrylic acid mill base of 10 parts, the wetting agent of 2 parts and the silicone antifoam agent of 1 part and the water of 16 parts more successively, be uniformly mixed with dispersion machine, mix rear metre filter, collect filtrate, finally add the silicone antifoam agent of 1 part, a kind of blended and modified polypropylene acid esters ink.
Embodiment three:
Get a container, load the maleic anhydride modified polymeric amide emulsion of 20 parts, the acrylic ester emulsion of 30 parts, stir and make it composite, add the water soluble acrylic acid mill base of 20 parts, the wetting agent of 2 parts and the silicone antifoam agent of 1.5 parts and the water of 25 parts more successively, be uniformly mixed with dispersion machine, mix rear metre filter, collect filtrate, finally add the silicone antifoam agent of 1.5 parts, a kind of blended and modified polypropylene acid esters ink.

Claims (2)

1. a blended and modified polypropylene acid esters ink, is characterized in that, this ink comprises the material of following weight percent:
Maleic anhydride modified polymeric amide emulsion 20-30%
Acrylic ester emulsion 30-50%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 2-3%
Water surplus.
2. a kind of blended and modified polypropylene acid esters ink according to claim 1, it is characterized in that, the preparation method of this ink carries out as follows:
(1) get a container, drop into a certain proportion of maleic anhydride modified polymeric amide emulsion, acrylic ester emulsion, stir and make it composite;
(2) add water soluble acrylic acid mill base, wetting agent and silicone antifoam agent and water successively again, be uniformly mixed with dispersion machine;
(3) use metre filter, collect filtrate;
(4) finally add appropriate silicone antifoam agent, a kind of blended and modified polypropylene acid esters ink.
CN201410847443.4A 2014-12-31 2014-12-31 Blending modified polyacrylic ester printing ink Pending CN104559471A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410847443.4A CN104559471A (en) 2014-12-31 2014-12-31 Blending modified polyacrylic ester printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410847443.4A CN104559471A (en) 2014-12-31 2014-12-31 Blending modified polyacrylic ester printing ink

Publications (1)

Publication Number Publication Date
CN104559471A true CN104559471A (en) 2015-04-29

Family

ID=53076575

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410847443.4A Pending CN104559471A (en) 2014-12-31 2014-12-31 Blending modified polyacrylic ester printing ink

Country Status (1)

Country Link
CN (1) CN104559471A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021666A (en) * 2018-08-01 2018-12-18 佛山市高明绿色德化工有限公司 A kind of aqueous self-drying glass ink and preparation method thereof
CN110605926A (en) * 2019-10-11 2019-12-24 乌兰浩特森辉印务有限公司 Cigarette case printing process

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4973617A (en) * 1988-08-15 1990-11-27 Basf Corporation Water-borne surface printing inks containing acrylic resin and carboxylated rosin modified polyamide

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4973617A (en) * 1988-08-15 1990-11-27 Basf Corporation Water-borne surface printing inks containing acrylic resin and carboxylated rosin modified polyamide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021666A (en) * 2018-08-01 2018-12-18 佛山市高明绿色德化工有限公司 A kind of aqueous self-drying glass ink and preparation method thereof
CN110605926A (en) * 2019-10-11 2019-12-24 乌兰浩特森辉印务有限公司 Cigarette case printing process
CN110605926B (en) * 2019-10-11 2020-08-21 乌兰浩特森辉印务有限公司 Cigarette case printing process

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C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150429