CN105001710A - Preparation technology for ink added with polymerized rosin resin - Google Patents
Preparation technology for ink added with polymerized rosin resin Download PDFInfo
- Publication number
- CN105001710A CN105001710A CN201510445266.1A CN201510445266A CN105001710A CN 105001710 A CN105001710 A CN 105001710A CN 201510445266 A CN201510445266 A CN 201510445266A CN 105001710 A CN105001710 A CN 105001710A
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- China
- Prior art keywords
- ink
- rosin resin
- preparation technology
- polymerized rosin
- dispersed
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a preparation technology for ink added with polymerized rosin resin. According to the preparation technology, modified polymerized rosin resin is added in the preparation process of vegetable oil solvent ink, and polymerized rosin is stable and not prone to oxidation; the polymerized rosin resin is added in the ink preparation process, the obtained ink is high in bonding strength and good in stability, and the adhesive promotion effect of the rosin resin is improved.
Description
Technical field
The present invention relates to a kind of novel ink, particularly a kind of environment-friendlyink ink and preparation method thereof, belong to ink chemical field.
Summary of the invention
Along with the development of press, ink application is also increasingly extensive, output constantly increases, China's ink industry in 2010 is produced and is reached all-time high, " Chinese ink industry production and marketing demand and investment forecasting analysis report are looked forward to the prospect " adds up, whole nation ink gross annual output amount amounts to 58.99 ten thousand tons, accounts for 14% of the whole world, exceedes Germany first, Japan occupies the second in the world.
Ink is a kind of to be mixed equably by pigment, low-melting ink vehicle and auxiliary agent etc. and through the gluey fluid of a kind of viscosity of repeat-rolling.In China, what ink production was produced substantially is traditional synthetic resins ink, containing the high point petroleum solvent of 35% ~ 40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and 3,4-benzo pyrroles, 3-nitro benzo ketone etc. are wherein also containing carcinogenic components, on printed matter, residual quantity is large, the survival time is long, can endanger user's health, is also the important source of pollution in Printing ink producing process simultaneously.Along with the attention degree of environmental protection is increasing, the reinforcement of Green Packaging concept, have the regulation limitations such as heavy metal content, packing material solvent residues amount and other VOC limit standard in other related fields such as food product pack especially, exploitation non-toxic ink is the study hotspot of current ink.
Solvent is made with vegetables oil, not only environmental protection but also the resource of available regenerative replaced non-renewable petroleum solvent to the ink of preparation, and when reclaiming, than traditional ink, deinking is easier to useless printed matter process, little to the damage of paper, but vegetable oil solvent adhesive power is not strong, preparing in ink process by adding Gum Rosin, the viscosity of ink can be increased, improve the bonding strength of ink.Some acid in rosin is containing conjugated double bond, therefore reactivity is higher, unstable, oxidizable.Polymerized rosin is that the conjugated double bond of rosin is under the catalyzer such as sulfuric acid, boron trifluoride, tin tetrachloride, zinc chloride exist, with benzene,toluene,xylene, gasoline or tetracol phenixin etc. for reaction medium, the product of polyreaction is carried out at-10 ~ 65 DEG C of temperature, polymerized rosin is comparatively stable and not oxidizable, add polymeric rosin resin preparing in ink process, prepared ink not only bonding strength is high and stability good, improves the Efficient Adhesive Promotion of Gum Rosin.
Summary of the invention
The invention provides a kind of preparation technology adding polymeric rosin resin ink, this preparation technology carries out as follows:
With one dispersion cylinder load 20% water, 25% vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and 1% soybean lecithin wetting agent;
(2) press the rotating speed of 500-600 r/min, dispersed 1-2 hour;
(3) after dispersion, by liquid filtering;
(4) collect the emulsion of filtration, then pour in dispersion cylinder, add the water soluble acrylic resin of 25%, the polymeric rosin resin of 3%, the water soluble acrylic acid mill base of 10% successively, by the rotating speed of 600-800r/min, dispersed 2-4 hour;
(5) filter after finally adding the silicone antifoam agent of 0.5%, a kind of interpolation polymeric rosin resin ink.
Step (4) in, in described water soluble acrylic acid mill base, the color of pigment powder is one or more in red, yellow, blue, black.
The present invention has following advantages and characteristic:
(1) this ink adhesion intensity is good;
(2) the Gum Rosin good stability added;
(3) raw material sources are extensive, with low cost.
Embodiment
Embodiment one:
The water of 20% is loaded by a dispersion cylinder, 25% part of vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and the soybean lecithin wetting agent of 1%, by the rotating speed of 500 r/min, dispersed 2 hours, after being uniformly dispersed, by liquid filtering, the emulsion of filtering is put in dispersion cylinder more again, add the water soluble acrylic resin of 25% successively, the polymeric rosin resin of 3%, the water soluble acrylic acid mill base of 10%, by the rotating speed of 600 r/min, dispersed 4 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of interpolation polymeric rosin resin ink.
Embodiment two:
The water of 20% is loaded by a dispersion cylinder, 25% part of vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and the soybean lecithin wetting agent of 1%, by the rotating speed of 600 r/min, dispersed 1 hour, after being uniformly dispersed, by liquid filtering, the emulsion of filtering is put in dispersion cylinder more again, add the water soluble acrylic resin of 25% successively, the polymeric rosin resin of 3%, the water soluble acrylic acid mill base of 10%, by the rotating speed of 600 r/min, dispersed 4 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of interpolation polymeric rosin resin ink.
Embodiment three:
The water of 20% is loaded by a dispersion cylinder, 25% part of vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and the soybean lecithin wetting agent of 1%, by the rotating speed of 500 r/min, dispersed 2 hours, after being uniformly dispersed, by liquid filtering, the emulsion of filtering is put in dispersion cylinder more again, add the water soluble acrylic resin of 25% successively, the polymeric rosin resin of 3%, the water soluble acrylic acid mill base of 10%, by the rotating speed of 800 r/min, dispersed 2 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of interpolation polymeric rosin resin ink.
Claims (1)
1. add a preparation technology for polymeric rosin resin ink, this preparation technology comprises the steps:
With one dispersion cylinder load 20% water, 25% vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and 1% soybean lecithin wetting agent;
(2) press the rotating speed of 500-600 r/min, dispersed 1-2 hour;
(3) after dispersion, by liquid filtering;
(4) collect the emulsion of filtration, then pour in dispersion cylinder, add the water soluble acrylic resin of 25%, the polymeric rosin resin of 3%, the water soluble acrylic acid mill base of 10% successively, by the rotating speed of 600-800r/min, dispersed 2-4 hour;
(5) filter after finally adding the silicone antifoam agent of 0.5%, a kind of interpolation polymeric rosin resin ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510445266.1A CN105001710A (en) | 2015-07-27 | 2015-07-27 | Preparation technology for ink added with polymerized rosin resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510445266.1A CN105001710A (en) | 2015-07-27 | 2015-07-27 | Preparation technology for ink added with polymerized rosin resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105001710A true CN105001710A (en) | 2015-10-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510445266.1A Pending CN105001710A (en) | 2015-07-27 | 2015-07-27 | Preparation technology for ink added with polymerized rosin resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105001710A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384317A (en) * | 2018-02-05 | 2018-08-10 | 珠海悦美水墨新材料股份有限公司 | A kind of high temperature resistant type gravure water-based ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559468A (en) * | 2014-12-28 | 2015-04-29 | 乐渭林 | Soy ink and method for preparing same |
-
2015
- 2015-07-27 CN CN201510445266.1A patent/CN105001710A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559468A (en) * | 2014-12-28 | 2015-04-29 | 乐渭林 | Soy ink and method for preparing same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384317A (en) * | 2018-02-05 | 2018-08-10 | 珠海悦美水墨新材料股份有限公司 | A kind of high temperature resistant type gravure water-based ink and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151028 |
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| WD01 | Invention patent application deemed withdrawn after publication |