CN104559451A - Novel environmental friendly printing ink and preparation method thereof - Google Patents
Novel environmental friendly printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN104559451A CN104559451A CN201410847313.0A CN201410847313A CN104559451A CN 104559451 A CN104559451 A CN 104559451A CN 201410847313 A CN201410847313 A CN 201410847313A CN 104559451 A CN104559451 A CN 104559451A
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- ink
- silicone antifoam
- antifoam agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a novel environmental friendly printing ink which is prepared by stirring and mixing water, soybean oil fatty acid ethyl ester, ethanol amine, rosin maleic anhydride polyol ester, water-based acrylic acid color paste, a wetting agent and an organic silicon defoamer in a disperser. The printing ink prepared by taking soybean oil fatty acid ethyl ester as a solvent has the characteristics of zero toxicity, environmental protection and the like.
Description
Technical field
The present invention relates to a kind of environment-friendly ink, particularly a kind of plant oil resin ink and preparation technology thereof, belong to ink area.
Summary of the invention
Ink is by tinting material, low-melting ink vehicle and auxiliary agent according to a certain ratio, and the coloured viscosity pulpous state fluid formed after the techniques such as grinding, rolling, is the important materials of Printing industry, is widely used in numerous industrial circle such as publication and printing, packing and decorating.
Tradition manufacture ink is the raw material using industrial petroleum resin as ink, high point petroleum solvent containing 35%-40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and wherein 3,4-benzo pyrrole, 3-nitro benzo ketone etc. are also containing carcinogenic components, and on printed matter, residual quantity is large, and the survival time is long, can endanger user's health, be also the important source of pollution in Printing ink producing process simultaneously.
Environmental consciousness due to people strengthens and people improve the security requirement that food product pack is printed, require that in ink composition, aromatic hydrocarbon toxic volatile organic composition ratio reduces, environment-friendlyink ink experienced by without benzene ink gradually, alcohol-soluble printing ink and water color ink, and progressively replace traditional volatile organic solvent type ink.
Vegetables oil is widely used as the solvent of ink, and particularly with soybean oil, but the ink performance that vegetables oil is prepared as solvent is single, and the present invention is that ink prepared by solvent with ethyl ester of soybean oil.This ink has the features such as asepsis environment-protecting.
Summary of the invention
The invention provides a kind of novel environment friendly ink and preparation method thereof, for realizing this purpose, this ink comprises the material of following weight percent:
Ethyl ester of soybean oil 20-40%
Thanomin 10-20%
Rosin Maleic polyol ester 20-30%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 1-2%
Water surplus.
The preparation method of this ink carries out as follows:
(1) get a container, load a certain proportion of water, ethyl ester of soybean oil, thanomin and silicone antifoam agent, be uniformly mixed with dispersion machine;
(2) after dispersion, then add appropriate silicone antifoam agent, mixture is filtered;
(3) the emulsion of collecting filtration is put in container more again;
(4) in container, add Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and silicone antifoam agent successively again, be uniformly mixed with dispersion machine;
(5) filter after finally adding appropriate silicone antifoam agent, a kind of novel environment friendly ink.
Preferentially, step (1) in, dispersing speed is set to 500-600 r/min, and jitter time is 1-2 hour.
Preferentially, step (4) in, dispersing speed is set to 600-800r/min, and jitter time is 2-4 hour.
The present invention has following advantages and characteristic:
(1) good environmental protection;
(2) raw material sources are extensive.
Embodiment
Embodiment one:
Get a container, load the water of 17% ratio, the ethyl ester of soybean oil of 20% ratio, the thanomin of 10% ratio and the silicone antifoam agent of 0.5% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 500 r/min, disperse after 2 hours, add the silicone antifoam agent of 0.5% ratio again, mixture is filtered, collect the emulsion of filtering again to put in container, the Rosin Maleic polyol ester of 30% ratio is added successively in container, the water soluble acrylic acid mill base of 20% ratio, the wetting agent of 1% ratio and the silicone antifoam agent of 0.5% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 600r/min, the silicone antifoam agent of 0.5% ratio is added after dispersed 4 hours, finally filter to obtain a kind of novel environment friendly ink.
Embodiment two:
Get a container, load the water of 12% ratio, the ethyl ester of soybean oil of 30% ratio, the thanomin of 20% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 600 r/min, disperse after 1 hour, add the silicone antifoam agent of 0.25% ratio again, mixture is filtered, collect the emulsion of filtering again to put in container, the Rosin Maleic polyol ester of 25% ratio is added successively in container, the water soluble acrylic acid mill base of 10% ratio, the wetting agent of 2% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 800r/min, the silicone antifoam agent of 0.5% ratio is added after dispersed 2 hours, finally filter to obtain a kind of novel environment friendly ink.
Embodiment three:
Get a container, load the water of 8% ratio, the ethyl ester of soybean oil of 40% ratio, the thanomin of 15% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 550 r/min, disperse after 1.5 hours, add the silicone antifoam agent of 0.25% ratio again, mixture is filtered, collect the emulsion of filtering again to put in container, the Rosin Maleic polyol ester of 20% ratio is added successively in container, the water soluble acrylic acid mill base of 15% ratio, the wetting agent of 1% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 700r/min, the silicone antifoam agent of 0.25% ratio is added after dispersed 3 hours, finally filter to obtain a kind of novel environment friendly ink.
Claims (2)
1. a novel environment friendly ink, is characterized in that, this ink comprises following percent composition:
Ethyl ester of soybean oil 20-40%
Thanomin 10-20%
Rosin Maleic polyol ester 20-30%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 1-2%
Water surplus.
2. a kind of novel environment friendly ink according to claim 1, is characterized in that, the preparation method of this ink carries out as follows:
(1) get a container, load a certain proportion of water, ethyl ester of soybean oil, thanomin and silicone antifoam agent, be uniformly mixed with dispersion machine;
(2) after dispersion, then add appropriate silicone antifoam agent, mixture is filtered;
(3) the emulsion of collecting filtration is put in container more again;
(4) in container, add Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and silicone antifoam agent successively again, be uniformly mixed with dispersion machine;
(5) filter after finally adding appropriate silicone antifoam agent, a kind of novel environment friendly ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410847313.0A CN104559451A (en) | 2014-12-31 | 2014-12-31 | Novel environmental friendly printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410847313.0A CN104559451A (en) | 2014-12-31 | 2014-12-31 | Novel environmental friendly printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104559451A true CN104559451A (en) | 2015-04-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410847313.0A Pending CN104559451A (en) | 2014-12-31 | 2014-12-31 | Novel environmental friendly printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104559451A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153791A (en) * | 2015-07-30 | 2015-12-16 | 安徽省中彩印务有限公司 | Printing ink |
| CN105462344A (en) * | 2015-12-16 | 2016-04-06 | 无锡吉进环保科技有限公司 | Environment-friendly ink composition |
| CN105462350A (en) * | 2015-12-16 | 2016-04-06 | 无锡吉进环保科技有限公司 | Method for preparing environment-friendly ink composition |
| CN106590152A (en) * | 2016-11-30 | 2017-04-26 | 蒋玉莲 | Preparation method of plant oil-based ink |
| CN106590144A (en) * | 2016-11-30 | 2017-04-26 | 蒋玉莲 | Preparation process for vegetable oil based ink with manganese naphthenate |
| CN106590145A (en) * | 2016-12-01 | 2017-04-26 | 蒋玉莲 | Modification and preparation technology of printing ink |
| CN106634168A (en) * | 2016-11-30 | 2017-05-10 | 蒋玉莲 | Vegetable-oil-base ink with cobalt naphtenate and preparation method of vegetable-oil-base ink |
| CN106752309A (en) * | 2016-11-30 | 2017-05-31 | 蒋玉莲 | A kind of ink and preparation method for adding lead naphthenate |
| CN107216708A (en) * | 2017-06-20 | 2017-09-29 | 江苏特丰新材料科技有限公司 | A kind of preparation technology of new resistance to ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010023532A1 (en) * | 2008-08-26 | 2010-03-04 | Ennatura Technology Ventures (P) Ltd. | Water reducible alkyd resins |
| CN102675968A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based soybean oil ink and preparation method thereof |
| CN102717615A (en) * | 2012-06-26 | 2012-10-10 | 华新(佛山)彩色印刷有限公司 | Method for producing lamination-free anti-curl automatic labeling label |
| CN102888284A (en) * | 2011-07-19 | 2013-01-23 | 天津天元天昊化工有限公司 | Preparation method of fatty acid ethyl esters of soybean oil |
-
2014
- 2014-12-31 CN CN201410847313.0A patent/CN104559451A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010023532A1 (en) * | 2008-08-26 | 2010-03-04 | Ennatura Technology Ventures (P) Ltd. | Water reducible alkyd resins |
| CN102888284A (en) * | 2011-07-19 | 2013-01-23 | 天津天元天昊化工有限公司 | Preparation method of fatty acid ethyl esters of soybean oil |
| CN102675968A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based soybean oil ink and preparation method thereof |
| CN102717615A (en) * | 2012-06-26 | 2012-10-10 | 华新(佛山)彩色印刷有限公司 | Method for producing lamination-free anti-curl automatic labeling label |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153791A (en) * | 2015-07-30 | 2015-12-16 | 安徽省中彩印务有限公司 | Printing ink |
| CN105462344A (en) * | 2015-12-16 | 2016-04-06 | 无锡吉进环保科技有限公司 | Environment-friendly ink composition |
| CN105462350A (en) * | 2015-12-16 | 2016-04-06 | 无锡吉进环保科技有限公司 | Method for preparing environment-friendly ink composition |
| CN106590152A (en) * | 2016-11-30 | 2017-04-26 | 蒋玉莲 | Preparation method of plant oil-based ink |
| CN106590144A (en) * | 2016-11-30 | 2017-04-26 | 蒋玉莲 | Preparation process for vegetable oil based ink with manganese naphthenate |
| CN106634168A (en) * | 2016-11-30 | 2017-05-10 | 蒋玉莲 | Vegetable-oil-base ink with cobalt naphtenate and preparation method of vegetable-oil-base ink |
| CN106752309A (en) * | 2016-11-30 | 2017-05-31 | 蒋玉莲 | A kind of ink and preparation method for adding lead naphthenate |
| CN106590145A (en) * | 2016-12-01 | 2017-04-26 | 蒋玉莲 | Modification and preparation technology of printing ink |
| CN107216708A (en) * | 2017-06-20 | 2017-09-29 | 江苏特丰新材料科技有限公司 | A kind of preparation technology of new resistance to ink |
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Application publication date: 20150429 |