CN106752309A - A kind of ink and preparation method for adding lead naphthenate - Google Patents
A kind of ink and preparation method for adding lead naphthenate Download PDFInfo
- Publication number
- CN106752309A CN106752309A CN201611084441.XA CN201611084441A CN106752309A CN 106752309 A CN106752309 A CN 106752309A CN 201611084441 A CN201611084441 A CN 201611084441A CN 106752309 A CN106752309 A CN 106752309A
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- CN
- China
- Prior art keywords
- lead naphthenate
- ink
- organic silicon
- silicon defoamer
- preparation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of ink and preparation method for adding lead naphthenate.The method is first to mix vegetable oil esters, monoethanolamine, organic silicon defoamer and water, appropriate organic silicon defoamer is added after stirring again, filtering, collect emulsion, Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and organic silicon defoamer are added again, stirring mixing, lead naphthenate and organic silicon defoamer are added after being well mixed, and are finally filtered.
Description
Technical field
The present invention relates to a kind of plant oil-based ink, more particularly to a kind of vegetable oil base oil for adding lead naphthenate drying aids
Ink and preparation method thereof, belongs to ink manufacture field.
The content of the invention
As China's ink yield constantly increases, ink designs and varieties are on the increase, and quality and class are improved constantly, some
The quality of product has portioned product to export close to or up the advanced level of same kind of products at abroad, 2015 national ink year
Total output amounts to 800,000 tons.But ink consumption per head is still not as good as world average level, this shows the market development of China ink also
With larger potentiality.
Ink is a kind of equably to be mixed and through a kind of sticky glue of repeat-rolling by pigment, link stuff and auxiliary agent etc.
Shape fluid.In China, what ink manufacturing industry was substantially produced is traditional synthetic resin ink, will be contained mostly in this kind of ink
Organic (or inorganic) solvent, thus contain more multiring aromatic hydrocarbon substance, and therein 3,4- benzos pyrrole, 3- nitro benzos
Ketone etc. also contains carcinogenic components, and residual quantity is big on printed matter, and the survival time is long, can endanger user's health, while being also oil
Important pollution sources in black production process.Nowadays, with people's environmental consciousness raising and environmental protection cry it is increasingly high
Rise, ink also increasingly strengthens its environmental requirement as the chief component of green printing, especially packaging for foodstuff etc. its
His related fields have the regulations such as content of beary metal, packing material solvent residues amount and others VOC limit standards to limit, and develop nontoxic
Ink is the study hotspot of current ink.Make solvent, ink not only environmental protection but also the resource replacement of available regeneration of preparation with vegetable oil
Non-renewable petroleum solvent, and deinking is easier to than traditional ink to useless printed matter treatment when reclaiming.But plant oil base contains
There are a large amount of unrighted acids, slow drying speed limits the use scope of plant oil-based ink.
The present invention adds lead naphthenate drying aids so that consaturated oil is aoxidized in ink-making process, is inhaling
After oxygen, solid-state is become from liquid, macromolecular is become by small molecule, so as to accelerate grease xeroma.Improve ink setting performance.
The content of the invention
The present invention provides a kind of plant oil-based ink for adding lead naphthenate and preparation method thereof, and the ink includes following weight
The material of percentage：
Vegetable oil esters 20-40%
Monoethanolamine 10-20%
Rosin Maleic polyol ester 20-30%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Organic silicon defoamer 1-2%
Lead naphthenate 1-2%
Water surplus.
A kind of preparation method of the plant oil-based ink for adding lead naphthenate, the preparation method is carried out as follows：
(1) first a certain proportion of vegetable oil esters, water, monoethanolamine and organic silicon defoamer are fitted into a container, are stirred with dispersion machine
It is well mixed；
(2) after being uniformly dispersed, appropriate organic silicon defoamer is added, mixture is filtered；
(3) the emulsion of filtering is collected, then puts into container again；
(4) and then toward sequentially adding Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and organosilicon froth breaking in container
Agent, is uniformly mixed with dispersion machine；
(5) filtered after being eventually adding appropriate lead naphthenate and organic silicon defoamer, you can obtain a kind of plant oil base for adding lead naphthenate
Ink.
Preferentially, step (1) in, vegetable oil esters are soybean grease.
Preferentially, step (1) in, dispersing speed is set to 500-600 r/min, and jitter time is 1-2 hours.
Preferentially, step (4) in, dispersing speed is set to 600-800r/min, and jitter time is 2-4 hours.
The present invention has following advantages and characteristic：
(1) simple to operate, flow is short；
(2) raw material sources are extensively, cheap.
Specific embodiment
Embodiment one：
First by the organosilicon froth breaking of the soybean grease of 20% ratio, the water of 16% ratio, the monoethanolamine of 10% ratio and 0.5% ratio
Agent is fitted into a container, is uniformly mixed with dispersion machine, and dispersing speed is set to 500 r/min, after disperseing 2 hours, then
The organic silicon defoamer of 0.5% ratio is added, mixture is filtered, the emulsion that collection is filtered is put into container again, toward container
In sequentially add the Rosin Maleic polyol ester of 30% ratio, the water soluble acrylic acid mill base of 20% ratio, the wetting agent of 1% ratio and
The organic silicon defoamer of 0.5% ratio, is uniformly mixed with dispersion machine, and dispersing speed is set to 600r/min, dispersed
The lead naphthenate of 1% ratio and the organic silicon defoamer of 0.5% ratio are added after 4 hours, finally filtering can obtain a kind of addition naphthoic acid
The plant oil-based ink of lead.
Embodiment two：
First by the organosilicon of the soybean grease of 30% ratio, the water of 10.5% ratio, the monoethanolamine of 20% ratio and 0.25% ratio
Defoamer is fitted into a container, is uniformly mixed with dispersion machine, and dispersing speed is set to 600 r/min, disperses 1 hour
Afterwards, the organic silicon defoamer of 0.25% ratio is added, mixture is filtered, the emulsion that collection is filtered is put into container again,
Rosin Maleic polyol ester, the water soluble acrylic acid mill base of 10% ratio, the profit of 2% ratio of 25% ratio are sequentially added toward container
The organic silicon defoamer of humectant and 0.25% ratio, is uniformly mixed with dispersion machine, and dispersing speed is set to 800r/min,
The lead naphthenate of 1.5% ratio and the organic silicon defoamer of 0.25% ratio are added after dispersed 2 hours, finally filtering can obtain one
Plant the plant oil-based ink of addition lead naphthenate.
Embodiment three：
Take a container, water, the soybean grease of 40% ratio, the monoethanolamine of 15% ratio and 0.25% ratio for loading 6% ratio have
Machine silicon defoaming agent, is uniformly mixed with dispersion machine, and dispersing speed is set to 550 r/min, after disperseing 1.5 hours, then is added
Enter the organic silicon defoamer of 0.25% ratio, mixture is filtered, the emulsion that collection is filtered is put into container again, toward container
In sequentially add the Rosin Maleic polyol ester of 20% ratio, the water soluble acrylic acid mill base of 15% ratio, the wetting agent of 1% ratio and
The organic silicon defoamer of 0.25% ratio, is uniformly mixed with dispersion machine, and dispersing speed is set to 700r/min, uniform point
The lead naphthenate of 2% ratio and the organic silicon defoamer of 0.25% ratio are added after dissipating 3 hours, finally filtering can obtain a kind of addition naphthalene
The plant oil-based ink of lead plumbate.
Claims (4)
1. it is a kind of add lead naphthenate ink preparation method, it is characterised in that the preparation method comprises the following steps：
(1) first a certain proportion of vegetable oil esters, water, monoethanolamine and organic silicon defoamer are fitted into a container, are stirred with dispersion machine
It is well mixed；
(2) after being uniformly dispersed, appropriate organic silicon defoamer is added, mixture is filtered；
(3) the emulsion of filtering is collected, then puts into container again；
(4) and then toward sequentially adding Rosin Maleic polyol ester, water soluble acrylic acid mill base, wetting agent and organosilicon froth breaking in container
Agent, is uniformly mixed with dispersion machine；
(5) filtered after being eventually adding appropriate lead naphthenate and organic silicon defoamer, you can obtain a kind of plant oil base for adding lead naphthenate
Ink.
2. it is according to claim 1 it is a kind of add lead naphthenate ink preparation method, it is characterised in that in step (1)
In, vegetable oil esters are soybean grease.
3. it is according to claim 1 it is a kind of add lead naphthenate ink preparation method, it is characterised in that in step (1)
In, dispersing speed is set to 500-600 r/min, and jitter time is 1-2 hours.
4. it is according to claim 1 it is a kind of add lead naphthenate ink preparation method, it is characterised in that in step (4)
In, dispersing speed is set to 600-800r/min, and jitter time is 2-4 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611084441.XA CN106752309A (en) | 2016-11-30 | 2016-11-30 | A kind of ink and preparation method for adding lead naphthenate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611084441.XA CN106752309A (en) | 2016-11-30 | 2016-11-30 | A kind of ink and preparation method for adding lead naphthenate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106752309A true CN106752309A (en) | 2017-05-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611084441.XA Pending CN106752309A (en) | 2016-11-30 | 2016-11-30 | A kind of ink and preparation method for adding lead naphthenate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106752309A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122816A (en) * | 1994-11-11 | 1996-05-22 | 黄炳云 | Magnetic anti-counterfeit ink |
| CN104559451A (en) * | 2014-12-31 | 2015-04-29 | 李放芬 | Novel environmental friendly printing ink and preparation method thereof |
-
2016
- 2016-11-30 CN CN201611084441.XA patent/CN106752309A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122816A (en) * | 1994-11-11 | 1996-05-22 | 黄炳云 | Magnetic anti-counterfeit ink |
| CN104559451A (en) * | 2014-12-31 | 2015-04-29 | 李放芬 | Novel environmental friendly printing ink and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |
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| WD01 | Invention patent application deemed withdrawn after publication |