CN104559448A - Printing ink taking linseed oil as dissolving agent and preparation method for printing ink - Google Patents

Printing ink taking linseed oil as dissolving agent and preparation method for printing ink Download PDF

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Publication number
CN104559448A
CN104559448A CN201410825812.XA CN201410825812A CN104559448A CN 104559448 A CN104559448 A CN 104559448A CN 201410825812 A CN201410825812 A CN 201410825812A CN 104559448 A CN104559448 A CN 104559448A
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CN
China
Prior art keywords
linseed oil
agent
ink
printing ink
silicone antifoam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410825812.XA
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Chinese (zh)
Inventor
乐渭林
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Individual
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Individual
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Publication date
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Priority to CN201410825812.XA priority Critical patent/CN104559448A/en
Publication of CN104559448A publication Critical patent/CN104559448A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention provides printing ink taking linseed oil as a dissolving agent. The printing ink consists of the following components: linseed oil, ethanol amine, water-soluble acrylic resin, water-based acrylic mill base, a soya bean lecithin wetting agent, an organic silicon de-foaming agent and water. Printing ink prepared by taking linseed oil as the dissolving agent is low in VOC (volatile organic compounds) content, and has the characteristics of biodegradability and good environmental protection performance.

Description

A kind of take linseed oil as ink of solvating agent and preparation method thereof
Technical field
The present invention relates to a kind of ink, particularly a kind of vegetables oil that utilizes is as the environment-friendly ink of solvent, belongs to ink manufacture field.
Summary of the invention
Ink is a kind of to be mixed equably by pigment, low-melting ink vehicle and auxiliary agent etc. and through the gluey fluid of a kind of viscosity of repeat-rolling.It is the important materials for wrapping material printing, such as, for fields such as books and periodicals, packing and decorating, building decorations by printing by pattern, literal table now on the substrate.The U.S. is maximum ink producing country and country of consumption in the world, and Japan takes second place, and Germany the 3rd, China occupies the 4th.Along with the develop rapidly of Chinese national economy, the fast development of China's nearly ten years packaging industries, make the ink industry of China have also been obtained larger expansion, emerge rapidly and become one of ink manufacture big country of the world, current domestic ink industry size just maintains sustained and rapid growth with the speed of more than 10%.
Develop the ink kind of various performance in recent years, along with the attention degree of environmental protection is increasing, have the regulation limitations such as heavy metal content, packing material solvent residues amount and other VOC limit standard in other related fields such as food product pack especially, exploitation non-toxic ink is the study hotspot of current ink.
In China, what ink production was produced substantially is traditional synthetic resins ink, containing the high point petroleum solvent of 35% ~ 40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and 3,4-benzo pyrroles, 3-nitro benzo ketone etc. are wherein also containing carcinogenic components, on printed matter, residual quantity is large, the survival time is long, can endanger user's health, is also the important source of pollution in Printing ink producing process simultaneously.In today that environmental pollution attracts people's attention day by day, non-toxic ink replaces traditional ink will be inexorable trend.Linseed oil is produced by linseed oil and is formed, and as the interpolation raw material of ink, the ink VOC content of preparation is low, has the various features such as upper machine stability and good post-press finishing of biological degradation and excellence.
This ink not only environmental protection but also the resource of available regenerative replaces non-renewable petroleum solvent, and when reclaiming, than traditional ink, deinking is easier to useless printed matter process, little to the damage of paper, the waste residue after deinking is also better degraded, packing and decorating printing can be widely used in, to beautifying printed matter.
Summary of the invention
The invention provides a kind of take linseed oil as ink of solvating agent and preparation method thereof, and for realizing this purpose, this ink comprises the material of following weight percent:
Linseed oil 20-40%
Thanomin 10-20%
Water soluble acrylic resin 20-30%
Water soluble acrylic acid mill base 10-20%
Soybean lecithin wetting agent 1-2%
Silicone antifoam agent 1-2%
Water surplus.
The preparation method of this ink carries out as follows:
(1) load a certain proportion of water, linseed oil, thanomin and silicone antifoam agent by a dispersion cylinder, by the rotating speed of 500-600 r/min, dispersed 1-2 hour;
(2) after dispersion, then add appropriate silicone antifoam agent, filter;
(3) the emulsion of filtration is put in dispersion cylinder more again;
(4) add water soluble acrylic resin, water soluble acrylic acid mill base, soybean lecithin wetting agent and silicone antifoam agent more successively, by the rotating speed of 600-8000r/min, dispersed 2-4 hour;
(5) filter after finally adding appropriate silicone antifoam agent, a kind of take linseed oil as the ink of solvating agent.
Step (4) in, in described water soluble acrylic acid mill base, the color of pigment powder is one or more in red, yellow, blue, black.
The present invention has following advantages and characteristic:
(1) this ink colors is pure, look full;
(2) good environmental protection;
(3) raw material sources are extensive and renewable, reduce the dependence to Nonrenewable resources.
Embodiment
Embodiment one:
The water of 17 parts is loaded by a dispersion cylinder, the linseed oil of 20 parts, the silicone antifoam agent of the thanomin of 10 parts and 0.5 part, by the rotating speed of 500 r/min, the silicone antifoam agent of 0.5 part is added again after dispersed 2 hours, filter, the emulsion of filtration is put in dispersion cylinder more again, then the water soluble acrylic resin of 30 parts is added successively, the water soluble acrylic acid mill base of 20 parts, the silicone antifoam agent of the soybean lecithin wetting agent of 1 part and 0.5 part, by the rotating speed of 600 r/min, dispersed 4 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of take linseed oil as the ink of solvating agent.
Embodiment two:
The water of 12 parts is loaded by a dispersion cylinder, the linseed oil of 30 parts, the silicone antifoam agent of the thanomin of 20 parts and 0.25 part, by the rotating speed of 600 r/min, the silicone antifoam agent of 0.25 part is added again after dispersed 1 hour, filter, the emulsion of filtration is put in dispersion cylinder more again, then the water soluble acrylic resin of 25 parts is added successively, the water soluble acrylic acid mill base of 10 parts, the silicone antifoam agent of the soybean lecithin wetting agent of 2 parts and 0.25 part, by the rotating speed of 800 r/min, dispersed 2 hours, filter after finally adding the silicone antifoam agent of 0.25 part, a kind of take linseed oil as the ink of solvating agent.
Embodiment three:
The water of 8 parts is loaded by a dispersion cylinder, the linseed oil of 40 parts, the silicone antifoam agent of the thanomin of 15 parts and 0.25 part, by the rotating speed of 550 r/min, the silicone antifoam agent of 0.25 part is added again after dispersed 1.5 hours, filter, the emulsion of filtration is put in dispersion cylinder more again, then the water soluble acrylic resin of 20 parts is added successively, the water soluble acrylic acid mill base of 15 parts, the silicone antifoam agent of the soybean lecithin wetting agent of 1 part and 0.25 part, by the rotating speed of 700 r/min, dispersed 3 hours, filter after finally adding the silicone antifoam agent of 0.25 part, a kind of take linseed oil as the ink of solvating agent.

Claims (3)

1. be an ink for solvating agent with linseed oil, it is characterized in that, this ink comprises the material of following weight percent:
Oleum lini 20-40%
Thanomin 10-20%
Water soluble acrylic resin 20-30%
Water soluble acrylic acid mill base 10-20%
Soybean lecithin wetting agent 1-2%
Silicone antifoam agent 1-2%
Water surplus.
2. according to claim 1 a kind of take linseed oil as the ink of solvating agent, it is characterized in that, the preparation method of this ink comprises the steps:
(1) load a certain proportion of water, linseed oil, thanomin and silicone antifoam agent by a dispersion cylinder, by the rotating speed of 500-600 r/min, dispersed 1-2 hour;
(2) after dispersion, then add appropriate silicone antifoam agent, filter;
(3) the emulsion of filtration is put in dispersion cylinder more again;
(4) add water soluble acrylic resin, water soluble acrylic acid mill base, soybean lecithin wetting agent and silicone antifoam agent more successively, by the rotating speed of 600-8000r/min, dispersed 2-4 hour;
(5) filter after finally adding appropriate silicone antifoam agent, a kind of take linseed oil as the ink of solvating agent.
3. according to claim 2 a kind of take linseed oil as the preparation method of the ink of solvating agent, it is characterized in that, step (4) in, in described water soluble acrylic acid mill base, the color of pigment powder is one or more in red, yellow, blue, black.
CN201410825812.XA 2014-12-28 2014-12-28 Printing ink taking linseed oil as dissolving agent and preparation method for printing ink Pending CN104559448A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410825812.XA CN104559448A (en) 2014-12-28 2014-12-28 Printing ink taking linseed oil as dissolving agent and preparation method for printing ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410825812.XA CN104559448A (en) 2014-12-28 2014-12-28 Printing ink taking linseed oil as dissolving agent and preparation method for printing ink

Publications (1)

Publication Number Publication Date
CN104559448A true CN104559448A (en) 2015-04-29

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017858A (en) * 2015-07-31 2015-11-04 李可 Polymerized-rosin-modified-phenolic-resin-added ink and preparation method thereof
CN111019436A (en) * 2019-12-27 2020-04-17 西安至简网络文化传播有限公司 Myopia-preventing printing ink capable of effectively absorbing high-energy harmful blue light and preparation and spraying method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1628159A (en) * 2001-11-09 2005-06-15 太阳化学公司 Low tack water washable lithographic printing inks
JP2011231217A (en) * 2010-04-27 2011-11-17 Sakata Corp Water-soluble ink composition for dry offset printing, offset printing method, and printed matter
CN103483909A (en) * 2013-09-23 2014-01-01 严亚木 Preparation method for water-based ink

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1628159A (en) * 2001-11-09 2005-06-15 太阳化学公司 Low tack water washable lithographic printing inks
JP2011231217A (en) * 2010-04-27 2011-11-17 Sakata Corp Water-soluble ink composition for dry offset printing, offset printing method, and printed matter
CN103483909A (en) * 2013-09-23 2014-01-01 严亚木 Preparation method for water-based ink

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017858A (en) * 2015-07-31 2015-11-04 李可 Polymerized-rosin-modified-phenolic-resin-added ink and preparation method thereof
CN111019436A (en) * 2019-12-27 2020-04-17 西安至简网络文化传播有限公司 Myopia-preventing printing ink capable of effectively absorbing high-energy harmful blue light and preparation and spraying method thereof

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Application publication date: 20150429