CN104592808A - Castor oil fatty acid methyl ester ink composition - Google Patents
Castor oil fatty acid methyl ester ink composition Download PDFInfo
- Publication number
- CN104592808A CN104592808A CN201410847399.7A CN201410847399A CN104592808A CN 104592808 A CN104592808 A CN 104592808A CN 201410847399 A CN201410847399 A CN 201410847399A CN 104592808 A CN104592808 A CN 104592808A
- Authority
- CN
- China
- Prior art keywords
- fatty acid
- castor oil
- acid methyl
- oil fatty
- silicone antifoam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention discloses a castor oil fatty acid methyl ester ink composition and a preparation method thereof. The composition is prepared from water, castor oil fatty acid methyl ester, ethanol amine, rosin maleic anhydride polyol ester, water-borne acrylic color paste, a wetting agent and an organic silicon antifoaming agent. The ink prepared by using the castor oil fatty acid methyl ester as the raw material has the characteristics of high drying property, no toxicity, environmental protection and the like.
Description
Technical field
The present invention relates to a kind of ink composite, particularly a kind of ink composite utilizing plant oil resin, belongs to ink area.
Summary of the invention
Ink is by tinting material, low-melting ink vehicle and auxiliary agent according to a certain ratio, and the coloured viscosity pulpous state fluid formed after the techniques such as grinding, rolling, is the important materials of Printing industry, is widely used in numerous industrial circle such as publication and printing, packing and decorating.
Tradition manufacture ink is the raw material using industrial petroleum resin as ink, high point petroleum solvent containing 35%-40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and wherein 3,4-benzo pyrrole, 3-nitro benzo ketone etc. are also containing carcinogenic components, and on printed matter, residual quantity is large, and the survival time is long, can endanger user's health, be also the important source of pollution in Printing ink producing process simultaneously.
Environmental consciousness due to people strengthens and people improve the security requirement that food product pack is printed, require that in ink composition, aromatic hydrocarbon toxic volatile organic composition ratio reduces, environment-friendlyink ink experienced by without benzene ink gradually, alcohol-soluble printing ink and water color ink, and progressively replace traditional volatile organic solvent type ink.
The seed (oil-containing about 50%) of castor-oil plant taken from by Viscotrol C.Seed benevolence oleaginousness after shelling is up to nearly 70%, and Viscotrol C is uniquely based on containing the commodity grease of hydroxyl through base acid, is the raw material manufacturing coating, paint and ink.Hardly oxidative rancidity occurs in atmosphere, storage stability is good, is typical non-drying liquid oils.After Viscotrol C synthetic castor oil fatty acid methyl ester, and the ink that it can be used as raw material to prepare has the features such as good drying property and asepsis environment-protecting.
Summary of the invention
The invention provides a kind of Castor Oil Fatty Acid methyl esters ink composite and preparation method thereof, for realizing this purpose, this ink comprises the material of following weight percent:
Castor Oil Fatty Acid methyl esters 20-40%
Thanomin 10-20%
Rosin Maleic polyol ester 20-30%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 1-2%
Water surplus.
The preparation method of this ink carries out as follows:
(1) get a container, load a certain proportion of water, Castor Oil Fatty Acid methyl esters, thanomin and silicone antifoam agent, be uniformly mixed with dispersion machine;
(2) after dispersion, then add appropriate silicone antifoam agent, mixture is filtered;
(3) the emulsion of collecting filtration is put in container more again;
(4) in container, add Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and silicone antifoam agent successively again, be uniformly mixed with dispersion machine;
(5) filter after finally adding appropriate silicone antifoam agent, a kind of Castor Oil Fatty Acid methyl esters ink composite.
Preferentially, step (1) in, dispersing speed is set to 500-600 r/min, and jitter time is 1-2 hour.
Preferentially, step (4) in, dispersing speed is set to 600-800r/min, and jitter time is 2-4 hour.
The present invention has following advantages and characteristic:
(1) good environmental protection;
(2) raw material sources are extensive.
Embodiment
Embodiment one:
Get a container, load the water of 17% ratio, the Castor Oil Fatty Acid methyl esters of 20% ratio, the thanomin of 10% ratio and the silicone antifoam agent of 0.5% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 500 r/min, disperse after 2 hours, add the silicone antifoam agent of 0.5% ratio again, mixture is filtered, collect the emulsion of filtering again to put in container, the Rosin Maleic polyol ester of 30% ratio is added successively in container, the water soluble acrylic acid mill base of 20% ratio, the wetting agent of 1% ratio and the silicone antifoam agent of 0.5% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 600r/min, the silicone antifoam agent of 0.5% ratio is added after dispersed 4 hours, finally filter to obtain a kind of Castor Oil Fatty Acid methyl esters ink composite.
Embodiment two:
Get a container, load the water of 12% ratio, the Castor Oil Fatty Acid methyl esters of 30% ratio, the thanomin of 20% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 600 r/min, disperse after 1 hour, add the silicone antifoam agent of 0.25% ratio again, mixture is filtered, collect the emulsion of filtering again to put in container, the Rosin Maleic polyol ester of 25% ratio is added successively in container, the water soluble acrylic acid mill base of 10% ratio, the wetting agent of 2% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 800r/min, the silicone antifoam agent of 0.5% ratio is added after dispersed 2 hours, finally filter to obtain a kind of Castor Oil Fatty Acid methyl esters ink composite.
Embodiment three:
Get a container, load the water of 8% ratio, the Castor Oil Fatty Acid methyl esters of 40% ratio, the thanomin of 15% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 550 r/min, disperse after 1.5 hours, add the silicone antifoam agent of 0.25% ratio again, mixture is filtered, collect the emulsion of filtering again to put in container, the Rosin Maleic polyol ester of 20% ratio is added successively in container, the water soluble acrylic acid mill base of 15% ratio, the wetting agent of 1% ratio and the silicone antifoam agent of 0.25% ratio, be uniformly mixed with dispersion machine, dispersing speed is set to 700r/min, the silicone antifoam agent of 0.25% ratio is added after dispersed 3 hours, finally filter to obtain a kind of Castor Oil Fatty Acid methyl esters ink composite.
Claims (2)
1. a Castor Oil Fatty Acid methyl esters ink composite, is characterized in that, this ink comprises following percent composition:
Castor Oil Fatty Acid methyl esters 20-40%
Thanomin 10-20%
Rosin Maleic polyol ester 20-30%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 1-2%
Water surplus.
2. a kind of Castor Oil Fatty Acid methyl esters ink composite according to claim 1, it is characterized in that, the preparation method of this ink composite carries out as follows:
(1) get a container, load a certain proportion of water, Castor Oil Fatty Acid methyl esters, thanomin and silicone antifoam agent, be uniformly mixed with dispersion machine;
(2) after dispersion, then add appropriate silicone antifoam agent, mixture is filtered;
(3) the emulsion of collecting filtration is put in container more again;
(4) in container, add Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and silicone antifoam agent successively again, be uniformly mixed with dispersion machine;
(5) filter after finally adding appropriate silicone antifoam agent, a kind of Castor Oil Fatty Acid methyl esters ink composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410847399.7A CN104592808A (en) | 2014-12-31 | 2014-12-31 | Castor oil fatty acid methyl ester ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410847399.7A CN104592808A (en) | 2014-12-31 | 2014-12-31 | Castor oil fatty acid methyl ester ink composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104592808A true CN104592808A (en) | 2015-05-06 |
Family
ID=53118885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410847399.7A Pending CN104592808A (en) | 2014-12-31 | 2014-12-31 | Castor oil fatty acid methyl ester ink composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104592808A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1408797A (en) * | 2000-04-07 | 2003-04-09 | 大日本油墨化学工业株式会社 | Printing ink composition |
| US20070232786A1 (en) * | 2001-01-05 | 2007-10-04 | Sun Chemical Corporation | Acrylated maleic-modified rosin ester and method of preparation |
-
2014
- 2014-12-31 CN CN201410847399.7A patent/CN104592808A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1408797A (en) * | 2000-04-07 | 2003-04-09 | 大日本油墨化学工业株式会社 | Printing ink composition |
| US20070232786A1 (en) * | 2001-01-05 | 2007-10-04 | Sun Chemical Corporation | Acrylated maleic-modified rosin ester and method of preparation |
Non-Patent Citations (1)
| Title |
|---|
| 崔锦锋等: "顺酐松香加成树脂水性油墨的生产技术", 《甘肃化工》 * |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150506 |